CN105462359A - Preparation method of water-based colored fluorescent ink - Google Patents
Preparation method of water-based colored fluorescent ink Download PDFInfo
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- CN105462359A CN105462359A CN201610064526.5A CN201610064526A CN105462359A CN 105462359 A CN105462359 A CN 105462359A CN 201610064526 A CN201610064526 A CN 201610064526A CN 105462359 A CN105462359 A CN 105462359A
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- fluorescent ink
- dyestuff
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- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 49
- 238000003756 stirring Methods 0.000 claims abstract description 35
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 239000000080 wetting agent Substances 0.000 claims abstract description 16
- 230000000149 penetrating effect Effects 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 9
- 238000005516 engineering process Methods 0.000 claims abstract description 5
- 239000000976 ink Substances 0.000 claims description 63
- 239000000975 dye Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 12
- -1 sanitas Substances 0.000 claims description 11
- 239000007850 fluorescent dye Substances 0.000 claims description 10
- 239000012466 permeate Substances 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 8
- 238000007639 printing Methods 0.000 claims description 8
- 238000002525 ultrasonication Methods 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004146 energy storage Methods 0.000 claims description 6
- 239000000796 flavoring agent Substances 0.000 claims description 6
- 235000019634 flavors Nutrition 0.000 claims description 6
- PHLYOKFVXIVOJC-UHFFFAOYSA-N gallein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C(O)=C1OC1=C(O)C(O)=CC=C21 PHLYOKFVXIVOJC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 4
- 235000018958 Gardenia augusta Nutrition 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000004283 Sodium sorbate Substances 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000006071 cream Substances 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- 231100000252 nontoxic Toxicity 0.000 claims description 4
- 230000003000 nontoxic effect Effects 0.000 claims description 4
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 4
- 235000010235 potassium benzoate Nutrition 0.000 claims description 4
- 239000004300 potassium benzoate Substances 0.000 claims description 4
- 229940103091 potassium benzoate Drugs 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 4
- 235000010234 sodium benzoate Nutrition 0.000 claims description 4
- 239000004299 sodium benzoate Substances 0.000 claims description 4
- LROWVYNUWKVTCU-STWYSWDKSA-M sodium sorbate Chemical compound [Na+].C\C=C\C=C\C([O-])=O LROWVYNUWKVTCU-STWYSWDKSA-M 0.000 claims description 4
- 235000019250 sodium sorbate Nutrition 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- 244000248349 Citrus limon Species 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 3
- 241000218378 Magnolia Species 0.000 claims description 3
- 241000220317 Rosa Species 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 5
- 239000002518 antifoaming agent Substances 0.000 abstract 2
- 230000003020 moisturizing effect Effects 0.000 abstract 2
- 239000003755 preservative agent Substances 0.000 abstract 2
- 230000002335 preservative effect Effects 0.000 abstract 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 238000001132 ultrasonic dispersion Methods 0.000 abstract 1
- 239000000049 pigment Substances 0.000 description 5
- 239000002696 acid base indicator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- 229940047670 sodium acrylate Drugs 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a preparation method of water-based colored fluorescent ink. The preparation method comprises the steps that deionized water is added into an ultrasonic disperser with stirring, dye, a film forming agent, a wetting agent, a defoaming agent, a preservative, a penetrating agent, a pH adjusting agent, a moisturizing agent and a flatting agent are added into the deionized water, essence is added into the mixture after uniform ultrasonic dispersion and complete stirring dissolution and stirred to be uniform, and therefore the water-based colored fluorescent ink is obtained, wherein the mass percent of the dye to the film forming agent to the wetting agent to the defoaming agent to the preservative to the penetrating agent to the pH adjusting agent to the moisturizing agent to the flatting agent to the essence to the deionized water is (0.01%-5.00%):(0.1%-10.0%):(0.1%-5.0%):(0.01%-2.0%):(0.01%-5.0%):(0.1%-5.0%):(0.1%-5.0%):(0.1%-5.0%):(0.01%-1.0%):(0.01%-2.0%):(60%-95%). The method is simple in technology, easy to implement, small in investment and beneficial to application and popularization.
Description
Technical field
The present invention relates to a kind of preparation method of hydrate colour fluorescent ink, belong to field of fine chemical.
Background technology
Ink is a kind of mixture containing dyestuff (or pigment), membrane-forming agent, solvent, dispersion agent and other related auxiliaries, and ink is mainly used in writing, paint, spray, print and printing etc., is the indispensable class I goods of society.Our primary and secondary students are in learning process, like using color fluorescence pen to scratch in learning materials, scribble and write and punctuate, to highlight the priority and difficulty content will remembering grasp, deepen the understanding to priority and difficulty knowledge and memory, especially in the review stage, directly can review the priority and difficulty content of memory fluorescent ink water-color paintbrush mark, only grab priority and difficulty and review, effectively improve learning efficiency.Therefore, color fluorescence pen is one of our important tool of carrying out study.
At present, there are some problems in the color fluorescence ink on market.First, existing color fluorescence ink is produce fluorescent effect by adding photo-induced energy storage luminescent powder mostly, because the price of photo-induced energy storage luminescent powder is high, consumption is large, use cost is high, reduces the economic benefit of color fluorescence ink.Secondly, existing color fluorescence ink is that use homogencous dyes or pigment are formulated mostly, and the color kind of color fluorescence ink is not enriched, and color is single non-adjustable.3rd, existing color fluorescence ink often containing some poisonous and hazardous compositions, affects the health of we primary and secondary students in various degree.
In the learning process of middle chemistry course, we have acquired acid base indicator as the knowledge such as phenolphthalein, tropeolin-D, under the guidance of teacher, we also utilize fresh flower to extract pigment, and test as acid base indicator with the pigment extracted, and have had certain understanding to colour developing and variable color.In middle school's drawing course, we have learned red (Red is designated as R), green (Green is designated as G) of light, blue (Blue is designated as B) trichromatic knowledge, utilize three primary colors can mix any color; The material of two or more different colours except three primary colors also can mix Protean color according to different ratios mixing.Utilize these knowledge, we are under the guidance and help of totur, utilize Baidu to search plain engine and search and have learned knowledge about aspects such as dyestuff, pigment, fluorescent ink and ink color matchings, carry out the research of color fluorescence ink, in order to provide, production cost is low, the production technology of Color tunable wide ranges, nontoxic hydrate colour fluorescent ink, special application patent of the present invention.
Summary of the invention
The preparation method of a kind of hydrate colour fluorescent ink of the present invention, be with dyestuff, membrane-forming agent, wetting agent, defoamer, sanitas, permeate agent, pH adjusting agent, wetting Agent for Printing Inks, flow agent, essence and deionized water for raw material, obtain hydrate colour fluorescent ink by ultrasonic disperse and stirring and dissolving.
The preparation method of a kind of hydrate colour fluorescent ink of the present invention, obtained product has that production technique is simple, cost is low, color tunable wide ranges and nontoxic feature.
The preparation method of a kind of hydrate colour fluorescent ink of the present invention, is characterized in that:
1, according to dyestuff, membrane-forming agent, wetting agent, defoamer, sanitas, permeate agent, pH adjusting agent, wetting Agent for Printing Inks, flow agent, the mass percent of essence and deionized water is (0.01% ~ 5.00%): (0.1% ~ 10.0%): (0.1% ~ 5.0%): (0.01% ~ 2.0%): (0.01% ~ 5.0%): (0.1% ~ 5.0%): (0.1% ~ 5.0%): (0.1% ~ 5.0%): (0.01% ~ 1.0%): (0.01% ~ 2.0%): the ratio of (60% ~ 95%), deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, successively by dyestuff, membrane-forming agent, wetting agent, defoamer, sanitas, permeate agent, pH adjusting agent, wetting Agent for Printing Inks and flow agent add in deionized water, after all even stirring and dissolving of ultrasonic disperse is complete, add essence again and stir, namely hydrate colour fluorescent ink is obtained.
2, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, its outstanding feature is:
First, utilize two or more dyestuff (wherein a kind of is fluorescence dye), in same set of production unit, only two or more dyestuff (wherein a kind of is fluorescence dye) can need be mixed colours according to not arranging mixing on year-on-year basis in very wide scope, obtain the color fluorescence ink that a series of color is different, enormously simplify the production technique of serial color fluorescence ink, production technique is simple, facility investment is little, and production efficiency is high.
The second, when producing fluorescent effect by adding photo-induced energy storage luminescent powder, because the price of photo-induced energy storage luminescent powder is high, consumption large, cause use cost high; By contrast, the present invention produces fluorescent effect by adding fluorescence dye, and the consumption of fluorescence dye is few, and production cost is low.
3rd, improving the penetrating power of ink in paper fiber by adding permeate agent, being conducive to improving the sticking power of ink at paper, improving the performance of ink.
4th. improving the levelling property of ink by adding flow agent, being conducive to ink and injecting the rear fluent writing of pen, improving use properties.
5th, select raw material all nontoxic, guarantee the Product Green environmental protection of producing by patented technology of the present invention.
3, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, dyestuff used, except uranine fluorescence dye, also has any one or two kinds of in pyrogallol phthalein, CuPc (II) tetrasulfonic acid tetra-na salt.
4, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, membrane-forming agent used is any one in carboxymethyl cellulose, Natvosol and acrylic resin.
5, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, wetting agent used is any one in sodium lauryl sulphate, alkylpolyoxyethylene sodium sulfate, alkylphenol polyoxyethylene and fatty alcohol-polyoxyethylene ether.
6, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, any one in defoamer used to be kilfoam be dimethyl silicone oil, acrylate and vinyl ether co-polymer and castor oil polyoxyethylene ether.
7, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, sanitas used is any one in Sodium Benzoate, potassium benzoate, sodium sorbate and potassium sorbate.
8, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, permeate agent used is any one in penetrating agent JFC, fast penetrant T.
9, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, pH adjusting agent used is any one in thanomin, diethanolamine and trolamine.
10, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, wetting Agent for Printing Inks used is any one in glycerine, propylene glycol and Diethylene Glycol.
11, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, flow agent used is flow agent BYK-333.
12, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, essence used is any one in cream jasmin france, rose compound, lemon flavour, apple flavour and magnolia compound.
13, the preparation method of a kind of hydrate colour fluorescent ink of the present invention, the frequency of ultrasonic disperser used is 20KHz ~ 1MHz, power is 30W ~ 15KW.
Embodiment
Here is the non-limiting example of the preparation method of a kind of hydrate colour fluorescent ink of the present invention.The providing of these examples is only used to the object illustrated, can not be interpreted as limitation of the invention.Because without departing from the spirit and scope of the present invention, many conversion can be carried out to the present invention.In these embodiments, unless stated otherwise, all per-cent all refers to mass percent.
Embodiment 1
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, pyrogallol phthalein, carboxymethyl cellulose, sodium lauryl sulphate, dimethyl silicone oil, Sodium Benzoate, penetrating agent JFC, thanomin, glycerine and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add cream jasmin france again and stir, namely obtaining hydrate colour fluorescent ink.
Embodiment 2
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, pyrogallol phthalein, carboxymethyl cellulose, fatty alcohol-polyoxyethylene ether, dimethyl silicone oil, Sodium Benzoate, penetrating agent JFC, thanomin, glycerine and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add cream jasmin france again and stir, namely obtaining hydrate colour fluorescent ink.
Embodiment 3
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, CuPc (II) tetrasulfonic acid tetra-na salt, Natvosol, alkylpolyoxyethylene sodium sulfate, acrylate and vinyl ether co-polymer, potassium benzoate, fast penetrant T, diethanolamine, propylene glycol and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add rose compound again and stir, namely obtaining hydrate colour fluorescent ink.
Embodiment 4
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, CuPc (II) tetrasulfonic acid tetra-na salt, Natvosol, alkylpolyoxyethylene sodium sulfate, acrylate and vinyl ether co-polymer, potassium benzoate, fast penetrant T, diethanolamine, propylene glycol and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add apple flavour again and stir, namely obtaining hydrate colour fluorescent ink.
Embodiment 5
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, pyrogallol phthalein, CuPc (II) tetrasulfonic acid tetra-na salt, acrylic resin, alkylphenol polyoxyethylene, castor oil polyoxyethylene ether, sodium sorbate, penetrating agent JFC, trolamine, Diethylene Glycol and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add magnolia compound again and stir, namely obtaining hydrate colour fluorescent ink.
Embodiment 6
According to the mass percent of above-mentioned raw materials, deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, add uranine, pyrogallol phthalein, CuPc (II) tetrasulfonic acid tetra-na salt, acrylic resin, alkylphenol polyoxyethylene, castor oil polyoxyethylene ether, sodium sorbate, penetrating agent JFC, trolamine, Diethylene Glycol and flow agent BYK-333 successively, after all even stirring and dissolving of ultrasonic disperse is complete, add lemon flavour again and stir, namely obtaining hydrate colour fluorescent ink.
Claims (10)
1. a preparation method for hydrate colour fluorescent ink, is characterized in that:
According to dyestuff, membrane-forming agent, wetting agent, defoamer, sanitas, permeate agent, pH adjusting agent, wetting Agent for Printing Inks, flow agent, the mass percent of essence and deionized water is (0.01% ~ 5.00%): (0.1% ~ 10.0%): (0.1% ~ 5.0%): (0.01% ~ 2.0%): (0.01% ~ 5.0%): (0.1% ~ 5.0%): (0.1% ~ 5.0%): (0.1% ~ 5.0%): (0.01% ~ 1.0%): (0.01% ~ 2.0%): the ratio of (60% ~ 95%), deionized water is added in the ultrasonic disperser of band stirring, under stirring and ultrasonication, successively by dyestuff, membrane-forming agent, wetting agent, defoamer, sanitas, permeate agent, pH adjusting agent, wetting Agent for Printing Inks and flow agent add in deionized water, after all even stirring and dissolving of ultrasonic disperse is complete, add essence again and stir, namely hydrate colour fluorescent ink is obtained.
2. preparation method according to claim 1, is characterized in that gained hydrate colour fluorescent ink product has following distinguishing feature:
First, utilize two or more dyestuff (wherein a kind of is fluorescence dye), in same set of production unit, only two or more dyestuff (wherein a kind of is fluorescence dye) can need be mixed colours according to not arranging mixing on year-on-year basis in very wide scope, obtain the color fluorescence ink that a series of color is different, enormously simplify the production technique of serial color fluorescence ink, production technique is simple, facility investment is little, and production efficiency is high;
The second, when producing fluorescent effect by adding photo-induced energy storage luminescent powder, because the price of photo-induced energy storage luminescent powder is high, consumption large, cause use cost high; By contrast, the present invention produces fluorescent effect by adding fluorescence dye, and the consumption of fluorescence dye is few, and production cost is low;
3rd, improving the penetrating power of ink in paper fiber by adding permeate agent, being conducive to improving the sticking power of ink at paper, improving the performance of ink;
4th, improving the levelling property of ink by adding flow agent, being conducive to ink and injecting the rear fluent writing of pen, improving use properties;
5th, select raw material all nontoxic, guarantee the Product Green environmental protection of producing by patented technology of the present invention.
3. preparation method according to claim 1, is characterized in that dyestuff used is except uranine fluorescence dye, also has any one or two kinds of in pyrogallol phthalein, CuPc (II) tetrasulfonic acid tetra-na salt.
4. preparation method according to claim 1, is characterized in that membrane-forming agent used is any one in carboxymethyl cellulose, Natvosol and acrylic resin etc.
5. preparation method according to claim 1, is characterized in that wetting agent used is any one in sodium lauryl sulphate, alkylpolyoxyethylene sodium sulfate, alkylphenol polyoxyethylene and fatty alcohol-polyoxyethylene ether etc.
6. preparation method according to claim 1, is characterized in that defoamer used to be kilfoam is any one in dimethyl silicone oil, acrylate and vinyl ether co-polymer and castor oil polyoxyethylene ether.
7. preparation method according to claim 1, is characterized in that sanitas used is any one in Sodium Benzoate, potassium benzoate, sodium sorbate and potassium sorbate.
8. preparation method according to claim 1, is characterized in that permeate agent used is any one in penetrating agent JFC, fast penetrant T.
9. preparation method according to claim 1, is characterized in that used:
1. pH adjusting agent is any one in thanomin, diethanolamine and trolamine;
2. wetting Agent for Printing Inks is any one in glycerine, propylene glycol and Diethylene Glycol;
3. flow agent is flow agent BYK-333;
4. essence is any one in cream jasmin france, rose compound, lemon flavour, apple flavour and magnolia compound etc.
10. preparation method according to claim 1, is characterized in that the frequency of ultrasonic disperser used in process is 20KHz ~ 1MHz, power is 30W ~ 15KW.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610064526.5A CN105462359B (en) | 2016-01-29 | 2016-01-29 | A kind of preparation method of hydrate colour fluorescent ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610064526.5A CN105462359B (en) | 2016-01-29 | 2016-01-29 | A kind of preparation method of hydrate colour fluorescent ink |
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| Publication Number | Publication Date |
|---|---|
| CN105462359A true CN105462359A (en) | 2016-04-06 |
| CN105462359B CN105462359B (en) | 2017-11-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610064526.5A Active CN105462359B (en) | 2016-01-29 | 2016-01-29 | A kind of preparation method of hydrate colour fluorescent ink |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266657A (en) * | 2020-10-22 | 2021-01-26 | 上海纳诺微新材料科技有限公司 | Special water-based fluorescent ink for fluorescent plate and preparation method thereof |
| CN117866469A (en) * | 2023-12-29 | 2024-04-12 | 广州市美帮祈富文仪有限公司 | Environment-friendly easy-to-clean pigment for children painting and preparation method thereof |
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| CN101993635A (en) * | 2009-08-24 | 2011-03-30 | 刘海生 | Erasable ink and preparation method thereof |
| CN102190925A (en) * | 2010-03-10 | 2011-09-21 | 江南大学 | Preparation method of disperse fluorescence red dye ink used in terylene ink-jet transfer printing |
| CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993635A (en) * | 2009-08-24 | 2011-03-30 | 刘海生 | Erasable ink and preparation method thereof |
| CN102190925A (en) * | 2010-03-10 | 2011-09-21 | 江南大学 | Preparation method of disperse fluorescence red dye ink used in terylene ink-jet transfer printing |
| CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266657A (en) * | 2020-10-22 | 2021-01-26 | 上海纳诺微新材料科技有限公司 | Special water-based fluorescent ink for fluorescent plate and preparation method thereof |
| CN117866469A (en) * | 2023-12-29 | 2024-04-12 | 广州市美帮祈富文仪有限公司 | Environment-friendly easy-to-clean pigment for children painting and preparation method thereof |
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| CN105462359B (en) | 2017-11-21 |
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Effective date of registration: 20230412 Address after: Building M22, 101, South China International Hardware, Chemical, Plastic Raw Materials Logistics Zone (Phase I), Hehua Community, Pinghu Street, Longgang District, Shenzhen City, Guangdong Province, 518111 Patentee after: Shenzhen Yicai Technology Co.,Ltd. Address before: Room 6-404, No. 3, Xikang Road, Nanjing, Jiangsu 210024 Patentee before: Liu Ruixuan Patentee before: Jiang Yingluo |