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CN105366876B - Urban industry sewage disposal system - Google Patents

Urban industry sewage disposal system Download PDF

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Publication number
CN105366876B
CN105366876B CN201510616629.3A CN201510616629A CN105366876B CN 105366876 B CN105366876 B CN 105366876B CN 201510616629 A CN201510616629 A CN 201510616629A CN 105366876 B CN105366876 B CN 105366876B
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pond
inorganic
food
sewage
route
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CN105366876A (en
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陈学军
陈辉
李慧颖
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Dongying Guoan Chemical Co ltd
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Dongying Guoan Chemical Co Ltd
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Abstract

The invention discloses a kind of urban industry sewage disposal system, include the food industry sewage disinfection treatment route of parallel connection, industrial inorganic sewage disinfection treatment route and industrial organic sewage pretreatment route, the food industry sewage disinfection treatment route, industrial inorganic sewage disinfection treatment route and industrial organic sewage pretreatment route are intersected in total processing route;The food industry sewage disinfection treatment route includes the food filtering ponds one being linked in sequence, food sedimentation basin one, food filtering ponds two and food sedimentation basin two;The industrial inorganic sewage disinfection treatment route includes the inorganic filter pond one being linked in sequence, soda acid pond, oxidation pond, inorganic precipitation pond, inorganic filter pond two and membrane filtration pond;The industrial organic sewage pretreatment route includes organic filter pond and the abstraction pool being linked in sequence;Total processing route includes the anaerobic pond being linked in sequence, Aerobic Pond, wetland, detection cell and ultraviolet sterilization pond.

Description

Urban industry sewage disposal system
Technical field
The present invention relates to a kind of sewage disposal system, particularly a kind of urban industry sewage disposal system.
Background technology
In the last few years, the rate of economic development in China city was relatively fast, produces and lives and caused sewage in city Quantity is also gradually increasing, and compared with developed countries, China's treatment rate of domestic sewage is not also high, and technique has need Kind, management is also relatively backward, and average every 1,500,000 people or so just possesses a sewage treatment plant, and sewage treatment plant also be present Build effective investment utilization rate and processing water rate low problems up to standard.Wastewater treatment in China facility is relative to developed country It is also very backward.
The technique of Industrial Waste Water Treatments is more single in the prior art, mainly uses activated sludge process or chemical method, living Property influence of the sludge to environment it is smaller, but the effect removed is not so good, and the residual such as heavy metal is higher;The removal of chemical method Effect is preferable, but environment is had a great influence, and easily causes secondary pollution.
The content of the invention
The goal of the invention of the present invention is:For above-mentioned problem, there is provided one kind can have high clearance, meet Various regions city needs, and can extensively, efficiently handle the urban industry sewage disposal system of all kinds of sewage.
The technical solution adopted by the present invention is as follows:
Urban industry sewage disposal system of the present invention, including food industry sewage disinfection treatment route in parallel, industrial inorganic Sewage disinfection treatment route and industrial organic sewage pretreatment route, the food industry sewage disinfection treatment route, industrial inorganic are dirty Water pretreatment route and industrial organic sewage pretreatment route are intersected in total processing route;The food industry sewage disinfection treatment road Line includes the food filtering ponds one being linked in sequence, food sedimentation basin one, food filtering ponds two and food sedimentation basin two;The industry Inorganic sewage disinfection treatment route includes the inorganic filter pond one being linked in sequence, soda acid pond, oxidation pond, inorganic precipitation pond, inorganic mistake Filter tank two and membrane filtration pond;The industrial organic sewage pretreatment route includes organic filter pond and the abstraction pool being linked in sequence;Institute State the anaerobic pond that total processing route includes being linked in sequence, Aerobic Pond, wetland, detection cell and ultraviolet sterilization pond;The industry is organic Sewage disinfection treatment route and industrial inorganic sewage disinfection treatment route are intersected in membrane filtration pond, the WASTEWATER TREATMENT OF FOOD PROCESSING INDUSTRY route with Industrial inorganic processing route is intersected in anaerobic pond.
By adopting the above-described technical solution, the contaminant component of different types of trade effluent is different, content is different, work Industry sewage can be divided into food industry sewage, industrial inorganic sewage and industrial organic sewage, the pollutant in food industry sewage Constituent content is substantially the same with food industry sewage, predominantly N, P pollutants;In industrial inorganic sewage content of beary metal compared with Height, poisonous and hazardous organic constituentses content is higher in organic sewage;By food industry sewage and trade effluent categorised collection, pin Different preprocess methods is carried out to each different pollutant components, after different pollutant removals are fallen, focused on Shared pollutant N, P, improve treatment effeciency, have extensive adaptability, cope with the production and living process in city Middle be likely to occur all sewage.
The urban industry sewage disposal system of the present invention, the anaerobic pond is interior to be provided with nitrifier and polyP bacteria, described aerobic Denitrifying bacterium is provided with pond, delivery port is provided with detection means in the Aerobic Pond, can detect nitrogen content and phosphorus content in water, described Aerobic Pond is provided with to the half-duplex channel of anaerobic pond;The plant of wetland plantation includes 26 ~ 31% typha angustifolia, 19 ~ 22% Cattail, 32 ~ 40% reed and 16 ~ 23% chlorella.
By adopting the above-described technical solution, pollutant containing P can be effectively got rid of in the presence of polyP bacteria, in nitre Pollutant containing N can be effectively got rid of in the presence of change bacterium and denitrifying bacterium, while delivery port is provided with detection dress in Aerobic Pond Put, the processing of next step can be just carried out after ensureing that detection nitrogen content and phosphorus content are up to standard, is returned if not up to standard and continues this The processing of one step, it is such to be circularly set, can efficiently it be handled repeatedly, until the qualified place for just carrying out next step of content Reason so that by anaerobic pond and the pollutant load of the water outlet of Aerobic Pond processing in a stable scope, so that The processing of next step will not cause the reduction of final process effect because content exceedes bearing capacity, ensure the stabilization of processing system Property.Plant in wetland can effectively absorb the pollutants such as N in sewage, P.Removed by bioanalysises such as nitrifier, wetlands Fall N, P pollutant in sewage, there is the characteristics of environment-friendly, surrounding environment will not be damaged, will not more cause secondary dirt Dye.
The urban industry sewage disposal system of the present invention, the outlet of food sedimentation basin two are provided with detection means, can detected Solid particle size in filtrate;The food sedimentation basin two is provided with to the half-duplex channel for crossing food filter tank one.
Due to being provided with detection means using above-mentioned technical proposal, the pond delivery port of sedimentation basin two, can ensure to detect solid The processing of next step is just carried out after granule content is up to standard, the processing for continuing this step is returned if not up to standard, such circulation is set Put, can efficiently be handled repeatedly, until the qualified processing for just carrying out next step of content so that by filtering ponds and precipitation The pollutant load of the water outlet of pond processing is in a stable scope, so that the processing of next step will not be because of content Cause the reduction of final process effect more than bearing capacity, ensure the stability of processing system
The urban industry sewage disposal system of the present invention, the food filtering ponds one are interior to be provided with aperture plate, the grid of the aperture plate Lattice gap length is 5 ~ 8cm;Flocculation agent is provided with the food sedimentation basin one, separation filter is provided with the food sedimentation basin one Plate, the separation filter plate can be by separation of solid and liquid;Thermostat is provided with the food sedimentation basin one, temperature can be maintained constant 25 In the range of ~ 28 DEG C, the flocculation agent is 1 by mol ratio:1 ZnCl2 and sodium carboxymethylcellulose composition, the flocculation agent Concentration is 25ppm;Aperture plate is provided with the food filtering ponds two, the grid gap length of the aperture plate is 0.3 ~ 0.8cm;It is described Separation filter plate is provided with food sedimentation basin two, the separation filter plate can be by separation of solid and liquid, and the food sedimentation basin two is connected with system fertilizer System.
By adopting the above-described technical solution, the pollutant such as polybag, paper of bulky grain are disposed by filtering ponds one Deng, the solid pollutant in the interior addition flocculation agent of sedimentation basin one can largely get rid of sewage, including swill, inorganic chemical Thing etc., thermostat ensures to play a role within the scope of the optimal temperature of flocculation agent, so as to obtain optimal clearance;Filtering ponds two Aperture plate can get rid of less solid particle, and the material such as caused flock under flocculation agent effect, sedimentation basin two Interior separation filter plate can get rid of more short grained solid matter, and sewage is after preceding filtering twice, and larger solid is all Have been removed, now solid particle is less, the aperture that separate filter plate will not be caused to block, so as to cause to separate The reduction of efficiency, the solid matter separated by sedimentation basin two contain the chemical elements such as abundant N, P, S, are the good of manufacture fertilizer Good raw material, solid matter is delivered into fertilizer producing system being capable of maximum twice laid.
The urban industry sewage disposal system of the present invention, the outlet in the inorganic filter pond two is provided with detection means, can examined Survey in filtrate and contain heavy metal amount;The inorganic filter pond two is provided with to the half-duplex channel of oxidation pond.
By adopting the above-described technical solution, the delivery port of inorganic filter pond two is provided with detection means, can ensure to detect The processing of next step is just carried out after up to standard containing heavy metal amount, the processing for continuing this step, such circulation are returned if not up to standard Set, can efficiently be handled repeatedly, until the qualified processing for just carrying out next step of content so that treated water outlet Pollutant load in a stable scope so that the processing of next step will not because of content exceed bearing capacity and Cause the reduction of final process effect, ensure the stability of processing system
The urban industry sewage disposal system of the present invention, the inorganic filter pond one is provided with aperture plate, the grid of the aperture plate Gap length is 5 ~ 8cm;Use ferrite process in the oxidation pond, n (Fe in the ferrite process2+)/n(M2+)=15;It is described Inorganic flocculation agent is provided with inorganic precipitation pond, the inorganic flocculation agent is 1 by mol ratio:1:0.4:1.2 chitosan, Na2B4O7·10H2O, MgSO4·7H2O, AlCl3·6H2O is formed, and the concentration of the inorganic flocculation agent is 25ppm;It is described inorganic Filter screen is provided with filtering ponds two, the grid gap length of the filter screen is 0.05 ~ 0.08cm;The inlet and outlet in the membrane filtration pond Pressure regulating pump is equipped with, the membrane filtration pond is provided with thermostat, can maintain temperature constant in the range of 51 ~ 55 DEG C, the membrane filtration 50nm multi-channel industrial inorganic ceramic membranes are provided with pond.
By adopting the above-described technical solution, inorganic flocculation agent can effectively get rid of most heavy metal ion dirts Thing is contaminated, 99% ion can be got rid of by membrane filtration film, the processing to industrial inorganic contaminant water has the characteristics of efficient, stable.
The urban industry sewage disposal system of the present invention, aperture plate, the grid of the aperture plate are provided with the organic filter pond Gap length is 5 ~ 8cm;Sequential extractions are used in the abstraction pool, extractant is respectively:Petroleum ether, ethyl acetate:Oil Ether=1:5, ethyl acetate:Petroleum ether=1:1, ethyl acetate:Petroleum ether=5:1, ethyl acetate;The abstraction pool is provided with segregative line System, can separate organic layer with water layer;The abstraction pool is connected with fertilizer producing system.
By adopting the above-described technical solution, the organic matter in industrial organically-polluted water substantially can by sequential extractions It is removed, extractant recovery can recycle, and add the utilization rate of resource, reduce cost, meanwhile, extract Organic matter after treatment can turn into system fertilizer raw material, therefore the organic matter extracted deliver to fertilizer producing system being capable of maximum limit The twice laid of degree.
The urban industry sewage disposal system of the present invention, the detection cell are provided with and respectively lead to food sedimentation basin two, soda acid Pond, membrane filtration pond, abstraction pool, the individual event passage of anaerobic pond and wetland;Detection means is provided with the detection cell, can be detected in water Size>The content of 0.3cm solid particle, containing heavy metal amount, phosphorus content, nitrogen content and phosphorus content.
By adopting the above-described technical solution, the treatment effect of each step processing is may determine that by the detection of detection cell, when When the processing of a certain step is not up to standard, different return terminals is selected according to the content of pollutant, is handled again, so as to ensure finally to enter It is up to standard to enter each pollutant load in the sewage in ultraviolet sterilization pond so that processing system copes with produces life in city All sewage being likely to occur during work, the drop for the treatment of effect will not be caused because a certain pollutant emission is excessive It is low, ensure the stability of processing system.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
1st, rationally effectively it is arranged, different types of sewage is pre-processed, so as to ensures in different pollutions Good, stable treatment effect can still be ensured under thing emission behaviour.
2nd, segmented is provided with return-flow system, ensures the pollutant load of water outlet of segment processing in a stable scope It is interior, so that the processing of next step will not cause the reduction of final process effect because content exceedes bearing capacity, at guarantee The stability of reason system.
3rd, by the way of physical treatment, chemical treatment and biological treatment are combined, targetedly handled, environment Close friend, the ecosystem of surrounding will not be impacted, Conventional pollution can not only be got rid of in combination with the method for processing, The clearance of various pollutants is improved simultaneously, has prevented secondary pollution.
Brief description of the drawings
Fig. 1 is urban industry sewage disposal system schematic diagram;
Fig. 2 is the curve map that temperature influences on clearance;
Fig. 3 is the curve map that pH value influences on clearance;
Fig. 4 is the curve map that concentration influences on clearance;
Fig. 5 is the curve map that membrane aperture size influences on clearance;
Fig. 6 is the curve map that time of ultraviolet irradiation influences on clearances such as germ, parasite, viruses
Embodiment
Below in conjunction with the accompanying drawings, the present invention is described in detail.
In order that the object, technical solution and advantage of invention are more clearly understood, below in conjunction with drawings and Examples, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
Embodiment 1
As shown in figure 1, urban industry sewage disposal system, it is dirty to be divided into food industry sewage, industrial inorganic by trade effluent Water and industrial organic sewage separate collection;The trade effluent of separate collection passes through food industry sewage disinfection treatment route, work respectively The inorganic sewage disinfection treatment route of industry and industrial organic sewage pretreatment route are pre-processed;The food industry sewage disinfection treatment Route, industrial inorganic sewage disinfection treatment route and industrial organic sewage pretreatment route are intersected in total processing route, always handle road Line includes anaerobic pond, Aerobic Pond, wetland, detection cell and the ultraviolet sterilization pond being linked in sequence.
Food industry sewage disinfection treatment route includes the filtering ponds one being linked in sequence, sedimentation basin one, filtering ponds two and precipitation Pond two, is provided with aperture plate in filtering ponds one, and the grid gap length of aperture plate be 5cm in filtering ponds one, provided with separating in sedimentation basin one Separation of solid and liquid can be provided with aperture plate by filter plate, separation filter plate in filtering ponds two, the grid gap length of aperture plate is in filtering ponds two 0.3cm, the outlet of sedimentation basin two are provided with detection means, can detect solid particle size in filtrate, and sedimentation basin two is provided with to filtering ponds One half-duplex channel, sedimentation basin two are connected with fertilizer producing system;Food industry sewage flows through the aperture plate of filtering ponds one, filters out and is more than 5cm particle, liquid flow to sedimentation basin one, and thermostat is provided with sedimentation basin one, and thermostat keeps temperature in sedimentation basin one to maintain The flocculation agent that concentration is 25ppm is added in the range of 25 DEG C, in the sewage into sedimentation basin one, stands 2d, flocculation agent is by rubbing You are than being 1:1 ZnCl2Formed with sodium carboxymethylcellulose, can largely get rid of COD (COD) material in water, Including reducing substances such as, nitrite, sulfide, ferrous salt, detergent etc., the temperature of flocculation agent, concentration, rub You are than as shown in Figures 2 to 4, separation filter plate in sedimentation basin one is by solid, floccule etc. and liquid with the curve map of removal effect Body separates, and the liquid after separation flow to the aperture plate of filtering ponds two, filters out the particle more than 0.3cm, and liquid flow to sedimentation basin two, After standing 2d, solid and liquid are separated;Liquid of the detecting system detection after the separation of sedimentation basin two in sedimentation basin two In more than 0.3cm particulate matter content, work as granule content>During 0.2ppm, liquid flows back into filtering ponds by half-duplex channel One;Work as granule content<During 0.2ppm, liquid flow to anaerobic pond;The solid matter separated by sedimentation basin two is transported to system fertilizer system System, carry out the processing and fabricating of fertilizer.
Industrial inorganic sewage disinfection treatment route includes the inorganic filter pond one that is linked in sequence, soda acid pond, and oxidation pond is inorganic heavy Shallow lake pond, inorganic filter pond two and membrane filtration pond.The grid gap length of aperture plate is 5 ~ 8cm in inorganic filter pond one, and industrial inorganic is dirty Current pass through the aperture plate in inorganic filter tank one, and after filtering out the particle more than 5 ~ 8cm, liquid flow to soda acid pond.Used in soda acid pond Ca(OH)2Liquid is made as saturated solution, saturated solution flow to oxidation pond, ferrite process is passed through in oxidation pond, in n (Fe2+)/ n(M2+After removing heavy metal ion under conditions of)=15, liquid flow to inorganic precipitation pond.Sewage is at inorganic precipitation pond, into pond The inorganic flocculation agent that concentration is 25ppm is added, inorganic flocculation agent is 1 by mol ratio:1:0.4:1.2 chitosan, Na2B4O7· 10H2O, MgSO4·7H2O, AlCl3·6H2O form, stand 2 ~ 3d, the inorganic flocculation agent can get rid of substantial amounts of heavy metal from Son, sewage is in by inorganic precipitation pond, and after inorganic flocculation agent processing, after getting rid of substantial amounts of heavy metal ion, liquid is flow to Inorganic filter pond two, inorganic filter pond two is interior to be provided with filter screen, and the grid gap length of filter screen is 0.05cm, and liquid is by grid Filtering, filters out the particle more than 0.05cm, and the outlet in inorganic filter pond two is provided with detection means, can detect in filtrate containing a huge sum of money Category amount, inorganic filter pond two are provided with to the half-duplex channel of oxidation pond, and detection means detection is after the filtering of inorganic filter pond two Contain heavy metal amount in liquid, when containing heavy metal amount>During 3ppm, liquid flows back to oxidation pond;When containing heavy metal amount<During 3ppm, liquid It flow to membrane filtration pond.
The inlet and outlet in membrane filtration pond is equipped with pressure regulating pump, pressure regulating pump of the sewage Jing Guo the import of membrane filtration pond, pressure is adjusted For 0.32MPa, membrane filtration pond is provided with thermostat, can maintain temperature constant in the range of 51 DEG C, and it is more that 50nm is provided with membrane filtration pond Passage industrial inorganic ceramic membrane, sewage can further remove heavy metal ion compound and polymerization after inorganic ceramic membrane Thing, liquid of influence of the temperature to clearance as shown in Figure 5 after filtering passes through membrane filtration in the pore size of inorganic ceramic membrane and pond The pressure regulating pump of pond outlet, is adjusted to 0.10MPa, liquid flow to anaerobic pond by pressure.
Industrial organic sewage pretreatment route includes the organic filter pond being linked in sequence and abstraction pool, industrial organic sewage are pre- Processing route is intersected in membrane filtration pond with industrial inorganic sewage disinfection treatment route.Aperture plate, organic filter pond are provided with organic filter pond The grid gap length of interior aperture plate is 5cm, and sewage is by the aperture plate in organic filter pond, particle of the filtering more than 5cm.After filtering Sewage flow to abstraction pool, sequential extractions are passed through in abstraction pool, are respectively using extractant:Petroleum ether, ethyl acetate:Stone Oily ether=1:5, ethyl acetate:Petroleum ether=1:1, ethyl acetate:Petroleum ether=5:1, ethyl acetate is extracted, and abstraction pool is provided with Piece-rate system, organic layer can be separated with water layer, after separating, after the organic solvent recovery of organic layer, gained solid is delivered to Fertilizer producing system;Water layer flow to membrane filtration pond.
Nitrifier and polyP bacteria are provided with anaerobic pond, sewage is quiet in the presence of nitrifier and polyP bacteria in anaerobic pond 3d is put, ammoxidation can be nitrous acid by nitrifier, and it is nitric acid to retell nitrite-oxidizing, and reaction equation is as follows:
2NH4 ++3O2→2NO2 -+4H++2H2O
2NO2 -+O2→2NO3 -
PolyP bacteria is gone out after can phosphorus be assembled from water, and the sewage handled by nitrifier and polyP bacteria flow to aerobic Pond.Denitrifying bacterium is provided with Aerobic Pond, ammonolysis craft can be turned into nitrogen by denitrifying bacterium, then is released back into air, and reaction equation is such as Under:
2 NO3 + 10 e + 12 H+→ N2 + 6 H2O
Delivery port is provided with detection means in Aerobic Pond, can detect nitrogen content and phosphorus content in water, and Aerobic Pond is provided with to anaerobism The half-duplex channel in pond, detection means detection pass through nitrogen content and phosphorus content in the sewage that Aerobic Pond is handled, work as nitrogen content>8ppm, Phosphorus content>During 0.3ppm, liquid flows back into anaerobic pond by half-duplex channel;Work as nitrogen content<8ppm, phosphorus content<During 0.3ppm, liquid Body flow to wetland.
The plant of wetland plantation includes 26% typha angustifolia, 22% cattail, 32% reed and 20% chlorella, these Plant can effectively remove carbonaceous material, nitrogen substance and phosphorus containg substances in water removal, and sewage is in the presence of wetland, processing 10d, it flow to detection cell.
Detection cell leads to provided with the individual event for respectively leading to sedimentation basin two, soda acid pond, membrane filtration pond, abstraction pool, anaerobic pond and wetland Road;Detection means is provided with the detection cell, size in water can be detected>The content of 0.3cm solid particle, containing heavy metal Amount, phosphorus content, nitrogen content and phosphorus content.The size in water body after the sewage of multi step strategy distinguishes detection process in detection cell >The content of 0.3cm solid particle, containing heavy metal amount, phosphorus content, nitrogen content and phosphorus content;When the content of solid particle> During 0.2ppm, liquid flows back to filtering ponds one;When containing heavy metal amount>During 3ppm, liquid flows back into soda acid pond, works as 3ppm>Containing a huge sum of money Category amount>During 0.05ppm, liquid flows back into membrane filtration Chi Chi;Work as phosphorus content>During 0.02ppm, liquid flows back into abstraction pool, when 0.02ppm>Phosphorus content>During 0.003ppm, liquid flows back into membrane filtration pond;Work as nitrogen content>8ppm or phosphorus content>During 0.3ppm, liquid Body flows back into anaerobic pond;Work as 8ppm>Nitrogen content>0.1ppm, or 0.3ppm>Phosphorus content>During 0.1ppm, liquid flows back into wetland; Work as solid content<0.2ppm, containing heavy metal amount<0.05ppm, phosphorus content<During 0.02ppm, nitrogen content<0.1ppm, it is phosphorous Amount<During 0.1ppm, liquid flow to ultraviolet sterilization pond.
Ultraviolet sterilization pond, wavelength 200nm, the μ W.s/cm of dosage 13000 can be sent2In the range of ultraviolet waves.At multistep Water after reason is in wavelength 200nm, the μ W.s/cm of dosage 130002In the range of, handle 40s after can eliminate 99% germ, parasitism Worm, virus etc., the time is to the influence curve of clearance as shown in fig. 6, the water after multi step strategy can discharge.
Embodiment 2
As shown in figure 1, urban industry sewage disposal system, it is dirty to be divided into food industry sewage, industrial inorganic by trade effluent Water and industrial organic sewage separate collection;The trade effluent of separate collection passes through food industry sewage disinfection treatment route, work respectively The inorganic sewage disinfection treatment route of industry and industrial organic sewage pretreatment route are pre-processed;The food industry sewage disinfection treatment Route, industrial inorganic sewage disinfection treatment route and industrial organic sewage pretreatment route are intersected in total processing route, always handle road Line includes anaerobic pond, Aerobic Pond, wetland, detection cell and the ultraviolet sterilization pond being linked in sequence.
Food industry sewage disinfection treatment route includes the filtering ponds one being linked in sequence, sedimentation basin one, filtering ponds two and precipitation Pond two, is provided with aperture plate in filtering ponds one, and the grid gap length of aperture plate be 8cm in filtering ponds one, provided with separating in sedimentation basin one Separation of solid and liquid can be provided with aperture plate by filter plate, separation filter plate in filtering ponds two, the grid gap length of aperture plate is in filtering ponds two 0.8cm, the outlet of sedimentation basin two are provided with detection means, can detect solid particle size in filtrate, and sedimentation basin two is provided with to filtering ponds One half-duplex channel, sedimentation basin two are connected with fertilizer producing system;Food industry sewage flows through the aperture plate of filtering ponds one, filters out and is more than 8cm particle, liquid flow to sedimentation basin one, and thermostat is provided with sedimentation basin one, and thermostat keeps temperature in sedimentation basin one to maintain The flocculation agent that concentration is 25ppm is added in the range of 28 DEG C, in the sewage into sedimentation basin one, stands 3d, flocculation agent is by rubbing You are than being 1:1 ZnCl2Formed with sodium carboxymethylcellulose, can largely get rid of COD (COD) material in water, Including reducing substances such as, nitrite, sulfide, ferrous salt, detergent etc., the separation filter plate in sedimentation basin one will be solid Body, floccule etc. separate with liquid, and the liquid after separation flow to the aperture plate of filtering ponds two, filter out the particle more than 0.8cm, liquid Body flow to sedimentation basin two, and after standing 3d, solid and liquid are separated;Sedimentation basin is passed through in detecting system detection in sedimentation basin two The content of particulate matter in liquid after two separation more than 0.3cm, works as granule content>During 0.2ppm, liquid is by unidirectional logical Road flows back into filtering ponds one;Work as granule content<During 0.2ppm, liquid flow to anaerobic pond;The solids separated by sedimentation basin two Matter is transported to fertilizer producing system, carries out the processing and fabricating of fertilizer.
Industrial inorganic sewage disinfection treatment route includes the inorganic filter pond one that is linked in sequence, soda acid pond, and oxidation pond is inorganic heavy Shallow lake pond, inorganic filter pond two and membrane filtration pond.The grid gap length of aperture plate is 8cm in inorganic filter pond one, industrial inorganic sewage Stream is by the aperture plate in inorganic filter tank one, and after filtering out the particle more than 8cm, liquid flow to soda acid pond.Ca is used in soda acid pond (OH)2Liquid is made as saturated solution, saturated solution flow to oxidation pond, ferrite process is passed through in oxidation pond, in n (Fe2+)/n (M2+After removing heavy metal ion under conditions of)=15, liquid flow to inorganic precipitation pond.Sewage is at inorganic precipitation pond, into pond The inorganic flocculation agent that concentration is 25ppm is added, inorganic flocculation agent is 1 by mol ratio:1:0.4:1.2 chitosan, Na2B4O7· 10H2O, MgSO4·7H2O, AlCl3·6H2O form, stand 3d, the inorganic flocculation agent can get rid of substantial amounts of heavy metal from Son, sewage is in by inorganic precipitation pond, and after inorganic flocculation agent processing, after getting rid of substantial amounts of heavy metal ion, liquid is flow to Inorganic filter pond two, inorganic filter pond two is interior to be provided with filter screen, and the grid gap length of filter screen is 0.08cm, and liquid is by grid Filtering, filters out the particle more than 0.08cm, and the outlet in inorganic filter pond two is provided with detection means, can detect in filtrate containing a huge sum of money Category amount, inorganic filter pond two are provided with to the half-duplex channel of oxidation pond, and detection means detection is after the filtering of inorganic filter pond two Contain heavy metal amount in liquid, when containing heavy metal amount>During 3ppm, liquid flows back to oxidation pond;When containing heavy metal amount<During 3ppm, liquid It flow to membrane filtration pond.
The inlet and outlet in membrane filtration pond is equipped with pressure regulating pump, pressure regulating pump of the sewage Jing Guo the import of membrane filtration pond, pressure is adjusted For 0.32MPa, membrane filtration pond is provided with thermostat, can maintain temperature constant in the range of 55 DEG C, and it is more that 50nm is provided with membrane filtration pond Passage industrial inorganic ceramic membrane, sewage can further remove heavy metal ion compound and polymerization after inorganic ceramic membrane Thing, the liquid after filtering pass through the pressure regulating pump of membrane filtration pond outlet, pressure are adjusted into 0.10MPa, liquid flow to anaerobic pond.
Industrial organic sewage pretreatment route includes the organic filter pond being linked in sequence and abstraction pool, industrial organic sewage are pre- Processing route is intersected in membrane filtration pond with industrial inorganic sewage disinfection treatment route.Aperture plate, organic filter pond are provided with organic filter pond The grid gap length of interior aperture plate is 8cm, and sewage is by the aperture plate in organic filter pond, particle of the filtering more than 8cm.After filtering Sewage flow to abstraction pool, sequential extractions are passed through in abstraction pool, are respectively using extractant:Petroleum ether, ethyl acetate:Stone Oily ether=1:5, ethyl acetate:Petroleum ether=1:1, ethyl acetate:Petroleum ether=5:1, ethyl acetate is extracted, and abstraction pool is provided with Piece-rate system, organic layer can be separated with water layer, after separating, after the organic solvent recovery of organic layer, gained solid is delivered to Fertilizer producing system;Water layer flow to membrane filtration pond.
Nitrifier and polyP bacteria are provided with anaerobic pond, sewage is quiet in the presence of nitrifier and polyP bacteria in anaerobic pond 5d is put, ammoxidation can be nitrous acid by nitrifier, and it is nitric acid to retell nitrite-oxidizing, and reaction equation is as follows:
2NH4 ++3O2→2NO2 -+4H++2H2O
2NO2 -+O2→2NO3 -
PolyP bacteria is gone out after can phosphorus be assembled from water, and the sewage handled by nitrifier and polyP bacteria flow to aerobic Pond.Denitrifying bacterium is provided with Aerobic Pond, ammonolysis craft can be turned into nitrogen by denitrifying bacterium, then is released back into air, and reaction equation is such as Under:
2 NO3 + 10 e + 12 H+→ N2 + 6 H2O
Delivery port is provided with detection means in Aerobic Pond, can detect nitrogen content and phosphorus content in water, and Aerobic Pond is provided with to anaerobism The half-duplex channel in pond, detection means detection pass through nitrogen content and phosphorus content in the sewage that Aerobic Pond is handled, work as nitrogen content>8ppm, Phosphorus content>During 0.3ppm, liquid flows back into anaerobic pond by half-duplex channel;Work as nitrogen content<8ppm, phosphorus content<During 0.3ppm, liquid Body flow to wetland.
The plant of wetland plantation includes 26% typha angustifolia, 19% cattail, 32% reed and 23% chlorella, these Plant can effectively remove carbonaceous material, nitrogen substance and phosphorus containg substances in water removal, and sewage is in the presence of wetland, processing 15d, it flow to detection cell.
Detection cell leads to provided with the individual event for respectively leading to sedimentation basin two, soda acid pond, membrane filtration pond, abstraction pool, anaerobic pond and wetland Road;Detection means is provided with the detection cell, size in water can be detected>The content of 0.3cm solid particle, containing heavy metal Amount, phosphorus content, nitrogen content and phosphorus content.The size in water body after the sewage of multi step strategy distinguishes detection process in detection cell >The content of 0.3cm solid particle, containing heavy metal amount, phosphorus content, nitrogen content and phosphorus content;When the content of solid particle> During 0.2ppm, liquid flows back to filtering ponds one;When containing heavy metal amount>During 3ppm, liquid flows back into soda acid pond, works as 3ppm>Containing a huge sum of money Category amount>During 0.05ppm, liquid flows back into membrane filtration Chi Chi;Work as phosphorus content>During 0.02ppm, liquid flows back into abstraction pool, when 0.02ppm>Phosphorus content>During 0.003ppm, liquid flows back into membrane filtration pond;Work as nitrogen content>8ppm or phosphorus content>During 0.3ppm, liquid Body flows back into anaerobic pond;Work as 8ppm>Nitrogen content>0.1ppm, or 0.3ppm>Phosphorus content>During 0.1ppm, liquid flows back into wetland; Work as solid content<0.2ppm, containing heavy metal amount<0.05ppm, phosphorus content<During 0.02ppm, nitrogen content<0.1ppm, it is phosphorous Amount<During 0.1ppm, liquid flow to ultraviolet sterilization pond.
Ultraviolet sterilization pond, wavelength 275nm, the μ W.s/cm of dosage 15000 can be sent2In the range of ultraviolet waves.At multistep Water after reason is in wavelength 275nm, the μ W.s/cm of dosage 150002In the range of, handle 60s after can eliminate 99% germ, parasitism Worm, virus etc., the water after multi step strategy can discharge.
Embodiment 3
As shown in figure 1, urban industry sewage disposal system, it is dirty to be divided into food industry sewage, industrial inorganic by trade effluent Water and industrial organic sewage separate collection;The trade effluent of separate collection passes through food industry sewage disinfection treatment route, work respectively The inorganic sewage disinfection treatment route of industry and industrial organic sewage pretreatment route are pre-processed;The food industry sewage disinfection treatment Route, industrial inorganic sewage disinfection treatment route and industrial organic sewage pretreatment route are intersected in total processing route, always handle road Line includes anaerobic pond, Aerobic Pond, wetland, detection cell and the ultraviolet sterilization pond being linked in sequence.
Food industry sewage disinfection treatment route includes the filtering ponds one being linked in sequence, sedimentation basin one, filtering ponds two and precipitation Pond two, is provided with aperture plate in filtering ponds one, and the grid gap length of aperture plate be 7cm in filtering ponds one, provided with separating in sedimentation basin one Separation of solid and liquid can be provided with aperture plate by filter plate, separation filter plate in filtering ponds two, the grid gap length of aperture plate is in filtering ponds two 0.5cm, the outlet of sedimentation basin two are provided with detection means, can detect solid particle size in filtrate, and sedimentation basin two is provided with to filtering ponds One half-duplex channel, sedimentation basin two are connected with fertilizer producing system;Food industry sewage flows through the aperture plate of filtering ponds one, filters out and is more than 7cm particle, liquid flow to sedimentation basin one, and thermostat is provided with sedimentation basin one, and thermostat keeps temperature in sedimentation basin one to maintain In the range of 26 DEG C, in the sewage into sedimentation basin one add concentration be 25ppm flocculation agent, stand 2.5d, flocculation agent by Mol ratio is 1:1 ZnCl2Formed with sodium carboxymethylcellulose, can largely get rid of COD (COD) thing in water Matter, including reducing substances such as, nitrite, sulfide, ferrous salt, detergent etc., the separation filter plate in sedimentation basin one Solid, floccule etc. are separated with liquid, the liquid after separation flow to the aperture plate of filtering ponds two, filters out more than 0.5cm Grain, liquid flow to sedimentation basin two, and after standing 2.5d, solid and liquid are separated;Detecting system detection warp in sedimentation basin two The content of the particulate matter in the liquid after sedimentation basin two separates more than 0.3cm is crossed, works as granule content>During 0.2ppm, liquid warp Cross half-duplex channel and flow back into filtering ponds one;Work as granule content<During 0.2ppm, liquid flow to anaerobic pond;Separated by sedimentation basin two Solid matter be transported to fertilizer producing system, carry out the processing and fabricating of fertilizer.
Industrial inorganic sewage disinfection treatment route includes the inorganic filter pond one that is linked in sequence, soda acid pond, and oxidation pond is inorganic heavy Shallow lake pond, inorganic filter pond two and membrane filtration pond.The grid gap length of aperture plate is 7cm in inorganic filter pond one, industrial inorganic sewage Stream is by the aperture plate in inorganic filter tank one, and after filtering out the particle more than 7cm, liquid flow to soda acid pond.Ca is used in soda acid pond (OH)2Liquid is made as saturated solution, saturated solution flow to oxidation pond, ferrite process is passed through in oxidation pond, in n (Fe2+)/n (M2+After removing heavy metal ion under conditions of)=15, liquid flow to inorganic precipitation pond.Sewage is at inorganic precipitation pond, into pond The inorganic flocculation agent that concentration is 25ppm is added, inorganic flocculation agent is 1 by mol ratio:1:0.4:1.2 chitosan, Na2B4O7· 10H2O, MgSO4·7H2O, AlCl3·6H2O form, stand 2.5d, the inorganic flocculation agent can get rid of substantial amounts of heavy metal from Son, sewage is in by inorganic precipitation pond, and after inorganic flocculation agent processing, after getting rid of substantial amounts of heavy metal ion, liquid is flow to Inorganic filter pond two, inorganic filter pond two is interior to be provided with filter screen, and the grid gap length of filter screen is 0.07cm, and liquid is by grid Filtering, filters out the particle more than 0.07cm, and the outlet in inorganic filter pond two is provided with detection means, can detect in filtrate containing a huge sum of money Category amount, inorganic filter pond two are provided with to the half-duplex channel of oxidation pond, and detection means detection is after the filtering of inorganic filter pond two Contain heavy metal amount in liquid, when containing heavy metal amount>During 3ppm, liquid flows back to oxidation pond;When containing heavy metal amount<During 3ppm, liquid It flow to membrane filtration pond.
The inlet and outlet in membrane filtration pond is equipped with pressure regulating pump, pressure regulating pump of the sewage Jing Guo the import of membrane filtration pond, pressure is adjusted For 0.32MPa, membrane filtration pond is provided with thermostat, can maintain temperature constant in the range of 53 DEG C, and it is more that 50nm is provided with membrane filtration pond Passage industrial inorganic ceramic membrane, sewage can further remove heavy metal ion compound and polymerization after inorganic ceramic membrane Thing, the liquid after filtering pass through the pressure regulating pump of membrane filtration pond outlet, pressure are adjusted into 0.10MPa, liquid flow to anaerobic pond.
Industrial organic sewage pretreatment route includes the organic filter pond being linked in sequence and abstraction pool, industrial organic sewage are pre- Processing route is intersected in membrane filtration pond with industrial inorganic sewage disinfection treatment route.Aperture plate, organic filter pond are provided with organic filter pond The grid gap length of interior aperture plate is 7cm, and sewage is by the aperture plate in organic filter pond, particle of the filtering more than 7cm.After filtering Sewage flow to abstraction pool, sequential extractions are passed through in abstraction pool, are respectively using extractant:Petroleum ether, ethyl acetate:Stone Oily ether=1:5, ethyl acetate:Petroleum ether=1:1, ethyl acetate:Petroleum ether=5:1, ethyl acetate is extracted, and abstraction pool is provided with Piece-rate system, organic layer can be separated with water layer, after separating, after the organic solvent recovery of organic layer, gained solid is delivered to Fertilizer producing system;Water layer flow to membrane filtration pond.
Nitrifier and polyP bacteria are provided with anaerobic pond, sewage is quiet in the presence of nitrifier and polyP bacteria in anaerobic pond 4d is put, ammoxidation can be nitrous acid by nitrifier, and it is nitric acid to retell nitrite-oxidizing, and reaction equation is as follows:
2NH4 ++3O2→2NO2 -+4H++2H2O
2NO2 -+O2→2NO3 -
PolyP bacteria is gone out after can phosphorus be assembled from water, and the sewage handled by nitrifier and polyP bacteria flow to aerobic Pond.Denitrifying bacterium is provided with Aerobic Pond, ammonolysis craft can be turned into nitrogen by denitrifying bacterium, then is released back into air, and reaction equation is such as Under:
2 NO3 + 10 e + 12 H+→ N2 + 6 H2O
Delivery port is provided with detection means in Aerobic Pond, can detect nitrogen content and phosphorus content in water, and Aerobic Pond is provided with to anaerobism The half-duplex channel in pond, detection means detection pass through nitrogen content and phosphorus content in the sewage that Aerobic Pond is handled, work as nitrogen content>8ppm, Phosphorus content>During 0.3ppm, liquid flows back into anaerobic pond by half-duplex channel;Work as nitrogen content<8ppm, phosphorus content<During 0.3ppm, liquid Body flow to wetland.
The plant of wetland plantation includes 31% typha angustifolia, 20% cattail, 33% reed and 16% chlorella, these Plant can effectively remove carbonaceous material, nitrogen substance and phosphorus containg substances in water removal, and sewage is in the presence of wetland, processing 13d, it flow to detection cell.
Detection cell leads to provided with the individual event for respectively leading to sedimentation basin two, soda acid pond, membrane filtration pond, abstraction pool, anaerobic pond and wetland Road;Detection means is provided with the detection cell, size in water can be detected>The content of 0.3cm solid particle, containing heavy metal Amount, phosphorus content, nitrogen content and phosphorus content.The size in water body after the sewage of multi step strategy distinguishes detection process in detection cell >The content of 0.3cm solid particle, containing heavy metal amount, phosphorus content, nitrogen content and phosphorus content;When the content of solid particle> During 0.2ppm, liquid flows back to filtering ponds one;When containing heavy metal amount>During 3ppm, liquid flows back into soda acid pond, works as 3ppm>Containing a huge sum of money Category amount>During 0.05ppm, liquid flows back into membrane filtration Chi Chi;Work as phosphorus content>During 0.02ppm, liquid flows back into abstraction pool, when 0.02ppm>Phosphorus content>During 0.003ppm, liquid flows back into membrane filtration pond;Work as nitrogen content>8ppm or phosphorus content>During 0.3ppm, liquid Body flows back into anaerobic pond;Work as 8ppm>Nitrogen content>0.1ppm, or 0.3ppm>Phosphorus content>During 0.1ppm, liquid flows back into wetland; Work as solid content<0.2ppm, containing heavy metal amount<0.05ppm, phosphorus content<During 0.02ppm, nitrogen content<0.1ppm, it is phosphorous Amount<During 0.1ppm, liquid flow to ultraviolet sterilization pond.
Ultraviolet sterilization pond, wavelength 255nm, the μ W.s/cm of dosage 14000 can be sent2In the range of ultraviolet waves.At multistep Water after reason is in wavelength 255nm, the μ W.s/cm of dosage 140002In the range of, handle 50s after can eliminate 99% germ, parasitism Worm, virus etc., the water after multi step strategy can discharge.
Embodiment 4
The plant of wetland plantation includes 30% typha angustifolia, 21% cattail, 33% reed and 16% chlorella.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.

Claims (7)

1. urban industry sewage disposal system, it is characterised in that include the food industry sewage disinfection treatment route of parallel connection, industrial nothing Machine sewage disinfection treatment route and industrial organic sewage pretreatment route, the food industry sewage disinfection treatment route, industrial inorganic Sewage disinfection treatment route and industrial organic sewage pretreatment route are intersected in total processing route;The food industry sewage disinfection treatment Route includes the food filtering ponds one being linked in sequence, food sedimentation basin one, food filtering ponds two and food sedimentation basin two;The work The inorganic sewage disinfection treatment route of industry includes the inorganic filter pond one that is linked in sequence, soda acid pond, oxidation pond, and inorganic precipitation pond is inorganic Filtering ponds two and membrane filtration pond;The industrial organic sewage pretreatment route includes organic filter pond and the abstraction pool being linked in sequence; Total processing route includes the anaerobic pond being linked in sequence, Aerobic Pond, wetland, detection cell and ultraviolet sterilization pond;The industry has Machine sewage disinfection treatment route is intersected in membrane filtration pond, the WASTEWATER TREATMENT OF FOOD PROCESSING INDUSTRY route with industrial inorganic sewage disinfection treatment route Anaerobic pond is intersected in industrial inorganic processing route;
Is provided with nitrifier and polyP bacteria in the anaerobic pond, the Aerobic Pond is interior to be provided with denitrifying bacterium, water outlet in the Aerobic Pond Mouth is provided with detection means, can detect nitrogen content and phosphorus content in water, and the Aerobic Pond is provided with to the half-duplex channel of anaerobic pond;It is described The plant of wetland plantation includes 26 ~ 31% typha angustifolia, 19 ~ 22% cattail, 32 ~ 40% reed and 16 ~ 23% chlorella.
2. urban industry sewage disposal system as claimed in claim 1, it is characterised in that:The outlet of food sedimentation basin two is set There is detection means, solid particle size in filtrate can be detected;The food sedimentation basin two is provided with unidirectional to food filtering ponds one Passage.
3. urban industry sewage disposal system as claimed in claim 2, it is characterised in that:It is provided with the food filtering ponds one Aperture plate, the grid gap length of the aperture plate is 5 ~ 8cm;Flocculation agent, the food precipitation are provided with the food sedimentation basin one Separation filter plate is provided with pond one, the separation filter plate can be by separation of solid and liquid;Thermostat, energy are provided with the food sedimentation basin one Maintain temperature constant in the range of 25 ~ 28 DEG C, the flocculation agent is 1 by mol ratio:1 ZnCl2And sodium carboxymethylcellulose Composition, the concentration of the flocculation agent is 25ppm;Aperture plate is provided with the food filtering ponds two, the grid gap of the aperture plate is big Small is 0.3 ~ 0.8cm;Separation filter plate is provided with the food sedimentation basin two, the separation filter plate can be by separation of solid and liquid, the food Product sedimentation basin two is connected with fertilizer producing system.
4. the urban industry sewage disposal system as described in claim 1 or 3, it is characterised in that:The inorganic filter pond two Outlet is provided with detection means, can detect and contain heavy metal amount in filtrate;The inorganic filter pond two, which is provided with to the unidirectional of oxidation pond, to be led to Road.
5. urban industry sewage disposal system as claimed in claim 4, it is characterised in that:The inorganic filter pond one is provided with grid Net, the grid gap length of the aperture plate is 5 ~ 8cm;Use ferrite process in the oxidation pond, n (Fe in the ferrite process2 +)/n(M2+)=15;Inorganic flocculation agent is provided with the inorganic precipitation pond, the inorganic flocculation agent is 1 by mol ratio:1:0.4: 1.2 chitosan, Na2B4O7·10H2O, MgSO4·7H2O, AlCl3·6H2O is formed, and the concentration of the inorganic flocculation agent is 25ppm;Filter screen is provided with the inorganic filter pond two, the grid gap length of the filter screen is 0.05 ~ 0.08cm;The membrane filtration The inlet and outlet in pond is equipped with pressure regulating pump, and the membrane filtration pond is provided with thermostat, can maintain the constant model at 51 ~ 55 DEG C of temperature In enclosing, 50nm multi-channel industrial inorganic ceramic membranes are provided with the membrane filtration pond.
6. the urban industry sewage disposal system as described in claim 2 or 5, it is characterised in that:Set in the organic filter pond There is aperture plate, the grid gap length of the aperture plate is 5 ~ 8cm;Sequential extractions are used in the abstraction pool, extractant is respectively: Petroleum ether, ethyl acetate:Petroleum ether=1:5, ethyl acetate:Petroleum ether=1:1, ethyl acetate:Petroleum ether=5:1, ethyl acetate; The abstraction pool is provided with piece-rate system, can separate organic layer with water layer;The abstraction pool is connected with fertilizer producing system.
7. urban industry sewage disposal system as claimed in claim 6, it is characterised in that:The detection cell is provided with and respectively led to Food sedimentation basin two, soda acid pond, membrane filtration pond, abstraction pool, the individual event passage of anaerobic pond and wetland;Detection is provided with the detection cell Device, size in water can be detected>The content of 0.3cm solid particle, containing heavy metal amount, phosphorus content, nitrogen content and phosphorus content.
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CN205115218U (en) * 2015-09-25 2016-03-30 张荣斌 City industrial wastewater treatment system

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CN103011529A (en) * 2012-12-07 2013-04-03 常州大学 Industrial wastewater treatment technology
CN203768188U (en) * 2014-04-03 2014-08-13 安徽蓝鼎环保能源科技有限公司 Wind-power complementary integrated wastewater treatment system
CN104829043A (en) * 2015-04-20 2015-08-12 江西金达莱环保股份有限公司 Method for treatment of foodstuff wastewater based on technology of facultative anaerobic membrane bioreactor
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