CN105295451A - Preparation method for nanometer aluminium oxide composite - Google Patents
Preparation method for nanometer aluminium oxide composite Download PDFInfo
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- CN105295451A CN105295451A CN201510850919.4A CN201510850919A CN105295451A CN 105295451 A CN105295451 A CN 105295451A CN 201510850919 A CN201510850919 A CN 201510850919A CN 105295451 A CN105295451 A CN 105295451A
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- kaolin
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- aluminium oxide
- precursor solution
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Abstract
The invention discloses a preparation method for a nanometer aluminium oxide composite. The preparation method comprises the following steps: adding kaolin into deionized water, conducting ultrasonic dispersion, adding sodium biphosphate and aluminium phosphate, and conducting ultrasonic dispersion to obtain a precursor solution; then conducting heating reflux on the precursor solution under the nitrogen atmosphere; after that, conducting natural cooling and suction filtration; drying obtained solid powder at 60-90 DEG C, and grinding for 30-60 min, wherein the prepared composite is spherical, the shell of the prepared composite is made of nanometer aluminium oxide, and kaolin is coated with nanometer aluminium oxide. The composite integrates excellent performance of kaolin and nanometer aluminium oxide, and can be further used as a binding agent or reinforcing filler of other materials.
Description
Technical field
The present invention relates to the technical field of nano aluminium oxide.
Background technology
Kaolin has been widely used in the industrial production, such as can be used as binding agent, reinforcing filler, oil pad etc., in these cases, kaolinic self performance and dispersion effect often have obvious impact to the performance of material, the usual toughness of kaolin of conventional form is poor, adds after in material and easily occurs the bad phenomenon such as reunion.
Summary of the invention
The object of the invention is to the preparation method proposing a kind of nano oxidized aluminum composite, can prepare adhesive property and intensity kaolin-nano oxidized aluminum composite all preferably by this preparation method, this matrix material can be further used as binding agent or the reinforcing filler use of other materials.
Technical scheme of the present invention is as follows:
A preparation method for nano oxidized aluminum composite, comprises the following steps:
1) kaolin is added in deionized water, carry out ultrasonic disperse 10 ~ 30min, add SODIUM PHOSPHATE, MONOBASIC and aluminum phosphate in its backward dispersion liquid, again carry out ultrasonic disperse 10 ~ 30min, obtain precursor solution;
2) by precursor solution reflux 20 ~ 40min at 60 ~ 80 DEG C, in nitrogen atmosphere, thereafter naturally cooling is carried out, suction filtration is carried out after cooling, the pressed powder obtained is carried out washing with dry, at 60 ~ 90 DEG C, grind 30 ~ 60min after drying, namely obtain described nano oxidized aluminum composite.
Preferably: the mass parts of described kaolin and described SODIUM PHOSPHATE, MONOBASIC and described aluminum phosphate is respectively 5 ~ 7 parts, 0.1 ~ 0.3 part, 2 ~ 5 parts.
In addition preferably: the mass parts of described kaolin and described SODIUM PHOSPHATE, MONOBASIC and described aluminum phosphate is respectively 6 parts, 0.2 part, 4 parts.
Preparation method of the present invention is simple and easy to control, the matrix material obtained is spherical, its shell is formed primarily of nano aluminium oxide, by nano aluminium oxide, kaolin is coated on wherein, this matrix material combines the premium properties of kaolin and nano aluminium oxide, and binding agent or the reinforcing filler that can be further used as other materials use.
Embodiment
Embodiment 1
1) be that the kaolin of 5 parts adds in 60 parts of deionized waters by mass parts, carry out ultrasonic disperse 10min, add 0.1 part of SODIUM PHOSPHATE, MONOBASIC and 2 parts of aluminum phosphates in its backward dispersion liquid, again carry out ultrasonic disperse 10min, obtain precursor solution;
2) by precursor solution reflux 20min at 60 DEG C, in nitrogen atmosphere, thereafter naturally cooling is carried out, suction filtration is carried out after cooling, the pressed powder obtained is carried out washing with dry, at 60 DEG C, 60min is ground after drying, namely obtain described nano oxidized aluminum composite, the nano oxidized aluminum composite median size of gained is 50nm.
Embodiment 2
1) be that the kaolin of 7 parts adds in 90 parts of deionized waters by mass parts, carry out ultrasonic disperse 30min, add 0.3 part of SODIUM PHOSPHATE, MONOBASIC and 5 parts of aluminum phosphates in its backward dispersion liquid, again carry out ultrasonic disperse 30min, obtain precursor solution;
2) by precursor solution reflux 40min at 80 DEG C, in nitrogen atmosphere, thereafter naturally cooling is carried out, suction filtration is carried out after cooling, the pressed powder obtained is carried out washing with dry, at 90 DEG C, 30min is ground after drying, namely obtain described nano oxidized aluminum composite, the nano oxidized aluminum composite median size of gained is 25nm.
Embodiment 3
1) be that the kaolin of 6 parts adds in 80 parts of deionized waters by mass parts, carry out ultrasonic disperse 20min, add 0.2 part of SODIUM PHOSPHATE, MONOBASIC and 4 parts of aluminum phosphates in its backward dispersion liquid, again carry out ultrasonic disperse 20min, obtain precursor solution;
2) by precursor solution reflux 30min at 70 DEG C, in nitrogen atmosphere, thereafter naturally cooling is carried out, suction filtration is carried out after cooling, the pressed powder obtained is carried out washing with dry, at 80 DEG C, 40min is ground after drying, namely obtain described nano oxidized aluminum composite, the nano oxidized aluminum composite median size of gained is 30nm.
Claims (3)
1. a preparation method for nano oxidized aluminum composite, is characterized in that: comprise the following steps:
1) kaolin is added in deionized water, carry out ultrasonic disperse 10 ~ 30min, add SODIUM PHOSPHATE, MONOBASIC and aluminum phosphate in its backward dispersion liquid, again carry out ultrasonic disperse 10 ~ 30min, obtain precursor solution;
2) by precursor solution reflux 20 ~ 40min at 60 ~ 80 DEG C, in nitrogen atmosphere, thereafter naturally cooling is carried out, suction filtration is carried out after cooling, the pressed powder obtained is carried out washing with dry, at 60 ~ 90 DEG C, grind 30 ~ 60min after drying, namely obtain described nano oxidized aluminum composite.
2. the preparation method of nano oxidized aluminum composite according to claim 1, is characterized in that: the mass parts of described kaolin and described SODIUM PHOSPHATE, MONOBASIC and described aluminum phosphate is respectively 5 ~ 7 parts, 0.1 ~ 0.3 part, 2 ~ 5 parts.
3. the preparation method of nano oxidized aluminum composite according to claim 1, is characterized in that: the mass parts of described kaolin and described SODIUM PHOSPHATE, MONOBASIC and described aluminum phosphate is respectively 6 parts, 0.2 part, 4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510850919.4A CN105295451A (en) | 2015-11-30 | 2015-11-30 | Preparation method for nanometer aluminium oxide composite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510850919.4A CN105295451A (en) | 2015-11-30 | 2015-11-30 | Preparation method for nanometer aluminium oxide composite |
Publications (1)
| Publication Number | Publication Date |
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| CN105295451A true CN105295451A (en) | 2016-02-03 |
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| CN201510850919.4A Pending CN105295451A (en) | 2015-11-30 | 2015-11-30 | Preparation method for nanometer aluminium oxide composite |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3151993A (en) * | 1960-03-31 | 1964-10-06 | Georgia Kaolin Co | Planographic inks containing aluminum hydroxide coated kaolinite particles |
| CN101590432A (en) * | 2008-05-28 | 2009-12-02 | 中国石油天然气股份有限公司 | Modified clay and preparation method thereof |
| CN102618093A (en) * | 2012-01-18 | 2012-08-01 | 常州大学 | Clay composite material and preparation method thereof |
| CN102786818A (en) * | 2012-06-29 | 2012-11-21 | 赵曰浩 | Method for whitening kaolin by using surface cladding method |
| CN103436055A (en) * | 2013-09-09 | 2013-12-11 | 郴州四方立投资有限公司 | Preparation method of nanometer aluminum oxide clad kaoline composite material |
| CN104971768A (en) * | 2014-04-01 | 2015-10-14 | 中国石油大学(北京) | SAPO-34/natural clay composite material as well as preparation method and application thereof |
-
2015
- 2015-11-30 CN CN201510850919.4A patent/CN105295451A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3151993A (en) * | 1960-03-31 | 1964-10-06 | Georgia Kaolin Co | Planographic inks containing aluminum hydroxide coated kaolinite particles |
| CN101590432A (en) * | 2008-05-28 | 2009-12-02 | 中国石油天然气股份有限公司 | Modified clay and preparation method thereof |
| CN102618093A (en) * | 2012-01-18 | 2012-08-01 | 常州大学 | Clay composite material and preparation method thereof |
| CN102786818A (en) * | 2012-06-29 | 2012-11-21 | 赵曰浩 | Method for whitening kaolin by using surface cladding method |
| CN103436055A (en) * | 2013-09-09 | 2013-12-11 | 郴州四方立投资有限公司 | Preparation method of nanometer aluminum oxide clad kaoline composite material |
| CN104971768A (en) * | 2014-04-01 | 2015-10-14 | 中国石油大学(北京) | SAPO-34/natural clay composite material as well as preparation method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| G.B罗森伯格著 储岩等译: "《美国耐火材料》", 30 November 1981, 冶金工业出版社 * |
| 化学工业部天津化工研究院: "《化工产品手册 无机化工产品》", 31 October 1993, 化学工业出版社 * |
| 杨华明 唐爱东: "《硅酸盐矿物精细化加工基础与技术》", 30 April 2012, 冶金工业出版社 * |
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Application publication date: 20160203 |
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