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CN105483391B - Determine the device and method of technological parameter in the esr process of single supply double loop - Google Patents

Determine the device and method of technological parameter in the esr process of single supply double loop Download PDF

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CN105483391B
CN105483391B CN201510911525.5A CN201510911525A CN105483391B CN 105483391 B CN105483391 B CN 105483391B CN 201510911525 A CN201510911525 A CN 201510911525A CN 105483391 B CN105483391 B CN 105483391B
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voltage regulator
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metal sheet
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董艳伍
姜周华
曹海波
侯栋
曹玉龙
徐光�
任陪
李传峥
封乾隆
汤庆飞
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Northeastern University China
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/16Remelting metals
    • C22B9/18Electroslag remelting

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Abstract

本发明提供一种确定单电源双回路电渣重熔过程中工艺参数的装置及方法,所述装置包括绝缘支架、石英烧杯、调压器、金属电极、模拟导电体的导电金属片和模拟底部铜板的导电金属片。方法的工艺步骤为:(1)按照1600~1800℃含氟渣系的电导率参数范围配置导电溶液,装入石英烧杯中,调整导电溶液的液面高度;(2)调整模拟导电体的导电金属片和金属电极在导电溶液中的插入深度;(3)接通电源,调节调压器的电压值10~36V,产生两条通电回路;(4)待数显电压表读数稳定后,记录溶液50~80°C下两个数显电流表的多组电流读数,求取电流分配比的总平均值。

The invention provides a device and method for determining process parameters in the process of electroslag remelting with a single power source and double circuits. Conductive metal sheet of copper plate. The process steps of the method are: (1) configure the conductive solution according to the conductivity parameter range of the fluorine-containing slag system at 1600-1800°C, put it into a quartz beaker, and adjust the liquid level of the conductive solution; (2) adjust the conductivity of the simulated conductor The insertion depth of the metal sheet and the metal electrode in the conductive solution; (3) Turn on the power supply, adjust the voltage value of the voltage regulator to 10~36V, and generate two power circuits; (4) After the reading of the digital display voltmeter is stable, record Multiple sets of current readings of two digital display ammeters at a solution temperature of 50-80°C are used to obtain the total average value of the current distribution ratio.

Description

确定单电源双回路电渣重熔过程中工艺参数的装置及方法Device and method for determining process parameters in single-power supply double-loop electroslag remelting process

技术领域technical field

本发明属于冶金技术领域,具体涉及一种确定单电源双回路电渣重熔过程中工艺参数的装置及方法。The invention belongs to the technical field of metallurgy, and in particular relates to a device and a method for determining process parameters in a single-power supply double-circuit electroslag remelting process.

背景技术Background technique

电渣重熔因其生产的铸锭缩孔、疏松、宏观偏析等缺陷较少,并且具有成分均匀、组织致密以及夹杂物细小弥散分布等特点,因此被广泛的应用于多种材料的终端冶炼工艺。电渣重熔的金属熔池形状和深度直接决定材料的凝固质量,一般“V”字形的金属熔池往往会导致铸锭表面质量不好,并且材料的结晶方向往往为径向结晶,这对凝固质量不利。众多研究者普遍认为,“U”字形的金属熔池对铸锭表面质量和内部质量的控制更为有利。然而,电渣重熔过程金属熔池的控制往往受到电流、电极插入深度、渣池高度等工艺参数的影响。Electroslag remelting is widely used in the terminal smelting of various materials because of its less defects such as shrinkage cavity, porosity and macro segregation in the ingot produced, and it has the characteristics of uniform composition, compact structure and fine dispersion of inclusions. craft. The shape and depth of the electroslag remelting metal pool directly determine the solidification quality of the material. Generally, a "V"-shaped metal pool often leads to poor surface quality of the ingot, and the crystallization direction of the material is often radial crystallization, which has great influence on the quality of the material. The coagulation quality is unfavorable. Many researchers generally believe that the "U"-shaped molten metal pool is more beneficial to the control of the surface quality and internal quality of the ingot. However, the control of the molten metal pool in the electroslag remelting process is often affected by process parameters such as current, electrode insertion depth, and slag pool height.

电流电压过高,渣温升高,元素的氧化加重;电压过高,电极埋入渣池的深度减小,增加电极的氧化,使钢中的夹杂物数量增加;合适的电流有利于形成良好表面质量的铸锭,但电流过大会使电压过低,电极插入渣池太深,造成渣池表面的温度太低,反而不利于表面质量的控制。If the current and voltage are too high, the temperature of the slag will increase, and the oxidation of the elements will increase; if the voltage is too high, the depth of the electrode buried in the slag pool will decrease, which will increase the oxidation of the electrode and increase the number of inclusions in the steel; a suitable current is conducive to the formation of a good Surface quality of the ingot, but if the current is too high, the voltage will be too low, and the electrode will be inserted too deep into the slag pool, causing the surface temperature of the slag pool to be too low, which is not conducive to the control of the surface quality.

Holly学者曾经指出,为了获得良好的电渣钢锭表面质量,需要金属熔池具有圆柱段高度10mm以上。由于电渣重熔过程中大部分电流在渣池中都是在渣金界面的中心区域通过的,而渣金界面靠近结晶器内壁的位置电流很小,这就会导致这个区域焦耳生热率很低,金属熔池成“V”形,使渣金界面靠近结晶器内壁位置基本不能获得圆柱段。综上,传统的电渣重熔过程工艺参数设置不合理,就无法获得金属熔池的圆柱段高度。究其原因是传统的电渣重熔过程,电流主要集中于自耗电极下方,导致渣金界面结晶器内壁位置渣池发热量不足。因此,良好的铸锭表面质量和浅平状的金属熔池很难同时实现。Scholars Holly once pointed out that in order to obtain good surface quality of electroslag steel ingots, it is necessary for the molten metal pool to have a cylindrical section height of more than 10 mm. Since most of the current in the electroslag remelting process passes through the central area of the slag-gold interface in the slag pool, and the current is very small at the position where the slag-gold interface is close to the inner wall of the crystallizer, this will cause the Joule heat generation rate in this area It is very low, and the metal molten pool is in a "V" shape, so that the slag-gold interface is close to the inner wall of the crystallizer, and it is basically impossible to obtain a cylindrical section. In summary, if the process parameters of the traditional electroslag remelting process are set unreasonably, the height of the cylindrical section of the molten metal pool cannot be obtained. The reason is that in the traditional electroslag remelting process, the current is mainly concentrated under the consumable electrode, resulting in insufficient calorific value of the slag pool at the inner wall of the crystallizer at the slag-gold interface. Therefore, it is difficult to achieve good ingot surface quality and shallow metal molten pool at the same time.

采用导电结晶器的电渣重熔过程,不仅具有传统电渣重熔系统的电流回路:变压器→自耗电极→渣池→金属熔池→底水箱→变压器,而且还具有靠近结晶器侧的电流回路:变压器→导电结晶器→渣池→金属熔池→底水箱→变压器。导电结晶器侧的电路供电为渣金界面圆周位置提供了更大的电流密度,有利于结晶器内壁周围渣池的生成热传递给金属熔池,从而有利于获得比较理想的“U”字形的金属熔池,进而有利于得到结晶质量良好的电渣铸锭。The electroslag remelting process using a conductive crystallizer not only has the current loop of the traditional electroslag remelting system: transformer→consumable electrode→slag pool→metal molten pool→bottom water tank→transformer, but also has a circuit close to the mold side Current loop: transformer→conductive crystallizer→slag pool→metal molten pool→bottom water tank→transformer. The circuit power supply on the side of the conductive crystallizer provides a greater current density for the circumferential position of the slag-gold interface, which is conducive to the transfer of heat generated by the slag pool around the inner wall of the mold to the molten metal pool, thereby helping to obtain an ideal "U" shape. The molten metal pool is conducive to obtaining electroslag ingots with good crystallization quality.

文献(Investigation of the implications of the current conductive moldtechnology with respect to the internal and surface quality of ESR ingots,Liquid Metal Processing and Casting 2011, 57-64.)提出了一种采用双电源双回路导电结晶器冶炼X12CrNiMoV钢的方法,并指出采用导电结晶器双电源双回路进行冶炼后,金属熔池成“U”形;元素的偏析程度降低,且当电流的分配比为1:1,且熔速较快的情况下,铸锭的表面质量最好。但双电源双回路的两个电源在处理过程很容易发生相互干扰而影响最终的实施效果。而单电源双回路不仅能够达到双电源双回路的冶炼效果,而且只是用一个变压器供电,因此有利于国内现有电渣炉技术的改造。但采用单电源双回路供电后,两条回路的电流分配情况以及总回路工艺参数将存在一定的依赖关系,如果电流分配比不合理,所冶炼铸锭的表面质量和凝固质量均较差。对于合适的电流分配,铸锭的表面质量和内部凝固质量均能够得到较大的提高。如果采用真正的电渣炉摸索这种依赖关系,则需要浪费大量的人力物力。The literature (Investigation of the implications of the current conductive moldtechnology with respect to the internal and surface quality of ESR ingots, Liquid Metal Processing and Casting 2011, 57-64.) proposed a method of smelting X12CrNiMoV steel using a dual-power supply and double-circuit conductive mold method, and pointed out that after smelting with a conductive crystallizer with dual power sources and dual circuits, the molten metal pool will form a "U" shape; the degree of segregation of elements will be reduced, and when the current distribution ratio is 1:1 and the melting rate is faster Below, the surface quality of the ingot is the best. However, the two power sources of the dual power source and the dual circuit are likely to interfere with each other during the processing process and affect the final implementation effect. The single power supply and double circuit can not only achieve the smelting effect of dual power supply and double circuit, but also only use a transformer for power supply, so it is beneficial to the transformation of the existing domestic electroslag furnace technology. However, after using single power supply and double circuit power supply, there will be a certain dependence on the current distribution of the two circuits and the process parameters of the total circuit. If the current distribution ratio is unreasonable, the surface quality and solidification quality of the smelted ingot will be poor. With proper current distribution, both the surface quality and the internal solidification quality of the ingot can be greatly improved. If a real electroslag furnace is used to explore this dependency, a lot of manpower and material resources will be wasted.

CN104330411公开了一种动态观测模拟电渣重熔过程熔滴行为的装置,该装置可模拟传统单电源单回路电渣重熔过程中熔滴滴落过程,并未考虑导电结晶器对电渣重熔过程的作用,且未考虑导电溶液液面高度的影响。CN104330411 discloses a device for dynamically observing and simulating the droplet behavior in the electroslag remelting process. The device can simulate the droplet dripping process in the traditional single-power single-circuit electroslag remelting process, and does not consider the impact of the conductive crystallizer on the electroslag remelting process. The effect of the melting process is not considered, and the influence of the height of the conductive solution is not considered.

发明内容Contents of the invention

针对现有技术存在的问题,本发明提供一种确定单电源双回路电渣重熔过程中工艺参数的装置及方法,所述装置及方法采用物理模拟实际单电源双回路电渣重熔生产过程的熔炼体系,确定其中的渣池高度、电极插入深度、电流分配比等主要工艺参数,为实际生产过程提供有利参考。本发明的技术方案如下:Aiming at the problems existing in the prior art, the present invention provides a device and method for determining process parameters in the process of single-power supply double-circuit electroslag remelting. The device and method adopt physical simulation of the actual single-power supply double-circuit electroslag remelting production process The main process parameters such as slag pool height, electrode insertion depth, and current distribution ratio are determined to provide a favorable reference for the actual production process. Technical scheme of the present invention is as follows:

一种确定单电源双回路电渣重熔过程中工艺参数的装置,包括绝缘支架、石英烧杯、调压器、金属电极、模拟导电体的导电金属片和模拟底部铜板的导电金属片;绝缘支架上设有支撑平台,石英烧杯和用于测量导电溶液高度及金属电极插入导电溶液深度的刻度尺位于支撑平台上;金属电极上部通过导线与调压器的一极相连,下部浸入至石英烧杯内部的导电溶液中;模拟导电体的导电金属片形状为环形,固定于石英烧杯内壁上,并部分浸入导电溶液中,模拟导电体的导电金属片暴漏在导电溶液外的部分通过导线与调压器的一极相连;模拟底部铜板的导电金属片设置在石英烧杯底部,通过导线与调压器的另一极相连。A device for determining process parameters in the process of electroslag remelting with a single power supply and double loops, including an insulating support, a quartz beaker, a voltage regulator, a metal electrode, a conductive metal sheet simulating a conductor, and a conductive metal sheet simulating a bottom copper plate; the insulating support There is a support platform on the top, the quartz beaker and the scale used to measure the height of the conductive solution and the depth of the metal electrode inserted into the conductive solution are located on the support platform; the upper part of the metal electrode is connected to one pole of the voltage regulator through a wire, and the lower part is immersed in the inside of the quartz beaker In the conductive solution; the conductive metal sheet of the simulated conductor is ring-shaped, fixed on the inner wall of the quartz beaker, and partially immersed in the conductive solution, and the part of the conductive metal sheet of the simulated conductor exposed to the conductive solution is passed through the wire and the voltage regulator. Connected to one pole of the voltage regulator; the conductive metal sheet simulating the bottom copper plate is set at the bottom of the quartz beaker, and connected to the other pole of the voltage regulator through a wire.

所述装置中,还设有温度计,插入石英烧杯内部的导电溶液中。In the device, a thermometer is also provided, which is inserted into the conductive solution inside the quartz beaker.

所述装置中,还设有数显电压表,且数显电压表与调压器并联。In the device, a digital display voltmeter is also provided, and the digital display voltmeter is connected in parallel with the voltage regulator.

所述装置中,还设有数显电流表,数量为2,分别位于模拟导电体的导电金属片与调压器连接的导线上以及金属电极与调压器连接的导线上。In the device, there are also two digital display ammeters, which are respectively located on the wire connecting the conductive metal sheet of the analog conductor and the voltage regulator and on the wire connecting the metal electrode and the voltage regulator.

所述装置中,金属电极以及模拟导电体的导电金属片与调压器的同一极连接。In the device, the metal electrode and the conductive metal sheet simulating a conductor are connected to the same pole of the voltage regulator.

所述装置中,金属电极的尺寸与石英烧杯的尺寸关系按照电渣重熔过程中直径充填比的要求设置。In the device, the relationship between the size of the metal electrode and the size of the quartz beaker is set according to the requirement of the diameter filling ratio in the electroslag remelting process.

所述装置中,金属电极的材质为伍德合金、不锈钢,用于模拟电极。In the device, the metal electrode is made of Wood's alloy or stainless steel, which is used to simulate the electrode.

所述装置中,导电金属片的材质选用不和导电溶液起反应的金属材料,包括钼片、铜片、镍片、锡片和铂片,用于模拟导电体。In the device, the material of the conductive metal sheet is selected from metal materials that do not react with the conductive solution, including molybdenum sheet, copper sheet, nickel sheet, tin sheet and platinum sheet, which are used to simulate the conductor.

所述的调压器为接触式自耦调压器。The voltage regulator is a contact type auto-coupling voltage regulator.

采用所述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the device to determine the process parameters in the process of single-power double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1600~1800℃含氟渣系的电导率参数范围配置导电溶液,并将导电溶液装入石英烧杯中,调整导电溶液的液面高度在30~60mm;(1) Configure the conductive solution according to the conductivity parameter range of the fluorine-containing slag system at 1600~1800°C, put the conductive solution into a quartz beaker, and adjust the liquid level of the conductive solution to be 30~60mm;

(2)调整模拟导电体的导电金属片在导电溶液中的插入深度在5~20mm,以及金属电极在导电溶液中的插入深度在5~10mm;(2) Adjust the insertion depth of the conductive metal sheet of the simulated conductor in the conductive solution to 5~20mm, and the insertion depth of the metal electrode in the conductive solution to 5~10mm;

(3)接通电源,调节调压器的电压值在10~36V,金属电极、导电溶液、模拟底部铜板的导电金属片和调压器以及模拟导电体的导电金属片、导电溶液、模拟底部铜板的导电金属片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10~36V, metal electrodes, conductive solution, conductive metal sheet and voltage regulator that simulate the bottom copper plate, and conductive metal sheets that simulate conductors, conductive solution, and simulate the bottom The conductive metal sheet of the copper plate and the voltage regulator form two energized circuits;

(4)待数显电压表读数稳定后,记录在50~80℃下两个数显电流表的多组电流示数,并分别得到相应温度下双回路的电流分配比,求取电流分配比的总平均值。(4) After the reading of the digital display voltmeter is stable, record multiple sets of current readings of the two digital display ammeters at 50~80°C, and obtain the current distribution ratio of the double circuit at the corresponding temperature, and calculate the current distribution ratio overall average.

所述方法中,导电溶液为氯化钠溶液或氯化钾溶液,浓度为0.1221~0.4884mol/L。In the method, the conductive solution is sodium chloride solution or potassium chloride solution, and the concentration is 0.1221-0.4884mol/L.

所述方法中,通过调节导电溶液在石英烧杯中的液面高度来模拟电渣重熔的渣池高度。In the method, the height of the slag pool of electroslag remelting is simulated by adjusting the liquid level height of the conductive solution in the quartz beaker.

所述方法中,通过导电溶液自身的电阻加热导电溶液至不同的温度,使导电溶液的电导率同电渣重熔高温熔渣电导率相匹配的情况下,得到双回路的功率分配情况。In the method, the conductive solution is heated to different temperatures through the resistance of the conductive solution itself, so that the conductivity of the conductive solution matches the conductivity of the electroslag remelting high-temperature slag, and the power distribution of the double circuit is obtained.

所述方法中,根据步骤(4)获得的电流分配比例、导电溶液的高度、电极充填比以及模拟导电体的导电金属片插入导电溶液的深度,进而推导出工业上电渣重熔过程中在一定充填比的前提下,适合此结晶器进行冶炼的其他工艺参数。In the method, according to the current distribution ratio obtained in step (4), the height of the conductive solution, the electrode filling ratio, and the depth of the conductive metal sheet simulating the conductor inserted into the conductive solution, the industrial electroslag remelting process is deduced at Under the premise of a certain filling ratio, other process parameters suitable for smelting in this crystallizer.

本发明的有益效果:本发明利用可视化的微型单电源双回路电渣重熔模拟系统对工业生产上电渣重熔过程中的电流分配比、电极插入深度、导电溶液高度、导电体插入深度进行探索,并且本发明系统所采用的氯化钠或氯化钾导电溶液,与1600~1800℃含氟渣系的电导率参数范围相近,实现了实验室范围的电渣重熔冶炼过程模拟,可以有效获得适合大型单电源双回路电渣重熔的冶炼工艺参数。Beneficial effects of the present invention: the present invention utilizes a visualized miniature single-power supply double-loop electroslag remelting simulation system to carry out the current distribution ratio, electrode insertion depth, conductive solution height, and conductor insertion depth in the electroslag remelting process in industrial production. Exploration, and the sodium chloride or potassium chloride conductive solution used in the system of the present invention is similar to the conductivity parameter range of the fluorine-containing slag system at 1600~1800 ° C, and the simulation of the electroslag remelting smelting process in the laboratory range is realized, which can Effectively obtain smelting process parameters suitable for large-scale single-power double-circuit electroslag remelting.

附图说明Description of drawings

图1为本发明实施例1的确定单电源双回路电渣重熔过程中工艺参数的装置的结构示意图;其中1、绝缘支架,2、横梁、3温度计,4、模拟导电体的钼片,5、石英烧杯,6、模拟底部铜板的钼片,7、支撑平台,8、刻度尺,9、模拟熔渣的导电溶液,10和11、数显电流表,12、接触式自耦调压器,13、数显电压表,14、伍德合金电极;Fig. 1 is the structural representation of the device for determining the process parameters in the double-loop electroslag remelting process of the embodiment of the present invention 1; Wherein 1, insulating support, 2, crossbeam, 3 thermometer, 4, the molybdenum sheet of simulation conductor, 5. Quartz beaker, 6. Molybdenum sheet simulating the bottom copper plate, 7. Support platform, 8. Scale, 9. Conductive solution simulating slag, 10 and 11. Digital display ammeter, 12. Contact autovoltage regulator , 13. Digital voltmeter, 14. Wood metal electrode;

图2为本发明装置的电路原理图,其中A1和A2表示电流表,V表示电压表,R表示电阻。Fig. 2 is the schematic circuit diagram of the device of the present invention, wherein A1 and A2 represent the ammeter, V represents the voltmeter, and R represents the resistance.

具体实施方式detailed description

本发明实施例中采用的接触式自耦调压器型号为德力西TDGC2-3KVA系列调压器。The model of the contact auto-coupling voltage regulator used in the embodiment of the present invention is Delixi TDGC2-3KVA series voltage regulator.

实施例1Example 1

一种确定单电源双回路电渣重熔过程中工艺参数的装置,包括绝缘支架1、温度计3、石模拟导电体的钼片4、石英烧杯5、模拟底部铜板的钼片6、数显电流表10和11、接触式自耦调压器12、数显电压表13、以及伍德合金电极14;绝缘支架2上设有悬挂金属电极的横梁2和支撑平台7;石英烧杯5的直径为80mm,其和用于测量导电溶液高度及金属电极插入导电溶液深度的刻度尺8位于支撑平台7上;温度计3插入石英烧杯5内部的导电溶液中;模拟导电体的钼片4形状为环形,固定于石英烧杯内壁上,并部分浸入导电溶液中,模拟导电体的钼片4暴漏在导电溶液外的部分通过导线与接触式自耦调压器12的一极相连;模拟底部铜板的钼片6设置在石英烧杯5底部,通过导线与接触式自耦调压器12的另一极相连;数显电流表10和11分别位于模拟导电体的钼片4与接触式自耦调压器13连接的导线上以及伍德合金电极14与接触式自耦调压器12连接的导线上;数显电压表13与接触式自耦调压器12并联;伍德合金电极14上部通过导线与接触式自耦调压器12的一极相连,下部浸入至石英烧杯5内部的导电溶液中,且伍德合金电极14以及模拟导电体的钼片4与接触式自耦调压器12的同一极连接。A device for determining process parameters in the process of single-power double-circuit electroslag remelting, including an insulating support 1, a thermometer 3, a stone molybdenum sheet 4 simulating a conductor, a quartz beaker 5, a molybdenum sheet 6 simulating a bottom copper plate, and a digital display ammeter 10 and 11, contact-type autovoltage regulator 12, digital display voltmeter 13, and Wood metal electrode 14; insulating support 2 is provided with crossbeam 2 and support platform 7 for hanging metal electrodes; the diameter of quartz beaker 5 is 80mm, It and the scale 8 used to measure the height of the conductive solution and the depth of the metal electrode inserted into the conductive solution are located on the support platform 7; the thermometer 3 is inserted into the conductive solution inside the quartz beaker 5; the molybdenum sheet 4 of the simulated conductor is annular in shape and fixed on On the inner wall of the quartz beaker, and partially immersed in the conductive solution, the part of the molybdenum sheet 4 simulating the conductor exposed to the conductive solution is connected to one pole of the contact autovoltage regulator 12 through a wire; the molybdenum sheet 6 simulating the bottom copper plate It is arranged at the bottom of the quartz beaker 5 and is connected to the other pole of the contact autovoltage regulator 12 through a wire; the digital display ammeters 10 and 11 are respectively located at the places where the molybdenum sheet 4 of the analog conductor is connected to the contact autovoltage regulator 13 On the wire and on the wire connected between the Wood metal electrode 14 and the contact type auto-coupling voltage regulator 12; the digital display voltmeter 13 is connected in parallel with the contact type auto-coupling voltage regulator 12; One pole of the voltage regulator 12 is connected, the lower part is immersed in the conductive solution inside the quartz beaker 5, and the Wood metal electrode 14 and the molybdenum sheet 4 simulating a conductor are connected to the same pole of the contact autovoltage regulator 12.

上述装置中,充填比设置为0.5。In the above device, the filling ratio is set to 0.5.

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1700℃含氟渣系的电导率参数范围配置浓度为0.1221mol/L的氯化钠溶液,并将氯化钠溶液装入石英烧杯中,调整氯化钠溶液的液面高度在40mm;(1) Configure a sodium chloride solution with a concentration of 0.1221mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1700°C, put the sodium chloride solution into a quartz beaker, and adjust the liquid level of the sodium chloride solution at 40mm;

(2)调整模拟导电体的钼片在导电溶液中的插入深度在20mm,以及金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm;(2) Adjust the insertion depth of the molybdenum sheet of the simulated conductor in the conductive solution to 20mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm respectively;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的钼片和调压器以及模拟导电体的钼片、导电溶液、模拟底部铜板的钼片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator to 10V, the metal electrode, the conductive solution, the molybdenum sheet simulating the bottom copper plate and the voltage regulator, and the molybdenum sheet simulating the conductor, the conductive solution, and the molybdenum sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.205、1.276和1.884,根据电流分配比例,电极充填比0.5,导电溶液的高度40mm,模拟导电体的钼片插入导电溶液的深度20mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.5的前提下的其他工艺参数。According to the current readings in step (4), the total average values of the current distribution ratios of the two circuits when the insertion depths of the metal electrodes in the conductive solution are 5mm, 7mm and 8.5mm are 1.205, 1.276 and 1.884 respectively. According to the current distribution ratio , the electrode filling ratio is 0.5, the height of the conductive solution is 40mm, and the molybdenum sheet of the simulated conductor is inserted into the conductive solution to a depth of 20mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.5 other process parameters.

实施例2Example 2

本实施例的装置同实施例1,区别点在于:导电金属片为镍片,充填比为0.6;The device of this embodiment is the same as that of Embodiment 1, the difference is that: the conductive metal sheet is a nickel sheet, and the filling ratio is 0.6;

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1700℃含氟渣系的电导率参数范围配置浓度为0.1221mol/L的氯化钠溶液,并将氯化钠溶液装入石英烧杯中,调整氯化钠溶液的液面高度在40mm;(1) Configure a sodium chloride solution with a concentration of 0.1221mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1700°C, put the sodium chloride solution into a quartz beaker, and adjust the liquid level of the sodium chloride solution at 40mm;

(2)调整模拟导电体的镍片在导电溶液中的插入深度在20mm,以及金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm;(2) Adjust the insertion depth of the nickel sheet of the simulated conductor in the conductive solution to 20mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm respectively;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的镍片和调压器以及模拟导电体的镍片、导电溶液、模拟底部铜板的镍片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10V, metal electrodes, conductive solution, nickel sheet simulating the bottom copper plate and voltage regulator, and nickel sheet simulating conductors, conductive solution, and nickel sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.414、1.584和1.741,根据电流分配比例,电极充填比0.6,导电溶液的高度40mm,模拟导电体的镍片插入导电溶液的深度20mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.6的前提下的其他工艺参数。According to the current readings in step (4), the total average values of the current distribution ratios of the two circuits when the insertion depths of the metal electrodes in the conductive solution are 5mm, 7mm and 8.5mm are 1.414, 1.584 and 1.741, respectively. According to the current distribution ratio , the electrode filling ratio is 0.6, the height of the conductive solution is 40mm, and the depth of the nickel sheet simulating the conductor inserted into the conductive solution is 20mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.6 other process parameters.

实施例3Example 3

本实施例的装置同实施例1,区别点在于:电极为不锈钢电极,导电金属片为铂片,充填比为0.7;The device of this embodiment is the same as that of Embodiment 1, the difference is that the electrode is a stainless steel electrode, the conductive metal sheet is a platinum sheet, and the filling ratio is 0.7;

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1700℃含氟渣系的电导率参数范围配置浓度为0.1221mol/L的氯化钠溶液,并将氯化钠溶液装入石英烧杯中,调整氯化钠溶液的液面高度在40mm;(1) Configure a sodium chloride solution with a concentration of 0.1221mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1700°C, put the sodium chloride solution into a quartz beaker, and adjust the liquid level of the sodium chloride solution at 40mm;

(2)调整模拟导电体的铂片在导电溶液中的插入深度在20mm,以及金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm;(2) Adjust the insertion depth of the platinum sheet of the simulated conductor in the conductive solution to 20mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm respectively;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的铂片和调压器以及模拟导电体的铂片、导电溶液、模拟底部铜板的铂片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10V, metal electrodes, conductive solution, platinum sheet simulating the bottom copper plate and voltage regulator, platinum sheet simulating conductor, conductive solution, and platinum sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.884、2.065和2.227,根据电流分配比例,电极充填比0.7,导电溶液的高度40mm,模拟导电体的铂片插入导电溶液的深度20mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.7的前提下的其他工艺参数。According to the current reading in step (4), the total average values of the current distribution ratios of the two loops when the insertion depths of the metal electrodes in the conductive solution are 5mm, 7mm and 8.5mm are 1.884, 2.065 and 2.227 respectively. According to the current distribution ratio , the electrode filling ratio is 0.7, the height of the conductive solution is 40mm, and the depth of the platinum sheet of the simulated conductor inserted into the conductive solution is 20mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.7 other process parameters.

实施例4Example 4

本实施例的装置同实施例2;The device of this embodiment is the same as embodiment 2;

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1700℃含氟渣系的电导率参数范围配置浓度为0.1221mol/L的氯化钠溶液,并将氯化钠溶液装入石英烧杯中,调整氯化钠溶液的液面高度在40mm;(1) Configure a sodium chloride solution with a concentration of 0.1221mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1700°C, put the sodium chloride solution into a quartz beaker, and adjust the liquid level of the sodium chloride solution at 40mm;

(2)调整模拟导电体的镍片在导电溶液中的插入深度在10mm,以及金属电极在导电溶液中的插入深度为5mm、7mm和8,5mm;(2) Adjust the insertion depth of the nickel sheet simulating the conductor in the conductive solution to 10mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的镍片和调压器以及模拟导电体的镍片、导电溶液、模拟底部铜板的镍片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10V, metal electrodes, conductive solution, nickel sheet simulating the bottom copper plate and voltage regulator, and nickel sheet simulating conductors, conductive solution, and nickel sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.527、1.736和1.941,根据电流分配比例,电极充填比0.6,导电溶液的高度40mm,模拟导电体的镍片插入导电溶液的深度10mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.6的前提下的其他工艺参数。According to the current readings in step (4), the total average values of the current distribution ratios of the two circuits when the metal electrodes are inserted into the conductive solution are 5mm, 7mm and 8.5mm are respectively 1.527, 1.736 and 1.941. According to the current distribution ratio , the electrode filling ratio is 0.6, the height of the conductive solution is 40mm, and the depth of the nickel sheet simulating the conductor inserted into the conductive solution is 10mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.6 other process parameters.

实施例5Example 5

本实施例的装置同实施例2,区别点在于:导电金属片为锡片;The device of this embodiment is the same as embodiment 2, the difference is that: the conductive metal sheet is a tin sheet;

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1700℃含氟渣系的电导率参数范围配置浓度为0.1221mol/L的氯化钠溶液,并将氯化钠溶液装入石英烧杯中,调整氯化钠溶液的液面高度在30mm;(1) Configure a sodium chloride solution with a concentration of 0.1221mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1700°C, put the sodium chloride solution into a quartz beaker, and adjust the liquid level of the sodium chloride solution at 30mm;

(2)调整模拟导电体的锡片在导电溶液中的插入深度在20mm,以及金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm;(2) Adjust the insertion depth of the tin sheet of the simulated conductor in the conductive solution to 20mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm respectively;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的锡片和调压器以及模拟导电体的锡片、导电溶液、模拟底部铜板的锡片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10V, metal electrodes, conductive solution, tin sheet simulating the bottom copper plate and voltage regulator, and tin sheet simulating conductors, conductive solution, and tin sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.613、1.766和1.935,根据电流分配比例,电极充填比0.6,导电溶液的高度30mm,模拟导电体的锡片插入导电溶液的深度20mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.6的前提下的其他工艺参数。According to the current readings in step (4), the total average values of the current distribution ratios of the two circuits when the insertion depths of the metal electrodes in the conductive solution are 5mm, 7mm and 8.5mm are 1.613, 1.766 and 1.935, respectively. According to the current distribution ratio , the electrode filling ratio is 0.6, the height of the conductive solution is 30mm, and the depth of the tin sheet of the simulated conductor inserted into the conductive solution is 20mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.6 other process parameters.

实施例6Example 6

本实施例的装置同实施例2,区别点在于:导电金属片为铜片;The device of this embodiment is the same as embodiment 2, the difference is that: the conductive metal sheet is a copper sheet;

采用上述装置确定单电源双回路电渣重熔过程中工艺参数的方法,按照以下工艺步骤进行:The method of using the above-mentioned device to determine the process parameters in the process of single-power supply and double-circuit electroslag remelting is carried out according to the following process steps:

(1)按照1800℃含氟渣系的电导率参数范围配置浓度为0.4884mol/L的氯化钾溶液,并将氯化钾溶液装入石英烧杯中,调整氯化钾溶液的液面高度在40mm;(1) Configure a potassium chloride solution with a concentration of 0.4884mol/L according to the conductivity parameter range of the fluorine-containing slag system at 1800°C, put the potassium chloride solution into a quartz beaker, and adjust the liquid level of the potassium chloride solution at 40mm;

(2)调整模拟导电体的铜片在导电溶液中的插入深度在20mm,以及金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm;(2) Adjust the insertion depth of the copper sheet of the simulated conductor in the conductive solution to 20mm, and the insertion depth of the metal electrode in the conductive solution to 5mm, 7mm and 8.5mm respectively;

(3)接通电源,调节调压器的电压值在10V,金属电极、导电溶液、模拟底部铜板的铜片和调压器以及模拟导电体的铜片、导电溶液、模拟底部铜板的铜片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator to 10V, the metal electrode, the conductive solution, the copper sheet simulating the bottom copper plate and the voltage regulator, and the copper sheet simulating the conductor, the conductive solution, and the copper sheet simulating the bottom copper plate and the voltage regulator constitute two energization circuits;

(4)待数显电压表读数稳定后,记录在50℃、55℃、60℃、65℃、70℃、75℃和80℃下,两个数显电流表在相同温度下的多组电流示数。(4) After the reading of the digital display voltmeter is stable, record the current display of two digital display ammeters at the same temperature at 50°C, 55°C, 60°C, 65°C, 70°C, 75°C and 80°C. number.

根据步骤(4)的电流读数获得两条回路在金属电极在导电溶液中的插入深度分别为5mm、7mm和8.5mm时的电流分配比总平均值分别为1.472、1.639和1.857,根据电流分配比例,电极充填比0.6,导电溶液的高度40mm,模拟导电体的铜片插入导电溶液的深度20mm,进而可以推导出工业上电渣重熔过程中适合在结晶器的直径充填比为0.6的前提下的其他工艺参数。According to the current readings in step (4), the total average values of the current distribution ratios of the two circuits when the insertion depths of the metal electrodes in the conductive solution are 5mm, 7mm and 8.5mm are 1.472, 1.639 and 1.857, respectively. According to the current distribution ratio , the electrode filling ratio is 0.6, the height of the conductive solution is 40mm, and the depth of the copper sheet of the simulated conductor inserted into the conductive solution is 20mm, and then it can be deduced that the industrial electroslag remelting process is suitable for the premise that the diameter filling ratio of the crystallizer is 0.6 other process parameters.

Claims (2)

1.确定单电源双回路电渣重熔过程中工艺参数的方法,采用的装置包括绝缘支架、石英烧杯、调压器、金属电极、模拟导电体的导电金属片和模拟底部铜板的导电金属片;绝缘支架上设有支撑平台,石英烧杯和用于测量导电溶液高度及金属电极插入导电溶液深度的刻度尺位于支撑平台上;金属电极上部通过导线与调压器的一极相连,下部浸入至石英烧杯内部的导电溶液中;模拟导电体的导电金属片形状为环形,固定于石英烧杯内壁上,并部分浸入导电溶液中,模拟导电体的导电金属片暴漏在导电溶液外的部分通过导线与调压器的一极相连;模拟底部铜板的导电金属片设置在石英烧杯底部,通过导线与调压器的另一极相连;所述金属电极以及模拟导电体的导电金属片与调压器的同一极连接;所述装置还设有温度计、数显电压表和2个数显电流表,所述温度计插入石英烧杯内部的导电溶液中;所述数显电压表与调压器并联;所述2个数显电流表分别位于模拟导电体的导电金属片与调压器连接的导线上以及金属电极与调压器连接的导线上;其特征在于所述方法按照以下工艺步骤进行:1. The method of determining the process parameters in the process of single-power supply and double-loop electroslag remelting, the device used includes insulating support, quartz beaker, voltage regulator, metal electrode, conductive metal sheet simulating conductor and conductive metal sheet simulating bottom copper plate The insulating support is provided with a supporting platform, and the quartz beaker and the scale used to measure the height of the conductive solution and the depth of the metal electrode inserted into the conductive solution are located on the supporting platform; the upper part of the metal electrode is connected to one pole of the voltage regulator through a wire, and the lower part is immersed in the In the conductive solution inside the quartz beaker; the conductive metal sheet of the simulated conductor is ring-shaped, fixed on the inner wall of the quartz beaker, and partially immersed in the conductive solution, and the part of the conductive metal sheet of the simulated conductor exposed outside the conductive solution passes through the wire Connected to one pole of the voltage regulator; the conductive metal sheet simulating the bottom copper plate is set at the bottom of the quartz beaker, and connected to the other pole of the voltage regulator through a wire; the metal electrode and the conductive metal sheet simulating the conductor are connected to the voltage regulator The same pole is connected; the device is also provided with a thermometer, a digital display voltmeter and 2 digital display ammeters, and the thermometer is inserted into the conductive solution inside the quartz beaker; the digital display voltmeter is connected in parallel with the voltage regulator; the The two digital display ammeters are respectively located on the wires connecting the conductive metal sheet of the analog conductor and the voltage regulator and on the wires connecting the metal electrode and the voltage regulator; it is characterized in that the method is carried out according to the following process steps: (1)按照1600~1800℃含氟渣系的电导率参数范围配置导电溶液,并将导电溶液装入石英烧杯中,调整导电溶液的液面高度在30~60mm;(1) Configure the conductive solution according to the conductivity parameter range of the fluorine-containing slag system at 1600-1800°C, put the conductive solution into a quartz beaker, and adjust the liquid level of the conductive solution to be 30-60mm; (2)调整模拟导电体的导电金属片在导电溶液中的插入深度在5~20mm,以及金属电极在导电溶液中的插入深度在5~10mm;(2) Adjust the insertion depth of the conductive metal sheet of the simulated conductor in the conductive solution to be 5-20 mm, and the insertion depth of the metal electrode in the conductive solution to be 5-10 mm; (3)接通电源,调节调压器的电压值在10~36V,金属电极、导电溶液、模拟底部铜板的导电金属片和调压器以及模拟导电体的导电金属片、导电溶液、模拟底部铜板的导电金属片和调压器构成两条通电回路;(3) Turn on the power supply, adjust the voltage value of the voltage regulator at 10 ~ 36V, metal electrodes, conductive solution, conductive metal sheet and voltage regulator simulating the bottom copper plate, and conductive metal sheet simulating conductors, conductive solution, and simulating the bottom The conductive metal sheet of the copper plate and the voltage regulator form two energized circuits; (4)待数显电压表读数稳定后,记录在50~80℃下两个数显电流表的多组电流示数,并分别得到相应温度下双回路的电流分配比,求取电流分配比的总平均值。(4) After the reading of the digital display voltmeter is stable, record the multiple sets of current readings of the two digital display ammeters at 50-80°C, and obtain the current distribution ratio of the double circuit at the corresponding temperature, and calculate the current distribution ratio overall average. 2.根据权利要求1所述的确定单电源双回路电渣重熔过程中工艺参数的方法,其特征在于所述导电溶液为氯化钠溶液或氯化钾溶液,浓度为0.1221~0.4884mol/L。2. The method for determining process parameters in the single-power supply double-circuit electroslag remelting process according to claim 1, characterized in that the conductive solution is sodium chloride solution or potassium chloride solution, and the concentration is 0.1221~0.4884mol/ L.
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