CN105504954A - Solid correction material and preparation method thereof - Google Patents
Solid correction material and preparation method thereof Download PDFInfo
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- CN105504954A CN105504954A CN201510998453.2A CN201510998453A CN105504954A CN 105504954 A CN105504954 A CN 105504954A CN 201510998453 A CN201510998453 A CN 201510998453A CN 105504954 A CN105504954 A CN 105504954A
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- solid state
- alters
- acid
- water
- emulsion
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- 239000007787 solid Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title claims abstract description 44
- 239000002989 correction material Substances 0.000 title abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000011230 binding agent Substances 0.000 claims abstract description 38
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 3
- 229930195729 fatty acid Natural products 0.000 claims abstract description 3
- 239000000194 fatty acid Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 104
- 239000000839 emulsion Substances 0.000 claims description 69
- 239000003795 chemical substances by application Substances 0.000 claims description 61
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 57
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 38
- 239000000243 solution Substances 0.000 claims description 29
- 239000006185 dispersion Substances 0.000 claims description 28
- 239000013543 active substance Substances 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000012463 white pigment Substances 0.000 claims description 24
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 229920001451 polypropylene glycol Polymers 0.000 claims description 20
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 19
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 19
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 19
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 19
- 239000004408 titanium dioxide Substances 0.000 claims description 19
- 229920002472 Starch Polymers 0.000 claims description 18
- 239000008107 starch Substances 0.000 claims description 18
- 235000019698 starch Nutrition 0.000 claims description 18
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004816 latex Substances 0.000 claims description 12
- 229920000126 latex Polymers 0.000 claims description 12
- 239000002174 Styrene-butadiene Substances 0.000 claims description 11
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 11
- 239000011115 styrene butadiene Substances 0.000 claims description 11
- 150000002632 lipids Chemical class 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 229920002401 polyacrylamide Polymers 0.000 claims description 6
- 235000013336 milk Nutrition 0.000 claims description 5
- 239000008267 milk Substances 0.000 claims description 5
- 210000004080 milk Anatomy 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 239000012670 alkaline solution Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 239000004584 polyacrylic acid Substances 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 229920003169 water-soluble polymer Polymers 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 3
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 claims description 2
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 150000002462 imidazolines Chemical class 0.000 claims description 2
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 claims description 2
- 150000003016 phosphoric acids Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000223 polyglycerol Polymers 0.000 claims description 2
- 229940069328 povidone Drugs 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 abstract description 6
- 238000012937 correction Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 239000012265 solid product Substances 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000006254 rheological additive Substances 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 description 17
- 239000000178 monomer Substances 0.000 description 17
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 17
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 17
- 239000008117 stearic acid Substances 0.000 description 17
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 16
- 238000010189 synthetic method Methods 0.000 description 15
- 229920001577 copolymer Polymers 0.000 description 12
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 7
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 7
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 6
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 5
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 5
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 4
- NQSLZEHVGKWKAY-UHFFFAOYSA-N 6-methylheptyl 2-methylprop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C(C)=C NQSLZEHVGKWKAY-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 4
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical group O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 2
- 239000004471 Glycine Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920001002 functional polymer Polymers 0.000 description 2
- 235000013922 glutamic acid Nutrition 0.000 description 2
- 239000004220 glutamic acid Substances 0.000 description 2
- 239000003348 petrochemical agent Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a solid correction material. The solid correction material is mainly prepared from, by mass, 2-50 parts of binders, 3-8 parts of fatty acid and/or fatty alcohol, 1-15 parts of surfactant, 20-60 parts of white pigments, 2-6 parts of additives and 10-50 parts of water, wherein the additives contain rheological additives and dispersant in a mass part ratio of (1-5): (1-2.5). The solid correction material is a waterborne solid product without volatile organic solvent and is environmentally friendly, safe, free of pungent smell, capable of performing correction in a large area, good in re-writing performance after correction, recoverable after use and convenient to use. The invention further discloses a preparation method of the solid correction material. The preparation method is simple in process, and the cost is low.
Description
Technical field
The invention belongs to altering appliance technical field, be specifically related to a kind of solid state and alter material and preparation method thereof.
Background technology
Along with people's living standard is constantly improved, the requirement of stationery is also improved constantly, especially security and suitability.
Scribble articles for use mainly correction fluid and alter belt of correcting mistakes at present, wherein correction fluid is containing objectionable impuritiess such as organic solvents, injury is in various degree had to the health of user, even if water-based correction fluid is also containing a certain amount of organic solvent, and it is slow to there is dry and hard speed, be difficult to cover the problems such as free ink pen person's handwriting, alter belt uses inconvenience, be difficult to accurate covering, cost is high.
At present existing solid altering product research and production, as patent CN1165166A, CN1071440A, but is wax material due to the binder of these products, is coated with write performance more bad, especially to the free ink pen generally used now and gel ink pen after therefore altering.And, in order to make wax material and other component Homogeneous phase mixing, needing to add a certain amount of organic solvent, causing the harm to user and environment.
Summary of the invention
First technical problem to be solved by this invention is to provide a kind of solid state and alters material, and it is the aqueous solid product not containing volatile organic solvent that this solid state alters material, is coated with write performance better after correction, and easy to use, and cost is low.
Second technical problem to be solved by this invention is to provide the preparation method that above-mentioned solid state alters material, and this preparation method's technique is simple, and cost is low.
First technical problem to be solved by this invention is achieved through the following technical solutions: a kind of solid state alters material, raw material primarily of following proportion by weight is made: binder 2 ~ 50, lipid acid and/or fatty alcohol 3 ~ 8, tensio-active agent 1 ~ 12, white pigment 20 ~ 60, auxiliary agent 2 ~ 6, water 10 ~ 50, described auxiliary agent comprises auxiliary rheological agents and dispersion agent, and the proportion by weight of the two is 1 ~ 5:1 ~ 2.5.
Binder of the present invention is preferably but not limited to being water-soluble polymers and/or water and milk shaped polymer.
Described water-soluble polymers is preferably one or more in polyvinylpyrrolidone, polyvinyl alcohol, polyacrylic acid, polyacrylamide, polyacrylamide copolymer and treated starch.
Water and milk shaped polymer of the present invention is preferably one or more in pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, styrene-butadiene emulsion and organosilicon crylic acid latex.
Further, pure-acrylic emulsion is acrylate copolymer emulsion, benzene emulsion is latex of copolymer in cinnamic acrylic ester), acrylate and vinyl acetate emulsion is vinyl acetate between to for plastic-butyl acrylate copolymer emulsion, styrene-butadiene emulsion is styrene-butadiene copolymer emulsion, organosilicon crylic acid latex is acrylate-silicone copolymer emulsion.
Wherein pure-acrylic emulsion (acrylate copolymer emulsion) can be by the polymer emulsion comprising one or more following monomers and be polymerized: vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, isopropyl acrylate, Isooctyl acrylate monomer, Hydroxyethyl acrylate, glycidyl acrylate, acrylamide, methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, butyl methacrylate, isopropyl methacrylate, Isooctyl methacrylate, hydroxyethyl methylacrylate, glycidyl methacrylate and Methacrylamide.
The concrete synthetic method of pure-acrylic emulsion (acrylate copolymer emulsion) preferably can with reference to following technical literature: the preparation [J] of modification pure-acrylic emulsion. Hunan Institute Of Engineering's journal (natural science edition) .2002 (04).Also directly commercially available prod can be bought.Other preparation method well known in the art can also be adopted to prepare.
Wherein benzene emulsion (latex of copolymer in cinnamic acrylic ester) can be by vinylbenzene and comprise the polymer emulsion that one or more following monomers are polymerized: vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, isopropyl acrylate, Isooctyl acrylate monomer, Hydroxyethyl acrylate, glycidyl acrylate, acrylamide, methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, butyl methacrylate, isopropyl methacrylate, Isooctyl methacrylate, hydroxyethyl methylacrylate, glycidyl methacrylate, Methacrylamide.
The concrete synthetic method of benzene emulsion (latex of copolymer in cinnamic acrylic ester) preferably can with reference to following technical literature: the preparation and property of benzene emulsion characterizes [J]., Chinese tackiness agent, 1995 (03).Also above-mentioned commercially available prod can directly be bought.Other preparation method well known in the art can also be adopted to prepare.
Wherein acrylate and vinyl acetate emulsion (vinyl acetate between to for plastic-butyl acrylate copolymer emulsion) can be by vinyl acetate between to for plastic or tertiary ethylene carbonate and comprise the polymer emulsion that one or more following monomers are polymerized: vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, isopropyl acrylate, Isooctyl acrylate monomer, Hydroxyethyl acrylate, glycidyl acrylate, acrylamide, methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, butyl methacrylate, isopropyl methacrylate, Isooctyl methacrylate, hydroxyethyl methylacrylate, glycidyl methacrylate or Methacrylamide.
The concrete synthetic method of acrylate and vinyl acetate emulsion (vinyl acetate between to for plastic-butyl acrylate copolymer emulsion) preferably can with reference to following technical literature: preparation and application research [D] of acrylate and vinyl acetate emulsion. HeFei University of Technology (2010).Also above-mentioned commercially available prod can directly be bought.Other preparation method well known in the art can also be adopted to prepare.
Wherein styrene-butadiene emulsion (styrene-butadiene copolymer emulsion) can be containing but be not limited to the copolymer emulsion of vinylbenzene and divinylic monomer.As: Carboxy emulsion etc.
The concrete synthetic method of styrene-butadiene emulsion (styrene-butadiene copolymer emulsion) preferably can with reference to following technical literature: the study on the synthesis [J] of styrene-butadiene latex. Journal of Functional Polymers .2005 (03).Also above-mentioned commercially available prod can directly be bought.Other preparation method well known in the art can also be adopted to prepare.
Wherein organosilicon crylic acid latex (acrylate-silicone copolymer emulsion) can be by can copolymeric silicone with comprise the polymer emulsion that one or more following monomers are polymerized: vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, isopropyl acrylate, Isooctyl acrylate monomer, Hydroxyethyl acrylate, glycidyl acrylate, acrylamide, methacrylic acid, methyl methacrylate, β-dimethyl-aminoethylmethacrylate, butyl methacrylate, isopropyl methacrylate, Isooctyl methacrylate, hydroxyethyl methylacrylate, glycidyl methacrylate or Methacrylamide.
The concrete synthetic method of organosilicon crylic acid latex (acrylate-silicone copolymer emulsion) preferably can with reference to following technical literature: preparations and applicatio performance [J, Speciality Petrochemicals, 2012 (01) of organosilicon modified crylic acid resin emulsion; Also above-mentioned commercially available prod can directly be bought.Other preparation method well known in the art can also be adopted to prepare.
Lipid acid of the present invention is preferably containing one or more in the saturated and/or unsaturated fatty acids of 8-22 carbon.As stearic acid, oleic acid, sad, certain herbaceous plants with big flowers is sour.Fatty alcohol is preferably containing one or more in the saturated and/or unsaturated fatty alcohol of 8-22 carbon.As 18 alcohol, 22 alcohol, certain herbaceous plants with big flowers alcohol, hexylene glycol and 16-18 alcohol mixture or 18-22 alcohol mixture etc.
Tensio-active agent of the present invention is preferably alkylolamide, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, Polyoxyethylene Methyl Glucoside Ether, fatty acid methyl ester ethoxylate, aliphatic alcohol polyoxyethylene sulfonate, fatty alcohol-polyoxyethylene ether phosphoric acid salt, Soxylat A 25-7 sorbitan ester, sucrose ester, alkyl succinic acid sulfonate, imidazolines, higher aliphatic alcohol sulfate, betaines tensio-active agent, amino acid type surfactant is (as two (pungent amino-ethyl) glycine, N-acyl glutamic acid etc.), alkylbenzene sulfonate (as Witco 1298 Soft Acid etc.), glycerin fatty acid ester (as mono-glycerides), propylene glycol block polyether is (as CASNo106392-12-5, described in 9003-11-6) and polyglycerol (as three Polyglycerine, five Polyglycerine etc.) in one or more.
White pigment of the present invention is preferably titanium dioxide or lithopone; Described auxiliary rheological agents is preferably polyvalent alcohol and/or polyurethanes auxiliary rheological agents, and described dispersion agent is Natvosol or polyacrylic acid and its esters (as polyacrylic acid sodium salt, ammonium polyacrylate salt etc.).
Polyvalent alcohol of the present invention is preferably one or more in glycerine, ethylene glycol, polyoxyethylene glycol, propylene glycol and polypropylene glycol, and described polyurethanes auxiliary rheological agents is preferably SILOK7129W.
Further, auxiliary agent of the present invention also comprises sanitas.
Preferably, sanitas of the present invention is not containing the sanitas that this area routine of formaldehyde uses.
Second technical problem to be solved by this invention is achieved through the following technical solutions: above-mentioned solid state alters the preparation method of material, comprises the following steps:
(1) by using magnitude relation, water intaking and dispersing auxiliary join in white pigment, obtain material A after grinding;
(2) get binder and be heated to 50 ~ 90 DEG C, then mix with material A, obtain material B;
(3) in material B, add lipid acid and/or fatty alcohol, tensio-active agent and auxiliary rheological agents, and adjust ph is 8 ~ 13, obtains material C, by material C cooling forming, namely obtained solid state alters material.
Wherein adopt alkaline solution adjust ph to be 8 ~ 13 in step of the present invention (3), described alkaline solution is NaOH, KOH, Na
2cO
3, K
2cO
3or aqueous ethanolamine.
Further, in step (3), also can add lipid acid and/or fatty alcohol, tensio-active agent, auxiliary rheological agents and sanitas in material B, and adjust ph is 8 ~ 13, obtains material C, by material C cooling forming, namely obtained solid state alters material.
Compared with prior art, tool of the present invention has the following advantages:
(1) solid state in the present invention alters material, easy to use, alters effective, and is aqueous solid product, non-volatility organic solvent pollution;
(2) solid state in the present invention alters material, and safety and Health, has no irritating odor, and can big area alter, environmental protection, with rear recyclable.
Accompanying drawing explanation
Fig. 1 is the design sketch adopting solid state correction material to carry out altering and altering rear rewriting in embodiment 1.
Embodiment
Embodiment 1
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 5
Treated starch 1
Benzene emulsion (wherein monomer composition: vinylbenzene 45%, butyl acrylate 49%, methyl methacrylate 4%, methacrylic acid 2%, its synthetic method reference: the preparation and property of benzene emulsion characterizes [J]. Chinese tackiness agent .1995 (03)) 20
Stearic acid: 5
Tensio-active agent fatty alcohol-polyoxyethylene ether: 3
White pigment titanium dioxide: 40
Dispersion agent sodium polyacrylate: 1
Polyurethanes auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 3
Polypropylene glycol: 2
Water: 20.
The preparation method that this solid state alters material is as follows:
(1) in the water of 20 parts, add 1 part of dispersion agent, add white pigment titanium dioxide 40 parts after mixing, dispersion, grinding, obtains material A;
(2) get polyvinyl alcohol water solution 5 parts, treated starch 1 part, benzene emulsion 20 parts that mass concentration is 20%, be mixed to get binder, binder be heated to 70 DEG C, then mix with material A, obtain material B;
(3) in material B, stearic acid 5 parts is added, fatty alcohol-polyoxyethylene ether 1 part, polyurethanes auxiliary rheological agents 3 parts, polypropylene glycol 2 parts, stirs, then adds the aqueous sodium hydroxide solution that mass concentration is 30%, adjust ph is 8 ~ 11, obtain material C, by material C cooling forming, namely obtained solid state alters material.
Solid state in table 1 the present embodiment alters material and correction product performance of the prior art contrast
Adopt the solid state in the present embodiment to alter material and carry out altering and altering the design sketch of rear rewriting as shown in fig. 1.
In fact, through overtesting, present inventor finds that the solid state made in following examples 2-17 is altered material and also can be reached the effect be similar in table 1 and Fig. 1, repeat no longer one by one herein, namely adopt the technical scheme of summary of the invention part of the present invention, all can reach the technique effect that the present invention claims.
Embodiment 2
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 5
Treated starch 1
Benzene emulsion (wherein monomer composition: vinylbenzene 55%, Isooctyl acrylate monomer 35%, hydroxyethyl methylacrylate 8%, vinylformic acid 2%, its synthetic method reference: the preparation and property of benzene emulsion characterizes [J]. Chinese tackiness agent .1995 (03)) 20
Stearic acid: 6
Tensio-active agent fatty alcohol-polyoxyethylene ether: 3
White pigment titanium dioxide: 40
Dispersion agent sodium polyacrylate: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 3
Polypropylene glycol: 2
Water: 20.
The preparation method that this solid state alters material is as follows:
(1) in the water of 20 parts, add 1 part of dispersion agent sodium polyacrylate, add titanium dioxide 40 parts after mixing, dispersion, grinding, obtains material A;
(2) get polyvinyl alcohol water solution 5 parts, treated starch 1 part, benzene emulsion 20 parts that mass concentration is 20%, be mixed to get binder, binder be heated to 70 DEG C, then mix with material A, obtain material B;
(3) in material B, stearic acid 6 parts is added, fatty alcohol-polyoxyethylene ether 3 parts, urethane auxiliary rheological agents 3 parts, polypropylene glycol 2 parts, stirs, then adds the aqueous sodium hydroxide solution that mass concentration is 30%, adjust ph is 8 ~ 11, obtain material C, by material C cooling forming, namely obtained solid state alters material.
Embodiment 3
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 5
Treated starch 1
Benzene emulsion (wherein monomer composition: vinylbenzene 40%, butyl acrylate 49%, methyl methacrylate 4%, methacrylic acid 2%, acrylamide 5%, its synthetic method reference: the preparation and property of benzene emulsion characterizes [J]. Chinese tackiness agent .1995 (03)) 20
Stearic acid: 5
Tensio-active agent, fatty alcohol-polyoxyethylene ether: 4
White pigment titanium dioxide: 40
Dispersion agent: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 3
Polypropylene glycol: 2 parts
Water: 20.
The preparation method that this solid state alters material is as follows:
(1) in the water of 20 parts, add 1 part of dispersion agent sodium polyacrylate, add titanium dioxide 40 parts after mixing, dispersion, grinding, obtains material A;
(2) get polyvinyl alcohol water solution 5 parts, treated starch 1 part, benzene emulsion 20 parts that mass concentration is 20%, be mixed to get binder, binder be heated to 70 DEG C, then mix with material A, obtain material B;
(3) in material B, stearic acid 5 parts is added, fatty alcohol-polyoxyethylene ether 4 parts, urethane auxiliary rheological agents 3 parts, polypropylene glycol 2 parts, stirs, then adds the aqueous sodium hydroxide solution that mass concentration is 30%, adjust ph is 8 ~ 11, obtain material C, by material C cooling forming, namely obtained solid state alters material.
Embodiment 4
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 6
Treated starch 1
Benzene emulsion (commercially available prod) 20
Stearic acid: 5
Tensio-active agent fatty alcohol-polyoxyethylene ether: 3
White pigment titanium dioxide: 40
Dispersion agent sodium polyacrylate: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 3
Polypropylene glycol: 2
Water: 20.
The preparation method that this solid state alters material is as follows:
(1) in the water of 20 parts, add 1 part of dispersion agent, add titanium dioxide 40 parts after mixing, dispersion, grinding, obtains material A;
(2) get polyvinyl alcohol water solution 6 parts, treated starch 1 part, benzene emulsion 20 parts that mass concentration is 20%, be mixed to get binder, binder be heated to 70 DEG C, then mix with material A, obtain material B;
(3) in material B, stearic acid 5 parts is added, fatty alcohol-polyoxyethylene ether 3 parts, urethane auxiliary rheological agents 3 parts, polypropylene glycol 2 parts, stirs, then adds the aqueous sodium hydroxide solution that mass concentration is 30%, adjust ph is 8 ~ 11, obtain material C, by material C cooling forming, namely obtained solid state alters material.
Embodiment 5
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made (in 100 mass parts):
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 5
Treated starch 1
Pure-acrylic emulsion (wherein monomer composition: methyl methacrylate 55%, butyl acrylate 38%, isopropyl acrylate 4%, methacrylic acid 3%, its synthetic method reference: the preparation [J] of modification pure-acrylic emulsion. Hunan Institute Of Engineering's journal (natural science edition) .2002 (04)) 5
Stearic acid: 5
Tensio-active agent fatty alcohol-polyoxyethylene ether: 1
White pigment titanium dioxide: 55
Dispersion agent sodium polyacrylate: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 1
Polypropylene glycol: 1
Water: 25.
This solid state alters the preparation method of material with embodiment 1, and difference is, in step (2), binder is heated to 50 DEG C, adopts KOH aqueous solution adjust ph to be 8 ~ 13 in step (3).
Embodiment 6
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made (in 100 mass parts):
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 1
Treated starch 1
Pure-acrylic emulsion (wherein monomer composition: methyl methacrylate 60%, Isooctyl acrylate monomer 30%, isopropyl acrylate 4%, vinylformic acid 3%, acrylamide 3%, its synthetic method reference: the preparation [J] of modification pure-acrylic emulsion. Hunan Institute Of Engineering's journal (natural science edition) .2002 (04)) 5
Stearic acid: 4
Tensio-active agent, fatty alcohol-polyoxyethylene ether: 1
White pigment titanium dioxide: 60
Dispersion agent sodium polyacrylate: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 1
Polypropylene glycol: 1
Water: 25.
This solid state alters the preparation method of material with embodiment 1, and difference is, in step (2), binder is heated to 90 DEG C, adopts Na in step (3)
2cO
3aqueous solution adjust ph is 8 ~ 9.
Embodiment 7
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 6
Treated starch 1
Pure-acrylic emulsion (commercially available prod) 5
Lauric acid: 5
Tensio-active agent, fatty alcohol-polyoxyethylene ether: 3
White pigment titanium dioxide: 55
Dispersion agent: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 2
Polypropylene glycol: 2
Water: 20.
This solid state alters the preparation method of material with embodiment 1, and difference is, in step (2), binder is heated to 60 DEG C, adopts Na in step (3)
2cO
3aqueous solution adjust ph is 8 ~ 9.
Embodiment 8
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 15
Treated starch 1
Acrylate and vinyl acetate emulsion (wherein monomer composition: vinyl acetate 62%, butyl acrylate 32%, vinylformic acid 3%, Hydroxyethyl acrylate 3%, its synthetic method reference: preparation and application research [D] of acrylate and vinyl acetate emulsion. HeFei University of Technology 2010) 8
Stearic acid: 6
Tensio-active agent, fatty alcohol-polyoxyethylene ether: 4
White pigment titanium dioxide: 40
Dispersion agent: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 2
Polypropylene glycol: 3
Water: 20.
This solid state alters the preparation method of material with embodiment 1, and difference is, in step (2), binder is heated to 70 DEG C, adopts K in step (3)
2cO
3aqueous solution adjust ph is 8 ~ 10.
Embodiment 9
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 10
Treated starch 1
Tertiary vinegar milk liquid (wherein monomer composition: tertiary ethylene carbonate 10%, vinyl acetate 45%, butyl acrylate 39%, vinylformic acid 3%, Hydroxyethyl acrylate 3%, its synthetic method reference: the development [J] of VAC Vinyltertiary Carbonate-BA copolymer emulsion. Chinese tackiness agent .2002 (03)) 9
Lipid acid oleic acid 3
Certain herbaceous plants with big flowers acid: 2
Tensio-active agent alkylolamide: 1
White pigment lithopone: 50
Dispersion agent Natvosol, ammonium polyacrylate salt etc.: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 1
Water: 22.
This solid state alters the preparation method of material with embodiment 1, and difference is, in step (2), binder is heated to 80 DEG C, adopts NaOH aqueous solution adjust ph to be 8 ~ 13 in step (3).
Embodiment 10
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 15
Treated starch 1
Styrene-butadiene emulsion (wherein monomer composition: divinyl 45%, vinylbenzene 55%, its synthetic method reference: the study on the synthesis [J] of styrene-butadiene latex. Journal of Functional Polymers .2005 (03)) 20
Sad (lipid acid): 3
Stearic acid: 2
Surfactant polyoxyethylene ether sorbitan ester: 1
Tensio-active agent three Polyglycerine: 2
White pigment lithopone: 33
Dispersion agent Natvosol: 1
Auxiliary rheological agents glycerine and ethylene glycol: 2
Water: 20.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 11
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyacrylamide solution 15
Treated starch 1
Styrene-butadiene emulsion (wherein monomer composition: divinyl 65%, vinylbenzene 35%) 20
Stearic acid: 5
Tensio-active agent, Witco 1298 Soft Acid: 3
White pigment titanium dioxide: 33
Dispersion agent Natvosol: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 2
Polypropylene glycol: 1
Sanitas 1
Water: 18.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 12
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made (in 100 mass parts):
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 5
Treated starch 1
Organosilicon crylic acid latex (wherein monomer composition: methyl methacrylate 45%, butyl acrylate 39%, end-vinyl Polymethyl methacrylate 5%, isopropyl methacrylate 4%, Hydroxyethyl acrylate 3%, vinylformic acid 3%, glycidyl acrylate 1%, its synthesized reference: the preparations and applicatio performance [J] of organosilicon modified crylic acid resin emulsion. Speciality Petrochemicals .2012 (01)) 20
Stearic acid: 5
Tensio-active agent, fatty alcohol-polyoxyethylene ether: 4
White pigment titanium dioxide: 40
Dispersion agent: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 3
Polypropylene glycol: 2
Water: 20.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 13
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: pure-acrylic emulsion, commercially available, 2
18/16 alcohol: 6
Stearic acid: 2
Tensio-active agent, alkyl acid ester sulfonates: 7
Alkylolamide 2
White pigment titanium dioxide: 29.5
Dispersion agent: 2.5
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 0.5
Polypropylene glycol: 0.5
Water: 48.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 14
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 15
Polyacrylamide solution 1
Benzene emulsion (wherein monomer composition: vinylbenzene 42%, butyl acrylate 47%, methyl methacrylate 4%, methacrylic acid 2%, acrylamide 5%, its synthetic method reference: the preparation and property of benzene emulsion characterizes [J]. Chinese tackiness agent .1995 (03)), also can adopt commercially available prod 12
18/16 alcohol: 5
N-acyl glutamic acid 1
Tensio-active agent, betaines tensio-active agent (dodecyldimethylamine base trimethyl-glycine): 1
White pigment titanium dioxide: 40
Dispersants ammonium polyacrylate: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 2
Polypropylene glycol: 2
Water: 20.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 15
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: Carboxy emulsion (wherein monomer composition: divinyl 62%, vinylbenzene 35%, unsaturated carboxylic acid 3%, its synthetic method can reference: a kind of technology of preparing [P] of novel carboxylic styrene-butadiene latex. Chinese patent: CN1891728) and, also can adopt commercially available prod 50
Lipid acid stearic acid, oleic acid, sad and certain herbaceous plants with big flowers is sour: 5
Tensio-active agent two (pungent amino-ethyl) glycine: 10
White pigment lithopone: 20
Dispersion agent: 1
Urethane auxiliary rheological agents (Guangzhou Si Luoke company, SILOK7129W): 0.5
Polypropylene glycol: 2
Water: 11.5.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 16
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: polyvinyl alcohol water solution (mass percentage is 20%) 1
Aqueous povidone solution 1
Surfactant sodium dodecyl base Phenylsulfonic acid: 12
18/16 alcohol: 3
White pigment titanium dioxide: 35
Dispersion agent Natvosol: 2
Auxiliary rheological agents ethylene glycol: 1
Water: 45.
This solid state alters the preparation method of material with embodiment 1.
Embodiment 17
The solid state that the present embodiment provides alters material, and the raw material primarily of following proportion by weight is made:
Binder: styrene-butadiene emulsion, commercially available prod 30
18/16 alcohol: 6
Sad: 2
Surfactant polyoxyethylene ether sorbitan ester: 6
Tensio-active agent three Polyglycerine: 4
White pigment lithopone: 32
Dispersion agent Natvosol: 1
Auxiliary rheological agents glycerine and ethylene glycol: 2
Water: 25.
This solid state alters the preparation method of material with embodiment 1.
Above embodiment is only for setting forth the present invention, and protection scope of the present invention is not only confined to above embodiment.The those of ordinary skill of described technical field, according to above content disclosed by the invention and scope that each parameter is got, all can realize object of the present invention.
Claims (10)
1. a solid state alters material, it is characterized in that: the raw material primarily of following proportion by weight is made: binder 2 ~ 50, lipid acid and/or fatty alcohol 3 ~ 8, tensio-active agent 1 ~ 12, white pigment 20 ~ 60, auxiliary agent 2 ~ 6, water 10 ~ 50, described auxiliary agent comprises auxiliary rheological agents and dispersion agent, and the proportion by weight of the two is 1 ~ 5:1 ~ 2.5.
2. solid state according to claim 1 alters material, it is characterized in that: described binder is water-soluble polymers and/or water and milk shaped polymer.
3. solid state according to claim 2 alters material, it is characterized in that: described water-soluble polymers is one or more in aqueous povidone solution, polyvinyl alcohol water solution, the polyacrylic acid aqueous solution, polyacrylamide solution, the polyacrylamide copolymer aqueous solution and treated starch.
4. solid state according to claim 2 alters material, it is characterized in that: described water and milk shaped polymer is one or more in pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, styrene-butadiene emulsion and organosilicon crylic acid latex.
5. solid state according to claim 1 alters material, it is characterized in that: described lipid acid is containing one or more in the saturated of 8-22 carbon and/or unsaturated fatty acids, described fatty alcohol is containing one or more in the saturated of 8-22 carbon and/or unsaturated fatty alcohol, described tensio-active agent is alkylolamide, fatty alcohol-polyoxyethylene ether, polyoxyethylene nonylphenol ether, Polyoxyethylene Methyl Glucoside Ether, fatty acid methyl ester ethoxylate, aliphatic alcohol polyoxyethylene sulfonate, fatty alcohol-polyoxyethylene ether phosphoric acid salt, Soxylat A 25-7 sorbitan ester, sucrose ester, alkyl succinic acid sulfonate, imidazolines, higher aliphatic alcohol sulfate, betaines tensio-active agent, amino acid type surfactant, alkylbenzene sulfonate, glycerin fatty acid ester, one or more in propylene glycol block polyether and polyglycerol.
6. solid state according to claim 1 alters material, it is characterized in that: described white pigment is titanium dioxide or lithopone; Described auxiliary rheological agents is polyvalent alcohol and/or polyurethanes auxiliary rheological agents, and described dispersion agent is Natvosol, polyacrylic or polyacrylate.
7. solid state according to claim 6 alters material, it is characterized in that: described polyvalent alcohol is one or more in glycerine, ethylene glycol, polyoxyethylene glycol, propylene glycol and polypropylene glycol, or described polyvalent alcohol is one or more in the ethylene oxide adduct of glycerine, ethylene glycol, polyoxyethylene glycol, propylene glycol and polypropylene glycol.
8. the solid state according to any one of claim 1-7 alters material, it is characterized in that: described auxiliary agent also comprises sanitas.
9. the solid state described in any one of claim 1-7 alters the preparation method of material, it is characterized in that comprising the following steps:
(1) by using magnitude relation, water intaking and dispersing auxiliary join in white pigment, obtain material A after grinding;
(2) get binder and be heated to 50 ~ 90 DEG C, then mix with material A, obtain material B;
(3) in material B, add lipid acid and/or fatty alcohol, tensio-active agent and auxiliary rheological agents, and adjust ph is 8 ~ 13, obtains material C, by material C cooling forming, namely obtained solid state alters material.
10. solid state according to claim 9 alters the preparation method of material, it is characterized in that: adopt alkaline solution adjust ph to be 8 ~ 13 in step (3), described alkaline solution is NaOH, KOH, Na
2cO
3, K
2cO
3or aqueous ethanolamine.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110499089A (en) * | 2019-08-23 | 2019-11-26 | 湖北双键精细化工有限公司 | A kind of aqueous double-component epoxy paint for priming paint and top lacquer |
| CN113622207A (en) * | 2021-07-28 | 2021-11-09 | 沂水祥腾化工有限公司 | Glossiness dispersing agent for textile dye and preparation method thereof |
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| CN1256704A (en) * | 1997-04-09 | 2000-06-14 | 吉莱特公司 | Correction fluid |
| CN1414042A (en) * | 2002-03-24 | 2003-04-30 | 孙建军 | Solid obliteration composition and its production method |
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| CN110499089A (en) * | 2019-08-23 | 2019-11-26 | 湖北双键精细化工有限公司 | A kind of aqueous double-component epoxy paint for priming paint and top lacquer |
| CN113622207A (en) * | 2021-07-28 | 2021-11-09 | 沂水祥腾化工有限公司 | Glossiness dispersing agent for textile dye and preparation method thereof |
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