CN105313353B - Manufacture method of on-slip type synthetic paper and products thereof - Google Patents
Manufacture method of on-slip type synthetic paper and products thereof Download PDFInfo
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- CN105313353B CN105313353B CN201410254797.8A CN201410254797A CN105313353B CN 105313353 B CN105313353 B CN 105313353B CN 201410254797 A CN201410254797 A CN 201410254797A CN 105313353 B CN105313353 B CN 105313353B
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- slip
- raw material
- sheet
- type synthetic
- synthetic paper
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- 238000000034 method Methods 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 38
- 239000002994 raw material Substances 0.000 claims abstract description 54
- -1 polyethylene Polymers 0.000 claims abstract description 51
- 239000012528 membrane Substances 0.000 claims abstract description 36
- 239000004698 Polyethylene Substances 0.000 claims abstract description 35
- 229920000573 polyethylene Polymers 0.000 claims abstract description 34
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 229920005606 polypropylene copolymer Polymers 0.000 claims abstract description 7
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 239000011148 porous material Substances 0.000 claims abstract description 4
- 230000005611 electricity Effects 0.000 claims abstract description 3
- 230000035939 shock Effects 0.000 claims abstract description 3
- 239000004743 Polypropylene Substances 0.000 claims description 18
- 229920001155 polypropylene Polymers 0.000 claims description 17
- 239000000758 substrate Substances 0.000 claims description 16
- 229920001684 low density polyethylene Polymers 0.000 claims description 8
- 239000004702 low-density polyethylene Substances 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920001179 medium density polyethylene Polymers 0.000 claims description 4
- 239000004701 medium-density polyethylene Substances 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 238000010345 tape casting Methods 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 9
- 238000010586 diagram Methods 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
A kind of manufacture method of on-slip type synthetic paper and products thereof, the manufacture method comprises the steps of:(A) a kind of raw material of sheet is put into an extruder, and a kind of raw material of anti-slip layer is put into another extruder, the raw material of the sheet contains polyethylene and natural inorganic miberal powder, and the raw material of the anti-slip layer contains vinyl polymer and ethene and the copolymer of propylene;(B) extruder is respectively by the material extruding of the sheet and the anti-slip layer to a mould mouth, is discharged by the mould mouth and forms a piece of paper membrane;(C) paper membrane is cooled down;(D) paper membrane of cooling is subjected to elongation moulding;(E) two opposite long sides of the paper membrane are cut;(F) surface for the paper membrane that shocks by electricity and form several pores.On-slip type synthetic paper includes made of the manufacture method:One sheet and an anti-slip layer for being disposed therein a sheet face for including two opposite sheet faces.The effect of on-slip can be reached by the setting of the anti-slip layer.
Description
Technical field
The present invention relates to a kind of manufacture method of synthetic paper and products thereof, more particularly to a kind of system of on-slip type synthetic paper
Make method and products thereof.
Background technology
Refering to Fig. 1, a kind of manufacture method of existing synthetic paper includes:
(l) by 56 to 80 weight % natural inorganics miberal powders, 43 to l8 weight % polyethylene and l to 2 weight % auxiliary agents
Granular material is made in composition, blended extruding mixing.
(2) granular material is put into extruder 11, the temperature of control extruder 11 softens granular materials, via suppressing
Conveying, melted material discharge from mould mouth 12, form a tunic pipe 13.
(3) inflated in the membrane tube 13 with compressed air, make the 13 outside prolonged expansion of membrane tube, while with stretching device 14
The mould pipe 13 is stretched.
There is the shortcomings that on-slip property is bad as the synthetic paper obtained by above-mentioned manufacture method so that thing placed thereon
Body easily slides, and causes the inconvenience of user.
The content of the invention
The purpose of the present invention, that is, providing a kind of manufacture method of on-slip type synthetic paper.
The manufacture method of on-slip type synthetic paper of the present invention, is comprised the steps of:
(A) a kind of raw material of sheet is put into an extruder, and a kind of raw material of anti-slip layer is put into another extrusion
Machine;
The raw material of the sheet contains polyethylene and natural inorganic miberal powder, and the raw material of the anti-slip layer contains vinyl polymer and second
The copolymer of alkene and propylene;
(B) extruder is respectively by the material extruding of the raw material of the sheet and the anti-slip layer to a mould mouth, by the mould
Mouth discharges and forms a piece of paper membrane;
(C) paper membrane is cooled down;
(D) paper membrane of cooling is subjected to elongation moulding with stretching mode;
(E) two opposite long sides of the paper membrane are cut.
(F) surface for the paper membrane that shocks by electricity and form several pores.
The manufacture method of on-slip type synthetic paper of the present invention, the extruder of step (A) extrude temperature between 100
DEG C~250 DEG C, the mould mouth of step (B) is blown compressed air using an O font mould mouth for being applied to blowing, step (C)
Enter and cooled down in the paper membrane, and the paper membrane is cooled to less than 100 DEG C.
The manufacture method of on-slip type synthetic paper of the present invention, counted using the sheet as 100wt.%, the raw material of the sheet by
10wt.%~85wt.% natural inorganic miberal powder, 13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents institute
Composition, is counted using the anti-slip layer as 100wt.%, the raw material of the anti-slip layer by 50wt.%~99wt.% blown film level polyethylene and/
Or blown film grade polypropylene is formed with 1wt.%~50wt.% ethene and the copolymer of propylene.
The manufacture method of on-slip type synthetic paper of the present invention, step (A) described extruder extrude temperature between 180 DEG C
~350 DEG C, the mould mouth of step (B) will using cooling roller using an I font mould mouth for being applied to the tape casting, step (C)
The paper membrane is cooled to less than 30 DEG C.
The manufacture method of on-slip type synthetic paper of the present invention, counted using the sheet as 100wt.%, the raw material of the sheet by
10wt.%~85wt.% natural inorganic miberal powder, 13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents institute
Composition, is counted using the anti-slip layer as 100wt.%, the raw material of the anti-slip layer by 50wt.%~99wt.% Film grade polyethylene and/
Or the polypropylene of film-grade is formed with 1wt.%~50wt.% ethene and the copolymer of propylene.
Another object of the present invention, that is, providing a kind of stopping as obtained by previous building methods and with anti-slip effect
Slip synthetic paper.
Then, on-slip type synthetic paper of the present invention, comprising:One sheet and an anti-slip layer.
The sheet includes two opposite sheet faces.
The anti-slip layer is arranged at wherein on a sheet face of the sheet, and the material of the anti-slip layer is by a substrate raw material and one
Individual on-slip raw material composition, the substrate raw material use vinyl polymer, and the on-slip raw material is using ethene and the copolymer of propylene.
The manufacture method of on-slip type synthetic paper of the present invention, counted using the sheet as 100wt.%, the material of the sheet by
10wt.%~85wt.% natural inorganic miberal powder, 13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents institute
Composition, vinyl polymer is that high density polyethylene (HDPE), medium density polyethylene, low-density are gathered used by the substrate raw material of the anti-slip layer
Ethene, and a kind of at least within and its a kind of combination of LLDPE.
The manufacture method of on-slip type synthetic paper of the present invention, counted using the anti-slip layer as 100wt.%, the substrate raw material is situated between
In 50wt.%~99wt.%, the on-slip raw material is between 1wt.%~50wt.%.
The manufacture method of on-slip type synthetic paper of the present invention, vinyl polymer is blown film level used by the substrate raw material
Polyethylene and/or blown film grade polypropylene.
The manufacture method of on-slip type synthetic paper of the present invention, vinyl polymer is film-grade used by the substrate raw material
Polyethylene and/or film-grade polypropylene.
The beneficial effects of the present invention are:By the on-slip type synthetic paper obtained by the manufacture method, can effectively produce
The effect of on-slip so that object placed on it is not easy to slide, and can apply to ground cushion, mat applying and woven bag etc., has
A variety of application modes.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram, illustrates a kind of manufacture method of existing synthetic paper;
Fig. 2 is a kind of schematic diagram, illustrates first preferred embodiment of the manufacture method of on-slip type synthetic paper of the present invention;
Fig. 3 is a kind of schematic diagram, illustrates that first preferred embodiment includes an O font film mouth;
Fig. 4 is a kind of sectional view, illustrates a kind of on-slip type synthetic paper manufactured by first preferred embodiment;
Fig. 5 is a kind of similar Fig. 4 sectional view, illustrates another aspect of the on-slip type synthetic paper;
Fig. 6 is a kind of schematic diagram, illustrates second preferred embodiment of the manufacture method of on-slip type synthetic paper of the present invention;
Fig. 7 is a kind of schematic diagram, illustrates second preferred embodiment, includes an I font film mouth.
Embodiment
Below in conjunction with the accompanying drawings and embodiment the present invention is described in detail.
Before the present invention is described in detail, it shall be noted that in the following description content, similar element is with identical
Number to represent.
Refering to Fig. 2 and Fig. 3, the first preferred embodiment of the manufacture method of on-slip type synthetic paper of the present invention includes following step
Suddenly:
(A) the raw material (not shown) of sheet a kind of puts into the hopper 211 of an extruder 21, and by a kind of anti-slip layer
Raw material (not shown) puts into the hopper 211 of another extruder 21.The extruder extrudes temperature between 100 DEG C~250 DEG C
Between, it will be extruded in the sheet of molten state and the raw material of the anti-slip layer.
In terms of sheet 100wt.%, the raw material of the sheet by 10wt.%~85wt.% natural inorganic miberal powder,
13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents is formed.
Counted using the anti-slip layer as 100wt.%, the raw material of the anti-slip layer by 50wt.%~99wt.% blown film level polyethylene
And/or blown film grade polypropylene, formed with 1wt.%~50wt.% ethene and the copolymer of propylene.
(B) extruder 21 is respectively by respective feeding rod 212 by the sheet and the raw material strong pressing of the anti-slip layer
It is applied to the O font moulds mouth 213 of blowing to one, and is discharged by the O font moulds mouth 213 and form the paper membrane 3 of a tubulose.
(C) compressed air is poured into the paper membrane 3, and is cooled down below 3 to 100 DEG C of the paper membrane, passes through the swollen of compressed air
It is swollen and cause the paper membrane 3 expand outwardly 3~8 times.
(D) paper membrane 3 of cooling is delivered into a stretching device 22 and carries out elongation moulding.
Because the paper membrane 3 is in effect of the step (C) with lateral expansion, therefore, step (D) is that one kind is entered with stretching mode
Capable two-way elongation moulding.
(E) long side that the paper membrane 3 is located at two-phase and tosses about is cut via cut edge device 23, doubling position is cut open into two layers of separation
Paper membrane 3 turns into the paper membrane 3 of individual layer.
(F) via the discharge process of corona treatment 24, the surface of the paper membrane 3 forms several pores, to be made after
Increase the adhesive force of coating material in journey.
(G) uncoated on-slip type is collected by devices for taking-up 25 and synthesizes paper product.
Refering to Fig. 4, one kind on-slip type synthetic paper 4 made of above-mentioned manufacture method.The on-slip type synthetic paper 4 includes:One
Individual sheet 41 and an anti-slip layer 42.
The sheet 41 includes two opposite sheet faces 411.
By the sheet 41 for 100wt.% in terms of, the material of the sheet 41 by 10wt.%~85wt.% natural inorganic ore deposit
Powder, 13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents are formed.
The anti-slip layer 42 is arranged at a wherein sheet face 411 for the sheet 41.
The material of the anti-slip layer 42 is made up of a kind of substrate raw material and a kind of on-slip raw material, and the substrate raw material is vinyl polymerization
Thing, the on-slip raw material are the copolymer of ethene and propylene.
By the anti-slip layer 42 for 100wt.% in terms of, between 50wt.%~99wt.%, the on-slip raw material is situated between the substrate raw material
In 1wt.%~50wt.%.
Vinyl polymer is the polyethylene of blown film level and/or the polypropylene of blown film level used by the substrate raw material.
The polyethylene and blown film grade polypropylene of blown film level are that industry is customarily used in polyethylene and polyacrylic classification respectively.Blow
M.I. (melting index) property of film level polyethylene substantially between 0.05~3.00 (g/10min), can refer to following public affairs
The product type of department, platform modeling 9000,9001;Platform poly- NA112-27, NA205-15;And sub- poly- F1100, F2200.
The M.I. properties of blown film grade polypropylene substantially between 10.0~10.5 (g/10min), can refer to following company
Product type, the long Rong Huagong PD943 of Lee and platform mould Yongjia alkene 2080.
Blown film level polyethylene is high density polyethylene (HDPE), medium density polyethylene, low density polyethylene used by the substrate raw material
Alkene, and a kind of at least within and its a kind of combination of LLDPE.
By the manufacture method of on-slip type synthetic paper of the present invention, the anti-slip layer 42 can be formed to wherein the one of the sheet 41
Sheet face 411, and reach anti-slip effect.
Tested via the actual on-slip degree carried out of inventor, synthetic paper to be measured is coated into a weight, is placed in its phase
The synthetic paper surface of same material, gradually increases angle of inclination, when the weight starts to move, an as on-slip angle.
When using existing synthetic paper as experiment sample, the on-slip angle is between 27 °~28 °;Using on-slip type of the present invention
When synthetic paper is experiment sample, the on-slip angle can reach the effect of promoting on-slip property really up to more than 33 °, therefore, and
Many utilizations such as woven bag, mat applying, ground cushion are can apply to, are further able to PE the and PP ox-hides that substitution uses on the market at present
Paper woven bag uses paper.
In addition, the on-slip type synthetic paper 4 made of the manufacture method, the thickness of the sheet 41 can up to less than 10 μm,
The thickness of the anti-slip layer 42 can be up to less than 3 μm, with regard to that can have significant anti-slip effect.It is understood that it can be manufactured by adjusting
The parameter of method, to obtain the sheet 41 of different-thickness and the anti-slip layer 42.
Summary, the advantages of on-slip type synthetic paper of the present invention, can be summarized as follows:
1. because on-slip type synthetic paper of the present invention belongs to single material, therefore environmentally friendly can reclaim, and it can regenerate, recycle.
2. the raw material of paper processed is not required to add wood pulp, environmentally friendly concept is also complied with.
3. material bag can be effectively avoided to fall in storehouse because of slip during woven bag used by applied to transport material
Fall caused accident.
It is noted that the manufacture method of on-slip type synthetic paper of the present invention, also additionally can set up one again in step (A)
Extruder, and the raw material of the anti-slip layer is put into, and a kind of on-slip type synthetic paper is produced, as shown in figure 5, the on-slip type synthetic paper
4 include a sheet 41 for including two sheet faces 411, and two anti-slip layers 42 for being respectively formed in different sheet faces 411, lead to
The setting of the anti-slip layer 42 is crossed, can further increase the application mode of the on-slip type synthetic paper.
Refering to Fig. 6 and Fig. 7, the second preferred embodiment of the manufacture method of on-slip type synthetic paper of the present invention, this is second preferable
Embodiment is similar to first preferred embodiment, its difference:
The extruder of step (A) extrudes temperature between 180 DEG C~350 DEG C.Vinyl polymerization used by the substrate raw material
Thing is the polyethylene of film-grade and/or the polypropylene of film-grade, and Film grade polyethylene is high density used by the substrate raw material
Polyethylene, medium density polyethylene, low density polyethylene (LDPE), and a kind of at least within and its a kind of group of LLDPE
Close.
Counted by 100wt.% of the anti-slip layer described in step (A), the raw material of the anti-slip layer is by 50wt.%~99wt.%
Film grade polyethylene and/or firm grade polypropylene and 1wt.%~50wt.% polyethylene and polyacrylic copolymer institute group
Into.
Film grade polyethylene and firm grade polypropylene are that industry is customarily used in polyethylene and polyacrylic sorting technique respectively.It is thin
The M.I. properties of film level polyethylene, can be with reference to the product type of following company between 3.8~7.5 (g/10min):Sub- poly- C4100,
C7100;Platform moulds 6520G.
The M.I. properties of firm grade polypropylene substantially between 3.0~4.0 (g/10min), can refer to the production of following company
Product model:The long Rong Huagong PD402 of Lee and platform mould Yongjia alkene 2020s.
Step (B) is using an I font moulds mouth 214 for being applied to the tape casting.By the sheet and it is somebody's turn to do via the feeding rod
The raw material of anti-slip layer, which is suppressed, is delivered to the I font mould mouths, is discharged by the I font mould mouths and forms the paper membrane 3 of a sheet.
The temperature of the paper membrane 3 is down to less than 30 DEG C by step (C) using cooling roller 26.
Step (E), which cuts the paper membrane 3 and is located at two-phase, tosses about and the less uniform long side of thickness.
In this way, second preferred embodiments can also produce a kind of on-slip type synthetic paper 4.The on-slip type synthetic paper 4 with it is foregoing
On-slip type synthetic paper 4 difference in place of be the substrate raw material of the anti-slip layer 42 used by vinyl polymer be film-grade
The polypropylene of polyethylene and/or film-grade.
From the foregoing, second preferred embodiment can also reach and foregoing first preferred embodiment identical purpose and work(
Effect.
In summary, the manufacture method of on-slip type synthetic paper of the present invention can manufacture on-slip type synthetic paper, on-slip type synthesis
Paper can reach on-slip effect of lifting synthetic paper, therefore can reach the purpose of the present invention really.
Claims (10)
- A kind of 1. manufacture method of on-slip type synthetic paper, it is characterised in that:The manufacture method comprises the steps of:(A) a kind of raw material of sheet is put into an extruder, and a kind of raw material of anti-slip layer is put into another extruder, should The raw material of sheet contains polyethylene and natural inorganic miberal powder, is counted using the sheet as 100wt.%, the raw material of the sheet is by 10wt.% ~85wt.% natural inorganic miberal powder, 13wt.%~89wt.% polyethylene and 1wt.%~2wt.% auxiliary agents are formed, should The raw material of anti-slip layer contains vinyl polymer and ethene and the copolymer of propylene, is counted using the anti-slip layer as 100wt.%, the on-slip The raw material of layer by 50wt.%~99wt.% vinyl polymer and 1wt.%~50wt.% ethene and propylene copolymer institute Composition;(B) extruder is gone out respectively by the material extruding of the raw material of the sheet and the anti-slip layer to a mould mouth by the mould mouth Expect and form a piece of paper membrane;(C) paper membrane is cooled down;(D) paper membrane of cooling is subjected to elongation moulding with stretching mode;(E) two opposite long sides of the paper membrane are cut;(F) surface for the paper membrane that shocks by electricity and form several pores.
- 2. the manufacture method of on-slip type synthetic paper according to claim 1, it is characterised in that:The extrusion of step (A) Machine extrudes temperature between 100 DEG C~250 DEG C, and the mould mouth of step (B) uses an O font mould mouth for being applied to blowing, Compressed air is blown into the paper membrane by step (C) to be cooled down, and the paper membrane is cooled into less than 100 DEG C.
- 3. the manufacture method of on-slip type synthetic paper according to claim 2, it is characterised in that:The vinyl polymer is blown film Level polyethylene and/or blown film grade polypropylene.
- 4. the manufacture method of on-slip type synthetic paper according to claim 1, it is characterised in that:Step (A) described extruder Extrude temperature between 180 DEG C~350 DEG C, the mould mouth of step (B) is using an I font mould mouth for being applied to the tape casting, step Suddenly the paper membrane is cooled to less than 30 DEG C by (C) using cooling roller.
- 5. the manufacture method of on-slip type synthetic paper according to claim 1, it is characterised in that:The vinyl polymerization of the anti-slip layer Thing is Film grade polyethylene and/or the polypropylene of film-grade.
- A kind of 6. on-slip type synthetic paper obtained by manufacture method as claimed in claim 1, it is characterised in that:The on-slip type synthetic paper Comprising:One sheet, including two opposite sheet faces;AndOne anti-slip layer, be arranged on one of sheet face of the sheet, the material of the anti-slip layer by a kind of substrate raw material and A kind of on-slip raw material composition, the substrate raw material use vinyl polymer, and the on-slip raw material is using ethene and the copolymer of propylene.
- 7. on-slip type synthetic paper according to claim 6, it is characterised in that:The vinyl polymer of the anti-slip layer is high density One kind at least within of polyethylene, medium density polyethylene and low density polyethylene (LDPE).
- 8. on-slip type synthetic paper according to claim 6, it is characterised in that:The vinyl polymer is the polyethylene of blown film level And/or blown film grade polypropylene.
- 9. on-slip type synthetic paper according to claim 6, it is characterised in that:The vinyl polymer is the polyethylene of film-grade And/or the polypropylene of film-grade.
- 10. on-slip type synthetic paper according to claim 7, it is characterised in that:The low density polyethylene (LDPE) is linea low density Polyethylene.
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CN107674600A (en) * | 2017-09-05 | 2018-02-09 | 浙江山联新材料科技有限公司 | A kind of manufacture method of the film Environment protecting adhesive tape manufactured by inorganic mineral powder with the tape casting |
CN107501683A (en) * | 2017-09-05 | 2017-12-22 | 浙江山联新材料科技有限公司 | A kind of manufacture method of the film manufactured by inorganic mineral powder with the tape casting |
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