CN105519587A - Liquid mosquito repellent incense containing tea tree essential oil and preparation method of liquid mosquito repellent incense - Google Patents
Liquid mosquito repellent incense containing tea tree essential oil and preparation method of liquid mosquito repellent incense Download PDFInfo
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- CN105519587A CN105519587A CN201610058591.7A CN201610058591A CN105519587A CN 105519587 A CN105519587 A CN 105519587A CN 201610058591 A CN201610058591 A CN 201610058591A CN 105519587 A CN105519587 A CN 105519587A
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- Prior art keywords
- tea tree
- repellent incense
- mosquito repellent
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- ethereal oil
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- 239000007788 liquid Substances 0.000 title claims abstract description 49
- 235000009024 Ceanothus sanguineus Nutrition 0.000 title claims abstract description 39
- 240000003553 Leptospermum scoparium Species 0.000 title claims abstract description 39
- 235000015459 Lycium barbarum Nutrition 0.000 title claims abstract description 39
- 239000000341 volatile oil Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000000077 insect repellent Substances 0.000 title abstract description 25
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 15
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 15
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 claims abstract description 9
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 claims abstract description 8
- 229940024113 allethrin Drugs 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 241000255925 Diptera Species 0.000 claims description 51
- 239000006200 vaporizer Substances 0.000 claims description 29
- PXOYOCNNSUAQNS-AGNJHWRGSA-N alantolactone Chemical group C1[C@H]2OC(=O)C(=C)[C@H]2C=C2[C@@H](C)CCC[C@@]21C PXOYOCNNSUAQNS-AGNJHWRGSA-N 0.000 claims description 19
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 claims description 10
- BGEBZHIAGXMEMV-UHFFFAOYSA-N 5-methoxypsoralen Chemical compound O1C(=O)C=CC2=C1C=C1OC=CC1=C2OC BGEBZHIAGXMEMV-UHFFFAOYSA-N 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
- PXOYOCNNSUAQNS-UHFFFAOYSA-N alantolactone Natural products C1C2OC(=O)C(=C)C2C=C2C(C)CCCC21C PXOYOCNNSUAQNS-UHFFFAOYSA-N 0.000 claims description 9
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- -1 synergist Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 10
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 14
- 239000000779 smoke Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 230000002147 killing effect Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 208000035473 Communicable disease Diseases 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 3
- 239000002728 pyrethroid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 241000700159 Rattus Species 0.000 description 2
- 208000000705 Rift Valley Fever Diseases 0.000 description 2
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical group CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
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- 230000000749 insecticidal effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
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- 229940070846 pyrethrins Drugs 0.000 description 2
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- 238000012546 transfer Methods 0.000 description 2
- ZCVAOQKBXKSDMS-PVAVHDDUSA-N (+)-trans-(S)-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-PVAVHDDUSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 208000001490 Dengue Diseases 0.000 description 1
- 206010012310 Dengue fever Diseases 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 206010014596 Encephalitis Japanese B Diseases 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 201000005807 Japanese encephalitis Diseases 0.000 description 1
- 241000710842 Japanese encephalitis virus Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 206010041896 St. Louis Encephalitis Diseases 0.000 description 1
- 201000006449 West Nile encephalitis Diseases 0.000 description 1
- 206010057293 West Nile viral infection Diseases 0.000 description 1
- 208000003152 Yellow Fever Diseases 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 231100000921 acute inhalation toxicity Toxicity 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- ZCVAOQKBXKSDMS-UHFFFAOYSA-N allethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-UHFFFAOYSA-N 0.000 description 1
- 229960001901 bioallethrin Drugs 0.000 description 1
- 238000009534 blood test Methods 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 208000025729 dengue disease Diseases 0.000 description 1
- 239000007933 dermal patch Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 231100000321 erythema Toxicity 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 230000007688 immunotoxicity Effects 0.000 description 1
- 231100000386 immunotoxicity Toxicity 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 230000001537 neural effect Effects 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
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- 238000009423 ventilation Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses liquid mosquito repellent incense containing tea tree essential oil and a preparation method of the liquid mosquito repellent incense. The liquid mosquito repellent incense containing the tea tree essential oil comprises raw materials in parts by weight as follows: 0.5-2.5 parts of allethrin, 0.1-0.5 parts of the tea tree essential oil, 50-60 parts of triethylene glycol momobutyl ether, 0.05-0.15 parts of sodium 4-propan-2-ylbenzenesulfonate, 0.1-0.5 parts of a synergist, 0.1-0.5 parts of an antioxidant and 35-45 parts of water. The liquid mosquito repellent incense containing the tea tree essential oil has fresh and fragrant smell and a higher mosquito repellent effect, is environment-friendly, has the advantages of powerful efficacy, safety, non-combustible property and volatilization stability, can reduce content of indoor organic volatile impurities and is an ideal choice of healthy home life.
Description
Technical field:
The present invention relates to a kind of mosquito-repellent incense, be specifically related to a kind of tea tree ethereal oil vaporizer mosquito liquid and preparation method thereof.
Background technology:
Mosquito is a kind of worldwide sanitary insect pest, its all one's life through ovum, larva, pupa, four periods of adult.Mosquito is importantly that it is one of communication media of infectious disease.According to the study, the disease of mosquitoes spread reaches more than kind more than 80.In the whole world, 1,200,000 people are about had to infect filariosis.The disease of the mosquito meeting infectious disease toxicity of major part kind, comprises yellow fever, dengue fever, Japanese encephalitis, St. Louis encephalitis, polyarthirtis, Rift Valley fever (RiftValleyfever), contract elder brother Gen Yare and West Nile fever.On earth, then do not have which kind of animal to have larger harm than mosquito to the mankind.Mosquito serious threat human health, only drives these disgusting mosquitoes, could control epidemic infectious diseases, could ensure human health as can be seen here, improves the quality of life of people.
For many years, people develop and employ a large amount of hygienic insecticide products, are used for killing mosquitoes.Mosquito-repellent incense is the most ancient natural drug mosquito repellent way.Just the culicifuge incense rod that Chinese medicine is made is there is period as far back as the Southern Song Dynasty.Containing active ingredient in modern mosquito-repellent incense is pyrethrins, and it has the effect of mosquito.After burning mosquito incense, pyrethrins in mosquito-repellent incense evaporates along with smog, send out in the air of indoor, make the neural paralysis of mosquito, so mosquito or bornly to get killed, or four loosely run away, thus the effect playing mosquito killer current mosquito-repellent incense production industry insecticidal active ingredient, the mainly pyrethrin such as cypermethrin, Prallethrin, allethrin, Esbiothrin, the nerve can benumbing mosquito causes that it is dead.
Electric liquid device is actually the general name of mosquito liquid and electronic thermostatic heater that liquid is evenly volatilized, and the former claims mosquito expelling liquid, and the latter claims electric heater.In electric liquid device work, when after electric heater access power supply, PTCR element just starts the heating that heats up, and relies on the temp regulating function of PTCR element self afterwards, makes its temperature remain certain value.PTCR element produce heat by radiant heat transfer to liquid volatilize core, by volatilization core capillarity, liquid is drawn to plug upper end from medicinal liquid bottle, liquid is improved under thermal radiation heating and is vaporized speed, after the insecticidal active ingredient in space reaches finite concentration, just mosquito is produced and drive, thus knock down and kill mosquito.Electric liquid device because of its use light, smokeless without features such as dust, efficacy stability, high-efficiency low-toxicities, be subject to the welcome of consumer.
Existing electric liquid device formula system for component, by mixing, stirs solvent formation homogeneous system with alkane solvent, pyrethroid, antioxidant and essence etc.Alkane solvent is owing to being the formation such as rectifying, its carbochain is distributed more widely, especially wherein low-carbon paraffin easily forms organic volatile and VOC, in the daily life staying idle at home of consumer, can be used by the heating of electric liquid device and naturally volatilize and cause the pollution of domestic environment, bring certain influence to consumer health.
The invention provides a kind of tea tree ethereal oil vaporizer mosquito liquid, is a kind of vaporizer mosquito liquid of safety and environmental protection.
Summary of the invention:
For prior art above shortcomings, one of technical problem to be solved by this invention is to provide a kind of tea tree ethereal oil vaporizer mosquito liquid.
One of technical problem to be solved by this invention is to provide the preparation method of above-mentioned tea tree ethereal oil vaporizer mosquito liquid.
Technical problem of the present invention, is achieved by following technical proposals:
A kind of tea tree ethereal oil vaporizer mosquito liquid, is made up of the raw material of following weight parts: 0.5-2.5 part allethrin, 0.1-0.5 part tea tree ethereal oil, 50-60 part triethylene glycol butyl ether, 0.05-0.15 part 4-cumene sodium sulfonate, 0.1-0.5 part synergist, 0.1-0.5 part antioxidant, 35-45 part water.
Preferably, described synergist is alantolactone and/or majudin.
More preferably, described synergist is made up of 40-60wt% alantolactone and 40-60wt% majudin.
Preferably, described antioxidant is 2,6-di-tert-butyl-4-methy phenol and/or 2,6-di-tert-butyl hydroquinone.
More preferably, described antioxidant is made up of 40-60wt%2,6-di-tert-butyl-4-methy phenol and 40-60wt%2,6-di-tert-butyl hydroquinone.
Present invention also offers the preparation method of above-mentioned tea tree ethereal oil vaporizer mosquito liquid, allethrin, tea tree ethereal oil, triethylene glycol butyl ether, synergist, antioxidant are mixed, then add 4-cumene sodium sulfonate and mix, finally add water and mix.
Concrete, in the present invention:
Allethrin, No. CAS: 584-79-2.
Tea tree ethereal oil, No. CAS: 68647-73-4.
Triethylene glycol butyl ether, No. CAS: 143-22-6.
4-cumene sodium sulfonate, No. CAS: 32073-22-6.
Alantolactone, No. CAS: 546-43-0.
Majudin, No. CAS: 484-20-8.
2,6-di-tert-butyl-4-methy phenol, No. CAS: 128-37-0.
2,6-di-tert-butyl hydroquinone, No. CAS: 2444-28-2.
Tea tree ethereal oil vaporizer mosquito liquid of the present invention, the pure and fresh fragrance of taste, has mosquito and stronger kills effect, it is a kind of environment-friendly liquid mosquito-repellent incense, it has, and drug effect is powerful, safety is non-combustible, volatilization is stable, and can also reduce indoor organic volatile matter content, be the ideal chose of healthy life staying idle at home.
Embodiment:
Below in conjunction with embodiment, the present invention is described further, the following stated, only to preferred embodiment of the present invention, not do other forms of restriction to the present invention, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed to the Equivalent embodiments of equal change.Everyly do not depart from the present invention program's content, any simple modification done following examples according to technical spirit of the present invention or equivalent variations, all drop in protection scope of the present invention.
Embodiment 1
Tea tree ethereal oil vaporizer mosquito liquid raw material (weight portion): 1.2 parts of allethrins, 0.2 part of tea tree ethereal oil, 55 parts of triethylene glycol butyl ether, 0.1 part of 4-cumene sodium sulfonate, 0.3 part of synergist, 0.3 part of antioxidant, 40 parts of deionized waters.
Described synergist is mixed by 50wt% alantolactone and 50wt% majudin and obtains.
Described antioxidant is mixed by 50wt%2,6-di-tert-butyl-4-methy phenol and 50wt%2,6-di-tert-butyl hydroquinone and obtains.
The preparation method of tea tree ethereal oil vaporizer mosquito liquid:
Allethrin, tea tree ethereal oil, triethylene glycol butyl ether, synergist, antioxidant are mixed and stirs, then adds 4-cumene sodium sulfonate and mix and stir, finally add deionized water and mix and stir.Obtain the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, difference is only: described synergist is only alantolactone.Obtain the tea tree ethereal oil vaporizer mosquito liquid of embodiment 2.
Embodiment 3
Substantially the same manner as Example 1, difference is only: described synergist is only majudin.Obtain the tea tree ethereal oil vaporizer mosquito liquid of embodiment 3.
Embodiment 4
Substantially the same manner as Example 1, difference is only: described antioxidant is only 2,6-di-tert-butyl-4-methy phenol.Obtain the tea tree ethereal oil vaporizer mosquito liquid of embodiment 4.
Embodiment 5
Substantially the same manner as Example 1, difference is only: described antioxidant is only 2,6-di-tert-butyl hydroquinone.Obtain the tea tree ethereal oil vaporizer mosquito liquid of embodiment 5.
Test case 1
Indoor harmacological effect test is carried out to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, adopts GB18418-2009 domestic sanitary desinsection articles for use electric liquid device standard, test.In the standard, it is qualified that KT50 value (boxing method)≤10 minute can be judged to, and the time, shorter explanation was better to mosquito driving and killing effect, and test data is in table 1.
Table 1: vaporizer mosquito liquid indoor harmacological effect table (boxing method)
| KT50 value | |
| Embodiment 1 | 3 points 43 seconds |
| Embodiment 2 | 5 points 57 seconds |
| Embodiment 3 | 6 points 20 seconds |
| Embodiment 4 | 5 points 02 second |
| Embodiment 5 | 5 points 36 seconds |
Comparing embodiment 1-3, embodiment 1 (alantolactone, majudin are composite) mosquito driving and killing effect, is obviously better than embodiment 2-3 (in alantolactone, majudin single raw material); Comparing embodiment 1 and embodiment 4-5, embodiment 1 (2,6-di-tert-butyl-4-methy phenol, 2,6-di-tert-butyl hydroquinone is composite) mosquito driving and killing effect, obviously be better than embodiment 4-5 (2, single raw material in 6-di-tert-butyl-4-methy phenol, 2,6-di-tert-butyl hydroquinones).
Test case 2
Toxotest is carried out to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, with reference to health ministry " management of occupational acute chemicals Poisoning disease in the blood system diagnostic criteria " and " technological guidance's principle of Chinese medicine, natural drug immunotoxicity research " standard, formulate test case of the present invention.
Experiment kind: two young age small white mouse.
Experimental technique:
(1) experiment condition: laboratory temperature (27 ± 2) DEG C
(2) experimental provision: in the laboratory of two 25 square metres of identical temperature, each 80 × 80 × 80cm placing a size same size is fine and closely woven ventilative nettedly to be shrouded.
(3) experimental procedure: by two young ages, small white mouse was separately respectively put in two laboratories netted shroud in, and be divided into control group and smoke mosquito-repellent incense group of the present invention, give respectively do not smoke mosquito-repellent incense of the present invention and smoke mosquito-repellent incense of the present invention, measure children's small white mouse body weight in age, the biochemical index of observation hematology, changes in histopathology and stopping smoke the recovery situation etc. after mosquito-repellent incense of the present invention.Place mosquito-repellent incense of the present invention time to be arranged on netted shroud interior from the end 30 centimeters.Dosage: electrical heating mosquito-repellent incense, keeps 24 hours Long-Time Service.Time: continuously use one month, observe control group and smoke the small white mouse in young age of mosquito-repellent incense group of the present invention, Long-Time Service mosquito-repellent incense of the present invention is to the toxicity of children small white mouse in age and side effect.Clean: to shroud and clean once for interior two days.
Result: after two young age small white mouse blood tests, every biochemical indicator is normally, shows that mosquito-repellent incense of the present invention has no side effect, when only indoor mosquito-repellent incense smog was too dense more than 24 hours to children small white mouse in age, need be windowed ventilation 10-15 minute, draws blood first 8 hours not to two children small white mouse in age feeds.
Conclusion: Long-Time Service mosquito-repellent incense of the present invention to children age small white mouse without any toxicity.
Test case 3
Carry out acute oral toxicity test to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, latter 5 minutes activities in rats of contaminating increase, and continue about 2 minutes, activity transfers to normally, and diet is normal, and the observation period, LD50 was greater than 5000 mgs/kg without death, belong to actual nontoxic.
Test case 4
Carry out acute inhalation toxicity test to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, rat diet activity no abnormality seen after contamination, the observation period, LD50 was greater than 10 grams/cubic metre without death, belonged to actual nontoxic.
Test case 5
Carry out skin patch test to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, it is 0 that experimental group erythema and oedema form sum of marking, and illustrates and has no stimulation to skin.
Test case 6
Carry out eye irritant test to the tea tree ethereal oil vaporizer mosquito liquid of embodiment 1-5, experimental group acute ocular stimulates integration number to be 0, illustrates and has no stimulation to mucous membrane.
Claims (6)
1. a tea tree ethereal oil vaporizer mosquito liquid, it is characterized in that, be made up of the raw material of following weight parts: 0.5-2.5 part allethrin, 0.1-0.5 part tea tree ethereal oil, 50-60 part triethylene glycol butyl ether, 0.05-0.15 part 4-cumene sodium sulfonate, 0.1-0.5 part synergist, 0.1-0.5 part antioxidant, 35-45 part water.
2. tea tree ethereal oil vaporizer mosquito liquid as claimed in claim 1, is characterized in that: described synergist is alantolactone and/or majudin.
3. tea tree ethereal oil vaporizer mosquito liquid as claimed in claim 2, is characterized in that: described synergist is made up of 40-60wt% alantolactone and 40-60wt% majudin.
4. the tea tree ethereal oil vaporizer mosquito liquid according to any one of claim 1-3, is characterized in that: described antioxidant is 2,6-di-tert-butyl-4-methy phenol and/or 2,6-di-tert-butyl hydroquinone.
5. tea tree ethereal oil vaporizer mosquito liquid as claimed in claim 4, is characterized in that: described antioxidant is made up of 40-60wt%2,6-di-tert-butyl-4-methy phenol and 40-60wt%2,6-di-tert-butyl hydroquinone.
6. the preparation method of tea tree ethereal oil vaporizer mosquito liquid according to any one of claim 1-5, it is characterized in that: allethrin, tea tree ethereal oil, triethylene glycol butyl ether, synergist, antioxidant are mixed, then add 4-cumene sodium sulfonate and mix, finally add water and mix.
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| CN109805033A (en) * | 2019-01-16 | 2019-05-28 | 佛山市南海添惠日化有限公司 | A kind of tea tree ethereal oil mosquito liquid |
| CN110037020A (en) * | 2019-03-21 | 2019-07-23 | 佛山市南海添惠日化有限公司 | A kind of tea tree ethereal oil mosquito liquid |
| CN111869687A (en) * | 2020-07-21 | 2020-11-03 | 重庆金合蚊香制品有限公司 | Volatilizable fragrance-free mosquito-repellent incense essential oil |
| CN115669649A (en) * | 2022-11-02 | 2023-02-03 | 中山榄菊日化实业有限公司 | Mosquito-repellent incense tablet and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109805033A (en) * | 2019-01-16 | 2019-05-28 | 佛山市南海添惠日化有限公司 | A kind of tea tree ethereal oil mosquito liquid |
| CN110037020A (en) * | 2019-03-21 | 2019-07-23 | 佛山市南海添惠日化有限公司 | A kind of tea tree ethereal oil mosquito liquid |
| CN111869687A (en) * | 2020-07-21 | 2020-11-03 | 重庆金合蚊香制品有限公司 | Volatilizable fragrance-free mosquito-repellent incense essential oil |
| CN115669649A (en) * | 2022-11-02 | 2023-02-03 | 中山榄菊日化实业有限公司 | Mosquito-repellent incense tablet and preparation method thereof |
| CN115669649B (en) * | 2022-11-02 | 2024-06-11 | 中山榄菊日化实业有限公司 | Mosquito-repellent incense tablet and preparation method thereof |
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| CN105519587B (en) | 2018-06-19 |
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