CN105315405A - Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent - Google Patents
Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent Download PDFInfo
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- CN105315405A CN105315405A CN201510785458.7A CN201510785458A CN105315405A CN 105315405 A CN105315405 A CN 105315405A CN 201510785458 A CN201510785458 A CN 201510785458A CN 105315405 A CN105315405 A CN 105315405A
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- 229920002401 polyacrylamide Polymers 0.000 title claims abstract description 17
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940047670 sodium acrylate Drugs 0.000 claims abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 239000012986 chain transfer agent Substances 0.000 claims abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000001301 oxygen Substances 0.000 claims abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 3
- 239000012966 redox initiator Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000004159 Potassium persulphate Substances 0.000 claims description 7
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical group [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 7
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical group CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 7
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 7
- 235000019394 potassium persulphate Nutrition 0.000 claims description 7
- 238000013467 fragmentation Methods 0.000 claims description 5
- 238000006062 fragmentation reaction Methods 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 239000000693 micelle Substances 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- -1 polyoxyethylene Polymers 0.000 claims description 4
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 3
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical group [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 230000000977 initiatory effect Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000002829 reductive effect Effects 0.000 claims 1
- 239000006185 dispersion Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 229910001873 dinitrogen Inorganic materials 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 4
- PKQIZTGHFBCYEN-UHFFFAOYSA-N 4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2,3,5,6-tetrafluorobenzenesulfonamide Chemical compound CC1=CC(C)=NC(SC=2C(=C(F)C(=C(F)C=2F)S(N)(=O)=O)F)=N1 PKQIZTGHFBCYEN-UHFFFAOYSA-N 0.000 description 3
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 description 3
- 238000006392 deoxygenation reaction Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paper (AREA)
Abstract
The invention discloses a preparation method of a quick-dissolving polyacrylamide paper-making dispersing agent. The preparation method comprises the following steps: preparing a solution from 180-280 parts of acrylamide, 120-250 parts of a sodium acrylate solution, 0.5-2 parts of a surfactant, 10-20 parts of an additive and 550-650 parts of deionized water, and properly adjusting the temperature and the pH value, and then transferring the adjusted solution into a reaction kettle; pumping nitrogen gas into the reaction kettle to completely remove oxygen, and adding 0.03-0.06 part of a chain transfer agent, 0.1-0.5 part of a water-soluble azo-type initiator and 0.08-0.12 part of a redox initiator to arouse a polymerization reaction; granulating a colloidal polymer, obtained after the reaction is finished, with a granulator, drying the colloidal particles at 65-75 DEG C, and then crushing the colloidal particles to obtain the quick-dissolving polyacrylamide paper-making dispersing agent. The quick-dissolving polyacrylamide paper-making dispersing agent has the advantages of being high in dissolving speed and viscosity, good in solubility and dispersion effect, degradation-resistant, nontoxic and the like.
Description
Technical field
The present invention relates to a kind of preparation method of paper-making dispersant agent, be specifically related to a kind of preparation method of fast-solving polyacrylamide paper-making dispersant agent.
Background technology
At present, polyacrylamide is because containing carboxyl in molecular chain, and there is the capillary effect of reduction, contribute to moistening to solid of water, this is advantageous particularly for the dispersion in water such as fiber, filler, when polyacrylamide adds slurry, fiber, filling surface can be made to form bimolecular structure, extreme and the water of outer dispersion agent has stronger avidity, adds the degree that the solids such as fiber, filler are spontaneously wet out by water.Between the solid particulate such as fiber, filler because of electrostatic repulsion away from, reach good dispersion effect.Although anionic polyacrylamide dispersion agent is used widely because of cost advantage, and quality product is uneven, the problems such as ubiquity dissolution rate is slow, poorly soluble, easy degraded.
Summary of the invention
Object of the present invention is exactly the defect existed for prior art, a kind of preparation method of fast-solving polyacrylamide paper-making dispersant agent is provided, it is high and stable that this product has viscosity, solvability is good, and dispersion effect is good, anti-degraded, nontoxic, dissolution rate fast (having in 30min is that solubilized is complete, and the energy consumption that obvious shortening dissolution time and reduction dissolved product cause improves production efficiency).
The present invention is achieved through the following technical solutions:
By the acrylamide of 180-280 part, the sodium acrylate solution of 120-250 part, 0.5-2 part tensio-active agent, the additive of 10-20 part, 550-650 part deionized water is mixed with solution, proceeds to reactor after adjusting temperature, pH value; Pass into nitrogen, oxygen is eliminated, then add the chain-transfer agent of 0.03-0.06 part, the redox initiator of 0.08-0.12 part, the water-soluble azo class initiator initiated polymerization of 0.1-0.5 part; Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
The additive sodium vinyl sulfonate that the present invention introduces, improve the wetting ability of polymkeric substance and anti-degradation property, as paper-making dispersant agent, dispersion efficiency is high, and improves gloss and the surface property of coating; For paper, this coating makes its wear resistance be improved.
Embodiment
Embodiment 1
Parts by weight of raw materials is: acrylamide 200g, sodium acrylate solution 170g, NP-100.5g, anti-SVS10g, deionized water 620g, lauryl mercaptan 0.03g, Sunmorl N 60S 0.015g, V500.1, Potassium Persulphate 0.03, sodium bisulfite 0.03;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Embodiment 2
Parts by weight of raw materials is: acrylamide 220g, sodium acrylate solution 200g, NP-101g, anti-SVS15g, deionized water 565g, lauryl mercaptan 0.04g, Sunmorl N 60S 0.02g, V500.2, Potassium Persulphate 0.02, sodium bisulfite 0.01;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Embodiment 3
Parts by weight of raw materials is: acrylamide 245g, sodium acrylate solution 189g, NP-102g, anti-SVS16g, deionized water 550g, lauryl mercaptan 0.038g, Sunmorl N 60S 0.019g, V500.23, Potassium Persulphate 0.035, sodium bisulfite 0.021;
Acrylamide, ammonium acrylate solution, NP-10, SVS, deionized water are joined successively in 1000 ml beakers; After stirring, adjustment PH to 6.5, temperature to 5 DEG C;
The solution prepared is proceeded in vacuum flask, logical nitrogen 40min deoxygenation; Add lauryl mercaptan, Sunmorl N 60S, V50, Potassium Persulphate, bisulfite sodium polymerization successively;
Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying 3 hours in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
Above-described is only the preferred embodiment of the present invention, it should be pointed out that for the person of ordinary skill of the art, without departing from the concept of the premise of the invention, can also make some distortion and improvement, all belong to protection scope of the present invention.
Claims (7)
1. the preparation method of a fast-solving polyacrylamide paper-making dispersant agent, it is characterized in that: comprise following preparation process: by the acrylamide of 180-280 part, the sodium acrylate solution of 120-250 part, 0.5-2 part tensio-active agent, the additive of 10-20 part, 550-650 part deionized water is mixed with solution, proceeds to reactor after adjusting temperature, pH value; Pass into nitrogen, oxygen is eliminated, then add the chain-transfer agent of 0.03-0.06 part, the water-soluble azo class initiator of 0.1-0.5 part, the redox initiator initiated polymerization of 0.08-0.12 part; Obtain gum polymers after reaction terminates, by gum polymers granulator granulation, micelle carries out drying in 65-75 DEG C, namely obtains product after drying through pulverizer fragmentation.
2. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: the concentration of described sodium acrylate solution is 23%.
3. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: described tensio-active agent is alkylphenol polyoxyethylene (NP-10).
4. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, is characterized in that: described additive is sodium vinyl sulfonate (SVS).
5. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described chain-transfer agent is lauryl mercaptan and Sunmorl N 60S, mass ratio is 2:1.
6. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described temperature of reaction is 4-6 DEG C, pH value is 6.5-7.0.
7. the preparation method of a kind of fast-solving polyacrylamide paper-making dispersant agent according to claim 1, it is characterized in that: described initiator is redox and azo-initiator composition composite initiation system, wherein oxygenant is the one in Potassium Persulphate, hydrogen peroxide, reductive agent is sodium bisulfite, and described water-soluble azo class initiator is V50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510785458.7A CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
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|---|---|---|---|
| CN201510785458.7A CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
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| CN105315405A true CN105315405A (en) | 2016-02-10 |
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| CN201510785458.7A Pending CN105315405A (en) | 2015-11-17 | 2015-11-17 | Preparation method of quick-dissolving polyacrylamide paper-making dispersing agent |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050234176A1 (en) * | 2000-12-20 | 2005-10-20 | Coatex S.A.S. | Grinding and/or dispersing aid of mineral materials in aqueous suspension, resulting aqueous suspensions and uses thereof |
| CN1950336A (en) * | 2004-07-28 | 2007-04-18 | 可泰克斯有限合伙公司 | Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof |
| CN101532266A (en) * | 2008-12-29 | 2009-09-16 | 北京希涛技术开发有限公司 | Synthesis and production method for star polymer for paper making dispersant |
| CN104059194A (en) * | 2013-12-15 | 2014-09-24 | 安徽巨成精细化工有限公司 | Preparation method of rapidly-soluble papermaking dispersant polyacrylamide |
| CN104404824A (en) * | 2014-11-07 | 2015-03-11 | 安徽天润化学工业股份有限公司 | Star-shaped polymer papermaking dispersant and preparation method thereof |
| CN105315402A (en) * | 2014-07-04 | 2016-02-10 | 山东诺尔生物科技有限公司 | Preparation method of quick-dissolving polyacrylamide papermaking dispersant |
-
2015
- 2015-11-17 CN CN201510785458.7A patent/CN105315405A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050234176A1 (en) * | 2000-12-20 | 2005-10-20 | Coatex S.A.S. | Grinding and/or dispersing aid of mineral materials in aqueous suspension, resulting aqueous suspensions and uses thereof |
| CN1950336A (en) * | 2004-07-28 | 2007-04-18 | 可泰克斯有限合伙公司 | Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof |
| CN101532266A (en) * | 2008-12-29 | 2009-09-16 | 北京希涛技术开发有限公司 | Synthesis and production method for star polymer for paper making dispersant |
| CN104059194A (en) * | 2013-12-15 | 2014-09-24 | 安徽巨成精细化工有限公司 | Preparation method of rapidly-soluble papermaking dispersant polyacrylamide |
| CN105315402A (en) * | 2014-07-04 | 2016-02-10 | 山东诺尔生物科技有限公司 | Preparation method of quick-dissolving polyacrylamide papermaking dispersant |
| CN104404824A (en) * | 2014-11-07 | 2015-03-11 | 安徽天润化学工业股份有限公司 | Star-shaped polymer papermaking dispersant and preparation method thereof |
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Application publication date: 20160210 |