CN105409958A - 一种含氯氟氰虫酰胺和氟啶胺的农药组合物 - Google Patents
一种含氯氟氰虫酰胺和氟啶胺的农药组合物 Download PDFInfo
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- CN105409958A CN105409958A CN201510862949.7A CN201510862949A CN105409958A CN 105409958 A CN105409958 A CN 105409958A CN 201510862949 A CN201510862949 A CN 201510862949A CN 105409958 A CN105409958 A CN 105409958A
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- fluazinam
- pesticide composition
- cyantraniliprole
- insecticide
- sheath blight
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明提供了一种含有氯氟氰虫酰胺和氟啶胺的农药组合物，且氯氟氰虫酰胺与氟啶胺的重量比为50:1～1:50。本发明提供的农药组合物高效、低毒且持效期长，可同时防治农作物鳞翅目害虫和纹枯病。
Description
技术领域
本发明属于农药领域，具体涉及一种含氯氟氰虫酰胺和氟啶胺的农药组合物。
背景技术
农业害虫的抗性问题是一个全球性的问题。随着害虫化学防治的的延续、农药使用量的增加以及不科学使用农药，害虫抗性日益严重，产生抗性的害虫种类不断增多。特别是对农业生产为害严重的鳞翅目类害虫，抗性程度较高，抗性发展速度相对较快。同时，高强度的使用农药，导致农产品农药残留超标、环境污染和农民用药成本增加等，不利于农业可持续发展。因此，研究开发高效、低毒、环保的杀虫剂农药对农业可持续发展具有积极意义。
在水稻生产中，水稻在苗期阶段受到许多病虫害的影响，特别是二化螟和纹枯病等，对农业生产带来较大影响。目前，我国用于水稻苗期的农药基本上为单一防止虫害或病害，可同时防治病害和虫害的产品开发较少。因此，开发防治水稻病虫害的农药组合物，对于推进农业规模化发展具有积极意义。
氟啶胺是由日本石原产业公司开发的新型取代苯胺类、广谱杀菌剂，对灰葡萄孢引起的多种灰霉病有特效。对交链孢属、疫霉属、单轴霉属、核盘菌属和黑星菌属等病菌引起的病害亦有良好的活性。
氯氟氰虫酰胺是浙江省化工研究院自行研制的新型杀虫剂，代号ZJ4042，化学名称为：3－氯－N1－(2－甲基－4－七氟异丙基苯基)－N2－(1－甲基－1－氰基乙基)邻苯二甲酰胺，结构式如下(I)所示：
该杀虫剂属新型邻苯二甲酰胺类杀虫剂，通过激活兰尼碱受体细胞内钙释放通道，导致贮存钙离子的失控性释放，是目前为数不多的作用于昆虫细胞兰尼碱(Ryanodine)受体的化合物。对鳞翅目害虫有广谱防效。
氯氟氰虫酰胺或氟啶胺单独使用时用药成本较高，在一定程度上限制了其推广应用。将氯氟氰虫酰胺或氟啶胺混配可减少用药次数和用药成本，且扩大防治谱。因此，将氯氟氰虫酰胺和氟啶胺进行混配，是一种防治农业病虫害的有效方法。
发明内容
本发明要解决的技术问题是提供一种高效、低毒且持效期长、可有效防治农作物病虫害的农药组合物，有利于病虫害的综合治理。
为解决上述问题，本发明所采用的技术方案是：
一种农药组合物，其特征在于所述农药组合物含有氯氟氰虫酰胺和氟啶胺，且氯氟氰虫酰胺与氟啶胺的重量比为50:1～1:50。
本发明使用的氯氟氰虫酰胺，即为上述结构式(I)所示的化合物。
本发明所述农药组合物，氯氟氰虫酰胺和氟啶胺作为活性成分。优选的是，氯氟氰虫酰胺与氟啶胺的重量比为20:1～1:20。进一步优选的是，氯氟氰虫酰胺与氟啶胺的重量比为4:1～1:3。
本发明还提供了一种杀虫杀菌剂，以重量计含有5～90％上述农药组合物,其余为农业上可接受的载体和助剂。作为优选的实施方式，杀虫杀菌剂中优选含有5～40％的上述农药组合物。
本发明所述的载体可以是固体或液体，通常用于配制杀虫杀菌剂的任何载体均能使用。
合适的固体载体包括：矿物类，植物类，合成填料类和无机盐类。其中矿物类包括硅酸盐类，碳酸盐类，硫酸盐类和氧化物类。硅酸盐类例如高岭土，海泡石，珍珠陶土，蒙脱土，云母，蛭石，叶蜡石，滑石。碳酸盐类例如：碳酸钙，白云石。硫酸盐类如硫酸铵，硫酸钠，硫酸钙。氧化物类如生石灰，镁石灰，硅藻土。植物类例如：柑橘渣，玉米棒芯，谷壳粉，稻壳，大豆秸粉，烟草粉，胡桃壳，锯木粉。合成填料类如沉淀碳酸钙水合物，沉淀碳酸钙，白炭黑。无机盐类例如氯化钾，氯化钠。
液体载体包括水和有机溶剂。当有效成分为水乳剂或悬乳剂时，有机溶剂起到增溶和防冻作用。合适的有机溶剂包括芳烃，例如苯、二甲苯、甲苯、烷基苯、烷基萘和氯代芳烃；氯代脂肪烃，例如氯乙烯、三氯甲烷、二氯甲烷、氯仿、四氯化碳和多氯乙烷；脂肪烃，例如石油馏分、环己烷、轻质矿物油和石蜡。醇类例如甲醇，乙醇，异丙醇、丁醇、异丁醇，乙二醇、丙二醇、丙三醇、脂肪醇等；醚类例如甲基乙二醇醚，乙基乙二醇醚，石油醚。酮类例如丙酮、甲乙酮、甲基异丁基酮、环己酮以及异氟尔酮、N-甲基-吡咯烷酮；特种溶剂还有二甲基甲酰胺，二甲基亚砜，聚乙二醇，已腈；植物油及甲基化植物油。上述有机溶剂既可以单独使用，也可以混合使用，还可以与水一起混合使用。
本发明所述助剂可以根据需要包括表面活性剂、消泡剂、增稠剂、助悬剂和防冻剂中的一种或几种，还可以根据需要包括本行业常用的其他助剂。
表面活性剂可以是乳化剂、分散剂、稳定剂或湿润剂；可以是离子型的或非离子型的。合适的表面活性剂包括：聚丙烯酸和木质素磺酸的钠盐和钙盐；分子中含有至少12个碳原子的脂肪酸或脂肪胺与环氧乙烷和/环氧丙烷的缩聚产物；甘油、十二烷醇-1、十四烷醇-1、山梨醇、蔗糖或季戊四醇的脂肪酸酯；及它们与环氧乙烷和/或环氧丙烷的缩聚产物；它们的缩聚产物的硫酸盐或磺酸盐；在分子中至少含有10个碳原子的硫酸或磺酸的碱金属或碱土金属盐，较佳的为钠盐，如十二烷基硫酸钠、仲烷基硫酸钠、磺化蓖麻油的钠盐、烷芳基磺酸钠和十二烷基苯磺酸钠；环氧乙烷的聚合物、环氧乙烷和环氧丙烷的共聚物。
乳化剂包括非离子型乳化剂和市售的乳化剂。非离子型乳化剂优选聚氧乙烯脂肪酸脂、聚氧乙烯脂肪醇醚和聚氧乙烯脂肪氨，例如乙氧基化蓖麻油、聚氧乙烯(n20)苯乙基酚基醚油酸酯、烷基芳基聚氧乙烯聚氧丙烯醚、烷基芳基甲醛树脂聚氧乙烯醚、三苯乙烯基酚聚氧乙烯(n20)，醚磷酸化三乙醇胺盐、二苯乙基酚基聚氧乙烯醚(n18)甲醛缩合物、二苯基酚聚氧乙烯(n18)聚氧丙烯醚(n20)等。市售的乳化剂包括：农乳0201B、农乳0203B、农乳100#、农乳500#、农乳600#、农乳600-2#、农乳1601、农乳2201、农乳NP-10、农乳NP-15、农乳507#、农乳OX-635、农乳OX-622、农乳OX-653、农乳OX-667、农乳CS-7、宁乳36#。
本发明所述的分散剂包括：木质素磺酸钠、拉开粉、木质素磺酸钙、甲基萘磺酸甲醛缩合物、萘磺酸甲醛缩合物、亚甲基萘磺酸钠、油酸甲基氨基乙基磺酸钠、环氧聚醚、对叔丁基醚、二丁基萘磺酸甲醛缩合物、磷酸盐如六偏磷酸钠、烷基酚聚氧乙烯基磷酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、N-甲基-脂肪酰基-牛磺酸钠烷基酚聚氧乙烯醚甲醛缩合物、芳烷基酚聚氧乙烯醚磷酸酯烷基酚聚氧乙烯醚、蓖麻油环氧乙烷加成物、环氧乙烷-环氧丙烷嵌段共聚物烷基酚聚氧乙烯醚甲醛缩合物、烷基酚聚氧乙烯聚氧丙烯醚和甲基纤维素。
本发明所述的湿润剂包括：月桂醇硫酸钠、烷基醇聚氧乙烯基醚硫酸钠、辛基酚聚氧乙烯基醚硫酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、烷基磺酸钠、十二烷基苯磺酸钠、烷基萘磺酸钠、烷基丁二酸磺酸盐、月桂醇聚氧乙烯基醚磺酸钠、烷酰胺基牛磺酸钠、脂肪醇聚氧乙烯基醚、烷基酚聚氧乙烯基醚、聚氧乙烯聚氧丙烯嵌段聚合物、失水山梨醇脂肪酸酯聚氧乙烯基醚等。
本发明所述的增稠剂，既可以是人工合成的，例如羧甲基醇、聚乙烯醇或聚乙酸乙烯酯；也可以是天然的水溶性聚合物，例如黄原胶、明胶、阿拉伯树胶、聚乙烯吡咯烷酮、硅酸铝镁、聚乙烯醇、聚乙二醇、酚醛树脂、虫胶、羧甲基纤维素和海藻酸钠等。
本发明所述的消泡剂优选为：泡敌、硅酮类、C8～10脂肪醇、C10～20饱和脂肪酸类及酰胺等。
本发明所述的农药组合物可以按照本领域通用的方法配制成悬浮剂、乳油、水分散粒剂或油悬剂。
本发明所述的农药组合物和杀虫杀菌剂适合用于同时防治鳞翅目害虫和纹枯病，特别适合用于同时防治水稻二化螟和纹枯病。
本发明所述的农药组合物可以按普通的方法施用，如浇注、喷射、喷雾。施用量随气候条件或作物状态变化，施用时间可以在害虫危害之前或之后。保护作用的持续时间通常与组合物中单个化合物的含量有关，也与外界因素相关，例如气候，但通过使用适当的剂型可以减缓气候的影响。
本发明所述的农药组合物也可以与其它具有除草、杀菌性能的化合物混合使用，也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合使用。
本发明所述的农药组合物相比现有技术具有如下优势：
(1)组合物中二种药剂复配在一定配比范围内表现可明显扩大农药谱效果，达到病虫兼治的效果，且具有速效性好和持效性长的特点；
(2)降低了用药次数，减少农民用药成本。
具体实施方式
下面结合具体实施例来对本发明进行进一步说明，但并不将本发明局限于这些具体实施方式。本领域技术人员应该认识到，本发明涵盖了权利要求书范围内所可能包括的所有备选方案、改进方案和等效方案。
下述实施例中，固体制剂的配比为重量百分比，液体制剂的配比为体积百分比，生物活性部分的处理剂量为有效含量。
实施例1、20％氟啶胺·氯氟氰虫酰胺悬浮剂
按氟啶胺5％、氯氟氰虫酰胺15％、磷酸酯分散剂(FS3000)4％、磺酸盐润湿剂(SXC)1％、硅酸镁铝1％、黄原胶0.1％、有机硅消泡剂0.3％、乙二醇5％、余量为去离子水。将上述配方按比例进行预先粉碎，再加入砂磨机中研磨，经高剪切混合后调配制得20％氟啶胺·氯氟氰虫酰胺悬浮剂。
将制得的20％氟啶胺·氯氟氰虫酰胺悬浮剂应用于防治水稻二化螟、纹枯病。20％氟啶胺·氯氟氰虫酰胺悬浮剂按有效成分5克/亩于二化螟卵孵化幼虫发生盛期，以及纹枯病发生初期兑水均匀喷雾，药后7天对二化螟、纹枯病的防效分别为91.9％、87.8％。对照单剂30％氟啶胺悬浮剂(施药量为15克/亩)、20％氯氟氰虫酰胺悬浮剂(有效成分施药量为3克/亩)按同样方法施药，药后7天，50％氟啶胺悬浮剂对二化螟、纹枯病的防效分别为0.7％、75.2％，20％氯氟氰虫酰胺悬浮剂对二化螟、纹枯病的防效分别为80.5％、2.9％。氟啶胺和氯氟氰虫酰胺混配后可明显增加防治谱，达到病虫兼治作用，兼治防效优于单剂。
实施例2、50％氟啶胺·氯氟氰虫酰胺水分散性颗粒剂
按氟啶胺10％，氯氟氰虫酰胺40％，分散剂(NNO+木钠)5％、拉开粉BX3％、K-12(十二烷基硫酸钠)4％、粘结剂羧甲基(乙基)纤维素5％、崩解剂(葡萄糖)5％、硅藻土3％、高岭土补充至100％。按配方要求，把原药、分散剂、润湿剂、崩解剂、填料等混合均匀经气流粉碎成可湿性粉剂，然后加入适量水进行造粒、烘干、整粒得到50％氟啶胺·氯氟氰虫酰胺水分散颗粒剂。
将制得的50％氟啶胺·氯氟氰虫酰胺水分散颗粒剂应用于防治水稻二化螟、纹枯病。50％氟啶胺·氯氟氰虫酰胺水分散颗粒剂按有效成分5克/亩于二化螟卵孵化幼虫发生盛期，以及纹枯病发生初期兑水均匀喷雾，药后7天对二化螟、纹枯病的防效分别为95.2％、87.5％。对照单剂30％氟啶胺乳油(施药量为15克/亩)、20％氯氟氰虫酰胺悬浮剂(有效成分施药量为3克/亩)按同样方法施药，药后7天，30％氟啶胺悬乳油对二化螟、纹枯病的防效分别为5.7％、76.5％，20％氯氟氰虫酰胺悬浮剂对二化螟、纹枯病的防效分别为81.1％、3.7％。氟啶胺和氯氟氰虫酰胺混配后可明显增加防治谱，达到病虫兼治作用，兼治防效优于单剂。
实施例3、20％氟啶胺·氯氟氰虫酰胺乳油
氟啶胺15％，氯氟氰虫酰胺5％，十二烷基苯磺酸钙6％，三苯乙基酚聚氧乙烯醚6％，NMP8％，余量为二甲苯。将上述配方按比例混合搅拌均匀即得20％氟啶胺·氯氟氰虫酰胺乳油。
将制得的20％氟啶胺·氯氟氰虫酰胺乳油应用于防治水稻二化螟、纹枯病。20％氟啶胺·氯氟氰虫酰胺乳油按有效成分5克/亩于二化螟卵孵化幼虫发生盛期，以及纹枯病发生初期兑水均匀喷雾，药后7天对二化螟、纹枯病的防效分别为95.8％、87.6％。对照单剂30％氟啶胺乳油(施药量为15克/亩)、20％氯氟氰虫酰胺悬浮剂(有效成分施药量为3克/亩)按同样方法施药，药后7天，30％氟啶胺乳油对二化螟、纹枯病的防效分别为2.1％、70.5％，20％氯氟氰虫酰胺悬浮剂对二化螟、纹枯病的防效分别为83.2％、3.7％。氟啶胺和氯氟氰虫酰胺混配后可明显增加防治谱，达到病虫兼治作用，兼治防效优于单剂。
实施例4、20％氟啶胺·氯氟氰虫酰胺油悬剂
氟啶胺15％，氯氟氰虫酰胺5％，蓖麻油聚氧乙烯醚13％，三苯乙烯基苯酚聚氧乙烯醚磷酸酯3％，有机膨润土1％，油酸甲酯补至100％。将上述配方混合均匀后，砂磨至一定粒径即得20％氟啶胺·氯氟氰虫酰胺油悬剂。
将制得的20％氟啶胺·氯氟氰虫酰胺油悬剂应用于防治水稻二化螟、纹枯病。20％氟啶胺·氯氟氰虫酰胺悬浮剂按有效成分5克/亩于二化螟卵孵化幼虫发生盛期，以及纹枯病发生初期兑水均匀喷雾，药后7天对二化螟、纹枯病的防效分别为88.5％、89.6％。对照单剂30％氟啶胺乳油(施药量为15克/亩)、20％氯氟氰虫酰胺悬浮剂(有效成分施药量为3克/亩)按同样方法施药，药后7天，30％氟啶胺乳油对二化螟、纹枯病的防效分别为3.5％、73.4％，20％氯氟氰虫酰胺悬浮剂对二化螟、纹枯病的防效分别为81.2％、6.7％。氟啶胺和氯氟氰虫酰胺混配后可明显增加防治谱，达到病虫兼治作用，兼治防效优于单剂。
Claims (8)
1.一种农药组合物，其特征在于所述农药组合物含有氯氟氰虫酰胺和氟啶胺，且氯氟氰虫酰胺与氟啶胺的重量比为50:1～1:50。
2.按照权利要求1所述的农药组合物，其特征在于所述氯氟氰虫酰胺与氟啶胺的重量比为20:1～1:20。
3.按照权利要求2所述的农药组合物，其特征在于所述氯氟氰虫酰胺与氟啶胺的重量比为4:1～1:3。
4.一种杀虫杀菌剂，其特征在于所述杀虫杀菌剂以重量计含有5～90％的农药组合物，其余为农业上可接受的载体和助剂。
5.按照权利要求4所述的杀虫杀菌剂，其特征在于所述杀虫杀菌剂以重量计含有5～40％的农药组合物。
6.按照权利要求4所述的杀虫杀菌剂，其特征在于所述杀虫杀菌剂为悬浮剂、乳油、水分散粒剂或油悬剂。
7.按照权利要求1所述的农药组合物，其特征在于所述农药组合物用于防治鳞翅目害虫和纹枯病。
8.按照权利要求7所述的农药组合物，其特征在于所述农药组合物用于防治水稻二化螟和纹枯病。
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