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CN105529476A - A process for shortening the activation time of thermal batteries - Google Patents

A process for shortening the activation time of thermal batteries Download PDF

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Publication number
CN105529476A
CN105529476A CN201510886687.8A CN201510886687A CN105529476A CN 105529476 A CN105529476 A CN 105529476A CN 201510886687 A CN201510886687 A CN 201510886687A CN 105529476 A CN105529476 A CN 105529476A
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China
Prior art keywords
activation time
battery
ignition
shortening
activation
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CN201510886687.8A
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Inventor
袁光明
汤胜
高文秀
于金玉
郑侠
强杉杉
越云博
刘波
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Shanghai Academy of Spaceflight Technology SAST
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Shanghai Academy of Spaceflight Technology SAST
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Priority to CN201510886687.8A priority Critical patent/CN105529476A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/30Deferred-action cells
    • H01M6/36Deferred-action cells containing electrolyte and made operational by physical means, e.g. thermal cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/42Grouping of primary cells into batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/50Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Primary Cells (AREA)

Abstract

The invention discloses a technique for shortening activation time of thermal batteries. An ignition strip on the periphery of a galvanic pile is turned upwards to the lower part of a mesopore asbestos pad; the ignition strip is directly burnt after an electric igniter is detonated; and heating substances in each single battery are ignited through the ignition strip from top to bottom, so that the thermal batteries are activated. According to the technique, traditional activation processes of detonating the electric igniter, igniting a heating plate, burning the ignition strip and finally igniting each single battery from top to bottom are changed into the processes of directly burning the ignition strip after detonating the electric igniter and then igniting each single battery from top to bottom, so that the activation time can be shortened by about 0.1-0.2 second; and the technique is simple in process, does not generate a redundant substance, and is of great significance in improvement of the activation time.

Description

一种缩短热电池激活时间的工艺方法A process for shortening the activation time of thermal batteries

技术领域 technical field

本发明属于热电池技术领域,具体涉及一种缩短热电池激活时间的工艺方法。 The invention belongs to the technical field of thermal batteries, and in particular relates to a process for shortening the activation time of thermal batteries.

背景技术 Background technique

热电池是用电池本身的加热系统把不导电的固体状态盐类电解质加热熔融呈离子型导体而进入工作状态的一种热激活储备电池。热电池内部电解质由两种或两种以上的无机盐组成的低共熔体,常温时,电解质是不导电固体;使用时,用外界电流引燃电池内部电点火头,从而点燃电池内部的加热材料,使电池内部温度迅速上升,导致熔融盐电解质融化并导电,激活电池,输出电能。使用固体盐类电解质是热电池的主要特征,它明显区别于使用水溶液电解质、有机电解质和固体电解质的电池。这使得热电池具有贮存时间长、输出电流密度大、比能量较高、使用温度范围广、在贮存期间无需维护和保养等特点,因而在各种导弹、鱼雷及核武器的工作电源中得到广泛地应用。 The thermal battery is a kind of thermally activated reserve battery that uses the heating system of the battery itself to heat and melt the non-conductive solid-state salt electrolyte into an ionic conductor and enter the working state. The internal electrolyte of the thermal battery is a eutectic melt composed of two or more inorganic salts. At room temperature, the electrolyte is a non-conductive solid; when in use, the electric ignition head inside the battery is ignited by an external current, thereby igniting the heating inside the battery. material, the internal temperature of the battery rises rapidly, causing the molten salt electrolyte to melt and conduct electricity, activate the battery, and output electricity. The use of solid salt electrolytes is the main feature of thermal batteries, which are clearly distinguished from batteries using aqueous electrolytes, organic electrolytes, and solid electrolytes. This makes the thermal battery have the characteristics of long storage time, high output current density, high specific energy, wide temperature range, and no need for maintenance and maintenance during storage, so it is widely used in the working power supply of various missiles, torpedoes and nuclear weapons. application.

热电池的激活时间指从给出激活信号到热电池输出所需的最低电压所经历的时间,现代武器系统均要求快速响应、机动性好的特点,对电池的激活时间提出较高要求。热电池的激活一般经历:给出激活信号(电流)、引爆电点火头、引燃加热片、燃烧引燃条、引燃每个单体电池中的加热物质等步骤,当电堆中部温度达到电解质的熔点以上时,电解质熔融形成离子导体,即可激活电池输出电能。电池的激活时间同激活前的环境温度、激活时的负载电流、引燃条的燃速、加热片的燃速、单体电池直径、热值设计等有关,但这些条件一般同热电池的使用要求和设计方案有关,不能随便更改,因此要想进一步缩短电池的激活时间必须采取其它的设计措施。 The activation time of the thermal battery refers to the time elapsed from the activation signal being given to the minimum voltage required for the output of the thermal battery. Modern weapon systems require fast response and good mobility, and put forward higher requirements for the activation time of the battery. The general process of thermal battery activation: giving the activation signal (current), detonating the electric ignition head, igniting the heating sheet, burning the ignition strip, and igniting the heating material in each single battery, etc. When the temperature in the middle of the stack reaches When the melting point of the electrolyte is above, the electrolyte melts to form an ion conductor, which activates the battery to output electric energy. The activation time of the battery is related to the ambient temperature before activation, the load current during activation, the burning rate of the ignition strip, the burning rate of the heating plate, the diameter of the single battery, and the design of the calorific value, but these conditions are generally the same as the use of thermal batteries. The requirements are related to the design scheme and cannot be changed casually, so other design measures must be taken in order to further shorten the activation time of the battery.

发明内容 Contents of the invention

为了解决上述问题,本发明提供一种缩短热电池激活时间的工艺方法,所述热电池为多个单体电池串、并联组成的电堆,所述热电池包括电点火头、引燃条、加热物质,该方法包括以下步骤: In order to solve the above problems, the present invention provides a process for shortening the activation time of a thermal battery. The thermal battery is a stack composed of a plurality of single cells connected in series and in parallel. The thermal battery includes an electric ignition head, an ignition strip, heating a substance, the method comprising the steps of:

(1)引爆所述电点火头,所述电点火头引爆后直接燃烧所述引燃条; (1) detonate the electric ignition head, and directly burn the ignition strip after the electric ignition head is detonated;

(2)所述引燃条自上而下引燃每个单体电池中的加热物质; (2) The ignition strip ignites the heating substance in each single battery from top to bottom;

(3)所述各单体电池中的加热物质燃烧进而激活整个热电池。 (3) The heating material in each single battery burns to activate the whole thermal battery.

较佳地,所述步骤(1)中引爆电点火头采用的是电激活的方式。 Preferably, the detonation of the electric ignition head in the step (1) adopts an electric activation method.

较佳地,所述步骤(2)中所述引燃条在电堆周边上翻至点火头引爆后能燃烧的位置。 Preferably, the ignition strip in the step (2) is turned over on the periphery of the electric stack to a position where it can burn after the ignition head is detonated.

与现有技术相比,本发明涉及一种缩短热电池激活时间的工艺方法,将电堆周边的引燃条上翻至中孔石棉垫下部,将引爆电点火头、引燃加热片再燃烧引燃条、最后引燃电堆中的每个单体电池的激活流程,改变为引爆电点火头后直接燃烧引燃条、再引燃电堆中的每个单体电池,这样可以提高激活时间约0.1s~0.2s,该改进方法工艺简单,不会产生多余物,对提高激活时间具有重要意义。 Compared with the prior art, the present invention relates to a process for shortening the activation time of the thermal battery. The ignition strip around the electric stack is turned up to the lower part of the mesopore asbestos pad, and the electric ignition head and the ignition heating sheet are reburned. The ignition strip and the activation process of each single cell in the stack are changed to directly burn the ignition strip after detonating the electric ignition head, and then ignite each single cell in the stack, which can improve the activation The time is about 0.1s~0.2s. This improved method is simple in process and does not produce redundant products, which is of great significance for improving the activation time.

附图说明 Description of drawings

图1为本发明的一种缩短热电池激活时间的工艺方法流程图; Fig. 1 is a kind of technological process flowchart of shortening thermal battery activation time of the present invention;

图2(a)为传统结构的激活图; Figure 2(a) is the activation map of the traditional structure;

图2(b)为采用本发明后的激活图。 Fig. 2(b) is the activation map after adopting the present invention.

具体实施方式 detailed description

本发明实施例提供的单元电池直径68mm,总高度95mm,工作负载16A,低温工作温度-45℃,要求激活时间不大于0.8s;由于电池的激活时间要求高,工作电流密度较大,低温工作温度较低,为了保证电池的激活时间满足要求,需按本发明方法进行电堆中引燃条的分布设计;如图1、图2(a)和图2(b)所述,本发明提供一种缩短热电池激活时间的方法,该热电池为多个单体电池串、并联组成的电堆,所述热电池包括电点火头1、引燃条2、加热物质3,该方法包括以下步骤: The unit battery provided by the embodiment of the present invention has a diameter of 68mm, a total height of 95mm, a working load of 16A, and a low temperature working temperature of -45°C. The temperature is low, in order to ensure that the activation time of the battery meets the requirements, it is necessary to design the distribution of the ignition bars in the stack according to the method of the present invention; as shown in Figure 1, Figure 2(a) and Figure 2(b), the present invention provides A method for shortening the activation time of a thermal battery, the thermal battery is a stack composed of a plurality of single cells connected in series and in parallel, the thermal battery includes an electric ignition head 1, an ignition strip 2, and a heating substance 3, the method includes the following steps step:

(1)采用电激活的方式引爆电点火头1,电点火头1引爆后直接燃烧引燃条2; (1) The electric ignition head 1 is detonated by means of electric activation, and the ignition strip 2 is directly burned after the electric ignition head 1 is detonated;

(2)引燃条2自上而下引燃每个单体电池中的加热物质3; (2) The ignition strip 2 ignites the heating substance 3 in each single battery from top to bottom;

(3)各单体电池中的加热物质3燃烧进而激活整个热电池。 (3) The heating substance 3 in each single battery burns to activate the whole thermal battery.

试验结果显示,按照该发明生产的电池在低温满载条件下工作,激活时间不大于0.7s,不采取该发明方法制作的电池按相同的条件放电,其激活时间0.95s。 The test results show that the battery produced according to the invention works under the condition of low temperature and full load, and the activation time is not more than 0.7s. The battery produced without the method of the invention is discharged under the same conditions, and the activation time is 0.95s.

本发明涉及一种缩短热电池激活时间的工艺方法,即将传统的引爆电点火头、引燃加热片再燃烧引燃条的激活流程,改变为引爆电点火头后直接燃烧引燃条,这样可以提高激活时间约0.1s~0.2s,该改进方法工艺简单,不会产生多余物,对提高激活时间具有重要意义。 The invention relates to a process for shortening the activation time of a thermal battery, that is, the traditional activation process of detonating an electric ignition head, igniting a heating sheet, and then burning an ignition strip is changed to directly burning an ignition strip after detonating an electric ignition head, so that The activation time is increased by about 0.1 s to 0.2 s. This improved method is simple in process and does not produce redundant substances, which is of great significance for increasing the activation time.

以上公开的本发明优选实施例只是用于帮助阐述本发明。优选实施例并没有详尽叙述所有的细节,也不限制该发明仅为所述的具体实施方式。显然,根据本说明书的内容,可作很多的修改和变化。本说明书选取并具体描述这些实施例,是为了更好地解释本发明的原理和实际应用,从而使所属技术领域技术人员能很好地理解和利用本发明。本发明仅受权利要求书及其全部范围和等效物的限制。 The preferred embodiments of the invention disclosed above are only to help illustrate the invention. The preferred embodiments are not exhaustive in all detail, nor are the inventions limited to specific embodiments described. Obviously, many modifications and variations can be made based on the contents of this specification. This description selects and specifically describes these embodiments in order to better explain the principle and practical application of the present invention, so that those skilled in the art can well understand and utilize the present invention. The invention is to be limited only by the claims, along with their full scope and equivalents.

Claims (3)

1.一种缩短热电池激活时间的工艺方法,所述热电池为多个单体电池串、并联组成的电堆,所述热电池包括电点火头、引燃条、电堆、加热物质,其特征在于,该工艺方法包括以下步骤: 1. A process for shortening the activation time of a thermal battery, wherein the thermal battery is a stack composed of a plurality of single cells connected in series and in parallel, and the thermal battery comprises an electric ignition head, an ignition strip, a stack, and a heating substance, It is characterized in that the process method comprises the following steps: (1)引爆所述电点火头,所述电点火头引爆后直接燃烧所述引燃条; (1) detonate the electric ignition head, and directly burn the ignition strip after the electric ignition head is detonated; (2)所述引燃条自上而下引燃每个单体电池中的加热物质; (2) The ignition strip ignites the heating substance in each single battery from top to bottom; (3)所述各单体电池中的加热物质燃烧进而激活整个热电池。 (3) The heating material in each single battery burns to activate the whole thermal battery. 2.如权利要求1所述的缩短热电池激活时间的工艺方法,其特征在于,所述步骤(1)中引爆电点火头采用的是电激活的方式。 2 . The process for shortening the activation time of the thermal battery according to claim 1 , wherein the method of detonating the electric ignition head in the step (1) is electric activation. 3 . 3.如权利要求1所述的缩短热电池激活时间的工艺方法,其特征在于,所述步骤(2)中引燃条上翻并延长至电点火头引爆后能直接燃烧的位置。 3. The process for shortening the activation time of the thermal battery according to claim 1, characterized in that in the step (2), the ignition strip is turned up and extended to a position where it can be directly burned after the electric ignition head is detonated.
CN201510886687.8A 2015-12-07 2015-12-07 A process for shortening the activation time of thermal batteries Pending CN105529476A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106684402A (en) * 2017-01-18 2017-05-17 沈阳理工大学 Microminiature activating device for thermal batteries
CN106876737A (en) * 2017-03-01 2017-06-20 北方特种能源集团有限公司西安庆华公司 A kind of side insulation construction of fitted outside thermal cell
CN110783587A (en) * 2019-10-25 2020-02-11 上海空间电源研究所 A device and a thermal battery system for improving the reliability of a thermal battery activation circuit
CN113322115A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 Thermal battery composite ignition paper and preparation method thereof

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CN202373657U (en) * 2011-12-19 2012-08-08 梅岭化工厂 Internal ignition channel for thermal battery
CN202487704U (en) * 2012-03-26 2012-10-10 中国电子科技集团公司第十八研究所 A highly reliable battery for power supply and heating

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106684402A (en) * 2017-01-18 2017-05-17 沈阳理工大学 Microminiature activating device for thermal batteries
CN106684402B (en) * 2017-01-18 2023-06-06 沈阳理工大学 Micro thermal battery activation device
CN106876737A (en) * 2017-03-01 2017-06-20 北方特种能源集团有限公司西安庆华公司 A kind of side insulation construction of fitted outside thermal cell
CN110783587A (en) * 2019-10-25 2020-02-11 上海空间电源研究所 A device and a thermal battery system for improving the reliability of a thermal battery activation circuit
CN113322115A (en) * 2021-05-27 2021-08-31 贵州梅岭电源有限公司 Thermal battery composite ignition paper and preparation method thereof

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Application publication date: 20160427