CN105462522B - A kind of hook adhesive and the hook comprising the adhesive and its application - Google Patents
A kind of hook adhesive and the hook comprising the adhesive and its application Download PDFInfo
- Publication number
- CN105462522B CN105462522B CN201510943401.5A CN201510943401A CN105462522B CN 105462522 B CN105462522 B CN 105462522B CN 201510943401 A CN201510943401 A CN 201510943401A CN 105462522 B CN105462522 B CN 105462522B
- Authority
- CN
- China
- Prior art keywords
- hook
- adhesive
- parts
- foaming body
- polyurethane foaming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 82
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 82
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- -1 hydroxypropyl Chemical group 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920006026 co-polymeric resin Polymers 0.000 claims abstract description 10
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 claims abstract description 10
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 239000013530 defoamer Substances 0.000 claims abstract description 4
- 239000004814 polyurethane Substances 0.000 claims description 45
- 229920002635 polyurethane Polymers 0.000 claims description 45
- 238000005187 foaming Methods 0.000 claims description 44
- 239000011159 matrix material Substances 0.000 claims description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical group OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000010422 painting Methods 0.000 claims 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 238000004026 adhesive bonding Methods 0.000 abstract description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- BPOZNMOEPOHHSC-UHFFFAOYSA-N butyl prop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCCCOC(=O)C=C BPOZNMOEPOHHSC-UHFFFAOYSA-N 0.000 description 8
- 230000009172 bursting Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- 229940008099 dimethicone Drugs 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- SDNVJMZXSOXXQN-UHFFFAOYSA-N 3,4-ditert-butyl-2-methylphenol Chemical compound CC1=C(O)C=CC(C(C)(C)C)=C1C(C)(C)C SDNVJMZXSOXXQN-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of hook adhesive and the hook comprising the adhesive and its application, the adhesive is made up of the raw material of following parts by weight：100 parts of acrylic butyl ester copolymer resins, 35 parts of hydroxypropyl PASELLI EASYGEL, 26 parts of silica, 26 parts of dispersant, 0.5 1 parts of defoamer, 50 150 parts of 10 20 parts of butanediol and water.By optimizing gluing agent prescription and hook structure, long service life is linked up with, load capacity is big, and easy to use, bond properties is good.
Description
Technical field
The present invention relates to a kind of adhesive and its apply, a kind of more particularly to hook adhesive and comprising the adhesive
Hook and its application.
Background technology
Existing adhesive hook is pasted between hook and metope using adhesive sticker two-sided tape, is born using adhesive sticker viscosity
Weight, due to easy to use popular.But colloid is easily influenceed by humidity, temperature etc. environmental change, and hang weight state
Easy creep down so that such hook has that service life is short, hang that weight is few, hook easily falls down from wall.
CN105086888A A disclose a kind of preparation technology of high viscosity acrylic acid adhesive, comprise the following steps：Will
2.5 parts of nanoscale SiO2 powders, 1.5 parts of nanoscale Al2O30.9 part of powder and isocyanates carry out ultrasound in adding pre-dispersed liquid
Ripple processes pre-dispersed liquid after being modulated；By 75 parts of methyl methacrylate, 31 parts of ethyl acrylate and dimethyl diethoxy
18 parts of silane carries out mechanical agitation acquisition polymer solution in adding the second solvent；Pre-dispersed liquid, polymer solution after modulating
Mix and sequentially add 4.5 parts of rosin resin, 5 parts of note olefine resin, 1.2 parts of azo-compound is so as to obtain the high viscosity propylene
Sour adhesive.Pressure sensitive adhesive film of the present invention improves acrylic acid adhesive roughness in the case where particle diameter is not increased,
Avoid SiO2 powders, Al2O3Sedimentation of the powder in system, improves and base material adhesion.
CN105086899A discloses a kind of preparation method of adhesive for plastics composition, the constituent of the adhesive
Including following raw material count by weight percentage：40 parts -60 parts of organic solvent, 20 parts -35 parts of epoxy resin, 5 part -10
Part polybutadiene, 5 parts -10 parts of acrylic resin, 3 parts -5 parts of celluosic resin, 3 parts -5 parts of silica, 1 part -3
Various auxiliary agents of part.Gained adhesive of the invention, primarily directed to the use of Plastic product, possesses preferably water-fast weather-proof
Property, while also there is outstanding advantage in terms of the high resiliency that plastics are bonded, the adhesive raw material sources of preparation are extensively and price is very low,
There is larger promotional value in terms of the bonding for plastic product.
CN104927678A discloses a kind of environment-friendly adhesive and discloses its preparation method, by following weight percentage
Raw material composition：Polyvinyl alcohol 20-25%, acrylate 20-25%, catalyst 1-3%, di-t-butyl methylphenol 1-3%,
Mould inhibitor 1-3%, gelatin 10-15%, calcium carbonate 3-5%, 1,2-PD 3-5%, calcium chloride 1-3%, tackifier 1-3%,
Initiator 1-3%, dispersant 1-3%, deionized water 13-27%, the environment-friendly adhesive for preparing without poisonous and harmful element,
Safety and environmental protection, simple and with low cost environment-friendly adhesive is made, and the adhesive also has adhesive strength higher, preferably
Water resistance, splendid heat resistance and the advantages of relatively low solidification temperature, have a good application prospect.
CN87203123U disclose it is a kind of facilitate clothes-hook with adhesive, mainly there is main body and base to constitute, main body
It is interior with adhesive to there is adhesive in main body, adhesive is released when using, clothes-hook is bonded on attachment, have
Have easy to use, expense it is low, it is sturdy and durable the features such as.
The content of the invention
In view of the shortcomings of the prior art, the present invention provide a kind of hook adhesive and the hook comprising the adhesive and its
Using.
To achieve the above object of the invention, the present invention can use following any one technical scheme：
One aspect of the present invention provides a kind of hook adhesive, and the adhesive is made up of the raw material of following parts by weight：
100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, 3-5 parts of hydroxypropyl PASELLI EASYGEL, silica 2-6 parts, dispersant 2-
6 parts, defoamer 0.5-1 parts, butanediol 10-20 parts and water 50-150 parts.
The dispersant is hydroxypropyl methyl cellulose and/or polyvinyl alcohol (PVA).
The defoamer is polypropylene glycerol aether and/or dimethicone.
Another aspect of the present invention provides a kind of hook, and the hook includes hook adhesive described above, the hook bag
Containing linking up with matrix, polyurethane foaming body and coating the adhesive on polyurethane foaming body two sides, hook matrix one side leads to
Cross the adhesive to be bonded together with polyurethane foaming body, the polyurethane foaming body is away from the glue in the one side of hook matrix
Release liners are provided with glutinous agent.
The polyurethane foaming body is the polyurethane foaming body containing micropore.
A button is set on the hook matrix another side, curing agent is contained in button inner chamber, and is covered in button inner chamber
The through hole that UNICOM hooks two sides is provided with the hook matrix of cover area.
The button is the cylindrical button of a diameter of 5-20mm, and the curing agent is wrapped up by hermetic bag, the through hole
A diameter of 1-3mm.
The curing agent contains melmac and/or melamine formaldehyde resin.
The present invention also provides a kind of method using above-mentioned hook, it is characterised in that comprise the steps of：
(1) release liners are torn, hook is sticked on plane body；
(2) button is pressed so that curing agent bursting hermetic bag, curing agent pushes to polyurethane foam by through hole
Body, is then contacted so that adhesive is solidified by the micropore in polyurethane foaming body with adhesive.
The present invention improves the bonding effect of adhesive, and change by hook structure by optimizing gluing agent prescription
Enter, it is to avoid the cohesive of hook is reduced because of the influence of environment and time.Compared with prior art, the present invention has following beneficial
Effect：
1st, by adding 100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, it is ensured that the cohesive of adhesive.
2nd, by adding hydroxypropyl PASELLI EASYGEL, improve the cohesive of adhesive.
3rd, by adding other auxiliary components so that adhesive performance is more stablized, and is not easily susceptible to environment, resting period etc.
The influence of factor.
4th, by the improvement to hook structure, the bond properties of adhesive has been ensured, long service life is used simple
It is convenient, and bond properties is good.
Specific embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools
Body implementation method.One skilled in the art would recognize that present invention encompasses being potentially included in Claims scope
All alternatives, improvement project and equivalents.
Embodiment 1
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
3 parts of PASELLI EASYGEL, 2 parts of silica, 2 parts of hydroxypropyl methyl cellulose, 0.5 part of polypropylene glycerol aether, butanediol
10 parts and 50 parts of water.
Embodiment 2
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
4 parts of PASELLI EASYGEL, 4 parts of silica, 4 parts of hydroxypropyl methyl cellulose, 0.75 part of polypropylene glycerol aether, butanediol
15 parts and 100 parts of water.
Embodiment 3
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
5 parts of PASELLI EASYGEL, 6 parts of silica, 6 parts of hydroxypropyl methyl cellulose, 1 part of polypropylene glycerol aether, butanediol 20
150 parts of part and water.
Embodiment 4
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
3 parts of PASELLI EASYGEL, 2 parts of silica, 2 parts of polyvinyl alcohol, 0.5 part of dimethicone, 50 parts of 10 parts of butanediol and water.
Embodiment 5
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
4 parts of PASELLI EASYGEL, 4 parts of silica, 4 parts of polyvinyl alcohol, 0.75 part of dimethicone, 15 parts of butanediol and water 100
Part.
Embodiment 6
Adhesive is made up of the raw material of following parts by weight：100 parts of acrylic acid-acrylic acid butyl ester copolymer resins, hydroxypropyl
5 parts of PASELLI EASYGEL, 6 parts of silica, 6 parts of polyvinyl alcohol, 1 part of dimethicone, 150 parts of 20 parts of butanediol and water.
Embodiment 7
Hook links up with base comprising linking up with matrix, polyurethane foaming body and coating the adhesive on polyurethane foaming body two sides
Body one side is bonded together by adhesive with polyurethane foaming body, and polyurethane foaming body is away from the one side of hook matrix
Release liners are provided with adhesive.Polyurethane foaming body is the polyurethane foaming body containing micropore.On hook matrix another side
One button is set, and curing agent is contained in button inner chamber, and is provided with UNICOM's hook in the hook matrix of button inner chamber overlay area
Hang the through hole on two sides.Button is the cylindrical button of a diameter of 10mm, and the curing agent is wrapped up by hermetic bag, the through hole it is straight
Footpath is 2mm.Wherein, the adhesive uses the adhesive of embodiment 2, the curing agent to contain melamine formaldehyde resin.Hook makes
Used time, release liners are now torn, hook is sticked on plane body, then press button so that curing agent bursting hermetic bag, solidified
Agent pushes to polyurethane foaming body by through hole, is then contacted with adhesive by the micropore in polyurethane foaming body so that glue
Glutinous agent is solidified.The hook weighs 15 kilograms/square inch, static shear 3.1MPa through hanging experiment detection again, extension.
Embodiment 8
Hook links up with base comprising linking up with matrix, polyurethane foaming body and coating the adhesive on polyurethane foaming body two sides
Body one side is bonded together by adhesive with polyurethane foaming body, and polyurethane foaming body is away from the one side of hook matrix
Release liners are provided with adhesive.Polyurethane foaming body is the polyurethane foaming body containing micropore.On hook matrix another side
One button is set, and curing agent is contained in button inner chamber, and is provided with UNICOM's hook in the hook matrix of button inner chamber overlay area
Hang the through hole on two sides.Button is the cylindrical button of a diameter of 10mm, and the curing agent is wrapped up by hermetic bag, the through hole it is straight
Footpath is 2mm.Wherein, the adhesive uses the adhesive of embodiment 4, the curing agent to contain melamine formaldehyde resin.Hook makes
Used time, release liners are now torn, hook is sticked on plane body, then press button so that curing agent bursting hermetic bag, solidified
Agent pushes to polyurethane foaming body by through hole, is then contacted with adhesive by the micropore in polyurethane foaming body so that glue
Glutinous agent is solidified.The hook weighs 15 kilograms/square inch, static shear 3.0MPa through hanging experiment detection again, extension.
Embodiment 9
Hook links up with base comprising linking up with matrix, polyurethane foaming body and coating the adhesive on polyurethane foaming body two sides
Body one side is bonded together by adhesive with polyurethane foaming body, and polyurethane foaming body is away from the one side of hook matrix
Release liners are provided with adhesive.Polyurethane foaming body is the polyurethane foaming body containing micropore.On hook matrix another side
One button is set, and curing agent is contained in button inner chamber, and is provided with UNICOM's hook in the hook matrix of button inner chamber overlay area
Hang the through hole on two sides.Button is the cylindrical button of a diameter of 10mm, and the curing agent is wrapped up by hermetic bag, the through hole it is straight
Footpath is 2mm.Wherein, the adhesive uses the adhesive of one of embodiment 2, the curing agent to contain melmac.Hook makes
Used time, release liners are now torn, hook is sticked on plane body, then press button so that curing agent bursting hermetic bag, solidified
Agent pushes to polyurethane foaming body by through hole, is then contacted with adhesive by the micropore in polyurethane foaming body so that glue
Glutinous agent is solidified.The hook weighs 15 kilograms/square inch, static shear 3.2MPa through hanging experiment detection again, extension.
Embodiment 10
Hook links up with base comprising linking up with matrix, polyurethane foaming body and coating the adhesive on polyurethane foaming body two sides
Body one side is bonded together by adhesive with polyurethane foaming body, and polyurethane foaming body is away from the one side of hook matrix
Release liners are provided with adhesive.Polyurethane foaming body is the polyurethane foaming body containing micropore.On hook matrix another side
One button is set, and curing agent is contained in button inner chamber, and is provided with UNICOM's hook in the hook matrix of button inner chamber overlay area
Hang the through hole on two sides.Button is the cylindrical button of a diameter of 10mm, and the curing agent is wrapped up by hermetic bag, the through hole it is straight
Footpath is 2mm.Wherein, the adhesive uses the adhesive of one of embodiment 4, the curing agent to contain melmac.Hook makes
Used time, release liners are now torn, hook is sticked on plane body, then press button so that curing agent bursting hermetic bag, solidified
Agent pushes to polyurethane foaming body by through hole, is then contacted with adhesive by the micropore in polyurethane foaming body so that glue
Glutinous agent is solidified.The hook weighs 15 kilograms/square inch, static shear 3.1MPa through hanging experiment detection again, extension.
From embodiment 7-10 data, present invention optimizes adhesive formula and improve the structure of hook, compare
(1-2.5 kilograms/square inch, 0.1~0.35MPA of static shear) is linked up with commercially available not dry two-sided tape, extension of the invention
The caking property of hook and bear weight and to be far longer than commercially available prod.
Claims (9)
1. a kind of hook adhesive, it is characterised in that the adhesive is made up of the raw material of following parts by weight：Acrylic acid-the third
100 parts of olefin(e) acid butyl ester copolymer resins, 3-5 parts of hydroxypropyl PASELLI EASYGEL, silica 2-6 parts, dispersant 2-6 parts, froth breaking
Agent 0.5-1 parts, butanediol 10-20 parts and water 50-150 parts.
2. according to the hook adhesive described in claim 1, it is characterised in that the dispersant is hydroxypropyl methyl cellulose
And/or polyvinyl alcohol (PVA).
3. according to the hook adhesive described in claim 1, it is characterised in that defoamer is polypropylene glycerol aether and/or two
Methyl-silicone oil.
4. it is a kind of to link up with, it is characterised in that the adhesive of the hook comprising one of claim 1-3.
5. according to the hook described in claim 4, it is characterised in that the hook includes hook matrix, polyurethane foaming body and painting
The adhesive on polyurethane foaming body two sides is distributed in, hook matrix one side is glued by the adhesive with polyurethane foaming body
Be combined, the polyurethane foaming body away from hook matrix one side on adhesive on be provided with release liners.
6. according to the hook described in claim 5, it is characterised in that the polyurethane foaming body is the polyurethane hair containing micropore
Foam.
7. according to the hook described in claim 5, it is characterised in that set a button, button on the hook matrix another side
Curing agent is contained in inner chamber, and the through hole that UNICOM hooks two sides is provided with the hook matrix of button inner chamber overlay area.
8. according to the hook described in claim 7, it is characterised in that the button is the cylindrical button of a diameter of 5-20mm, institute
State curing agent to be wrapped up by hermetic bag, a diameter of 1-3mm of the through hole.
9. according to the hook described in claim 8, it is characterised in that the curing agent contains melmac and/or melamine
Amine-for-aldehyde resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510943401.5A CN105462522B (en) | 2015-12-18 | 2015-12-18 | A kind of hook adhesive and the hook comprising the adhesive and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510943401.5A CN105462522B (en) | 2015-12-18 | 2015-12-18 | A kind of hook adhesive and the hook comprising the adhesive and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105462522A CN105462522A (en) | 2016-04-06 |
| CN105462522B true CN105462522B (en) | 2017-06-27 |
Family
ID=55600694
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510943401.5A Expired - Fee Related CN105462522B (en) | 2015-12-18 | 2015-12-18 | A kind of hook adhesive and the hook comprising the adhesive and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105462522B (en) |
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| JP2004099740A (en) * | 2002-09-09 | 2004-04-02 | Nichiban Co Ltd | Acrylic adhesive composition |
| JP2009144068A (en) * | 2007-12-14 | 2009-07-02 | Nitomuzu:Kk | Stretch release tape |
| CN101928526A (en) * | 2009-11-26 | 2010-12-29 | 苏州皓鑫电子科技有限公司 | Method for preparing composite membrane and composite membrane prepared by using same |
| CN201762276U (en) * | 2010-07-23 | 2011-03-16 | 冯利 | Laminate layer adhesive film and hanger comprising same |
| CN102127381A (en) * | 2010-07-28 | 2011-07-20 | 叶锦标 | Traceless adhesive, and traceless free sticker prepared from same |
| WO2012018987A2 (en) * | 2010-08-04 | 2012-02-09 | 3M Innovative Properties Company | Adhesively mounted article support assembly with exposed pull tab |
| CN105018016A (en) * | 2015-09-03 | 2015-11-04 | 侯颖 | Preparation method of high-strength adhesive composition for leather |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030000643A1 (en) * | 1997-10-27 | 2003-01-02 | Bernhard Herlfterkamp | Aqueous adhesive preparation |
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2015
- 2015-12-18 CN CN201510943401.5A patent/CN105462522B/en not_active Expired - Fee Related
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|---|---|---|---|---|
| JP2004099740A (en) * | 2002-09-09 | 2004-04-02 | Nichiban Co Ltd | Acrylic adhesive composition |
| JP2009144068A (en) * | 2007-12-14 | 2009-07-02 | Nitomuzu:Kk | Stretch release tape |
| CN101928526A (en) * | 2009-11-26 | 2010-12-29 | 苏州皓鑫电子科技有限公司 | Method for preparing composite membrane and composite membrane prepared by using same |
| CN201762276U (en) * | 2010-07-23 | 2011-03-16 | 冯利 | Laminate layer adhesive film and hanger comprising same |
| CN102127381A (en) * | 2010-07-28 | 2011-07-20 | 叶锦标 | Traceless adhesive, and traceless free sticker prepared from same |
| WO2012018987A2 (en) * | 2010-08-04 | 2012-02-09 | 3M Innovative Properties Company | Adhesively mounted article support assembly with exposed pull tab |
| CN105018016A (en) * | 2015-09-03 | 2015-11-04 | 侯颖 | Preparation method of high-strength adhesive composition for leather |
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| CN105462522A (en) | 2016-04-06 |
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