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CN105428148B - The high-power compound electric connector of one kind and its processing technology - Google Patents

The high-power compound electric connector of one kind and its processing technology Download PDF

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Publication number
CN105428148B
CN105428148B CN201510809025.0A CN201510809025A CN105428148B CN 105428148 B CN105428148 B CN 105428148B CN 201510809025 A CN201510809025 A CN 201510809025A CN 105428148 B CN105428148 B CN 105428148B
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China
Prior art keywords
parts
tungsten
copper
powder
electric connector
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CN201510809025.0A
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CN105428148A (en
Inventor
吴明辉
李丽兴
谢道金
孙强
王蓉
蒋云才
熊纲强
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WUHU CHUANGJIANG ALLOY COPPER CO Ltd
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WUHU CHUANGJIANG ALLOY COPPER CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H33/00High-tension or heavy-current switches with arc-extinguishing or arc-preventing means
    • H01H33/60Switches wherein the means for extinguishing or preventing the arc do not include separate means for obtaining or increasing flow of arc-extinguishing fluid
    • H01H33/66Vacuum switches
    • H01H33/664Contacts; Arc-extinguishing means, e.g. arcing rings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • H01H11/048Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by powder-metallurgical processes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
  • Contacts (AREA)

Abstract

The invention discloses a kind of high-power compound electric connector and its processing technologys, are prepared by the raw material of following parts by weight: 20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle, iron close 5~10 parts of alloy, 2~4 parts of aluminium, 2.1~5.2 parts of chromium, 35~60 parts of zinc, 5~10 parts of heat filling.The present invention uses two-layer compound sintering technology, has produced completely new copper ferrotungsten composite contact material, has important breakthrough in terms of the copper-based composite contact material preparation of tradition, products innovation is strong.The product resistance fusion welding and Burning corrosion resistance are good, compressive resistance is high, contact electrical endurance improves for 20%, mechanical life and contact wear-resisting property is improved.Production cost can be not only reduced, and reduces the welding cost of down-stream enterprise, meanwhile, for realizing that energy conservation and environmental protection, low-carbon economy have important social benefit.

Description

The high-power compound electric connector of one kind and its processing technology
Technical field
The present invention relates to electrical contact material fields, and in particular to the high-power compound electric connector of one kind and its processing work Skill.
Background technique
In vacuum circuit breaker, the requirement of many aspects is proposed to contact material, main there are three aspects: high electricity It flows release property (electric current breaking capacity), discontinuous current characteristic (value of shutting off) and high current-carrying domestic animal property (electric conductivity).
The main silver-colored tungsten carbide material of material currently used for vacuum circuit breaker, Guillaume metal, copper-tungsten and chromiumcopper. Different materials respectively have advantage and disadvantage, and silver-colored tungsten carbide material makees conductor material, expensive using noble silver;Guillaume metal tool Have excellent, but electric current breaking capacity is undesirable;Although the good excellent breaking capacity of copper-tungsten tool and conductive power, discontinuous current Characteristic (value of shutting off) is undesirable, and due to taking infiltration process, is easy to appear copper aggregation;Chromiumcopper material potential is big, but existing Control of Impurities is more difficult in chromium material and contact material gas content is high, causes material property dispersibility high.
Summary of the invention
To solve the above problems, the present invention provides a kind of high-power compound electric connector and its processing technologys.
To achieve the above object, the technical scheme adopted by the invention is as follows:
The high-power compound electric connector of one kind and its processing technology, are prepared by the raw material of following parts by weight:
20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle, 5~10 parts of alloy of iron conjunction, aluminium 2~ 4 parts, 2.1~5.2 parts of chromium, 35~60 parts of zinc, 5~10 parts of heat filling.
Further, the iron closes alloy as any four in silicon, manganese, chromium, vanadium, titanium, tungsten, molybdenum.
Further, the heat filling is aluminium oxide, magnesia, zinc oxide, aluminium nitride, boron nitride, silicon carbide by matter Amount compares 2:2:1:1:1.
Further, include the following steps:
S1 weighs 20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle;Copper powder 20 is selected first ~30 parts, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle mixed between 3~6 μm by mesh in proportion respectively It closes, then weighs and iron conjunction 5~10 parts of alloy, 2~4 parts of aluminium, 35~60 parts of 2.1~5.2 parts of chromium, zinc mixtures, copper powder weight is added Content in the mixed powder is 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in 4.5~8.5 tons/square centimeter Pressure under compression moulding carried out at high temperature again heat treatment 2~5 hours to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours at high temperature again to being crushed after second of compression moulding, and 4.6~ It is suppressed for the third time under the pressure of 6.8 tons/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and 6~9 tons/ It is suppressed for the 4th time under the pressure of square centimeter;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again; Ensure green body after pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state, burn one to subsequent leaching A fabulous inducing action;
S5 finally by ready iron close the blank after 5~10 parts of alloy, fine copper and pre-burning be sintered together, infiltration just Obtain high-power hard copper tungsten iron composite electric contact material of the porosity less than 0.28%.
Further, the temperature of the heat treatment is 600~750 DEG C, and the time is 2~4h.
Further, the temperature of the pre-burning is 1100-1200 DEG C.
The present invention uses two-layer compound sintering technology, completely new copper ferrotungsten composite contact material has been produced, in traditional copper Base composite contact material preparation aspect has important breakthrough, and products innovation is strong.The product resistance fusion welding and Burning corrosion resistance are good, pressure-resistant Intensity is high, contact electrical endurance improves for 20%, mechanical life and contact wear-resisting property is improved.Production can not only be reduced Cost, and reduce the welding cost of down-stream enterprise, meanwhile, for realizing that energy conservation and environmental protection, low-carbon economy have important society It can benefit.
Specific embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further It is described in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this hair It is bright.
The present invention is prepared by the raw material of following parts by weight:
20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle, 5~10 parts of alloy of iron conjunction, aluminium 2~ 4 parts, 2.1~5.2 parts of chromium, 35~60 parts of zinc, 5~10 parts of heat filling.
The iron closes alloy as any four in silicon, manganese, chromium, vanadium, titanium, tungsten, molybdenum.
The heat filling is aluminium oxide, magnesia, zinc oxide, aluminium nitride, boron nitride, silicon carbide 2:2:1 in mass ratio: 1:1。
The high-power compound electric connector of one kind and its processing technology, include the following steps:
S1 weighs 20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle;Copper powder 20 is selected first ~30 parts, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle mixed between 3~6 μm by mesh in proportion respectively It closes, then weighs and iron conjunction 5~10 parts of alloy, 2~4 parts of aluminium, 35~60 parts of 2.1~5.2 parts of chromium, zinc mixtures, copper powder weight is added Content in the mixed powder is 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in 4.5~8.5 tons/square centimeter Pressure under compression moulding carried out at high temperature again heat treatment 2~5 hours to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours at high temperature again to being crushed after second of compression moulding, and 4.6~ It is suppressed for the third time under the pressure of 6.8 tons/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and 6~9 tons/ It is suppressed for the 4th time under the pressure of square centimeter;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again; Ensure green body after pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state, burn one to subsequent leaching A fabulous inducing action;
S5 finally by ready iron close the blank after 5~10 parts of alloy, fine copper and pre-burning be sintered together, infiltration just Obtain high-power hard copper tungsten iron composite electric contact material of the porosity less than 0.28%.
The temperature of the heat treatment is 600~750 DEG C, and the time is 2~4h.
The temperature of the pre-burning is 1100-1200 DEG C.
Embodiment 1:
S1 weighs 30 parts of copper powder, 40 parts of tungsten carbide, 35 parts of tungsten powder particle;First select 30 parts of copper powder, 40 parts of tungsten carbide, 35 parts of tungsten powder particle is mixed between 3~6 μm by mesh in proportion respectively, then weigh be added iron close 10 parts of alloy, 60 parts of 4 parts of aluminium, 5.2 parts of chromium, zinc mixtures, content of the copper powder weight in the mixed powder are 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in 4.5~8.5 tons/square centimeter Pressure under compression moulding carried out at high temperature again heat treatment 2~5 hours to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours at high temperature again to being crushed after second of compression moulding, and 4.6~ It is suppressed for the third time under the pressure of 6.8 tons/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and 6~9 tons/ It is suppressed for the 4th time under the pressure of square centimeter;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again; Ensure green body after pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state, burn one to subsequent leaching A fabulous inducing action;
S5 finally by ready iron close the blank after 5 parts of alloy, fine copper and pre-burning be sintered together, infiltration must hole High-power hard copper tungsten iron composite electric contact material of the gap rate less than 0.28%.
Embodiment 2:
S1 weighs 20 parts of copper powder, 10 parts of tungsten carbide, 25 parts of tungsten powder particle;20 parts of copper powder, tungsten carbide 10 are selected first Part, 25 parts of tungsten powder particle are mixed between 3~6 μm by mesh in proportion respectively, then weigh and iron conjunction alloy 5 is added 35 parts of part, 2 parts of aluminium, 2.1 parts of chromium, zinc mixtures, content of the copper powder weight in the mixed powder are 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in 4.5~8.5 tons/square centimeter Pressure under compression moulding carried out at high temperature again heat treatment 2~5 hours to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours at high temperature again to being crushed after second of compression moulding, and 4.6~ It is suppressed for the third time under the pressure of 6.8 tons/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and 6~9 tons/ It is suppressed for the 4th time under the pressure of square centimeter;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again; Ensure green body after pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state, burn one to subsequent leaching A fabulous inducing action;
S5 finally by ready iron close the blank after 10 parts of alloy, fine copper and pre-burning be sintered together, infiltration must High-power hard copper tungsten iron composite electric contact material of the porosity less than 0.28%.
Embodiment 3:
S1 weighs 25 parts of copper powder, 10 parts of tungsten carbide, 35 parts of tungsten powder particle;25 parts of copper powder, tungsten carbide 10 are selected first Part, 35 parts of tungsten powder particle are mixed between 3~6 μm by mesh in proportion respectively, then weigh and iron conjunction alloy 5 is added 60 parts of part, 2 parts of aluminium, 2.1 parts of chromium, zinc mixtures, content of the copper powder weight in the mixed powder are 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in 4.5~8.5 tons/square centimeter Pressure under compression moulding carried out at high temperature again heat treatment 2~5 hours to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours at high temperature again to being crushed after second of compression moulding, and 4.6~ It is suppressed for the third time under the pressure of 6.8 tons/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and 6~9 tons/ It is suppressed for the 4th time under the pressure of square centimeter;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again; Ensure green body after pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state, burn one to subsequent leaching A fabulous inducing action;
S5 finally by ready iron close the blank after 8 parts of alloy, fine copper and pre-burning be sintered together, infiltration must hole High-power hard copper tungsten iron composite electric contact material of the gap rate less than 0.28%.
The advantage of high-power compound electric connector:
1, the electrical contact material has the characteristics that hardness is high, wear resistance is good due to using iron to close alloy as substrate.
2, since material uses copper product, keep electric current breaking capacity, conductive capability and the electric current of the electrical contact of production disconnected The comprehensive performances height such as continuous characteristic are improved;For material within the service life period, performance uniformity is high.
3, electrical switch structure is simplified using the contact material, eliminates the dispersibility of spring in switch, increases substantially The reliability of component.
4, due to being combined into raw material using cheap copper, iron, the cost of electrical contact material is considerably reduced.
5, tungsten/tungsten carbide particle in material is controlled by the granulating process of innovation and to the meticulous selection of technological parameter The distance between, solve the problems, such as that material difficult forming and infiltration are difficult, without adding sintering aid in entire sintering process.
6, ensure that copper fully penetrates into green body when material production, produces porosity less than 0.28% by the technique of innovation Electrical contact material.
High-power hard copper ferrotungsten composite electrical contact processing technology points for attention:
1, the heat treatment carries out 2~4 hours at a temperature of 600~750 DEG C.
2, the pressure of the compacting is 4.5~8.5 tons/square centimeter.
3,1100~1200 DEG C of the temperature of the pre-burning, burn-in time are 1~2 hour.
4, the copper powder crosses 400 meshes, and the powder particle of tungsten carbide and tungsten is between 3~6 μm.
5, content of the copper powder weight in the mixed powder is 10~22%.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (5)

1. a kind of processing technology of high-power compound electric connector, which is characterized in that by the raw material preparation of following parts by weight At:
20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle, iron close 5~10 parts of alloy, 2~4 parts of aluminium, 2.1~5.2 parts of chromium, 35~60 parts of zinc, 5~10 parts of heat filling;
The processing technology of the above-mentioned high-power compound electric connector of one kind, includes the following steps:
S1 weighs 20~30 parts of copper powder, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle;Copper powder 20~30 is selected first Part, 10~40 parts of tungsten carbide, 25~35 parts of tungsten powder particle are mixed between 3~6 μm by mesh in proportion respectively, then It weighs and iron conjunction 5~10 parts of alloy, 2~4 parts of aluminium, 35~60 parts of 2.1~5.2 parts of chromium, zinc mixtures is added, copper powder weight is in institute Stating the content in mixed powder is 10~22%;
S2 carries out mixed raw material powder heat treatment 2~4 hours at high temperature, and in the pressure of 4.5~8.5 tons/square centimeter Compression moulding under power carries out heat treatment 2~5 hours at high temperature again to being crushed after first time compression moulding, and It is suppressed for the second time under the pressure of 4.6~6.8 tons/square centimeter;
S3 is carried out heat treatment 2~5 hours, and to being crushed after second of compression moulding 4.6~6.8 at high temperature again It is suppressed for the third time under the pressure of ton/square centimeter;
S4 is carried out under high temperature heat treatment 2~5 hours again to being crushed after third time compression moulding, and in 6~9 tons/square Centimetre pressure under suppressed for the 4th time;It carries out obtaining copper-tungsten blank in preheating 1~2 hour under high temperature again;Ensure After pre-burning, copper and tungsten carbide and tungsten particle have been under good wet face state green body, burn a pole to subsequent leaching Good inducing action;
S5 finally by ready iron close the blank after 5~10 parts of alloy, fine copper and pre-burning be sintered together, infiltration must hole High-power hard copper tungsten iron composite electric contact material of the gap rate less than 0.28%.
2. the processing technology of the high-power compound electric connector of one kind according to claim 1, which is characterized in that the iron Conjunction alloy is silicon, manganese, chromium, vanadium, titanium, tungsten, any four in molybdenum.
3. the processing technology of the high-power compound electric connector of one kind according to claim 1, which is characterized in that described to lead Hot filler is aluminium oxide, magnesia, zinc oxide, aluminium nitride, boron nitride, silicon carbide.
4. the processing technology of the high-power compound electric connector of one kind according to claim 1, which is characterized in that the heat The temperature of processing is 600~750 DEG C, and the time is 2~4h.
5. the processing technology of the high-power compound electric connector of one kind according to claim 1, which is characterized in that described pre- The temperature of burning is 1100-1200 DEG C.
CN201510809025.0A 2015-11-23 2015-11-23 The high-power compound electric connector of one kind and its processing technology Active CN105428148B (en)

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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3911904A1 (en) * 1988-04-16 1989-12-14 Duerrwaechter E Dr Doduco Powder-metallurgical process for producing a semifinished product for electric contacts from a silver-based composite with iron
JP3676365B2 (en) * 1993-08-23 2005-07-27 シーメンス アクチエンゲゼルシヤフト Silver-based contact material, use of this type of contact material in a power switchgear and method for producing this contact material
CN102347158A (en) * 2010-07-29 2012-02-08 蒋国泉 Processing technique for high-power hard copper-tungsten-iron (Cu-W-Fe) compound electrical contact
CN102162045B (en) * 2011-03-29 2013-04-03 温州银泰合金材料有限公司 Electrical contact based on powdered copper and manufacturing process thereof
CN102426867B (en) * 2011-08-25 2013-03-13 哈尔滨东大高新材料股份有限公司 Whisker reinforced copper-based electrical contact material and preparation method thereof

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