CN105419957B - A kind of glass cleaner composition of addition cationic polymer - Google Patents
A kind of glass cleaner composition of addition cationic polymer Download PDFInfo
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- CN105419957B CN105419957B CN201510946350.1A CN201510946350A CN105419957B CN 105419957 B CN105419957 B CN 105419957B CN 201510946350 A CN201510946350 A CN 201510946350A CN 105419957 B CN105419957 B CN 105419957B
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
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Abstract
The present invention relates to it is a kind of addition cationic polymer glass cleaner composition, it includes：A) cationic polymer of composition total weight 0.01% to about 3.0% is accounted for, the cationic polymer has following general formula：Wherein, R1, R3 are
Description
Technical field
The present invention relates to a kind of glass cleaner compositions, and in particular to for clean glass door and window, vehicle glass and its
The liquid detergent composition of his glass article surface.
Background technology
Glass has good light transmittance and cost performance because of its glossy clear, glittering and translucent, a kind of to be widely used
Construction timber and ornament materials.But glass is easy by the dirty contamination such as dust, oil stain when in use, and glass is by contamination
Afterwards, it can also seriously affect sight and arrange beautiful.Currently, glass cleaner on the market is usually by surfactant, alcohol ethers
The ingredients such as organic additive, chelating agent are constituted, and are easy to be fallen by rainwater, sewage flushing, so only have the dirt-removing power of single, without
Ability and resistance to flushing effect are maintained with long-acting cleaning effect, so needing that often glass surface is cleaned to maintain glass
The clear transparent of glass.With the improvement of living standards, people increasingly wish to free from heavy and scrappy housework, institute
Detergent product more time saving and energy saving, that cleaning effect is more longlasting is increasingly pursued with people.
By adding the more excellent parent that there is hydrophilic polymer can assign glass into cleaning glass product
It is aqueous can so that glass surface have many advantages, such as it is antifog, wash after not trace.
Addition is disclosed in United States Patent (USP) US 6331517 containing anion surfactant and maleic acid -- alkene is total
The glass cleaner composition of polymers.Since hydrophilic polymer is added so that glass surface is more hydrophilic, and contact angle is down to
25 degree hereinafter, and have preferable spreadability.The clearing glass of addition polyvinyl alcohol is disclosed in Chinese patent CN 104293499
Clean dose, the cleaning of the long period of glass surface can be kept.Addition acrylic acid-is disclosed in Chinese patent CN104611147
The glass cleaner composition of styrol copolymer can form one layer of shiny film in glass surface, it is anti-to assign glass surface
Recontamination, hydrophilic, quick-drying, the antifog and not performance of trace after washing.Addition amine oxide is disclosed in Chinese patent CN 97194477
The glass cleaner composition of polymer not only has good wetability and film-forming quality, but also can be subjected to more than three times
Rewetting cycle.Although these patents achieve certain effect in terms of surface filming and hydrophily improvement, due to this
The binding force on a little polymer and surface is not strong so that the limited duration of this hydrophilic effect, and do not have water-fast flushing
Ability.
Currently, the main component of most commercial glass is silica, and silica surface is molten more than 4 in pH value
Certain negative electrical charge (Langmuir1996,12,3188-3194) will be carried in liquid, therefore the cation with positive charge is poly-
Close object in neutral conditions with glass surface can be effectively adsorbed under alkaline condition, to change the physics and chemistry of glass surface
Matter.When this cationic polymer is also equipped with good hydrophilic and film forming characteristics, then glass surface can be not only set to have anti-
Water mist, resistant to pollution long-acting cleaning capacity, but also can have stronger resistance to rinse capability, to maintain longer cleaning to imitate
Fruit.It is disclosed in Chinese patent CN 103168093 containing a kind of hard-surface cleaning compositions of cationic polysaccharide, can be made
Hard surface hydrophiling and the resistant to pollution property of offer.But the cationic polysaccharide polymer is in the hydrophilic modifying of glass surface
The effect is unsatisfactory, and resistance to flushing effect is limited.Addition non-ionic surface is disclosed in Chinese patent CN 101821371 to live
Property agent, acid and hydrophilic polymer hard-surface cleaning compositions, although the composition achieves preferably in ceramic tile surface
Hydrophilic modifying effect, but anion surfactant and amophoteric surface active cannot be contained in the hard-surface cleaning compositions
Agent.In addition, the pH value of composition is 3 hereinafter, although this has preferable detergency for soap scum and incrustation scale, in low pH
The removal power to grease type dirt can be weakened under the conditions of value, the bright sense of glass may be influenced, while in use also
The eyes of consumer, skin may be stimulated and influence the safe to use of consumer.
It in summary it can be seen, hydrophilic polymer contributes positively to be promoted the washing effect of cleaning glass product, and assigns
The good hydrophilic effect of glass surface, but this hydrophilic effect holds time still meet with resistance to rinse capability and disappears at present
The demand of the person of expense.
Invention content
For presently commercially available glass cleaner there are the problem of, the purpose of the present invention is to provide a kind of addition cation is poly-
The glass cleaner composition for closing object is a kind of liquid for cleaning glass door and window, vehicle glass and other glass article surfaces
Body detergent composition, the glass cleaner composition can be effectively improved glass surface hydrophilicity, assign glass surface
Good water droplet spreading property, while also allowing repeatedly to be rinsed with water, assign glass surface long-acting cleaning effect.
The glass cleaner composition is composed of the following components：
1) cationic polymer of the total weight 0.01% to about 3.0% of glass cleaner composition, the cation are accounted for
Polymer has following general formula：
Wherein, R1, R3ForIn one or more, R2
It is one or more in poly (dially dialkyl) ammonium chloride, N- (quaternary ammonium group alkyl) acrylic acid amides；And the cation
The number-average molecular weight of polymer is 40,000~1,000,000；
2) the short carbon chain fat that the carbon atom number for accounting for the total weight 4% to about 40% of glass cleaner composition is 1~4
Alcohol；
3) total weight 0.1% of glass cleaner composition is accounted for about 5% surfactant system, at least contains one
Kind amphoteric surfactant or anion surfactant；
4) alkali of the total weight 0.01% to about 2% of glass cleaner composition is accounted for, the amount of the alkali is enough to make composition
The pH value range of system is 5 to 11；
5) 0.02% to about 0.8% one or more washing assisants of composition total weight are accounted for；
6) surplus is water.
The glass cleaner composition of the present invention, the preferably poly- (diallyidimethylammonium chloride of cationic polymer
Ammonium) copolymer of/acrylic acid, the copolymer of polyacrylic acid/(diallyldimethylammonium chloride)/acrylamide and they
Mixture, and the number-average molecular weight of the cationic polymer be 60,000~600,000.
The glass cleaner composition of the present invention, the amount of the cationic polymer are preferably 0.1% to about
2.0%, more preferably 0.2% to about 1.5%.
The glass cleaner composition of the present invention, the short carbon chain fatty alcohol that the carbon atom number is 1~4, preferably methanol,
Ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, glycerine, n-butanol, butanediol.
The amount of the glass cleaner composition of the present invention, the short carbon chain fatty alcohol that the carbon atom number is 1~4 is preferred
It is 4% to about 30%.
The glass cleaner composition of the present invention, the alkali are selected from ammonium hydroxide, aliphatic hydramine and alkali and alkaline earth metal ions
Hydroxide, carbonate, bicarbonate, silicate, mixture more than one or both of metasilicate.
The glass cleaner composition of the present invention, the aliphatic hydramine include ethanol amine, triethanolamine, isopropanolamine.
The glass cleaner composition of the present invention, the washing assisant are selected from ether compound, chelating agent, preservative, perfume (or spice)
It is one or more in essence, pigment, corrosion inhibitor, antioxidant etc., the content of the washing assisant be preferably 0.04% to
About 0.5%.
The glass cleaner composition of the present invention, is prepared by following processing step：
1) cationic polymer and alkali are separately added into water, and stirring and dissolving；
2) short carbon chain fatty alcohol and surfactant is added, stirs and evenly mixs；
3) washing assisant is added, adjusts solution ph, and moisturizing constant weight.
By above-mentioned technical proposal, the present invention has the advantage that is with advantageous effect：
1, the present invention provides a kind of glass cleaner composition of the hydrophilic polymer containing cationic, can effectively change
Kind glass surface hydrophilicity, assigns the good water droplet spreading property of glass surface.
2, the pH value range of composite formula is 5 to 11, and cationic polymer can tively firm be adsorbed on glass surface,
So as to allow repeatedly to be rinsed with water, and assign glass surface long-acting cleaning effect.
It 3, can be with the invention discloses a kind of glass cleaner composition that can maintain the long-acting hydrophilic effect of glass surface
The long-acting cleaning effect of glass surface and resistance to rinse capability are provided, it is more time saving and energy saving more longlasting with cleaning effect to meet people's pursuit
Detergent product demand.
Specific implementation mode
For those skilled in the art, feature of the invention, beneficial by reading the content of this disclosure
Effect and advantage will become obvious.
Unless otherwise specified, all percentages, score and ratio are calculated by the total weight of the present composition.It removes
Non- otherwise indicated, all wt in relation to ingredients listed gives the content of active material, thus they be not included in it is commercially available
The solvent or by-product that may include in the material of acquisition.This paper terms " weight content " available symbols " % " indicate.
Unless otherwise specified, all molecular weight herein are indicated as unit of dalton.
Unless otherwise specified, all preparations and test herein are happened at about 25 DEG C of environment.
Definition
Hydrophily
" hydrophilic " for describing, surface is easier that water droplet is allowed to sprawl and soak or its surface has 25 for the purpose of the present invention
It is less than 90 ° of water contact angle at DEG C.
Wetability
In the present invention, wetting is the phenomenon that solid interface is changed into solid-liquid interface by solid-air interface, and wetability refers to
A kind of liquid is in a kind of ability or tendentiousness that the surface of solids is sprawled.
Contact angle
In the present invention, contact angle refers to after dripping a drop in a solid level plane, in gas, liquid, solid three-phase point of intersection
Made by liquid-vapor interface angle theta of the tangent line across liquid and solid-liquid boundary line.The water of glass sheet surface in the present invention
Contact angle test is measured using Germany KRUSS companies DSA100 type optical contact angle measuring instruments.
Cationic polymer
In the present invention, the molecular weight of polymer is exactly the product of structural unit number and structural unit molecular weight.In fact, poly-
Close what the homologous mixture that object is identical by chemical composition and the degree of polymerization does not wait formed, i.e., by the different polymer of molecular chain length
Mixing composition, so using the size of average molecular weight characterization polymer molecule.Wherein, by molecule amount statistical average, claim
For number-average molecular weight, i.e. number-average molecular weight can be expressed as：Number-average molecular weight=(summation each component molecular weight × component molar
Number) ÷ total mole numbers.
Cationic polymer suitable for glass cleaner composition of the present invention is the polymer containing quaternary ammonium salt group, and is had
There is following general formula：
Wherein, R1, R3 areIn one or more, R2
It is one or more in poly (dially dialkyl) ammonium chloride, N- (quaternary ammonium group alkyl) acrylic acid amides；And the cation
The number-average molecular weight of polymer is 20,000~2,000,000.
Particularly preferred polymer is poly- (diallyldimethylammonium chloride)/acrylic copolymer, poly- (two in the present invention
Allyl dimethyl ammonium chloride)/acrylic acid/acrylamide copolymer and their mixture.It uses in the compositions of the present invention
To commercially available cationic polymer be that the Noverite 301 and Noverite 311 for being produced and being sold by Lubrizol companies is produced
Product.
Short carbon chain fatty alcohol
Based on the total weight of the glass cleaner composition, it is suitable for the short carbon chain of glass cleaner composition of the present invention
The content of fatty alcohol is 4%~40%, preferably 4%~30%.
The short carbon chain fatty alcohol is selected from cell alcohol and the polyalcohol that carbon atom number is 1~4, preferably methanol, ethyl alcohol, different
Propyl alcohol, ethylene glycol, propylene glycol, glycerine, n-butanol, butanediol.
Surfactant system
Surfactant system suitable for glass cleaner composition of the present invention is at least containing 0.1~5% one kind two
Property surfactant or anion surfactant.
The surfactant system provides good cleaning performance, and can reduce the surface of glass cleaner
Power provides more excellent quick humidification performance.
Zwitterionic surfactant
Zwitterionic surfactant includes betaine type amphoteric surfactant, Imidazoline Surfactants, amino acid pattern
Surfactant, amine oxide type surfactant.Zwitterionic surfactant is selected from：N- alkyl aminopropionic acid salt, N- alkyl
Glycine betaine, N- alkyl glycine salt, carboxyl glycinate, the surfactant based on alkyl imidazoline, fatty amide propyl hydroxyl
Propyl sulfonated betaine, one or more mixtures of amine oxide；C8 preferably is selected to the fatty amide propyl diformazan of C18 alkyl
Base glycine betaine, the alkyl dimethyl betaine of C8 to C18, the fatty amide propyl dimethyl amine of C8 to C18 alkyl, C8 is extremely
The alkyl dimethyl amine oxide of C18.
In some embodiments, the mixture of zwitterionic surfactant contains fatty amide propyl dimethyl beet
Alkali has following general formula：
Wherein, M+For cation；R1 is the alkyl that carbon number is 6 to 18；X is 1 to 10, preferably 1 to 5, more preferably 3；R4
It can be hydrogen or short carbon chain alkyl, contain 1~4 carbon atom, preferably be selected from methyl, ethyl, propyl, hydroxyl and replace
Ethyl, preferably methyl.
In some embodiments, the mixture of zwitterionic surfactant contains fatty alkyl propyl-dimethyl beet
Alkali has following general formula：
Wherein, M+For cation；R1 is the alkyl that carbon number is 6 to 18；X is 1 to 10, preferably 1 to 5, more preferably 3；R4
It can be hydrogen or short carbon chain alkyl, contain 1~4 carbon atom, preferably be selected from methyl, ethyl, propyl, hydroxyl and replace
Ethyl, preferably methyl.
The zwitterionic surfactant can also include fatty amide propyl dimethyls of the C8 to C18 alkyl
Amine, the alkyl dimethyl amine oxide of C8 to C18, the fatty acyl group methyl tauride of C8 to C18 alkyl.
Anion surfactant
Anion surfactant is selected from：Sulfated surfactant, sulfonate surfactant, carboxylic acid type table
One or more mixtures of face activating agent；It preferably is selected from the ethoxylated fatty alcohol sulfate of C8 to C18, the alkane of C8 to C18
Base sulfate, alpha-alkene sulfonate, alkylbenzene sulfonate, fatty acid alkyl ester sulfonate, ethoxylized fatty alcohol ether carboxylate
One kind and their mixture.
In some embodiments, the mixture of anion surfactant contains the aliphatic alcohol sulfate of ethoxylation.
Ethoxylated fatty alcohol sulfate is the derivative of ethoxylate fatty alcohol, has following general formula：
Wherein R1 is the alkyl that carbon number is 6 to 24；X is 0.5 to 30；Wherein M+For cation.R1 can be the alkane of straight chain
Base can also be the alkyl of branch；It can be the alkyl of saturation, can also be the alkane containing one or more unsaturated double-bonds
Base.It is preferred that R1 is the straight chained alkyl that carbon number is 8 to 18.X represents average ethoxylation degree, is 0.5 to 30, preferably 0.5 to 10,
More preferable 0.5 to 3.
The anion surfactant can also include alpha-alkene sulfonate, fatty acid alkyl esters sulfate, sulfo group amber
Amber hydrochlorate, disodium alkyl polyoxyethylene sulfosuccinate, one kind of alkyl sodium disulfonate or derivatives thereof and more
Kind mixture, preferably disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate salt, fatty acid methyl ester sulfate (MES), aliphatic acid carbon number preferably 8
To 18.It is preferably fatty alcohol carbon number preferably 8 to 18 that can also include, and average ethoxylation degree is preferably 2.0.
Nonionic surfactant
Nonionic surfactant is selected from：Fatty alcohol alkoxy compound, alkyl polyglycoside, fatty acid alkoxylates, fat
Fat acid ethoxylate, fatty acid alkyl alcohol amide, one or more of mixtures of ethoxylated sorbitan acid alcohol ester.
In some embodiments, non-ionic surfactant mixture preferably comprises fatty alcohol alkoxy compound, described
Fatty alcohol alkoxy compound has following general formula：
Wherein, n is 6 to 24；X is that 0.5 to 30, y is 0 to 10.
The fatty alcohol alkoxy compound is the ring-opening polymerisation under basic catalyst effect of fatty alcohol and epoxyalkane
Product, substantially mixture.Fatty alcohol includes the isomery alcohol of straight chain alcohol or branch.Alkoxy grp includes ethoxy group and the third oxygen
Group.The fatty alcohol that the preferred carbon number of fatty alcohol is 8 to 18, preferred alcohol includes but is not limited to hexanol, octanol, decyl alcohol, 2- second
Base alcohol, 3- propyl enanthols, laruyl alcohol, different three decyl alcohol, tridecanol, tetradecanol, hexadecanol, Palmitoleyl alcohol, stearyl alcohol,
One kind and its mixture of isooctadecanol, oleyl alcohol, sub- oleyl alcohol, linolenyl alcohol.Average ethoxylation degree x preferably 2 to 12.Preference
Son is SHELL companies NEODOL series linear primary alcohol ethoxylate products, the ECOSURF EH series ethoxylations of DOW companies
With the third oxidation 2-ethylhexanol product, BASF AG's Lutensol XL series ethoxylations and the third oxidation 3- propyl enanthol products
With BASF AG's Lutensol XP series ethoxylation 3- propyl enanthol products.
Non-ionic surfactant mixture can contain fatty acid alkoxylates, preferably be selected from ethoxylation C8 to C18
Aliphatic ester, average ethoxylation degree are 2 to 10.Ethoxylated sorbitan acid alcohol Arrcostab, alkyl carbon number can be contained
It is 6 to 18, average ethoxyquin degree is 4 to 20；Suitable example is Corda company's T ween series of products.
Non-ionic surfactant mixture can contain fatty acid alkyl alcohol amide, and the carbon number of aliphatic acid is 6 to 24, can
It can also be the aliphatic acid of branch to be the aliphatic acid of straight chain, can be the aliphatic acid of saturation, can also be undersaturated fat
Acid；Alkylol number is 0 to 2.The glycollic amide that preferred fatty acid carbon number is 8 to 18, diglycollic amide, isopropanol amide close
Suitable example is coconut acid diethanolamide.
Non-ionic surfactant mixture can contain alkyl polyglycoside, have following general formula：
Wherein, it is 1.1 to 3 that n, which is 6 to 24, p, and preferably n is 8 to 16.Suitable alkyl polyglycoside such as BASF AG
Glucopon series alkyl glycosides products.
Non-ionic surfactant mixture can contain fatty acid methyl ester ethoxylate, and general formula is as follows：
Wherein, n is 6 to 24；X is 2 to 20, and preferably n is that 8 to 18, x is 0.5 to 30.It is preferred that x is 4 to 10.Suitable example
It is LION companies MEE products.
Non-ionic surfactant mixture can contain polyether surfactant.Polyether surfactant is a kind of
Polymer, the nonionic surfactant containing oxidation ethylene and/or oxidation trimethylene repetitive unit, suitable example such as BASF are public
Take charge of Pluronic series of products.
Cationic surfactant
Cationic surfactant is selected from：Single long linear quaternary ammonium salt, double long linear quaternary ammonium salts, benzyl quaternary ammonium salt, hydroxyalkyl
Quaternary ammonium salt, fatty amide propyl hydroxyalkyl quaternary ammonium salt, vinyl pyrrolidone and unsaturated amides or unsaturated quaternary ammonium salt copolymerization
One or more of mixtures in obtained multi-quaternary ammonium salt.
In some embodiments, cationic surfactant mixture preferably comprises single long linear quaternary ammonium salt and double long straight
Chain quaternary ammonium salt, the list long linear quaternary ammonium salt have following general formula：
Wherein, X-It is halogen anion, sulfate ion, acetate ion or lactate ion；R1 is that carbon number is 6 to 18
Alkyl；R2 can be the alkyl chain length that carbon number is 1 to 18, can also be the aromatic compound containing aromatic ring containing phenyl ring；R4
It is short carbon chain alkyl, contains 1~4 carbon atom, selected from methyl, ethyl, propyl or the ethyl of hydroxyl substitution, preferably first
Base.
The cationic surfactant be preferably carbon number be 8 to 18 alkyl trimethyl quaternary ammonium salt, carbon number be 8 to 18
Alkyldimethylbenzylammonium quaternary ammonium salt.
Alkali
It includes one or more in following alkali to be suitble to the alkali used in glass cleaner composition of the present invention：
1) ammonium hydroxide；
2) aliphatic hydramine, such as ethanol amine, triethanolamine, isopropanolamine；
3) hydroxide of alkali and alkaline earth metal ions, carbonate, bicarbonate, silicate, metasilicate.
And the alkali be composition total weight 0.01%~2% so that the pH value range of composition system be 5 to
11。
Washing assisant
Glass cleaner composition of the present invention can be washed comprising a variety of routines for glass cleaner composition
Auxiliary agent is washed, the washing assisant is selected from ether compound, chelating agent, preservative, essence, pigment, corrosion inhibitor, antioxidant etc.
In it is one or more, and the detergent be composition total weight 0.02%~0.8%, preferably 0.04%~
0.5%.
Experimental section
The wetting evaluation experimental of sheet glass
1) newly purchase glass slide is flushed three times with clear water after cooling first with 15min is boiled in detergent, then uses acid solution
Middle immersion 1h, then clear water and deionized water is used to rinse twice respectively, it is finally placed in drying box and dries.
2) three sheets at room temperature, are impregnated into 10min in the above-mentioned cleaning glass agent solutions of 100mL, are hung after taking-up
In on clothes hanger, naturally dry at room temperature.
3) pendulum that the sheet glass after drying is clipped in pendulum washing machine is washed on frame, it is made to keep plumbness, each sheet glass leaching
Bubble is in a beaker (250mL deionized waters)；With stopwatch meter timing, sheet glass is first impregnated into 20s, then pendulum washes 3min (pendulum
The slew rate for washing instrument is set as 36 beats/min)；Sheet glass is removed, continues to be hung on clothes hanger.
4) observation clothes hanger upper glass plate surface is by the percentage of water layer area coverage.
5) wait for that sheet glass after natural drying, continues rinsing test next time at room temperature.
Appreciation gist：Rinsing back glass sheet is bigger by the accounting of water layer area coverage every time, then shows the wetting of sheet glass
Effect is better.
The hydrophilic evaluation experimental of resistance to rinsing
1) newly purchase glass slide is flushed three times with clear water after cooling first with 15min is boiled in detergent, then uses acid solution
Middle immersion 1h, then clear water and deionized water is used to rinse twice respectively, it is finally placed in drying box and dries.
2) three sheets at room temperature, are impregnated into 10min in the above-mentioned cleaning glass agent solutions of 100mL, are hung after taking-up
In on clothes hanger, naturally dry at room temperature.
3) pendulum that the sheet glass after drying is clipped in pendulum washing machine is washed on frame, it is made to keep plumbness, each sheet glass leaching
Bubble is in a beaker (250mL deionizations are housed)；With stopwatch meter timing, sheet glass is first impregnated into 20s, then pendulum washes 3min
(slew rate that pendulum washes instrument is set as 36 beats/min)；Sheet glass is removed, continues to be hung on clothes hanger, at room temperature naturally dry.
4) contact angle tester is utilized to measure the contact angle per sheets, and the contact angle for calculating three sheets is average
Value.
5) continue to rinse test next time.
Appreciation gist：The contact angle of rinsing back glass sheet is smaller every time, then shows that the wetting effect of sheet glass is better；Rinsing
Front and back contact angle variation is smaller, then shows that hydrophilic resistance to rinse capacity is better.
Compatibility
Compatibility refers to that a kind of substance coexists not in certain dicyandiamide solution with another or many kinds of substance in the present invention
It will appear layering, ability that is muddy, or even precipitating.The compatibility of substance is tested by visual observation and the evaluation of turbidity test synthesis.Mesh
Depending on obtaining transparent uniform appearance, turbidity is that compatibility is good less than 5NTU, and visual finding system is layered, muddy, or even heavy
It forms sediment, turbidity is greater than or equal to 5NTU then poor compatibilities.In liquid detergent composition, different types of anion surface active
General compatibility is good between agent, can form homogeneous and transparent mixture in water.
Anion surfactant and cationic surfactant poor compatibility, positive and negative charge when mixing in water
Neutralization forms insoluble matter, and mixture is placed for a long time and high temperature placement will appear muddy, split-phase and even precipitate.
The present invention evaluates compatibility using visually test and turbidity test synthesis.Unexpectedly, present invention discover that sun from
Sub- polymer Noverite 311 and anion surfactant and amphoteric surfactant are compatible within the scope of certain proportion
Property it is good, homogeneous and transparent mixture can be formed in water, muddy or layering will not occur in long term high temperature or low-temperature storage.
Specific embodiment
The present invention will be further elaborated by specific embodiment below, but the present invention be not limited in it is below
Embodiment.
Embodiment 1-6
The recipe ingredient and content such as the following table 1 of the glass cleaner composition 1-6 of the addition cationic polymer of the present invention
It is shown.Following table 1 is tested its and is combined to the glass cleaner of present invention addition cationic polymer by the pH value of change solution
The influence of the hydrophilic modifying of object 1-6.
Influence of 1 composition pH of table to cationic polymer hydrophilic modifying
The process of preparing of glass cleaner composition 1-6 that the present invention adds cationic polymer is：
1) cationic polymer Noverite 311 (or Noverite 301) is added to the water simultaneously stirring and dissolving；
2) NaOH aqueous solutions are added to adjust solution ph, and moisturizing constant weight.
By the test result of table 1 it can be found that by being soaked in solution under acid condition (composition 1 and composition 4)
Sheet glass after rinsing three times, contact angle is significantly greater than solution (composition 2,3,5 and 6) under neutral and weak basic condition
Contact angle.This shows that acid condition is unfavorable for the hydrophilic modifying of cationic polymer, and neutral and weak basic condition is more advantageous to
Cationic polymer plays its hydrophilic modifying effect.
Embodiment 7-11
In the glass cleaner composition 7~11 of the present invention, surfactant system includes anion surfactant, two
One or more mixtures of property ionic surface active agent, cationic surfactant, nonionic surfactant.This is because
Cationic polymer provided by the invention can be very good to be compatible with a variety of surfactants, and if under neutral and alkaline condition
It is similarly suitable.
The recipe ingredient and content of 2 glass cleaner composition 7~11 of the present invention of table
| Composition 7 | Composition 8 | Composition 9 | Composition 10 | Composition 11 | |
| Component | Content (%) | Content (%) | Content (%) | Content (%) | Content (%) |
| XP 80 | 0.3 | - | - | 0.3 | |
| AES270 | - | 0.43 | - | 0.43 | |
| BS-12 | - | - | 0.86 | 0.86 | |
| 1227 | - | - | - | 0.76 | |
| Noverite 311 | 0.68 | 0.68 | 0.68 | 0.68 | |
| Ethylene glycol | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Ethyl alcohol | 5 | 5 | 5 | 5 | 5 |
| Ammonium hydroxide | In right amount | In right amount | In right amount | In right amount | In right amount |
| Deionized water | Surplus | Surplus | Surplus | Surplus | Surplus |
| PH value | 9.1 | 9.1 | 9.0 | 5 | 9.5 |
| Solution appearance | Clear | Clear | Clear | Clear | Clear |
The process of preparing of glass cleaner composition 7-11 that the present invention adds cationic polymer is：
1) cationic polymer Noverite 311 and ammonium hydroxide are separately added into water, and stirring and dissolving；
2) it is separately added into ethylene glycol, ethyl alcohol and surfactant, is stirred and evenly mixed；
3) washing assisant is added, adjusts solution ph, and moisturizing constant weight.
The wetting evaluation experimental test result of 3 glass cleaner composition of table
The evaluation experimental of the resistance to rinsing test result of 4 sheet glass of table
By the data in table 3 and table 4 it can be proved that the sheet glass impregnated by composition 7~11 have it is more excellent
Good hydrophily；Even if being tested by 3 rinsings, glass sheet surface can still keep very excellent wetability and hydrophily.
This aspect is shown, and cationic polymer according to the present invention possesses preferable surfactant compatibility, while also table
The face glass cleaner composition according to the present invention containing cationic polymer has good resistance to flushing performance.
Embodiment 12-15
The recipe ingredient and content of 5 glass cleaner composition 12~15 of the present invention of table
The process of preparing of glass cleaner composition 12-15 that the present invention adds cationic polymer is：
1) cationic polymer Noverite 311 (or Noverite 301) and ammonium hydroxide (or NaOH solution) are added respectively
Enter in water, and stirring and dissolving；
2) it is separately added into short carbon chain fatty alcohol and surfactant, is stirred and evenly mixed；
3) washing assisant is added, adjusts solution ph, and moisturizing constant weight.
Data in table 5 fully prove that the glass cleaner composition containing cationic polymer can make sheet glass table
Face has more good hydrophily, and the hydrophilicity has preferable resistance to flushing performance.
Embodiment 16-18
The glass cleaner composition of the present invention is equally applicable to the glass cleaner product of concentration reducible.
The recipe ingredient and content of 6 glass cleaner composition 16-18 of the present invention of table
The process of preparing of glass cleaner composition 16-18 that the present invention adds cationic polymer is：
1) cationic polymer Noverite 311 (or Noverite 301) and ammonium hydroxide are separately added into water, and stirred
Dissolving；
2) it is separately added into short carbon chain fatty alcohol and surfactant, is stirred and evenly mixed；
3) washing assisant is added, adjusts solution ph, and moisturizing constant weight.
For the composition of the present invention by the hydrophilic polymer of addition cationic, the polymer, can by electrostatic interaction
To form more firm hydrophilic protective layer in glass surface, the Electrostatic Absorption of dust and glass surface can not only be prevented to make
With, and allow the water droplet of glass surface to sprawl and be more uniformly distributed, play effective scale-deposit-preventing and antifog effect.In addition, it is described sun from
The hydrophilic protective layer of sub- property water-fast can also rinse, and assign glass surface more longlasting cleaning effect.
The All Files quoted in invention content are included in herein by reference all in relevant portion.For any
The reference of file is not construed as recognizing that it is the prior art for the present invention.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, therefore
It is every without departing from technical solution of the present invention content, simply repaiied to any made by above example according to the technical essence of the invention
Change, equivalent variations and modification, in the range of still falling within technical solution of the present invention.
Claims (9)
1. a kind of glass cleaner composition of addition cationic polymer, it is characterised in that：The glass cleaner composition
It is grouped as by following groups：
A) cationic polymer of composition total weight 0.01% to 3.0% is accounted for, the cationic polymer has following general formula：
Wherein, R1, R3ForIn one or more, R2For diene
It is one or more in propyl dialkylammonium chloride, N- (quaternary ammonium group alkyl) acrylic acid amides；And the cationic polymer
Number-average molecular weight be 40,000~1,000,000；
B) the short carbon chain fatty alcohol that the carbon atom number of composition total weight 4% to 40% is 1~4 is accounted for；
C) account for the surfactant system of composition total weight 0.1% to 5%, at least contain a kind of amphoteric surfactant or
Anion surfactant；
D) account for the alkali of composition total weight 0.01% to 2%, the amount of the alkali be enough to make the pH value range of composition system be 5 to
11；
E) one or more washing assisants of composition total weight 0.02% to 0.8% are accounted for；
F) surplus is water.
2. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：The sun
Ionomer is copolymer, the polyacrylic acid/(diallydimethyl of poly- (diallyldimethylammonium chloride)/acrylic acid
Ammonium chloride)/acrylamide copolymer any one or more of mixing, the number-average molecular weight of the cationic polymer is
60,000~600,000.
3. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：The sun
The amount of ionomer is 0.1% to 2.0%.
4. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：The carbon
The short carbon chain fatty alcohol that atomicity is 1~4 is selected from methanol, ethyl alcohol, isopropanol, ethylene glycol, propylene glycol, glycerine, n-butanol, fourth two
The mixing of alcohol any one or more of.
5. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：The carbon
The amount for the short carbon chain fatty alcohol that atomicity is 1~4 is 4% to 30%.
6. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：The alkali
Selected from ammonium hydroxide, aliphatic hydramine, the hydroxide of alkali metal, the hydroxide of alkaline-earth metal, carbonate, bicarbonate, silicic acid
Mixture more than one or both of salt, metasilicate.
7. the glass cleaner composition of addition cationic polymer according to claim 6, it is characterised in that：The fat
Fat race hydramine includes ethanol amine, triethanolamine, isopropanolamine.
8. the glass cleaner composition of addition cationic polymer according to claim 1, it is characterised in that：It is described to wash
It is one or more in ether compound, chelating agent, preservative, essence, pigment, corrosion inhibitor, antioxidant to wash auxiliary agent,
The content of the washing assisant is 0.04% to 0.5%.
9. adding the glass cleaner composition of cationic polymer according to claim 1-8 any one of them, feature exists
In：It is to be prepared by following processing step：
1) cationic polymer and alkali are separately added into water, and stirring and dissolving；
2) short carbon chain fatty alcohol and surfactant is added, stirs and evenly mixs；
3) washing assisant is added, adjusts solution ph, and moisturizing constant weight.
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| CN111020608A (en) * | 2019-12-23 | 2020-04-17 | 三达奥克化学股份有限公司 | Train wheel pair bearing lubricating grease spray cleaning agent and preparation method thereof |
| CN119264990B (en) * | 2024-12-09 | 2025-03-21 | 广州市凯之达化工有限公司 | A motor vehicle sewage pipe cleaning agent and its preparation method and application |
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| US6608020B1 (en) * | 2002-09-06 | 2003-08-19 | Colgate-Palmolive Company | Liquid cleaning compositions |
| CN1639313A (en) * | 2002-02-22 | 2005-07-13 | 花王株式会社 | Antifouling detergent for hard surfaces |
| CN1960702A (en) * | 2004-03-31 | 2007-05-09 | 荷兰联合利华有限公司 | Liquid state cleansing composition with particulate optical modifiers |
| CN102388122A (en) * | 2009-03-20 | 2012-03-21 | 汽巴公司 | Fast drying ampholytic polymers for cleaning compositions |
| US8546314B2 (en) * | 2011-11-11 | 2013-10-01 | The Procter & Gamble Company | Surface treatment compositions including polyquaternium-22 and sheilding salts |
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| JP5631873B2 (en) * | 2008-06-30 | 2014-11-26 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Amphoteric polymers for hard surface treatment |
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|---|---|---|---|---|
| CN1639313A (en) * | 2002-02-22 | 2005-07-13 | 花王株式会社 | Antifouling detergent for hard surfaces |
| US6608020B1 (en) * | 2002-09-06 | 2003-08-19 | Colgate-Palmolive Company | Liquid cleaning compositions |
| CN1960702A (en) * | 2004-03-31 | 2007-05-09 | 荷兰联合利华有限公司 | Liquid state cleansing composition with particulate optical modifiers |
| CN102388122A (en) * | 2009-03-20 | 2012-03-21 | 汽巴公司 | Fast drying ampholytic polymers for cleaning compositions |
| US8546314B2 (en) * | 2011-11-11 | 2013-10-01 | The Procter & Gamble Company | Surface treatment compositions including polyquaternium-22 and sheilding salts |
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