CN105331063A - Thermoplastic prepared from algae - Google Patents
Thermoplastic prepared from algae Download PDFInfo
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- CN105331063A CN105331063A CN201510736063.8A CN201510736063A CN105331063A CN 105331063 A CN105331063 A CN 105331063A CN 201510736063 A CN201510736063 A CN 201510736063A CN 105331063 A CN105331063 A CN 105331063A
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- Prior art keywords
- algae
- thermoplastic
- prepared
- multipolymer
- hydroxybutyrate
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- 241000195493 Cryptophyta Species 0.000 title claims abstract description 51
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 36
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 36
- 239000002994 raw material Substances 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000004014 plasticizer Substances 0.000 claims abstract description 13
- 229920002988 biodegradable polymer Polymers 0.000 claims abstract description 11
- 239000004621 biodegradable polymer Substances 0.000 claims abstract description 11
- 229920000098 polyolefin Polymers 0.000 claims abstract description 11
- -1 poly(lactic acid) Polymers 0.000 claims description 12
- WHBMMWSBFZVSSR-UHFFFAOYSA-M 3-hydroxybutyrate Chemical compound CC(O)CC([O-])=O WHBMMWSBFZVSSR-UHFFFAOYSA-M 0.000 claims description 11
- WHBMMWSBFZVSSR-UHFFFAOYSA-N R3HBA Natural products CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 claims description 11
- 239000004902 Softening Agent Substances 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 240000002900 Arthrospira platensis Species 0.000 claims description 5
- 235000016425 Arthrospira platensis Nutrition 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 229940082787 spirulina Drugs 0.000 claims description 5
- NDPLAKGOSZHTPH-UHFFFAOYSA-N 3-hydroxyoctanoic acid Chemical compound CCCCCC(O)CC(O)=O NDPLAKGOSZHTPH-UHFFFAOYSA-N 0.000 claims description 4
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 claims description 4
- 108010082495 Dietary Plant Proteins Proteins 0.000 claims description 4
- 108010073771 Soybean Proteins Proteins 0.000 claims description 4
- 235000019710 soybean protein Nutrition 0.000 claims description 4
- 241000195649 Chlorella <Chlorellales> Species 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 3
- 241000192710 Microcystis aeruginosa Species 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920001273 Polyhydroxy acid Polymers 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920008262 Thermoplastic starch Polymers 0.000 claims description 3
- 229920002494 Zein Polymers 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 108010050792 glutenin Proteins 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 239000004628 starch-based polymer Substances 0.000 claims description 3
- 239000005019 zein Substances 0.000 claims description 3
- 229940093612 zein Drugs 0.000 claims description 3
- SJZRECIVHVDYJC-UHFFFAOYSA-N 4-hydroxybutyric acid Chemical compound OCCCC(O)=O SJZRECIVHVDYJC-UHFFFAOYSA-N 0.000 claims description 2
- 229940006015 4-hydroxybutyric acid Drugs 0.000 claims description 2
- 241000192542 Anabaena Species 0.000 claims description 2
- 244000056139 Brassica cretica Species 0.000 claims description 2
- 235000003351 Brassica cretica Nutrition 0.000 claims description 2
- 235000003343 Brassica rupestris Nutrition 0.000 claims description 2
- 241001232809 Chorista Species 0.000 claims description 2
- 108010068370 Glutens Proteins 0.000 claims description 2
- 244000020551 Helianthus annuus Species 0.000 claims description 2
- 235000003222 Helianthus annuus Nutrition 0.000 claims description 2
- 244000046109 Sorghum vulgare var. nervosum Species 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 235000021312 gluten Nutrition 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- 235000010460 mustard Nutrition 0.000 claims description 2
- 229920000070 poly-3-hydroxybutyrate Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 abstract description 11
- 229920003023 plastic Polymers 0.000 abstract description 11
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 239000004067 bulking agent Substances 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 241000192700 Cyanobacteria Species 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 229920006238 degradable plastic Polymers 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000007726 management method Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 230000000050 nutritive effect Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000019890 Amylum Nutrition 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229940088623 biologically active substance Drugs 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000021289 health related food Nutrition 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides thermoplastic prepared from algae. The thermoplastic is prepared from 30-70wt% of algae, 20-30wt% of plasticizer and 10-40% of plastification additives. The plastification additive is prepared from 50-70wt% of biodegradable polymers, 10-30wt% of natural thermoplastic raw materials, 5-20wt% of bulking agents and 5-10% of polyolefin. The degradable natural and environment-friendly raw materials are utilized for preparing plastic, cost is low, the preparing method is simple, products are easy to decompose, and the thermoplastic is beneficial for industrial production.
Description
Technical field
The present invention relates to technical field of polymer materials, especially relating to a kind of take algae as thermoplastics prepared by main raw material.
Background technology
Plastics oneself be widely used in each department of national economy, this is mainly because it has the advantages such as lightweight, satisfactory mechanical property, water-fast resistance to chemical attack, good looking appearance, making and installation be convenient and cheap; According to statistics, nearly 100,000,000 tons of the plastics ultimate production in the annual world, this accounts for greatly more than 75% of three large synthetic materials total amounts, reaches 92% with the volumetric production ratio of iron and steel.But the chemical stability of conventional plastic is fine, almost can not be degraded at occurring in nature, when plastics industry to a certain extent time, abandoned plastic garbage is just more and more, has almost arrived the degree be seen everywhere, therefore, the hidden danger that plastics itself exist comes out gradually; Such as in China; non-returnable container plastic material is as in 1/3; the annual plastic garbage just having more than 70 ten thousand tons produces; simultaneously; owing to lacking effective taking back and process system, relevant special management regulation and economic policy, " white pollution " is caused to become international environment protection and social concern.
Widely using and discarding of conventional petroleum based high molecular material, not only causes petroleum resources seriously deficient, but also causes the bed of nails that " white pollution " increasingly sharpens.Be subject to the attention of countries in the world with the matrix material that the filling-modified Polymer materialspreparation of the degradation materials such as plant amylum obtains Partial digestion, the method meets the theory of resources conservation, economical, environment protection; But the starch of plant origin, as W-Gum, the weighting agent being used as matrix material can cause food price to go up, and affects animal feed markets and take more agriculture plantation.
In recent years, along with the quick growth of economy and population, body eutrophication phenomenon is day by day serious, and blue-green alga bloom phenomenon occurs again and again, and blue-green algae problem has become the important subject of lake basin.When Blue-green Algae Fast Growth, directly salvaging blue-green algae is slow down outburst degree, protection water ecological setting the most directly and safely and effectively Emergency management method.According to statistics, during Taihu Lake blue algae blooms in 2011, the blue-green algae salvaging amount of every day reaches 3000 tons, and the annual blue-green algae of salvaging altogether amount is 970,000 tons.Except Taihu Lake, Dian Chi, Chaohu also have blue algae bloom for several times every year, have every day the blue-green algae of thousands of tons of to need process.The blue-green algae of salvaging disembarkation can take a large amount of soils and stack, and stacking blue-green algae generation percolate will form secondary pollution by osmosis, storm runoff etc.Therefore the blue-green algae dealt carefully with after salvaging seems particularly important.
Blue-green algae is rich in more rich nutritive ingredient (protein, fat, carbohydrate etc.), therefore can as the potential novel biomass resource of a kind of tool.At present, the recycling of bloom blue algae mainly concentrates on as aspects such as bioenergy, bio-feritlizer, microorganism culturing raw material and biologically active substance extractions.Be detect cyanophycean toxin, from the utilization limiting its nutritive ingredient in the health-related food of raw material with blue-green algae at some.
Summary of the invention
For the problems referred to above that prior art exists, the applicant provides thermoplastics prepared by a kind of algae.The present invention utilizes degradable natural green material to prepare plastics, and cost is low, and preparation method is simple, and product easily decomposes, and is conducive to suitability for industrialized production.
Technical scheme of the present invention is as follows:
A thermoplastics prepared by algae, comprises the algae of 30 ~ 70wt%, the softening agent of 20 ~ 30wt%, and the plasticizer additives of 10 ~ 40%.Described algae comprises at least one in Microcystis aeruginosa, anabena, spirulina, artrospira spirulina, plan Anabaena, chamber ball algae, tip algae, the algae that quivers, sheet algae, Xi Zao, joint ball algae, chlorella.Described softening agent comprises polyvalent alcohol, poly-polyhydroxy amine, at least one in polyhydroxy acid ester.
Described plasticizer additives comprises 50 ~ 70wt% biodegradable polymer, 10 ~ 30wt% native thermoplastic raw material and 5 ~ 20wt% expanding material.Described biodegradable polymer comprises poly(lactic acid), poly-hydroxy methane, poly-3-hydroxybutyrate, the multipolymer of 3-hydroxybutyrate and 3-hydroxypentanoic acid, the multipolymer of 3-hydroxybutyrate and 4 hydroxybutyric acid, the multipolymer of 3-hydroxybutyrate and diethoxalic acid, the multipolymer of 3-hydroxybutyrate and 3-caproic acid, at least one in the multipolymer of 3-hydroxybutyrate and 3-Hydroxyoctanoic acid.Described native thermoplastic's raw material comprises at least one in thermoplastic starch, thermoplastic vegetable protein matter.Described thermoplastic vegetable protein matter comprises zein, maize gluten, glutenin, mustard caul-fat, sunflower, Chinese sorghum, chorista soybean protein, at least one concentrated in body soybean protein, all albumen flour.
Described plasticizer additives also comprises 5 ~ 10% polyolefine.Described polyolefine comprises at least one in the multipolymer of polyethylene, polypropylene, ethene and propylene, polyethylene-co-vinyl acetate.
Described algae through removing impurity, oven dry, process of lapping, uses after crossing 200 ~ 500 mesh sieves before use.
The technique effect that the present invention is useful is:
Method of the present invention can reduce the use of non-degradable petroleum-based plastics, economizes on resources; Also for annual algal tufa burst period proposes the treatment process that a kind of algae changes harmful to treasure, protection of the environment is conducive to.Degradable plastics containing algae albumen of the present invention, low production cost, technique is simple, and has good mobility, is suitable for mold pressing, extrudes and injection molding, can be widely used in the process for processing fields such as food, agricultural, packaging and environmental protection.Degradable plastics containing algae albumen of the present invention, can be decomposed by the microorganisms completely in soil, environmentally safe, degradation production can be used as fertilizer.
Embodiment
Below in conjunction with embodiment, the present invention is specifically described.
Embodiment 1
Thermoplastics prepared by a kind of algae provided by the invention, by the algae of 30wt%, the softening agent of 30wt%, and the plasticizer additives composition of 40%.Described algae is Microcystis aeruginosa, and described softening agent is polyvalent alcohol.
Described plasticizer additives is made up of 50wt% biodegradable polymer, 30wt% native thermoplastic raw material, 15wt% expanding material, 5% polyolefine.Described biodegradable polymer is poly(lactic acid), and described native thermoplastic's raw material is thermoplastic starch, and polyolefine is polyethylene.
Described algae through removing impurity, oven dry, process of lapping, uses after crossing 200 mesh sieves before use.
Embodiment 2
Thermoplastics prepared by a kind of algae provided by the invention, by the algae of 50wt%, the softening agent of 20wt%, and the plasticizer additives composition of 30%.Described algae is spirulina, and described softening agent is poly-polyhydroxy amine.
Described plasticizer additives is made up of 60wt% biodegradable polymer, 10wt% native thermoplastic raw material, 20wt% expanding material, 10% polyolefine.Described biodegradable polymer is poly-hydroxy methane, and described native thermoplastic's raw material is zein, and described polyolefine is polypropylene.
Described algae through removing impurity, oven dry, process of lapping, uses after crossing 500 mesh sieves before use.
Embodiment 3
Thermoplastics prepared by a kind of algae provided by the invention, by the algae of 70wt%, the softening agent of 20wt%, and the plasticizer additives composition of 10%.Described algae is chlorella, and described softening agent is polyhydroxy acid ester.
Described plasticizer additives is made up of 70wt% biodegradable polymer, 20wt% native thermoplastic raw material, 5wt% expanding material, 5% polyolefine.Described biodegradable polymer is the multipolymer of 3-hydroxybutyrate and 3-caproic acid, and described native thermoplastic's raw material is glutenin, and described polyolefine bag is the multipolymer of ethene and propylene.
Described algae through removing impurity, oven dry, process of lapping, uses after crossing 400 mesh sieves before use.
Claims (10)
1. the thermoplastics prepared of algae, is characterized in that comprising the algae of 30 ~ 70wt%, the softening agent of 20 ~ 30wt%, and the plasticizer additives of 10 ~ 40%.
2. the thermoplastics prepared of algae according to claim 1, is characterized in that described algae comprises at least one in Microcystis aeruginosa, anabena, spirulina, artrospira spirulina, plan Anabaena, chamber ball algae, tip algae, the algae that quivers, sheet algae, Xi Zao, joint ball algae, chlorella.
3. the thermoplastics prepared of algae according to claim 1, is characterized in that described softening agent comprises polyvalent alcohol, poly-polyhydroxy amine, at least one in polyhydroxy acid ester.
4. the thermoplastics prepared of algae according to claim 1, is characterized in that described plasticizer additives comprises 50 ~ 70wt% biodegradable polymer, 10 ~ 30wt% native thermoplastic raw material and 5 ~ 20wt% expanding material.
5. the thermoplastics prepared of algae according to claim 4, it is characterized in that described biodegradable polymer comprises poly(lactic acid), poly-hydroxy methane, poly-3-hydroxybutyrate, the multipolymer of 3-hydroxybutyrate and 3-hydroxypentanoic acid, the multipolymer of 3-hydroxybutyrate and 4 hydroxybutyric acid, the multipolymer of 3-hydroxybutyrate and diethoxalic acid, the multipolymer of 3-hydroxybutyrate and 3-caproic acid, at least one in the multipolymer of 3-hydroxybutyrate and 3-Hydroxyoctanoic acid.
6. the thermoplastics prepared of algae according to claim 4, is characterized in that described native thermoplastic's raw material comprises at least one in thermoplastic starch, thermoplastic vegetable protein matter.
7. the thermoplastics prepared of algae according to claim 6, is characterized in that described thermoplastic vegetable protein matter comprises zein, maize gluten, glutenin, mustard caul-fat, sunflower, Chinese sorghum, chorista soybean protein, at least one concentrated in body soybean protein, all albumen flour.
8. the thermoplastics prepared of algae according to claim 4, is characterized in that described plasticizer additives also comprises 5 ~ 10% polyolefine.
9. the thermoplastics prepared of algae according to claim 8, is characterized in that described polyolefine comprises at least one in the multipolymer of polyethylene, polypropylene, ethene and propylene, polyethylene-co-vinyl acetate.
10. the thermoplastics prepared of algae according to claim 1, is characterized in that described algae before use through removing impurity, oven dry, process of lapping, using after crossing 200 ~ 500 mesh sieves.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736063.8A CN105331063A (en) | 2015-11-03 | 2015-11-03 | Thermoplastic prepared from algae |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510736063.8A CN105331063A (en) | 2015-11-03 | 2015-11-03 | Thermoplastic prepared from algae |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105331063A true CN105331063A (en) | 2016-02-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510736063.8A Pending CN105331063A (en) | 2015-11-03 | 2015-11-03 | Thermoplastic prepared from algae |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105331063A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021521A (en) * | 2018-07-09 | 2018-12-18 | 福建师范大学 | One kind wire rod of 3D printing containing chlorella and preparation method thereof |
| CN110591405A (en) * | 2019-09-25 | 2019-12-20 | 东莞市福码鞋材有限公司 | Green alga environment-friendly sole material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115576A (en) * | 2009-12-31 | 2011-07-06 | 金伯利-克拉克环球有限公司 | Natural biological polymer thermoplastic film |
| CN102414267A (en) * | 2009-04-28 | 2012-04-11 | 金伯利-克拉克环球有限公司 | Algae-blended compositions for thermoplastic articles |
| CN104870560A (en) * | 2012-08-30 | 2015-08-26 | Ptt全球化学公开有限公司 | A bio-based polymer additive, a process for preparing the bio-based polymer additive and a biodegradable polymer composition comprising said bio-based polymer additive |
-
2015
- 2015-11-03 CN CN201510736063.8A patent/CN105331063A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102414267A (en) * | 2009-04-28 | 2012-04-11 | 金伯利-克拉克环球有限公司 | Algae-blended compositions for thermoplastic articles |
| CN102115576A (en) * | 2009-12-31 | 2011-07-06 | 金伯利-克拉克环球有限公司 | Natural biological polymer thermoplastic film |
| CN104870560A (en) * | 2012-08-30 | 2015-08-26 | Ptt全球化学公开有限公司 | A bio-based polymer additive, a process for preparing the bio-based polymer additive and a biodegradable polymer composition comprising said bio-based polymer additive |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021521A (en) * | 2018-07-09 | 2018-12-18 | 福建师范大学 | One kind wire rod of 3D printing containing chlorella and preparation method thereof |
| CN109021521B (en) * | 2018-07-09 | 2021-05-04 | 福建师范大学 | A kind of chlorella-containing 3D printing wire and preparation method thereof |
| CN110591405A (en) * | 2019-09-25 | 2019-12-20 | 东莞市福码鞋材有限公司 | Green alga environment-friendly sole material and preparation method thereof |
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Application publication date: 20160217 |