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CN105505079A - Wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating - Google Patents

Wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating Download PDF

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Publication number
CN105505079A
CN105505079A CN201510829629.1A CN201510829629A CN105505079A CN 105505079 A CN105505079 A CN 105505079A CN 201510829629 A CN201510829629 A CN 201510829629A CN 105505079 A CN105505079 A CN 105505079A
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CN
China
Prior art keywords
polylactic acid
acrylic resin
wallpaper
emulsion
zeolite powder
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Pending
Application number
CN201510829629.1A
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Chinese (zh)
Inventor
李华令
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Anhui Suoya Decorative Materials Co Ltd
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Anhui Suoya Decorative Materials Co Ltd
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Priority to CN201510829629.1A priority Critical patent/CN105505079A/en
Publication of CN105505079A publication Critical patent/CN105505079A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating. A cellulose acetate-copolymerized modified waterborne acrylic resin emulsion is adopted as a resin adhesive in coating slurry used for the wallpaper, and is stable in performance and free of toxic compounds slow in volatilization such as formaldehyde. The formed coating is smooth and elastic and has antifouling and antibacterial functions and other functions. Added zeolite powder-polylactic acid porous fibers in the slurry are good in gas permeability, moisture penetrability and adsorbability, and can improve adsorbability with a substrate. Compared with traditional PVC paste, plasticizing temperature of the coating can be reduced to 120-150 DEG C, the service lifetime of the wallpaper is effectively prolonged, and strength and toughness of the wallpaper are better. The wallpaper has a certain indoor air cleaning function.

Description

A kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating
Technical field
The present invention relates to wallpaper technical field, particularly relate to a kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating.
Background technology
Wallpaper has another name called wallpaper, because of it, to have color various, pattern enriches, the advantage such as luxurious style, safety and environmental protection, easy construction, affordable is applied more and more extensive in house ornamentation, common wallpaper is greatly using the material such as pure paper, non-woven fabrics as base material, at its surface-coated resin slurry, make through operations such as high temperature plasticizing, printing embossing.
Modal coating paste is mainly made up of polyvinyl chloride resin and filler in the market, although this coated material has the advantages such as attractive and durable waterproof, but its poor air permeability, and containing organic solvent, long-time use can pollute room air, along with the raising of people's environmental consciousness, require also more and more higher to the feature of environmental protection of wallpaper, this needs to use new coated material to replace polyvinyl chloride resin undoubtedly.In recent years market emerges the water-base resin coated material of a collection of environmental protection, although this kind of material is not containing volatile organic solvent, but its ventilation property, plasticization temperature, additional functional and with the stickiness of base material etc. in still Shortcomings.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating.
The present invention is achieved by the following technical solutions:
A kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating, this wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, and described coating paste is made up of the raw material of following weight part: composite water soluble Emulsion acrylic resin 80-100, zeolite micro mist 4-5, polylactic acid slice 8-10, vinyl two stearic amide 0.1-0.2, sodium lignosulfonate 0.4-0.5, silane coupling agent kh5500.1-0.2.
Described coating paste preparation method is:
(1) zeolite powder-polylactic acid porous fiber preparation: first polylactic acid slice, zeolite micro mist, the two stearic amide of vinyl, silane coupling agent kh550 are carried out melt-spinning after being uniformly mixed, making length is 50-100 μm, and diameter is the porous staple fibre of 30-50 μm;
(2) zeolite powder-polylactic acid porous fiber is dropped in composite water soluble Emulsion acrylic resin, add other leftover materials after being uniformly mixed 30-50min, strong stirring mixing 4-5h, leave standstill after placing 30-40min subsequently and get final product.
Described composite water soluble Emulsion acrylic resin is made up of the raw material of following weight part: nano silicon 0.5-0.8, cellulose acetate 4-5, N, dinethylformamide 12-15, butyl acrylate 18-25, methyl methacrylate 15-20, vinylformic acid 10-15, ammonium persulphate 5-8, emulsifier op-10 2-3, sodium lauryl sulphate 1-3, ammoniacal liquor are appropriate, deionized water 50-60, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3-4h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) emulsifier op-10, sodium lauryl sulphate are dropped in reactor, add the deionized water of 10-15 weight part subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, vinylformic acid, be warming up to 70-75 DEG C, be uniformly mixed 2-3h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulphate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0-7.5, and be heated to 65-75 DEG C, then pre-emulsion prepared by this solution of 2/3 weight part and 1/4 weight part step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is that 45-60 drips/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of residual content again after leaving standstill 15-20min, after dropping terminates under 70-75 DEG C of condition constant temperature 50-60min, be heated to 75-80 DEG C subsequently, strong stirring mixing 1.5-2h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, subsequent filtration discharging and get final product.
The resin adhesive adopted in the coating paste that wallpaper of the present invention uses is cellulose acetate modification by copolymerization water-borne acrylic resin emulsion, stable performance, and not containing chronic volatility toxic compounds such as formaldehyde, the coating formed is smooth flexible, possess the functions such as anti-soil is antibacterial, the zeolite powder added in slurry-polylactic acid porous fiber possesses good breathable moisture permeability and adsorptivity, adsorptive power between enhancement and base material, this coating than traditional PVC paste material not only plasticization temperature can be low to moderate 120-150 DEG C, also effectively extend the work-ing life of wallpaper, intensity and toughness better, also certain cleaning action is had to the air of indoor.
Embodiment
This embodiment wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, and wherein coating paste is made up of the raw material of following weight part: composite water soluble Emulsion acrylic resin 80, zeolite micro mist 4, polylactic acid slice 8, vinyl two stearic amide 0.1, sodium lignosulfonate 0.4, silane coupling agent kh5500.1.
This coating paste preparation method is:
(1) zeolite powder polylactic acid porous fiber preparation: first polylactic acid slice, zeolite micro mist, the two stearic amide of vinyl, silane coupling agent kh550 are carried out melt-spinning after being uniformly mixed, making length is 50 μm, and diameter is the porous staple fibre of 30 μm;
(2) polylactic acid porous for zeolite powder fiber is dropped in composite water soluble Emulsion acrylic resin, add other leftover materials after being uniformly mixed 30min, strong stirring mixing 4h, leave standstill after placing 30min subsequently and get final product.
Wherein composite water soluble Emulsion acrylic resin is made up of the raw material of following weight part: nano silicon 0.5, cellulose acetate 4, N, dinethylformamide 12, butyl acrylate 18, methyl methacrylate 15, vinylformic acid 10, ammonium persulphate 5, polyoxyethylene nonylphenol ether 2, sodium lauryl sulphate 1, ammoniacal liquor are appropriate, deionized water 50, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) polyoxyethylene nonylphenol ether, sodium lauryl sulphate are dropped in reactor, add the deionized water of 10 weight parts subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, vinylformic acid, be warming up to 70 DEG C, be uniformly mixed 2h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulphate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0, and be heated to 65 DEG C, then pre-emulsion prepared by this solution of 2/3 weight part and 1/4 weight part step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is 45/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of residual content again after leaving standstill 15min, after dropping terminates under 70 DEG C of conditions constant temperature 50min, be heated to 75 DEG C subsequently, strong stirring mixing 1.5h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, subsequent filtration discharging and get final product.
Coating paste is coated in nonwoven fabric base paper surface, control glue spread is 15g/m 2, after its drying, plastify embossing under 135 DEG C of conditions, carry out performance test to product according to relevant criterion after cooling forming, test result is:
Formaldehyde clearance:
0h：35.4%；24h：65.8%；48h：85.8%；72h：92.5%；96h:95.5%；120h:96.5%。
Moisture regain: 0.45%; Gas permeability: 10.2L/(m 2s); Tensile strength: 3458N/m, bursting strength: 176.5KPa.
Antibacterial and mouldproof: can 96.0% be reached to streptococcus aureus bacteriostasis rate; Can 95.4% be reached to intestinal bacteria bacteriostasis rate; It is 0 grade to the antibacterial grade of aspergillus niger, chaetomium globosum, green sticky broom bacterium.
Wallpaper prepared by this embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing vinyl chloride monomer.

Claims (3)

1. the wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating, this wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, it is characterized in that, described coating paste is made up of the raw material of following weight part: composite water soluble Emulsion acrylic resin 80-100, zeolite micro mist 4-5, polylactic acid slice 8-10, vinyl two stearic amide 0.1-0.2, sodium lignosulfonate 0.4-0.5, silane coupling agent kh5500.1-0.2.
2. a kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating as claimed in claim 1, it is characterized in that, described coating paste preparation method is:
(1) zeolite powder-polylactic acid porous fiber preparation: first polylactic acid slice, zeolite micro mist, the two stearic amide of vinyl, silane coupling agent kh550 are carried out melt-spinning after being uniformly mixed, making length is 50-100 μm, and diameter is the porous staple fibre of 30-50 μm;
(2) zeolite powder-polylactic acid porous fiber is dropped in composite water soluble Emulsion acrylic resin, add other leftover materials after being uniformly mixed 30-50min, strong stirring mixing 4-5h, leave standstill after placing 30-40min subsequently and get final product.
3. a kind of wallpaper containing zeolite powder-polylactic acid porous fibre modification Emulsion acrylic resin coating as claimed in claim 1 or 2, it is characterized in that, described composite water soluble Emulsion acrylic resin is made up of the raw material of following weight part: nano silicon 0.5-0.8, cellulose acetate 4-5, N, dinethylformamide 12-15, butyl acrylate 18-25, methyl methacrylate 15-20, vinylformic acid 10-15, ammonium persulphate 5-8, emulsifier op-10 2-3, sodium lauryl sulphate 1-3, ammoniacal liquor are appropriate, deionized water 50-60, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3-4h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) emulsifier op-10, sodium lauryl sulphate are dropped in reactor, add the deionized water of 10-15 weight part subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, vinylformic acid, be warming up to 70-75 DEG C, be uniformly mixed 2-3h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulphate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0-7.5, and be heated to 65-75 DEG C, then pre-emulsion prepared by this solution of 2/3 weight part and 1/4 weight part step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is that 45-60 drips/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of residual content again after leaving standstill 15-20min, after dropping terminates under 70-75 DEG C of condition constant temperature 50-60min, be heated to 75-80 DEG C subsequently, strong stirring mixing 1.5-2h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, subsequent filtration discharging and get final product.
CN201510829629.1A 2015-11-25 2015-11-25 Wallpaper containing a zeolite powder-polylactic acid porous fiber modified acrylic resin emulsion coating Pending CN105505079A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105803793A (en) * 2016-04-21 2016-07-27 安徽皖翎羽绒制品有限公司 Water-borne polyurethane coating agent containing superfine down fiber-polylactic acid microspheres
CN105803794A (en) * 2016-04-21 2016-07-27 安徽皖翎羽绒制品有限公司 Water-borne polyurethane coating agent containing superfine down fiber grafted nano zeolite micropowder
CN106118298A (en) * 2016-07-14 2016-11-16 阜南县宏泰工艺品有限公司 A kind of wood artwork is with containing can the water paint and preparation method thereof of anthelmintic multiple cellulose acetate nanofiber
CN106118301A (en) * 2016-07-18 2016-11-16 阜南县大自然工艺品有限公司 A kind of wood artwork water paint containing super-hydrophobic multiple cellulose acetate nanofiber and preparation method thereof
CN106318074A (en) * 2016-08-25 2017-01-11 阜南县天亿工艺品有限公司 Water paint containing high-temperature-resisting porous composite cellulose acetate nanofibers for wooden artware and preparation method of water paint
CN106349840A (en) * 2016-08-25 2017-01-25 阜南县天亿工艺品有限公司 High-hardness-flame-retardant-composite-cellulose-acetate-nano-fiber-containing water-based paint for wooden crafts and preparation method thereof
CN117431007A (en) * 2023-12-08 2024-01-23 泉州市东宝科技集团有限公司 Stone-like paint and preparation method thereof

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CN101358382A (en) * 2008-08-26 2009-02-04 东华大学 A kind of antibacterial nanofiber material and preparation method thereof
CN102605679A (en) * 2012-03-15 2012-07-25 广东银洋树脂有限公司 Wallpaper
CN104452476A (en) * 2014-12-12 2015-03-25 广东玉兰装饰材料有限公司 Sand wallpaper and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101358382A (en) * 2008-08-26 2009-02-04 东华大学 A kind of antibacterial nanofiber material and preparation method thereof
CN102605679A (en) * 2012-03-15 2012-07-25 广东银洋树脂有限公司 Wallpaper
CN104452476A (en) * 2014-12-12 2015-03-25 广东玉兰装饰材料有限公司 Sand wallpaper and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105803793A (en) * 2016-04-21 2016-07-27 安徽皖翎羽绒制品有限公司 Water-borne polyurethane coating agent containing superfine down fiber-polylactic acid microspheres
CN105803794A (en) * 2016-04-21 2016-07-27 安徽皖翎羽绒制品有限公司 Water-borne polyurethane coating agent containing superfine down fiber grafted nano zeolite micropowder
CN106118298A (en) * 2016-07-14 2016-11-16 阜南县宏泰工艺品有限公司 A kind of wood artwork is with containing can the water paint and preparation method thereof of anthelmintic multiple cellulose acetate nanofiber
CN106118301A (en) * 2016-07-18 2016-11-16 阜南县大自然工艺品有限公司 A kind of wood artwork water paint containing super-hydrophobic multiple cellulose acetate nanofiber and preparation method thereof
CN106318074A (en) * 2016-08-25 2017-01-11 阜南县天亿工艺品有限公司 Water paint containing high-temperature-resisting porous composite cellulose acetate nanofibers for wooden artware and preparation method of water paint
CN106349840A (en) * 2016-08-25 2017-01-25 阜南县天亿工艺品有限公司 High-hardness-flame-retardant-composite-cellulose-acetate-nano-fiber-containing water-based paint for wooden crafts and preparation method thereof
CN117431007A (en) * 2023-12-08 2024-01-23 泉州市东宝科技集团有限公司 Stone-like paint and preparation method thereof
CN117431007B (en) * 2023-12-08 2024-03-08 泉州市东宝科技集团有限公司 Stone-like paint and preparation method thereof

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Application publication date: 20160420