CN105504227A - Synthetic method of novel environment-friendly chlorine-resistant color fixing agent - Google Patents
Synthetic method of novel environment-friendly chlorine-resistant color fixing agent Download PDFInfo
- Publication number
- CN105504227A CN105504227A CN201610002041.3A CN201610002041A CN105504227A CN 105504227 A CN105504227 A CN 105504227A CN 201610002041 A CN201610002041 A CN 201610002041A CN 105504227 A CN105504227 A CN 105504227A
- Authority
- CN
- China
- Prior art keywords
- solution
- synthetic method
- resistant
- novel environment
- environment friendly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/10—Polycondensates containing more than one epoxy group per molecule of polyamines with epihalohydrins or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
- D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Epoxy Compounds (AREA)
Abstract
The invention discloses a synthetic method of a novel environment-friendly chlorine-resistant color fixing agent. Epoxy chloropropane, diethylenetriamine and diallylamine serve as the raw materials, and the novel environment-friendly chlorine-resistant color fixing agent is prepared through a reaction. Hydroxyl and imino groups exist in the color fixing agent and can be combined with dye, chloridion of the dye can be closed, and a thin polymer film can further be formed on the fiber surface.
Description
Technical field
The present invention relates to the laking agent of yarn fabric, more specifically, the present invention relates to a kind of synthetic method of novel environment friendly chlorine-resistant laking agent.
Background technology
Cotton waits the dyeing of cellulose base fiber fabric usually to use substantive dyestuff and matching stain, DYED FABRICS can be made to obtain chromatic colour, but its look process fastness is poor, namely in washing process, the substantive dyestuff on DYED FABRICS surface and matching stain are easy to come off, DYED FABRICS is not only caused to be faded, but also other fabric can be infected with, make troubles to the consumption of textiles and arrangement.In addition, the oxygen in the use procedure of DYED FABRICS in the sweat of human body and saliva and environment and UV-light all can make the covalent linkage between reactive dyestuffs and cellulosic fibre fracture occur and occur fastness variation phenomenon, cause fabric fading.For improving dyestuff in the stability of fiber surface, resist the erosion of environmental factors to dyestuff, usually carry out fixation treatment to fabric after dyeing, the auxiliary agent that this process uses is laking agent.
Come out so far from early 1950s first-generation polymer laking agent, various countries develop the laking agent of different sorts different structure in succession.In cotton laking agent, according to Oeko-Tex standard, the index of textile color stability comprise resistance toly to soap, water-fastness, rub resistance, perspiration resistance, sun-resistant and chlorine-resistant, environmental protection is not containing formaldehyde, promote responsive colour fastness, check colors index request, the wherein chlorine-resistant such as influence of light is little, this index study progress that the dyefastness significantly improving sensitive colors reaches environmental protection formaldehydeless is simultaneously slower.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of synthetic method of novel environment friendly chlorine-resistant laking agent, and the laking agent of the method synthesis has the performance of the responsive colour fastness of environmental protection, chlorine-resistant and raising, can meet again the primary demand of conventional laking agent.
In order to solve the problem, the invention provides a kind of synthetic method of novel environment friendly chlorine-resistant laking agent.
In order to realize foregoing invention object, this invention takes following technical scheme:
A synthetic method for novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 50-80g, 80-110g, 80-110g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 45-55 DEG C, and in water trap, the water yield no longer increases;
(2) by heating temperatures to 55-70 DEG C, 3.3-3.85g oxidizing agent solution and 3.3-3.85g reductant solution is added in reaction system, after 25-40min, 29.7-34.65g oxidizing agent solution and 29.7-34.65g reductant solution are dripped 2.5-3.5h at 70-95 DEG C, reaction terminates;
(3), after reaction terminates, with superoxol, reaction product is bleached, obtain laking agent.
In one embodiment, described epoxy chloropropane is 55-70g, and diethylenetriamine is 85-100g, and diallyl amine is 85-100g.
In one embodiment, described oxidizing agent solution is ammonium persulfate solution.
In one embodiment, in described oxidizing agent solution, the quality of ammonium persulphate accounts for the 8.8-10.5% of oxidizing agent solution total mass.
In one embodiment, in described oxidizing agent solution, the quality of ammonium persulphate accounts for 9.09% of oxidizing agent solution total mass.
In one embodiment, described reductant solution is sodium metabisulfite solution.
In one embodiment, in described reductant solution, the quality of Sodium Pyrosulfite accounts for the 8.8-10.5% of reductant solution total mass.
In one embodiment, in described reductant solution, the quality of Sodium Pyrosulfite accounts for 9.09% of reductant solution total mass.
In one embodiment, in described superoxol, the quality of hydrogen peroxide accounts for 30% of superoxol total mass.
In one embodiment, described superoxol consumption is 10g.
Compared with prior art, the present invention has following beneficial effect:
1. laking agent of the present invention is cation compound, can generate color lake, be deposited on fiber surface with the anionic reactive in dyestuff.
2. the crosslinking reaction group of laking agent of the present invention not only can with some radical reaction in dye molecule, and can and fibrin reaction, by forming polynary interconnected system, effectively can improve the soaping fastness of dyestuff.In addition, the imino-in product encloses chlorion on dyestuff, greatly improves the resistance to chlorine of product dyed thereby.
3. after fixation bakes process, the various group crosslinking condensation in resin, define solid netted polymeric film at fiber surface, can the impact of effective organizational environment, promote the properties of product dyed thereby.
Be easier to understand the above-mentioned of the application and other features, aspect and advantage with reference to following detailed description.
Embodiment
Unless otherwise defined, all technology used herein and scientific terminology have the identical implication usually understood with one skilled in the art of the present invention.When there is contradiction, be as the criterion with the definition in this specification sheets.
Term as used herein " by ... preparation " and " comprising " synonym.Term used herein " comprises ", " comprising ", " having ", " containing " or its other distortion any, be intended to cover the comprising of non-exclusionism.Such as, comprise the composition of listed elements, step, method, goods or device and need not be only limitted to those key elements, but other key element of clearly not listing or the intrinsic key element of this kind of composition, step, method, goods or device can be comprised.
Conjunction " by ... composition " get rid of any key element, step or the component do not pointed out.If in claim, this phrase will make claim be closed, make it not comprise material except those materials described, but except relative customary impurities.When phrase " by ... composition " to appear in the clause of claim main body instead of immediately preceding after theme time, it is only limited to the key element described in this clause; Other key element is not excluded outside described claim as a whole.
During the Range Representation that equivalent, concentration or other value or parameter limit with scope, preferable range or a series of upper limit preferred value and lower preferable values, this is appreciated that all scopes specifically disclosing and formed by arbitrary pairing of any range limit or preferred value and any range lower limit or preferred value, no matter and whether this scope separately discloses.Such as, when disclosing scope " 1 to 5 ", described scope should be interpreted as comprising scope " 1 to 4 ", " 1 to 3 ", " 1-2 ", " 1-2 and 4-5 ", " 1-3 and 5 " etc.When numerical range is described in this article, unless otherwise indicated, otherwise this scope intention comprises its end value and all integers within the scope of this and mark.
In addition, the indefinite article " one " before key element of the present invention or component and " one " are to quantitative requirement (i.e. occurrence number) unrestriction of key element or component.Therefore " one " or " one " should be read as and comprise one or at least one, and the key element of singulative or component also comprise plural form, unless the obvious purport of described quantity refers to singulative.
Below by embodiment, the present invention is specifically described.What be necessary to herein means out is; following examples are only for the invention will be further described; limiting the scope of the invention can not be interpreted as; some nonessential improvement and adjustment that the professional and technical personnel in this field makes according to the content of foregoing invention, still belong to protection scope of the present invention.
In addition, if do not have other to illustrate, raw materials used is all commercially available.
In the examples below, in described oxidizing agent solution, the quality of ammonium persulphate accounts for 9.09% of oxidizing agent solution total mass; In described reductant solution, the quality of Sodium Pyrosulfite accounts for 9.09% of reductant solution total mass.
Embodiment 1
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 50g, 80g, 80g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 70 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 2
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 70 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 3
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 75 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 4
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 80 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 5
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 85 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 6
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 90 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 7
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 95 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 8
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 80g, 100g, 100g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 70 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 9
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 80g, 80g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 80 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Embodiment 10
The synthetic method of novel environment friendly chlorine-resistant laking agent, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 60g, 90g, 90g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 50 DEG C, and in water trap, the water yield no longer increases;
(2) take 3g oxygenant, be 1:10 dissolved oxidant according to the mass ratio of oxygenant and water, obtain oxidizing agent solution; Take 3g reductive agent, be the agent of 1:10 dissolving and reducing according to the mass ratio of reductive agent and water, obtain reductant solution;
(3) by heating temperatures to 60 DEG C, in reaction system, add the reductant solution of 3.3g oxidizing agent solution and 3.3g, after 0.5h, the oxidizing agent solution of 29.7g and the reductant solution of 29.7g dripped 3h at 70 DEG C, reaction terminate;
(4), after reaction terminates, be cooled to 50 DEG C of superoxols adding the 30wt% of 10g and reaction product is bleached, be finally cooled to room temperature, obtain laking agent.
Testing method:
Red cotton looped fabric (dye strength is 7%) is padded, and rolling chlorine residue is 85%, then dries by 120-160 DEG C of temperature.The cotton looped fabric of redness after oven dry crosses the relative cloth weight of 1%-3%() laking agent, test according to following standard:
1. soaping fastness is undertaken testing (1-5 level, 5 grades best) by GB/T420-90;
2. fastness to chlorine is tested by AATCC61-4A-2010 standard.
Aforesaid example is only illustrative, for explaining some features of feature of the present invention.Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and the embodiment presented herein is only the explanation of the embodiment of the selection of combination according to all possible embodiment.Therefore, the purpose of applicant is the selectional restriction that appended claim is not illustrated the example of feature of the present invention.And progress in science and technology is not replaced to be formed due to the inaccurate reason of language performance by the possible equivalent considered at present or son, and these changes also should be interpreted as being covered by appended claim in the conceived case.
Claims (10)
1. a synthetic method for novel environment friendly chlorine-resistant laking agent, is characterized in that, comprises the steps:
(1) diethylenetriamine of the epoxy chloropropane of 50-80g, 80-110g, 80-110g diallyl amine are added mix and blend in the round-bottomed flask that water trap and prolong are housed and be heated to 45-55 DEG C, and in water trap, the water yield no longer increases;
(2) by heating temperatures to 55-70 DEG C, 3.3-3.85g oxidizing agent solution and 3.3-3.85g reductant solution is added in reaction system, after 25-40min, 29.7-34.65g oxidizing agent solution and 29.7-34.65g reductant solution are dripped 2.5-3.5h at 70-95 DEG C, reaction terminates;
(3), after reaction terminates, with superoxol, reaction product is bleached, obtain laking agent.
2. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 1, is characterized in that, described epoxy chloropropane is 55-70g, and diethylenetriamine is 85-100g, and diallyl amine is 85-100g.
3. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 1, is characterized in that, described oxidizing agent solution is ammonium persulfate solution.
4. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 3, is characterized in that, in described oxidizing agent solution, the quality of ammonium persulphate accounts for the 8.8-10.5% of oxidizing agent solution total mass.
5. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 4, is characterized in that, in described oxidizing agent solution, the quality of ammonium persulphate accounts for 9.09% of oxidizing agent solution total mass.
6. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 1, is characterized in that, described reductant solution is sodium metabisulfite solution.
7. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 6, is characterized in that, in described reductant solution, the quality of Sodium Pyrosulfite accounts for the 8.8-10.5% of reductant solution total mass.
8. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 7, is characterized in that, in described reductant solution, the quality of Sodium Pyrosulfite accounts for 9.09% of reductant solution total mass.
9. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 1, is characterized in that, in described superoxol, the quality of hydrogen peroxide accounts for 30% of superoxol total mass.
10. the synthetic method of novel environment friendly chlorine-resistant laking agent according to claim 9, is characterized in that, described superoxol consumption is 10g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610002041.3A CN105504227B (en) | 2016-01-06 | 2016-01-06 | A kind of synthetic method of environmental protection chlorine-resistant color fixing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610002041.3A CN105504227B (en) | 2016-01-06 | 2016-01-06 | A kind of synthetic method of environmental protection chlorine-resistant color fixing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105504227A true CN105504227A (en) | 2016-04-20 |
| CN105504227B CN105504227B (en) | 2019-03-26 |
Family
ID=55712567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610002041.3A Active CN105504227B (en) | 2016-01-06 | 2016-01-06 | A kind of synthetic method of environmental protection chlorine-resistant color fixing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504227B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110735338A (en) * | 2019-11-21 | 2020-01-31 | 东莞市中纺化工有限公司 | Environment-friendly chlorine-resistant color fixing agent, and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1077936C (en) * | 1995-03-18 | 2002-01-16 | 克莱里安特财务(Bvi)有限公司 | Textile dye-fixing agents |
-
2016
- 2016-01-06 CN CN201610002041.3A patent/CN105504227B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1077936C (en) * | 1995-03-18 | 2002-01-16 | 克莱里安特财务(Bvi)有限公司 | Textile dye-fixing agents |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110735338A (en) * | 2019-11-21 | 2020-01-31 | 东莞市中纺化工有限公司 | Environment-friendly chlorine-resistant color fixing agent, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105504227B (en) | 2019-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102720078B (en) | Method for dyeing cotton-dacron-chinlon combined silk fabric | |
| CN102797170A (en) | Formaldehyde-free fixing agent and preparation method thereof | |
| CN103965653B (en) | The compound reactive dye of post-mercerizing and colouring method thereof and purposes | |
| KR100971265B1 (en) | Printing method of polyester fiber / cellulose fiber blend fabric | |
| CN106012584A (en) | Alkaline one-bath-process dyeing method for chinlon 56 fiber/cotton blended fabric | |
| CN110565416A (en) | printing process for flame-retardant fabric with high aramid fiber content | |
| CN109930403B (en) | Printing paste composition for textiles | |
| Cai et al. | Dyeing of jute and jute/cotton blend fabrics with 2: 1 pre-metallised dyes | |
| CN107419512B (en) | A kind of continuous dyeing and finishing technology of blended woven fabric of cotton instrument synthetic fibre | |
| TWI619773B (en) | Acid dye composition and dyeing method using same | |
| KR20060124717A (en) | Reactive dye composition and dyeing method using the same | |
| CN105220538B (en) | The flower dyeing technique of Fypro | |
| CN105504227A (en) | Synthetic method of novel environment-friendly chlorine-resistant color fixing agent | |
| CN109554939B (en) | Indigo dyeing method of polyamide 56 fiber or polyamide 56/cotton blended fabric and product thereof | |
| Tabba et al. | Effect of Cationic Pretreatment on Pigment Printing of Cotton Fabric. | |
| JP6776477B2 (en) | Basic dye composition and dyeing method and dyed product using it | |
| CN104032602B (en) | Anti-REACTIVE DYES staining agent | |
| CN108276801A (en) | A kind of disperse dye composition and its application | |
| CN106752077B (en) | A kind of blue active dye composition and its preparation method and application | |
| Cheek et al. | Relationship between direct dye characteristics and coverage of immature fibre neps in dyed cotton fabric | |
| CN108276800B (en) | A kind of disperse dye composition and its application | |
| CN114561818B (en) | Compounding method of reactive dye yellow suitable for dyeing composite cellulose fiber, product and application thereof | |
| Wang et al. | Superfine pigment dyeing of silk fabric by exhaust process | |
| KR102547981B1 (en) | Dyening method of spurn yarn | |
| CN108192380B (en) | A kind of disperse dye composition and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |