CN105440847A - Color change-preventing and wear-resistant protective agent of automotive interior metal zipper - Google Patents
Color change-preventing and wear-resistant protective agent of automotive interior metal zipper Download PDFInfo
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- CN105440847A CN105440847A CN201610005768.7A CN201610005768A CN105440847A CN 105440847 A CN105440847 A CN 105440847A CN 201610005768 A CN201610005768 A CN 201610005768A CN 105440847 A CN105440847 A CN 105440847A
- Authority
- CN
- China
- Prior art keywords
- wear
- agent
- look
- zip fastener
- resistant protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002184 metal Substances 0.000 title claims abstract description 31
- 239000003223 protective agent Substances 0.000 title abstract 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 26
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 20
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000011814 protection agent Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 15
- -1 polyoxyethylene Polymers 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 12
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 10
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 claims description 10
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 5
- PFRGGOIBYLYVKM-UHFFFAOYSA-N 15alpha-hydroxylup-20(29)-en-3-one Natural products CC(=C)C1CCC2(C)CC(O)C3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 PFRGGOIBYLYVKM-UHFFFAOYSA-N 0.000 claims description 5
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 claims description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 5
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- NCGUAROPCJYIPG-UHFFFAOYSA-N C(C)C=CC.[O].C1(=CC=CC=C1)C1=CC=CC=C1 Chemical group C(C)C=CC.[O].C1(=CC=CC=C1)C1=CC=CC=C1 NCGUAROPCJYIPG-UHFFFAOYSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- SOKRNBGSNZXYIO-UHFFFAOYSA-N Resinone Natural products CC(=C)C1CCC2(C)C(O)CC3(C)C(CCC4C5(C)CCC(=O)C(C)(C)C5CCC34C)C12 SOKRNBGSNZXYIO-UHFFFAOYSA-N 0.000 claims description 5
- RNFAKTRFMQEEQE-UHFFFAOYSA-N Tripropylene glycol butyl ether Chemical compound CCCCOC(CC)OC(C)COC(O)CC RNFAKTRFMQEEQE-UHFFFAOYSA-N 0.000 claims description 5
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 5
- 229920003180 amino resin Polymers 0.000 claims description 5
- 239000003153 chemical reaction reagent Substances 0.000 claims description 5
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 150000005690 diesters Chemical class 0.000 claims description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- JUMYIBMBTDDLNG-OJERSXHUSA-N hydron;methyl (2r)-2-phenyl-2-[(2r)-piperidin-2-yl]acetate;chloride Chemical compound Cl.C([C@@H]1[C@H](C(=O)OC)C=2C=CC=CC=2)CCCN1 JUMYIBMBTDDLNG-OJERSXHUSA-N 0.000 claims description 5
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 230000003252 repetitive effect Effects 0.000 claims description 5
- 229920003987 resole Polymers 0.000 claims description 5
- 229940099204 ritalin Drugs 0.000 claims description 5
- 238000005201 scrubbing Methods 0.000 claims description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 5
- 239000005051 trimethylchlorosilane Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 239000004744 fabric Substances 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000011241 protective layer Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 238000005457 optimization Methods 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 238000004500 asepsis Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C09D161/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a color change-preventing and wear-resistant protective agent of an automotive interior metal zipper. The color change-preventing and wear-resistant protective agent is prepared from the following components in parts by weight: 30 to 50 parts of resin, 0.3 to 1 part of surface modified nano SiO2, 0.1 to 5 parts of surfactant, 0.1 to 0.5 part of film forming matter, 1 to 35 parts of solvents, 5 to 8 parts of silane coupling agent and deionized water as the rest. According to the color change-preventing and wear-resistant protective agent, the zipper is soaked in a protective agent solution, or the protective agent is sprayed to the surface of the zipper, so as to form a uniform dense bright protective layer, so that the metal zipper is prevented from discoloring and fading, and the color overlapping of the metal zipper to fabrics is reduced, so as not to influence the product quality. The color change-preventing and wear-resistant protective agent is favorable for environmental protection and has the advantages of simplicity in arrangement, low treatment cost and convenience when the color change-preventing and wear-resistant protective agent is used for protecting the surface of the zipper.
Description
Technical field
Anti-oxidation, the anti-look that the present invention relates to automotive trim metal zip fastener becomes Wear-resistant Treatment, particularly relates to the protective membrane treatment agent generating one deck nanometer grade thickness at metal slide fastener surface.
Background technology
During current automotive trim metal zip fastener inspection after construction, usually find that dark metal slide fastener ratio is easier to pollute fabric, dark slide fastener is formed through chemical stain process by brass teeth zipper.This pigmented layer easily pollutes fabric, especially obvious to light fabric.This Study on chemical coloring technology is different from electroplating technology, and hole is comparatively large, and attachment fastness is relatively poor, after contact, friction, ENZYME WASH, look transfer easily occurs.The auxiliary agent of acidity or alkalescence encountered by slide fastener in dyeing process simultaneously, causes slide fastener variable color with regard to being easy to cause metallic surface oxidized.
Summary of the invention
Goal of the invention: object of the present invention be exactly provide a kind of safety non-toxic, strong adhesion to overcome defect that above-mentioned prior art exists, the anti-look of environment-friendly type automobile inner decoration metal zip fastener that anti-scratch, wear-resisting, resistance to chemical attack, anti-oxidation, anti-look become becomes wear-resistant protection agent.
Technical scheme: a kind of anti-look of automotive trim metal zip fastener becomes wear-resistant protection agent, described anti-look becomes wear-resistant protection agent and is made up of according to parts by weight following component:
As further optimization: described resin be selected from ACRYLIC EMULSION, acrylic resin, bisphenol A type epoxy resin, aminoresin, urethane resin, polyvalent alcohol, resol, urea-formaldehyde resin one or both.
As further optimization: described surface-modified nano SiO
2for surface-modifying agent and silane coupler modified Nano-meter SiO_2
2.
As further optimization: described tensio-active agent be selected from alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene, fatty alcohol-ether-25 one or both.
As further optimization: described filmogen be selected from propoxylated glycerol triacrylate, adjacent phenyl benzene oxygen ethyl propylene acid esters, modified dimethyl polysiloxane polymkeric substance, dipropylene, tripropylene glycol butyl ether, ethylene glycol phenyl ether one or both.
As further optimization: one or both in described solvent selected from acetone, butanone, ritalin, vinyl acetic monomer, N-BUTYL ACETATE, ethyl group 3-ethoxy propionic ester, diester mixture.
As further optimization: described surface-modified nano SiO
2preparation method is: take 2-8g drying nano SiO
2join in the there-necked flask of 100ml, add the sherwood oil 60-90 of 50ml, dispersion 30min, then surface-modifying agent is dripped wherein, drip deionized water again after dripping off, 60 DEG C of reaction 3h, reaction terminates rear filtration, repeatedly rinse to filtrate pH weakly acidic pH with dehydrated alcohol in suction filtration process, vacuum-drying; By the surface-modified nano 2-8gSiO of drying
2be dispersed in propyl carbinol, dispersion 30min, adds the silane coupling agent that massfraction is 20%, and 70 DEG C of reaction 6h, reaction terminates rear filtered while hot, uses dehydrated alcohol repetitive scrubbing, in vacuum-drying, obtain surface-modified nano SiO in suction filtration process
2.
As further optimization: described silane coupling agent is selected from silane coupling agent KH-560, Silane coupling reagent KH-570, silane coupling agent KH-580, one or both in silane coupling agent KH-590.
As further optimization: described Nano-meter SiO_2
2surface-modifying agent be selected from dimethyldichlorosilane(DMCS), monomethyl trichlorosilane, tri-methyl-chlorosilane and dimethyl dichlorosilane (DMCS) one or both.
Beneficial effect: concrete advantage of the present invention is as follows:
1, the metal zip fastener protective material in the present invention has the multinomial superiority such as remarkable hardness, anti-scratch, wear-resisting, high temperature resistant, resistance to chemical attack and film forming be ultra-thin, metal is had to extremely strong sticking power is free from environmental pollution, auxiliary agent environment-protecting asepsis.
2, the surface of the present invention to slide fastener is protected, and staining problem occurs perfect solution when metal zip fastener washs and when fabric matches.
3, the present invention stops acid or alkaline auxiliary agent to the erosion of metal zip fastener when ready-made clothes washing, avoids metallic surface oxidized and cause slide fastener variable color.
4, the present invention is easy to use, slide fastener is directly put into solution and soaks, dipping time 0.5-4.0min or be sprayed on slide fastener surface and naturally dry or dry.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail.
Specific embodiment one:
The anti-look of automotive trim metal zip fastener becomes a wear-resistant protection agent, and described anti-look becomes wear-resistant protection agent and is made up of according to parts by weight following component:
Described resin be selected from ACRYLIC EMULSION, acrylic resin, bisphenol A type epoxy resin, aminoresin, urethane resin, polyvalent alcohol, resol, urea-formaldehyde resin one or both.
Described surface-modified nano SiO
2for surface-modifying agent and silane coupler modified Nano-meter SiO_2
2.
Described tensio-active agent be selected from alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene, fatty alcohol-ether-25 one or both.
Described filmogen be selected from propoxylated glycerol triacrylate, adjacent phenyl benzene oxygen ethyl propylene acid esters, modified dimethyl polysiloxane polymkeric substance, dipropylene, tripropylene glycol butyl ether, ethylene glycol phenyl ether one or both.
One or both in described solvent selected from acetone, butanone, ritalin, vinyl acetic monomer, N-BUTYL ACETATE, ethyl group 3-ethoxy propionic ester, diester mixture.
Described surface-modified nano SiO
2preparation method is: take 2g drying nano SiO
2join in the there-necked flask of 100ml, add the sherwood oil 60-90 of 50ml, dispersion 30min, then surface-modifying agent is dripped wherein, drip deionized water again after dripping off, 60 DEG C of reaction 3h, reaction terminates rear filtration, repeatedly rinse to filtrate pH weakly acidic pH with dehydrated alcohol in suction filtration process, vacuum-drying; By the surface-modified nano 2gSiO of drying
2be dispersed in propyl carbinol, dispersion 30min, adds the silane coupling agent that massfraction is 20%, and 70 DEG C of reaction 6h, reaction terminates rear filtered while hot, uses dehydrated alcohol repetitive scrubbing, in vacuum-drying, obtain surface-modified nano SiO in suction filtration process
2.
Described silane coupling agent is selected from silane coupling agent KH-560, Silane coupling reagent KH-570, silane coupling agent KH-580, one or both in silane coupling agent KH-590.
Described Nano-meter SiO_2
2surface-modifying agent be selected from dimethyldichlorosilane(DMCS), monomethyl trichlorosilane, tri-methyl-chlorosilane and dimethyl dichlorosilane (DMCS) one or both.
Specific embodiment two:
The anti-look of automotive trim metal zip fastener becomes a wear-resistant protection agent, and described anti-look becomes wear-resistant protection agent and is made up of according to parts by weight following component:
Described resin be selected from ACRYLIC EMULSION, acrylic resin, bisphenol A type epoxy resin, aminoresin, urethane resin, polyvalent alcohol, resol, urea-formaldehyde resin one or both.
Described surface-modified nano SiO
2for surface-modifying agent and silane coupler modified Nano-meter SiO_2
2.
Described tensio-active agent be selected from alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene, fatty alcohol-ether-25 one or both.
Described filmogen be selected from propoxylated glycerol triacrylate, adjacent phenyl benzene oxygen ethyl propylene acid esters, modified dimethyl polysiloxane polymkeric substance, dipropylene, tripropylene glycol butyl ether, ethylene glycol phenyl ether one or both.
One or both in described solvent selected from acetone, butanone, ritalin, vinyl acetic monomer, N-BUTYL ACETATE, ethyl group 3-ethoxy propionic ester, diester mixture.
Described surface-modified nano SiO
2preparation method is: take 8g drying nano SiO
2join in the there-necked flask of 100ml, add the sherwood oil 60-90 of 50ml, dispersion 30min, then surface-modifying agent is dripped wherein, drip deionized water again after dripping off, 60 DEG C of reaction 3h, reaction terminates rear filtration, repeatedly rinse to filtrate pH weakly acidic pH with dehydrated alcohol in suction filtration process, vacuum-drying; By the surface-modified nano 8gSiO of drying
2be dispersed in propyl carbinol, dispersion 30min, adds the silane coupling agent that massfraction is 20%, and 70 DEG C of reaction 6h, reaction terminates rear filtered while hot, uses dehydrated alcohol repetitive scrubbing, in vacuum-drying, obtain surface-modified nano SiO in suction filtration process
2.
Described silane coupling agent is selected from silane coupling agent KH-560, Silane coupling reagent KH-570, silane coupling agent KH-580, one or both in silane coupling agent KH-590.
Described Nano-meter SiO_2
2surface-modifying agent be selected from dimethyldichlorosilane(DMCS), monomethyl trichlorosilane, tri-methyl-chlorosilane and dimethyl dichlorosilane (DMCS) one or both.
Specific embodiment three:
The anti-look of automotive trim metal zip fastener becomes a wear-resistant protection agent, and described anti-look becomes wear-resistant protection agent and is made up of according to parts by weight following component:
Described resin be selected from ACRYLIC EMULSION, acrylic resin, bisphenol A type epoxy resin, aminoresin, urethane resin, polyvalent alcohol, resol, urea-formaldehyde resin one or both.
Described surface-modified nano SiO
2for surface-modifying agent and silane coupler modified Nano-meter SiO_2
2.
Described tensio-active agent be selected from alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene, fatty alcohol-ether-25 one or both.
Described filmogen be selected from propoxylated glycerol triacrylate, adjacent phenyl benzene oxygen ethyl propylene acid esters, modified dimethyl polysiloxane polymkeric substance, dipropylene, tripropylene glycol butyl ether, ethylene glycol phenyl ether one or both.
One or both in described solvent selected from acetone, butanone, ritalin, vinyl acetic monomer, N-BUTYL ACETATE, ethyl group 3-ethoxy propionic ester, diester mixture.
Described surface-modified nano SiO
2preparation method is: take 6g drying nano SiO
2join in the there-necked flask of 100ml, add the sherwood oil 60-90 of 50ml, dispersion 30min, then surface-modifying agent is dripped wherein, drip deionized water again after dripping off, 6 () DEG C reaction 3h, reaction terminates rear filtration, repeatedly rinse to filtrate pH weakly acidic pH with dehydrated alcohol in suction filtration process, vacuum-drying; By the surface-modified nano 6gSiO of drying
2be dispersed in propyl carbinol, dispersion 30min, adds the silane coupling agent that massfraction is 20%, and 70 DEG C of reaction 6h, reaction terminates rear filtered while hot, uses dehydrated alcohol repetitive scrubbing, in vacuum-drying, obtain surface-modified nano SiO in suction filtration process
2.
Described silane coupling agent is selected from silane coupling agent KH-560, Silane coupling reagent KH-570, silane coupling agent KH-580, one or both in silane coupling agent KH-590.
Described Nano-meter SiO_2
2surface-modifying agent be selected from dimethyldichlorosilane(DMCS), monomethyl trichlorosilane, tri-methyl-chlorosilane and dimethyl dichlorosilane (DMCS) one or both.
Concrete advantage of the present invention is as follows:
1, the metal zip fastener protective material in the present invention has the multinomial superiority such as remarkable hardness, anti-scratch, wear-resisting, high temperature resistant, resistance to chemical attack and film forming be ultra-thin, metal is had to extremely strong sticking power is free from environmental pollution, auxiliary agent environment-protecting asepsis.
2, the surface of the present invention to slide fastener is protected, and staining problem occurs perfect solution when metal zip fastener washs and when fabric matches.
3, the present invention stops acid or alkaline auxiliary agent to the erosion of metal zip fastener when ready-made clothes washing, avoids metallic surface oxidized and cause slide fastener variable color.
4, the present invention is easy to use, slide fastener is directly put into solution and soaks, dipping time 0.5-4.0min or be sprayed on slide fastener surface and naturally dry or dry.
The present invention is not limited to above-mentioned preferred forms; anyone can draw other various forms of products under enlightenment of the present invention; no matter but any change is done in its shape or structure; every have identical with the application or akin technical scheme, all drops within protection scope of the present invention.
Claims (9)
1. the anti-look of automotive trim metal zip fastener becomes a wear-resistant protection agent, it is characterized in that: described anti-look becomes wear-resistant protection agent and is made up of according to parts by weight following component:
2. the anti-look of automotive trim metal zip fastener according to claim 1 becomes wear-resistant protection agent, it is characterized in that: described resin be selected from ACRYLIC EMULSION, acrylic resin, bisphenol A type epoxy resin, aminoresin, urethane resin, polyvalent alcohol, resol, urea-formaldehyde resin one or both.
3. the anti-look of automotive trim metal zip fastener according to claim 1 becomes wear-resistant protection agent, it is characterized in that: described surface-modified nano SiO
2for surface-modifying agent and silane coupler modified Nano-meter SiO_2
2.
4. the anti-look of automotive trim metal zip fastener according to claim 1 becomes wear-resistant protection agent, it is characterized in that: described tensio-active agent be selected from alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether, aliphatic alcohol polyoxyethylene, fatty alcohol-ether-25 one or both.
5. the anti-look of automotive trim metal zip fastener according to claim 1 becomes wear-resistant protection agent, it is characterized in that: described filmogen be selected from propoxylated glycerol triacrylate, adjacent phenyl benzene oxygen ethyl propylene acid esters, modified dimethyl polysiloxane polymkeric substance, dipropylene, tripropylene glycol butyl ether, ethylene glycol phenyl ether one or both.
6. the anti-look of automotive trim metal zip fastener according to claim 1 becomes wear-resistant protection agent, it is characterized in that: one or both in described solvent selected from acetone, butanone, ritalin, vinyl acetic monomer, N-BUTYL ACETATE, ethyl group 3-ethoxy propionic ester, diester mixture.
7. the anti-look of automotive trim metal zip fastener according to claim 3 becomes wear-resistant protection agent, it is characterized in that: described surface-modified nano SiO
2preparation method is: take 2-8g drying nano SiO
2join in the there-necked flask of 100ml, add the sherwood oil 60-90 of 50ml, dispersion 30min, then surface-modifying agent is dripped wherein, drip deionized water again after dripping off, 60 DEG C of reaction 3h, reaction terminates rear filtration, repeatedly rinse to filtrate pH weakly acidic pH with dehydrated alcohol in suction filtration process, vacuum-drying; By the surface-modified nano 2-8gSiO of drying
2be dispersed in propyl carbinol, dispersion 30min, adds the silane coupling agent that massfraction is 20%, and 70 DEG C of reaction 6h, reaction terminates rear filtered while hot, uses dehydrated alcohol repetitive scrubbing, in vacuum-drying, obtain surface-modified nano SiO in suction filtration process
2.
8. the anti-look of the automotive trim metal zip fastener according to claim 1 or 7 becomes wear-resistant protection agent; it is characterized in that: described silane coupling agent is selected from silane coupling agent KH-560; Silane coupling reagent KH-570, silane coupling agent KH-580, one or both in silane coupling agent KH-590.
9. the anti-look of automotive trim metal zip fastener according to claim 7 becomes wear-resistant protection agent, it is characterized in that: described Nano-meter SiO_2
2surface-modifying agent be selected from dimethyldichlorosilane(DMCS), monomethyl trichlorosilane, tri-methyl-chlorosilane and dimethyl dichlorosilane (DMCS) one or both.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610005768.7A CN105440847A (en) | 2016-01-06 | 2016-01-06 | Color change-preventing and wear-resistant protective agent of automotive interior metal zipper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610005768.7A CN105440847A (en) | 2016-01-06 | 2016-01-06 | Color change-preventing and wear-resistant protective agent of automotive interior metal zipper |
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|---|---|
| CN105440847A true CN105440847A (en) | 2016-03-30 |
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|---|---|---|---|
| CN201610005768.7A Pending CN105440847A (en) | 2016-01-06 | 2016-01-06 | Color change-preventing and wear-resistant protective agent of automotive interior metal zipper |
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Cited By (7)
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| CN106150645A (en) * | 2016-08-31 | 2016-11-23 | 芜湖恒耀汽车零部件有限公司 | The decorative tail tube of the automobile exhaust pipe surface treatment method of carbon fiber arc |
| CN107674737A (en) * | 2017-09-20 | 2018-02-09 | 安徽劲派纺织服饰有限公司 | Maintaining agent and preparation method thereof before a kind of metal slide fastener tooth dispatches from the factory |
| CN108677228A (en) * | 2018-06-08 | 2018-10-19 | 湖南东谷云商集团有限公司 | The anti-coated technique for darkening blackening of silver |
| CN108864911A (en) * | 2018-06-22 | 2018-11-23 | 广州森浩材料科技有限公司 | A kind of ready-made clothes metal zip fastener protective agent |
| CN111849407A (en) * | 2020-07-28 | 2020-10-30 | 浙江伟星实业发展股份有限公司 | Glue suitable for zipper, waterproof zipper and preparation method of waterproof zipper |
| CN112759958A (en) * | 2020-12-30 | 2021-05-07 | 深圳市杰昌实业有限公司 | Protective coating for metal material surface |
| CN118878898A (en) * | 2024-07-09 | 2024-11-01 | 中山市冠柔新材料有限公司 | A high-quality metal brushed decorative film and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106150645A (en) * | 2016-08-31 | 2016-11-23 | 芜湖恒耀汽车零部件有限公司 | The decorative tail tube of the automobile exhaust pipe surface treatment method of carbon fiber arc |
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| CN108677228A (en) * | 2018-06-08 | 2018-10-19 | 湖南东谷云商集团有限公司 | The anti-coated technique for darkening blackening of silver |
| CN108864911A (en) * | 2018-06-22 | 2018-11-23 | 广州森浩材料科技有限公司 | A kind of ready-made clothes metal zip fastener protective agent |
| CN111849407A (en) * | 2020-07-28 | 2020-10-30 | 浙江伟星实业发展股份有限公司 | Glue suitable for zipper, waterproof zipper and preparation method of waterproof zipper |
| CN112759958A (en) * | 2020-12-30 | 2021-05-07 | 深圳市杰昌实业有限公司 | Protective coating for metal material surface |
| CN118878898A (en) * | 2024-07-09 | 2024-11-01 | 中山市冠柔新材料有限公司 | A high-quality metal brushed decorative film and preparation method thereof |
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