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CN105350277A - Low-temperature bleaching formula and technology for cellulose fiber spunlace nonwoven fabric - Google Patents

Low-temperature bleaching formula and technology for cellulose fiber spunlace nonwoven fabric Download PDF

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Publication number
CN105350277A
CN105350277A CN201510951778.5A CN201510951778A CN105350277A CN 105350277 A CN105350277 A CN 105350277A CN 201510951778 A CN201510951778 A CN 201510951778A CN 105350277 A CN105350277 A CN 105350277A
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Prior art keywords
bleaching
nonwoven fabric
cellulose fibre
working solution
low
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CN201510951778.5A
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Inventor
李颖君
张庆
李慧霞
王蓉
张乃舒
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Shanghai Textile Research Institute
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Shanghai Textile Research Institute
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Priority to CN201510951778.5A priority Critical patent/CN105350277A/en
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Abstract

The invention relates to the technical field of spinning, particularly to a low-temperature bleaching formula and technology for cellulose fiber spunlace nonwoven fabric. The low-temperature bleaching formula for the cellulose fiber spunlace nonwoven fabric is characterized by comprising 0.5-5 g/L of caustic soda, 5-20 g/L of 30% hydrogen peroxide, 2-20 mu mol/L of Schiff base metal complexes, 1-2 g/L of a stabilizer and 0.5-2 g/L of a penetrating scouring agent. Compared with the prior art, the low-temperature bleaching technology has the advantages as follows: the low-temperature technology is adopted for scouring and bleaching, the technology is shortened, steps are simple, treated cellulose fibers or nonwoven fabric meets subsequent production requirements, and the working efficiency is greatly improved. With the adoption of the low-temperature technology, the flow is shortened, consumption of water, electricity and steam is substantially reduced, damage to the cellulose fibers is reduced, and the product quality can be improved.

Description

A kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth and technique thereof
Technical field
The present invention relates to textile technology field, specifically a kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth and technique thereof.
Background technology
Cellulose fibre spunlace non-woven cloth, the particularly conventional production process of cotton spunlace non-woven cloth be first by raw cotton opening picking, comb and parallel cotton fibers prior to spinning, cross lapping, multiple roll drawing-off, degreasing bleaching, then water sting, dry, reel, obtain finished product.Namely all foreign material, impurity are bleached together, this technique generally will through 5-6 hour, temperatures as high 98-100 DEG C, and some factories are even up to 105 DEG C, and not only length consuming time, water, electricity, the vapour energy are high, and waste is large, and cost is high.The sequencing of degreasing bleaching and water thorn operation is exchanged by another technique, and established technology is improved to raw cotton, opening picking, comb and parallel cotton fibers prior to spinning, cross lapping, multiple roll drawing-off, water thorn, degreasing bleaching, oven dry, winding, finished product.Avoid with cotton the problem that fine impurities when being raw material not easily removes, and further increase the cleanliness factor of product.But degreasing bleaching process still carries out boiling in drift pot, the density of yardage roll and the requirement such as shaping differ, and the energy consumptions such as the yardage roll of different densities need adopt different technique, and operation easier is high, and the time is long, water, electricity, gas are high, and production cost is high.The boiling and bleaching process that research is applied to fabric is innumerable, but rarely has people to study application about the boiling and bleaching process of non-weaving cloth.
Summary of the invention
The present invention is for overcoming the deficiencies in the prior art, and adopt low temperature process to carry out kiering, bleaching, process shortens, step is simple, and the cellulose fibre after process or nonwoven fabric meet the requirement of subsequent production, greatly provide operating efficiency.
For achieving the above object, design a kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth, it is characterized in that: bleaching formulation is made up of caustic soda, 30% hydrogen peroxide, Schiff base metal complexes, stabilizing agent, infiltration scouring agent, and its content is respectively: caustic soda is 0.5 ~ 5g/L; 30% hydrogen peroxide is 5 ~ 20g/L; Schiff base metal complexes is 2 ~ 20 μm of ol/L; Stabilizing agent is 1 ~ 2g/L; Infiltration scouring agent is 0.5 ~ 2g/L.
Described Schiff base metal complexes is amino acids presence of Schiff-base complex, comprises schiff bases copper complex, schiff bases cobalt complex and the violent complex of schiff bases.
Described stabilizing agent is sodium metasilicate or magnesium chloride or organophosphor acids stabilizing agent.
Described infiltration scouring agent is the combination of one or more surfactants of isomery 13C alcohol polyoxyethylene ether (9EO), isomery 13C alcohol polyoxyethylene ether (7EO), plant polyenoid phenol non-ionic surface active agent.
The concrete steps of cellulose fibre bleaching are as follows:
(1) working solution of preparation bleaching according to a certain percentage, is added in bucking kier;
(2) in bucking kier, drop into cellulose fibre, cellulose fibre is 1:5 ~ 10 with the weight ratio of bleaching working solution;
(3) temperature of the bleaching working solution in bucking kier is raised to 60 ~ 80 DEG C, the processing time is 60 ~ 120 minutes;
(4) cellulose fibre after kiering, bleaching is carried out washing, dewater stand-by;
(5) the cellulose fibre carding after dehydration, water are stung into nonwoven fabric;
(6) nonwoven fabric after being stung by water is dried, winding, finished product.
Cellulose fibre nonwoven fabric concrete steps are as follows:
(1) working solution of preparation bleaching according to a certain percentage, is added in bucking kier;
(2) in bucking kier, drop into the nonwoven fabric roll of non-degreasing bleaching, nonwoven fabric roll is 1:5 ~ 10 with the weight ratio of bleaching working solution;
(3) temperature of the bleaching working solution in bucking kier is raised to 60 ~ 80 DEG C, the processing time is 60 ~ 120 minutes;
(4) nonwoven fabric roll after kiering, bleaching is washed;
(5) nonwoven fabric roll after washing carried out drying, reel, finished product.
Compared with the existing technology, adopt low temperature process to carry out kiering, bleaching, process shortens, step is simple, and the cellulose fibre after process or nonwoven fabric meet the requirement of subsequent production, greatly provide operating efficiency in the present invention.Low temperature process not only shortens flow process, and the consumption first mate of water power vapour reduces, and decreases cellulose fibre damage, is conducive to the raising of product quality.
Detailed description of the invention
Embodiment 1
Nonwoven fabric raw material: type Y, grade 2 grades, principal length are the raw cotton of 28.
Raw cotton spunlace non-woven cloth production stage is as follows:
One, conventional shredding, removal of impurities, rolling and combing are carried out to raw cotton;
Two, low-temperature blanching technique is carried out to raw cotton;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add raw cotton, raw cotton is 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) raw cotton after process is carried out discharge opeing, washing, dewaters stand-by;
(5) by the raw cotton carding after dehydration, water thorn, oven dry, winding, finished product.
Bleaching Working solution prescription is as follows: caustic soda is 4g/L; 30% hydrogen peroxide is 15g/L; Schiff bases manganese complex is 20 μm of ol/L; Sodium metasilicate is 1g/L; Isomery 13C alcohol polyoxyethylene ether (9EO) is 1g/L; Plant polyenoid phenol non-ionic surface active agent NSF-10E is 1g/L.
Wherein, the structural formula of schiff bases manganese complex is as follows:
Embodiment 2
Nonwoven fabric raw material: viscose staple fibre, specification is 1.5D × 38mm.
Viscose acetal fibre spunlace non-woven cloth production stage is as follows:
One, conventional shredding, removal of impurities, rolling and combing are carried out to viscose acetal fibre;
Two, low-temperature blanching technique is carried out to viscose acetal fibre;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add viscose staple fibre, viscose staple fibre is 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) by the viscose staple fibre discharge opeing after process, washing, dewaters stand-by;
(5) by the viscose staple fibre carding after dehydration, water thorn, oven dry, winding, finished product.
Bleaching Working solution prescription is as follows: caustic soda is 1g/L; 30% hydrogen peroxide is 5g/L; Schiff bases manganese complex is 2 μm of ol/L; Organic phosphates stabilizing agent DTPMPSNa is 2g/L; Isomery 13C alcohol polyoxyethylene ether (7EO) is 0.2g/L; Plant polyenoid phenol non-ionic surface active agent NSF-9 is 0.3g/L.
Wherein, the structural formula of schiff bases cobalt complex is as follows:
Embodiment 3
Nonwoven fabric raw material: type Y, grade 2 grades, principal length are the raw cotton 70% of 28; Polyester staple fiber 30%.Raw cotton, polyester blended short-fiber spunlaced nonwoven production step is as follows:
One, conventional shredding, removal of impurities, blending, rolling and combing are carried out to raw cotton, polyester blended staple fibre;
Two, low-temperature blanching technique is carried out to raw cotton, polyester blended staple fibre;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add raw cotton, polyester blended staple fibre, raw cotton, polyester blended staple fibre are 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) raw cotton after process, polyester blended staple fibre are carried out discharge opeing, washing, dewaters stand-by;
(5) raw cotton after dehydration, polyester blended staple fibre are carried out carding, water thorn, oven dry, winding, finished product.
Boil drift Working solution prescription as follows: caustic soda is 2g/L; 30% hydrogen peroxide is 6g/L; Schiff bases copper complex is 10 μm of ol/L; Magnesium chloride hexahydrate is 1.5g/L; Isomery 13C alcohol polyoxyethylene ether (7EO) is 0.5g/L; Plant polyenoid phenol non-ionic surface active agent NSF-10E is 0.5g/L.
Wherein, the structural formula of schiff bases copper complex is as follows:
Implementation result is as shown in table 1:
Table 1
Embodiment 1 Embodiment 2 Embodiment 3
Whiteness 82.3 87.6 85.6
Water absorption 21g/g 17g/g 19g/g
Absorbent time 4.2s 3.5s 4s/s
Flexibility Good Good Good
Comprehensive Assessment Good Good Good
Embodiment 4
Nonwoven fabric roll: 100% cotton, specification is 150 grams/m 2.
Cotton spunlace non-woven cloth production stage is as follows:
One, conventional shredding, removal of impurities, rolling and combing are carried out to raw cotton;
Two, low-temperature blanching technique;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add cotton, cotton is 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) cotton after process is carried out discharge opeing, washing, dewaters stand-by;
(5) cotton after dehydration is carried out carding, water thorn, oven dry, winding, finished product.
Boil drift Working solution prescription as follows: caustic soda is 3g/L; 30% hydrogen peroxide is 12g/L; Schiff bases manganese complex is 20 μm of ol/L; Sodium metasilicate is 2g/L; Isomery 13C alcohol polyoxyethylene ether (9EO) is 1.5g/L; Plant polyenoid phenol non-ionic surface active agent NSF-10E is 0.5g/L.
Wherein, the structural formula of schiff bases manganese complex is as follows:
Embodiment 5
Nonwoven fabric roll: 70% viscose acetal fibre, 30% polyester fiber, specification is 50 grams/m 2.
Viscose, polyester blended fiber spun-laced nonwoven production step is as follows:
One, conventional shredding, removal of impurities, rolling and combing are carried out to viscose, polyester blended fiber;
Two, low-temperature blanching technique;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add viscose, polyester blended fiber, viscose, polyester blended fiber are 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) viscose after process, polyester blended fiber are carried out discharge opeing, washing, dewaters stand-by;
(5) viscose after dehydration, polyester blended fiber are carried out carding, water thorn, oven dry, winding, finished product.
Boil drift Working solution prescription as follows: caustic soda is 0.5g/L; 30% hydrogen peroxide is 5g/L; Schiff bases cobalt complex is 2 μm of ol/L; Organic phosphates stabilizing agent DTPMPSNa xfor 1g/L; Isomery 13C alcohol polyoxyethylene ether (7EO) is 0.2g/L; Plant polyenoid phenol non-ionic surface active agent NSF-9 is 0.3g/L.
Wherein, the structural formula of schiff bases cobalt complex is as follows:
Embodiment 6
Nonwoven fabric roll: cotton 70%, polyester fiber 30%, specification is 100 grams/m 2.
Cotton, polyester blended fiber spun-laced nonwoven production step is as follows:
One, conventional shredding, removal of impurities, blending, rolling and combing are carried out to cotton, polyester blended fiber;
Two, low-temperature blanching technique;
Step is as follows:
(1) preparation bleaching working solution, adds bucking kier;
(2) add cotton, polyester blended fiber, cotton, polyester blended fiber is 1:5 with the weight ratio of bleaching working solution;
(3) raised temperature to 80 DEG C, the processing time is 60 minutes;
(4) cotton after process, polyester blended fiber are carried out discharge opeing, washing, dewaters stand-by;
(5) cotton after dehydration, polyester blended fiber are carried out carding, water thorn, oven dry, winding, finished product.
Boil drift Working solution prescription as follows: caustic soda is 2g/L; 30% hydrogen peroxide is 10g/L; Schiff bases copper complex is 10 μm of ol/L; Magnesium chloride hexahydrate is 2g/L; Isomery 13C alcohol polyoxyethylene ether (7EO) is 1g/L; Plant polyenoid phenol non-ionic surface active agent NSF-10E is 0.5g/L.
Wherein, the structural formula of schiff bases copper complex is as follows:
Implementation result is as shown in table 2:
Table 2
Embodiment 4 Embodiment 5 Embodiment 6
Whiteness 84.2 88.5 85.6
Water absorption 22g/g 20g/g 19g/g
Absorbent time 4.5s 3.1s 4.2s/s
Flexibility Good Good Good
Comprehensive Assessment Good Good Good

Claims (6)

1. for a cold bleaching formula for cellulose fibre spunlace non-woven cloth, it is characterized in that: bleaching formulation is made up of caustic soda, 30% hydrogen peroxide, Schiff base metal complexes, stabilizing agent, infiltration scouring agent, and its content is respectively: caustic soda is 0.5 ~ 5g/L; 30% hydrogen peroxide is 5 ~ 20g/L; Schiff base metal complexes is 2 ~ 20 μm of ol/L; Stabilizing agent is 1 ~ 2g/L; Infiltration scouring agent is 0.5 ~ 2g/L.
2. a kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth according to claim 1, it is characterized in that: described Schiff base metal complexes is amino acids presence of Schiff-base complex, comprise schiff bases copper complex, schiff bases cobalt complex and the violent complex of schiff bases.
3. a kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth according to claim 1, is characterized in that: described stabilizing agent is sodium metasilicate or magnesium chloride or organophosphor acids stabilizing agent.
4. a kind of cold bleaching formula for cellulose fibre spunlace non-woven cloth according to claim 1, is characterized in that: described infiltration scouring agent is the combination of one or more surfactants of isomery 13C alcohol polyoxyethylene ether (9EO), isomery 13C alcohol polyoxyethylene ether (7EO), plant polyenoid phenol non-ionic surface active agent.
5. for a cold bleaching technique for cellulose fibre spunlace non-woven cloth, it is characterized in that: the concrete steps of cellulose fibre bleaching are as follows:
(1) working solution of preparation bleaching according to a certain percentage, is added in bucking kier;
(2) in bucking kier, drop into cellulose fibre, cellulose fibre is 1:5 ~ 10 with the weight ratio of bleaching working solution;
(3) temperature of the bleaching working solution in bucking kier is raised to 60 ~ 80 DEG C, the processing time is 60 ~ 120 minutes;
(4) cellulose fibre after kiering, bleaching is carried out washing, dewater stand-by;
(5) the cellulose fibre carding after dehydration, water are stung into nonwoven fabric;
(6) nonwoven fabric after being stung by water is dried, winding, finished product.
6. for a cold bleaching technique for cellulose fibre spunlace non-woven cloth, it is characterized in that: cellulose fibre nonwoven fabric concrete steps are as follows:
(1) working solution of preparation bleaching according to a certain percentage, is added in bucking kier;
(2) in bucking kier, drop into the nonwoven fabric roll of non-degreasing bleaching, nonwoven fabric roll is 1:5 ~ 10 with the weight ratio of bleaching working solution;
(3) temperature of the bleaching working solution in bucking kier is raised to 60 ~ 80 DEG C, the processing time is 60 ~ 120 minutes;
(4) nonwoven fabric roll after kiering, bleaching is washed;
(5) nonwoven fabric roll after washing carried out drying, reel, finished product.
CN201510951778.5A 2015-12-16 2015-12-16 Low-temperature bleaching formula and technology for cellulose fiber spunlace nonwoven fabric Pending CN105350277A (en)

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Cited By (6)

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CN109355895A (en) * 2018-10-29 2019-02-19 浙江三元纺织有限公司 A kind of hydrogen peroxide catalyzed bleaching pre-treating method of cone yarn
CN109535444A (en) * 2018-11-30 2019-03-29 泸州北方纤维素有限公司 The bleaching process of hydroxyethyl cellulose
CN109837733A (en) * 2019-01-29 2019-06-04 合肥市东方美捷分子材料技术有限公司 A kind of cellulose fibre ecological energy-saving degreasing bleaching process
CN111793969A (en) * 2020-07-17 2020-10-20 深圳全棉时代科技有限公司 Light bleaching method of composite non-woven fabric
CN116043555A (en) * 2023-01-05 2023-05-02 江苏新瑞贝科技股份有限公司 Bio-based super-soft pretreatment scouring agent and preparation method and application thereof
CN116163143A (en) * 2022-12-28 2023-05-26 多恩生物科技有限公司 Low-temperature multifunctional scouring agent and application thereof in low-temperature boiling and bleaching one-bath process

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109355895A (en) * 2018-10-29 2019-02-19 浙江三元纺织有限公司 A kind of hydrogen peroxide catalyzed bleaching pre-treating method of cone yarn
CN109535444A (en) * 2018-11-30 2019-03-29 泸州北方纤维素有限公司 The bleaching process of hydroxyethyl cellulose
CN109837733A (en) * 2019-01-29 2019-06-04 合肥市东方美捷分子材料技术有限公司 A kind of cellulose fibre ecological energy-saving degreasing bleaching process
CN109837733B (en) * 2019-01-29 2021-08-31 合肥市东方美捷分子材料技术有限公司 Vitamin state energy-saving degreasing bleaching process for cellulose fibers
CN111793969A (en) * 2020-07-17 2020-10-20 深圳全棉时代科技有限公司 Light bleaching method of composite non-woven fabric
CN116163143A (en) * 2022-12-28 2023-05-26 多恩生物科技有限公司 Low-temperature multifunctional scouring agent and application thereof in low-temperature boiling and bleaching one-bath process
CN116043555A (en) * 2023-01-05 2023-05-02 江苏新瑞贝科技股份有限公司 Bio-based super-soft pretreatment scouring agent and preparation method and application thereof

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Application publication date: 20160224