CN105419279B - But stone carving quarter uses color inserts to a kind of pad in shoe - Google Patents
But stone carving quarter uses color inserts to a kind of pad in shoe Download PDFInfo
- Publication number
- CN105419279B CN105419279B CN201510980139.1A CN201510980139A CN105419279B CN 105419279 B CN105419279 B CN 105419279B CN 201510980139 A CN201510980139 A CN 201510980139A CN 105419279 B CN105419279 B CN 105419279B
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- CN
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- Prior art keywords
- shoe
- pad
- inserts
- stone
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Golf Clubs (AREA)
Abstract
The present invention relates to a kind of pad in shoe, but stone carving quarter uses color inserts, belongs to engraving technology field.Inserts of the present invention includes：20~35 parts of unsaturated polyester resin, 3~10 parts of styrene, 5~12 parts of methacrylic acid β hydroxyl ethyl esters, 0.5~3 part of dimethylaniline, 0.01~0.1 part of hydroquinones, 1~5 part of benzoic acid, 0.1~2 part of naphthoic acid cobalt, 30~50 parts of talcum powder, 1~6 part of titanium dioxide, pad in shoe but 13~20 parts of stone flour.Color inserts of the present invention is using unsaturated polyester resin as polymerization bonding material, add talcum powder, pad in shoe but stone flour, high temperature resistant, resistance to support and the unfading of titanium dioxide raising inserts, component raw material is solidified using curing agent, reach with pad in shoe but stone same rigidity, realize to pad in shoe but the filling of stone carved product, it is viscous mend, the purpose that colouring and color are repaired.The present invention be it is a kind of can keep bright in luster for a long time, not be afraid of high temperature, it is difficult for drop-off, integrate the color inserts for being applied to pad in shoe but stone carving quarter that colouring is repaired with filling.
Description
Technical field
The invention belongs to engraving technology field, more particularly to a kind of engraving inserts, specially a kind of pad in shoe but carve by stone carving
Use color inserts.
Background technology
But stone belongs to non-renewable rare extraordinary mineral resources to pad in shoe, is formed at the Permian epoch, is Pan-Xi Rift magmatic activity
Metamorphic product is thermally contacted with country rock.Its protolith is Neoproterozoic Sinian system kwan-yin precipice group, is strand-shallow-sea facies
The argillaceous rocks (clay rock) of deposition, is toasted by mining area and periphery Jinningian and Variscan magma, is produced chemical property and is compared
Active heat, source of the gas, by the hole in rock stratum, water body, make rock produce different degrees of physicochemical change and rotten, plus
The huge extruding of overlying rock under rock stratum occur pressure-metamorphism, after more than one hundred million years formed have obvious ribbon, striated structure
The calcic argillaceous slate made.But stone endothecium structure is close for pad in shoe, faint to the penetration of water, and with good water storage function, warp
It is wear-resisting long.
Due to the pad in shoe but distinctive structure of stone and its preciousness of raw material, to pad in shoe, but stone is adopted for increasing stone material manufacturer
Collection, engraving, and are sold, and market is also increasing for the demand of pad in shoe but stone finished product.In pad in shoe, but stone carving carves production
During, in order that product pattern and effect reach more preferably, prevent that occurring color on finished product comes off or uneven, influence production
Product are attractive in appearance and client's usage experience sense, generally require and color filling is carried out to product repair and viscous mend.For now, it is general in the industry
Painted all over using acrylic paints, cloud stone glue carries out viscous benefit, but propylene color has non-refractory, easily comes off, easily takes off
The big problem such as color, cloud stone glue is there is also non-refractory and the problems such as can not mix colours.
As computer controls the development in engraving technology, initial hand engraving is instead of, it is large quantities of that computer control is carved
After amount production and large-scale works (such as screen, mural painting) occur, mechanization production is finer than what is manually carved, and quality is more easy to
Control, the defect occurred on product is fewer and fewer, and the probability of faulty materials is also more and more lower.But various " non-inkstone " products are opened
Hair, is filled to color and the viscous demand mended is increased, and existing acrylic paints and cloud stone glue can not meet and need at all in performance
Ask.Therefore, being badly in need of one kind can preserve bright in luster for a long time, and high temperature is not afraid of again, difficult for drop-off, and hardness is close with stone material, collection
Colouring repairs the inserts being integrated with filling.
The content of the invention
The purpose of the present invention is the non-refractory existed for existing pigment and sticker, easily come off, fugitive color etc. is asked
Inscribe there is provided it is a kind of can keep bright in luster for a long time, not be afraid of high temperature, it is difficult for drop-off, integrate that colouring and filling repair it is applicable
In pad in shoe, but stone carving quarter uses color inserts.The present invention is achieved through the following technical solutions：
But stone carving quarter uses color inserts to a kind of pad in shoe, includes the raw material of following mass fraction：
Unsaturated polyester resin of the present invention selects the unsaturated polyester resin that in the market is directly bought.As a preferred embodiment,
The unsaturated polyester resin is metaphenylene unsaturated polyester resin, the metaphenylene unsaturated polyester resin of the invention selected, with
Other unsaturated polyester resins are compared, with more preferable mechanical property, toughness, heat resistance, decay resistance and stability,
The bonding polymerization of inserts can be improved by adding it in inserts, at the same the heat resistance of inserts can also be improved, it is resistance to
Corrosivity and stability.
Preferred as one kind of the present invention, the content of cobalt is 5~10% in the naphthoic acid cobalt.
Preferred as one kind of the present invention, the inserts also includes toner pigment, and the mass fraction of toner pigment is 0.1
~1 part.
Preferred as one kind of the present invention, the inserts also includes curing agent, and the mass fraction of curing agent is 1~4 part.
Preferred as one kind of the present invention, cyclohexanone peroxide paste content is not less than 2% in the curing agent, and permanent yellow contains
Amount is not less than 0.5%.It is in order that curing agent has more that curing agent of the present invention, which limits cycle-hexanone peroxide slurry and the content of permanent yellow,
Good curing performance and mobility, improve the solidification effect and stability to inserts.
In the present invention, but stone flour is, by obtained from pad in shoe but stone processing powdering, can be entered during a large amount of productions with ball mill to pad in shoe
The preparation of row pad in shoe but stone flour, amount can saw out pad in shoe but stone powder when few with saw.
Pad in shoe of the present invention but carve with each component of color inserts by stone carving, unsaturated polyester resin mainly rise bond polymerization,
Improve the heat resistance and stability action of inserts；Talcum powder, pad in shoe but stone flour, titanium dioxide mainly rise protect color, high temperature resistant, support
Effect, it, which is added, can improve the hardness of inserts, reduction inserts the problems such as dilation caused by expanding with heat and contract with cold,
Improve filling capacity of the inserts to pad in shoe but stone carved product, the adaptive capacity to environment and stability of strengthening filler, after preventing
Phase inserts or color come off.Toning raw material is that the overall color of inserts is adjusted according to the color of pad in shoe but stone carved product
Section, making it, but the color of stone carved product is corresponding with pad in shoe, and the present invention adds toning raw material in inserts, can to pad in shoe but
The function of being repaired to color is realized while stone carved product is filled, colouring and reparation are disposably completed, and save operative employee
Sequence, improves operating efficiency, reduces production cost.Styrene, methacrylic acid-beta-hydroxy ethyl ester, dimethylaniline, hydroquinones, benzene
The raw materials such as formic acid, naphthoic acid cobalt mainly play polymerization, cementation, and it is used in combination with unsaturated polyester resin, can reach phase
Mutually coordinate, improve the effect of the bonding polymerization dynamics of inserts.
Curing agent is that the component raw material that will be mixed is solidified, and is reached and pad in shoe but stone same rigidity.It is of the invention used solid
Agent can be from the common curing agent of in the market.Curing agent is mixed with each component, and inserts each component raw material is carried out
Solidification, according to being reconciled with curing agent with measuring corresponding inserts component when using, is still non-solid, just after mediation
In filling.Then by the mixture after mediation, to pad in shoe, but stone is filled, directly place after certain time bond, solidify after shape
Into the hardness as pad in shoe but stone, realize to pad in shoe but the filling of stone carved product, viscous mend and purpose that color is repaired.
Beneficial effects of the present invention：Pad in shoe of the present invention but to pad in shoe, but paint with color inserts stone carving quarter by stone carved product
And filling is repaired, using unsaturated polyester resin as main polymerisation bonding material, additional styrene, methacrylic acid-beta-hydroxy ethyl ester etc.
Raw material improves the bonding polymerization dynamics of inserts.But stone flour, the addition of titanium dioxide can improve the resistance to height of inserts for talcum powder, pad in shoe
Warm, resistance to support and unfading；Curing agent can be solidified the component raw material mixed, reach that but stone is identical hard with pad in shoe
Degree, realize to pad in shoe but the filling of stone carved product, viscous mend and purpose that color is repaired.The present invention is that one kind can keep color for a long time
It is bright-coloured, be not afraid of high temperature, it is difficult for drop-off, integrate colouring with filling repair be applied to pad in shoe but stone carving quarter uses color inserts.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1：
The outfit of pad in shoe but stone carving quarter inserts is carried out according to inventive formulation, includes the component of following mass parts：
By above-mentioned each component be filled material outfit (wherein toner pigment should according to pad in shoe but stone carving carve product colour demand
Selected), and it is that 3 parts of curing agent is reconciled to add mass fraction, the inserts after mediation is non-solid.Utilize tune
Inserts with after to pad in shoe, but filled up and painted by stone carved product, is realized to product after solidifying after a while
Filling colouring, but stone has the same hardness with pad in shoe after inserts solidification, and can with pad in shoe but stone carving carve sample perfection fill out and, it is seamless
Gap, without unnecessary inserts alluvial, do not go out any vestige filled up from the appearance.
Embodiment 2
The outfit of pad in shoe but stone carving quarter inserts is carried out according to inventive formulation, includes the component of following mass parts：
By above-mentioned each component be filled material outfit (wherein toner pigment should according to pad in shoe but stone carving carve product colour demand
Selected), and it is that 4 parts of curing agent is reconciled to add mass fraction, the inserts after mediation is non-solid.Utilize tune
Inserts with after to pad in shoe, but filled up and painted by stone carved product, is realized to product after solidifying after a while
Filling colouring, but stone has the same hardness with pad in shoe after inserts solidification, and can with pad in shoe but stone carving carve sample perfection fill out and, it is seamless
Gap, without unnecessary inserts alluvial, do not go out any vestige filled up from the appearance.
Embodiment 3
The outfit of pad in shoe but stone carving quarter inserts is carried out according to inventive formulation, includes the component of following mass parts：
By above-mentioned each component be filled material outfit (wherein toner pigment should according to pad in shoe but stone carving carve product colour demand
Selected), and it is that 2 parts of curing agent is reconciled to add mass fraction, the inserts after mediation is non-solid.Utilize tune
Inserts with after to pad in shoe, but filled up and painted by stone carved product, is realized to product after solidifying after a while
Filling colouring, but stone has the same hardness with pad in shoe after inserts solidification, and can with pad in shoe but stone carving carve sample perfection fill out and, it is seamless
Gap, without unnecessary inserts alluvial, do not go out any vestige filled up from the appearance.
Embodiment 4
In order to be able to which to pad in shoe of the present invention, but stone carving quarter is verified with the performance of color inserts, comparison of design experiment utilizes city
Common acrylic paints and cloud stone glue inserts are contrasted with inserts of the present invention on face, and specific performance is contrasted such as table 1 below institute
Show：
The inserts performance comparison result of table 1
In table, --- represent without this performance
As can be seen from Table 1, pad in shoe of the present invention can but realize the work(of colouring and filling stone carving quarter simultaneously with color inserts
Can, and heat-resisting, high temperature resistant is up to 400 DEG C, and the heat resisting temperature of acrylic paints and cloud stone glue is only 80 DEG C, color of the present invention can be protected
Hold more than 5 years, and commercially available propylene color can only be maintained 1 year or so, i.e., the problems such as easily occurring coming off, fade；Present invention filling
The hardness of material apparently higher than cloud stone glue inserts, and outward appearance can with pad in shoe but stone carving carve sample perfection fill out and, it is seamless, filled out without unnecessary
Charge is deposited, and does not see any vestige filled up, but acrylic paints can not be bonded in carving surface, cloud stone glue filling well
There is gap, hence it is evident that the vestige filled up can be found out.So, compared with existing pigment and inserts, the present invention is that a kind of energy is long-term
Keep bright in luster, be not afraid of high temperature, it is difficult for drop-off, integrate that colouring and filling repair suitable for pad in shoe but stone carving quarter color
Inserts.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
Any modifications, equivalent substitutions and improvements made within refreshing and principle etc., should be included in the scope of the protection.
Claims (5)
- But 1. stone carving quarter uses color inserts to a kind of pad in shoe, it is characterised in that include the raw material of following mass parts：
- But 2. stone carving quarter uses color inserts to a kind of pad in shoe as claimed in claim 1, it is characterised in that the unsaturated polyester resin For metaphenylene unsaturated polyester resin.
- But 3. stone carving quarter uses color inserts to a kind of pad in shoe as claimed in claim 1, it is characterised in that cobalt contains in the naphthoic acid cobalt Measure as 5~10%.
- But 4. stone carving quarter uses color inserts to a kind of pad in shoe as claimed in claim 1, it is characterised in that the inserts also includes solid Agent, the mass fraction of curing agent is 1~4 part.
- But 5. stone carving quarter uses color inserts to a kind of pad in shoe as claimed in claim 1, it is characterised in that include the original of following mass parts Material：26 parts of metaphenylene unsaturated polyester resin, 6 parts of styrene, 7 parts of methacrylic acid-beta-hydroxy ethyl ester, 1 part of dimethylaniline, to benzene 0.08 part of diphenol, 2.5 parts of benzoic acid, 0.5 part of naphthoic acid cobalt, 40 parts of talcum powder, 2.5 parts of titanium dioxide, pad in shoe but 16.2 parts of stone flour, toning 0.5 part of pigment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510980139.1A CN105419279B (en) | 2015-12-23 | 2015-12-23 | But stone carving quarter uses color inserts to a kind of pad in shoe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510980139.1A CN105419279B (en) | 2015-12-23 | 2015-12-23 | But stone carving quarter uses color inserts to a kind of pad in shoe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105419279A CN105419279A (en) | 2016-03-23 |
| CN105419279B true CN105419279B (en) | 2017-08-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510980139.1A Expired - Fee Related CN105419279B (en) | 2015-12-23 | 2015-12-23 | But stone carving quarter uses color inserts to a kind of pad in shoe |
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| Country | Link |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109291721B (en) * | 2018-09-03 | 2020-09-15 | 桂林师范高等专科学校 | Clear acquisition method for pictures and texts on cultural relics |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1625573A (en) * | 2002-04-19 | 2005-06-08 | 株式会社日本触媒 | Reactive diluent composition and curable resin composition |
| CN1676487A (en) * | 2004-04-01 | 2005-10-05 | 阮建 | Marbleize decorative material and its manufacturing process |
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN102731020A (en) * | 2012-07-09 | 2012-10-17 | 阜阳市鑫美居特艺精雕有限公司 | Artificial stone for raised pieces and preparation method of artificial stone for raised pieces |
| CN103819135A (en) * | 2013-12-31 | 2014-05-28 | 武汉武新新型建材有限公司 | Artificial stone and production process thereof |
-
2015
- 2015-12-23 CN CN201510980139.1A patent/CN105419279B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1625573A (en) * | 2002-04-19 | 2005-06-08 | 株式会社日本触媒 | Reactive diluent composition and curable resin composition |
| CN1676487A (en) * | 2004-04-01 | 2005-10-05 | 阮建 | Marbleize decorative material and its manufacturing process |
| CN101735759A (en) * | 2009-12-10 | 2010-06-16 | 江苏大力士投资有限公司 | High-performance marble glue and preparation method thereof |
| CN102731020A (en) * | 2012-07-09 | 2012-10-17 | 阜阳市鑫美居特艺精雕有限公司 | Artificial stone for raised pieces and preparation method of artificial stone for raised pieces |
| CN103819135A (en) * | 2013-12-31 | 2014-05-28 | 武汉武新新型建材有限公司 | Artificial stone and production process thereof |
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| Publication number | Publication date |
|---|---|
| CN105419279A (en) | 2016-03-23 |
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Granted publication date: 20170811 Termination date: 20181223 |