CN105273312A - Shipborne antibacterial flame-retardant cable and manufacture method thereof - Google Patents
Shipborne antibacterial flame-retardant cable and manufacture method thereof Download PDFInfo
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- CN105273312A CN105273312A CN201510727941.XA CN201510727941A CN105273312A CN 105273312 A CN105273312 A CN 105273312A CN 201510727941 A CN201510727941 A CN 201510727941A CN 105273312 A CN105273312 A CN 105273312A
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- Prior art keywords
- hawser
- retardant
- antibacterial flame
- shipborne
- cable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses a shipborne antibacterial flame-retardant cable and a manufacture method of the shipborne antibacterial flame-retardant cable, and relates to the field of shipping equipment manufacture. The manufacture method comprises the following steps that the plastic shells of waste motorcycles, aircrafts and household electrical appliances as well as the waste tires of automobiles and motorcycles are taken as main raw materials; other auxiliary components, including 80-85% of PP (Propene Polymer), 10-15% of PE (Poly Ethylene), 1-5% of oily materials, 1-3% of plasticizer and 0.1-1% of auxiliary agent, are added; the shipborne cable with high strength, super tolerance to abrasion, antibacterial property and flame retardance is manufactured through a unique technology; the cable is not only abrasion-proof and durable, but also has the effects of antibacterial property and flame retardance, therefore the body health of crew is protected, and the service life of the cable is prolonged; most of the cable raw materials are abandoned plastic and rubber products, and the raw materials are low in price and are easily obtained, therefore a finished product is cheap; moreover, the shipborne antibacterial flame-retardant cable and the manufacture method of the shipborne antibacterial flame-retardant cable have the advantages that the effects of energy saving and environment friendliness are achieved, waste products and rubbish are recycled, and the national policies of greenness and environment friendliness are satisfied, so that not only are the economic benefits increased, but also the national environment is protected, and the effect of turning waste into treasure is achieved.
Description
Technical field:
The present invention relates to ship's gear and manufacture field, be specifically related to a kind of boats and ships antibacterial flame-retardant hawser and manufacture method thereof.
Background technology:
Ship cable is the flat rope of tying boats and ships, requires to possess tension, shock resistance, antibacterial damage, the pliable and tough performance such as light and soft.Existing ship cable due to manufactured materials costly, manufacturing process is relatively backward, cause ship cable market value expensive, work-ing life is short, especially in antibacterial flame-retardant damage, by sea washes, corrode, insolation weathering and the friction with marine surface, a lot of hawser becomes easily infected by bacterium, cause the infringement to HUMAN HEALTH, and hawser is heated easily burning, cannot continue after damage to use, frequent replacing needs to pay higher expense, therefore, a kind of cheap, low price, and the boats and ships hawser of antibacterial flame-retardant be shipbuilding industry in the urgent need to.
Summary of the invention:
For solving the problem, the invention provides boats and ships antibacterial flame-retardant hawser and manufacture method thereof, the present invention uses waste and old motorcycle, aircraft, and the plastic casing of household electrical appliance, the junked tire of automobile and motorcycle is main raw material, be equipped with other adjunct ingredients, high strength is gone out by Particular craft processing and manufacturing, super abrasive, the ship cable of antibacterial flame-retardant, this hawser is not only wear-resisting durable, and play the effect of antibacterial flame-retardant, thus protection crewman's is healthy, extend the work-ing life of hawser, this hawser raw material is owing to being mostly waste plastic and rubber item, cheaply to be easy to get, so finished product low price, and energy-conserving and environment-protective of the present invention, waste product and rubbish are re-used, meet the policy of national green environmental protection, both economic benefit was added, protect National Environmental again, reach the effect turned waste into wealth.
Technical problem to be solved by this invention adopts following technical scheme to realize:
A kind of boats and ships antibacterial flame-retardant hawser, it is characterized in that, described hawser is made up of the formulation ratio of following weight part:
PP：80-85％
PE：10-15％
Oily material: 1-5%
Antiseptic-germicide: 0.5-1.5%
Fire retardant: 0.5-1.5%
Auxiliary agent: 0.1-1%.
Described PP, PE have higher shock-resistance, mechanical properties is tough, anti-multiple organic solvent and acid and alkali corrosion, by the plastic casing of waste and old motorcycle, aircraft and household electrical appliance in the present invention, the junked tire recycling of automobile and motorcycle is extracted obtained, cheaper starting materials is easy to get, energy-conserving and environment-protective.
Described oily material, mainly refers to acrylic acid esters co-polymer, and this oily material forms a kind oil film shape structure on the hawser produced, reduce fiber surface frictional coefficient, reduce frictionally damage when using, reach and delay hawser loss of strength, improve the object in hawser work-ing life.
Described antiseptic-germicide is the powder small-particle of inorganic materials dispersion carrying silver ion, and nanometer silver powder is too little due to particle diameter, easily reunites, and the dispersion that antimicrobial component cannot be good, therefore does pre-dispersed process by inorganic materials, reaches good antibacterial effect.
Described fire retardant is Halogen hydroxide powder, greatly can improve the limiting oxygen index(LOI) of hawser, and flame retardant effect significantly and environmental protection.
Described auxiliary agent is one or more in photostabilizer, antioxidant, and the intensity that photostabilizer and antioxidant contribute to hawser internal fiber ensures, thus improves the anti-microbial property of hawser, extends the work-ing life of hawser.
A manufacture method for boats and ships antibacterial flame-retardant hawser, is characterized in that following steps:
According to above-mentioned weight part:
1), by oily material and auxiliary agent drop into mixing machine, with the speed of 1200 revs/min mixing, obtained mixture is for subsequent use;
2), single screw extrusion machine is passed through, adopt and quantitatively feed mode, logical and the step 1 by PP and PE) obtained mixture, in the ratio needed in fiber concentration feeding screw rod, melting, mixing, extrude, granulation, obtained masterbatch mix, extrusion temperature is set as 180-200 DEG C, and screw speed is 80 turns-120 revs/min;
3), by high-speed spinning colored terylene device for spinning, by above-mentioned masterbatch mix, add softening agent, by super-dry and Screw Extrusion, be melt into molten state spinning solution, be 200 DEG C-260 DEG C through filament spinning component at spinning temperature again, component pressure is that under the condition of 120 ~ 280bar, spinning forms strand, and strand is by cooling quench, cooling, solidification, package, formation hawser long filament;
4), by above-mentioned hawser long filament by rope-making equipment, according to actual needs, finished product hawser is woven into.
Beneficial effect of the present invention is, the present invention uses waste and old motorcycle, aircraft, and the plastic casing of household electrical appliance, the junked tire of automobile and motorcycle is main raw material, be equipped with other adjunct ingredients, high strength is gone out by Particular craft processing and manufacturing, super abrasive, the ship cable of antibacterial flame-retardant, this hawser is not only wear-resisting durable, and play the effect of antibacterial flame-retardant, thus protection crewman's is healthy, extend the work-ing life of hawser, this hawser raw material is owing to being mostly waste plastic and rubber item, cheaply to be easy to get, so finished product low price, and energy-conserving and environment-protective of the present invention, waste product and rubbish are re-used, meet the policy of national green environmental protection, both economic benefit was added, protect National Environmental again, reach the effect turned waste into wealth.
Embodiment:
The technique means realized to make the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with specific embodiment, setting forth the present invention further.
Embodiment one
A kind of boats and ships antibacterial flame-retardant hawser, it is characterized in that, described hawser is made up of the formulation ratio of following weight part:
PP：80％
PE：15％
Oily material: 1%
Antiseptic-germicide: 1.5%
Fire retardant: 1.5%
Auxiliary agent: 1%.
Described PP, PE are by the plastic casing of waste and old motorcycle, aircraft and household electrical appliance, and the junked tire recycling of automobile and motorcycle is extracted obtained.
Described oily material, mainly refers to acrylic acid esters co-polymer.
Described softening agent is epoxy plasticiser, comprises one or more in epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester.
Described auxiliary agent is one or more in photostabilizer, antioxidant.
A manufacture method for boats and ships antibacterial flame-retardant hawser, is characterized in that following steps:
According to above-mentioned weight part:
1), by oily material and auxiliary agent drop into mixing machine, with the speed of 1200 revs/min mixing, obtained mixture is for subsequent use;
2), single screw extrusion machine is passed through, adopt and quantitatively feed mode, logical and the step 1 by PP and PE) obtained mixture, in the ratio needed in fiber concentration feeding screw rod, melting, mixing, extrude, granulation, obtained masterbatch mix, extrusion temperature is set as 180-200 DEG C, and screw speed is 80 turns-120 revs/min;
3), by high-speed spinning colored terylene device for spinning, by above-mentioned masterbatch mix, add softening agent, by super-dry and Screw Extrusion, be melt into molten state spinning solution, be 200 DEG C-260 DEG C through filament spinning component at spinning temperature again, component pressure is that under the condition of 120 ~ 280bar, spinning forms strand, and strand is by cooling quench, cooling, solidification, package, formation hawser long filament;
4), by above-mentioned hawser long filament by rope-making equipment, according to actual needs, finished product hawser is woven into.
Embodiment two
A kind of boats and ships antibacterial flame-retardant hawser, it is characterized in that, described hawser is made up of the formulation ratio of following weight part:
PP：83％
PE：12.5％
Oily material: 2%
Antiseptic-germicide: 1%
Fire retardant: 1%
Auxiliary agent: 0.5%.
Described PP, PE are by the plastic casing of waste and old motorcycle, aircraft and household electrical appliance, and the junked tire recycling of automobile and motorcycle is extracted obtained.
Described oily material, mainly refers to acrylic acid esters co-polymer.
Described softening agent is epoxy plasticiser, comprises one or more in epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester.
Described auxiliary agent is one or more in photostabilizer, antioxidant.
A manufacture method for boats and ships antibacterial flame-retardant hawser, is characterized in that following steps:
According to above-mentioned weight part:
1), by oily material and auxiliary agent drop into mixing machine, with the speed of 1200 revs/min mixing, obtained mixture is for subsequent use;
2), single screw extrusion machine is passed through, adopt and quantitatively feed mode, logical and the step 1 by PP and PE) obtained mixture, in the ratio needed in fiber concentration feeding screw rod, melting, mixing, extrude, granulation, obtained masterbatch mix, extrusion temperature is set as 180-200 DEG C, and screw speed is 80 turns-120 revs/min;
3), by high-speed spinning colored terylene device for spinning, by above-mentioned masterbatch mix, add softening agent, by super-dry and Screw Extrusion, be melt into molten state spinning solution, be 200 DEG C-260 DEG C through filament spinning component at spinning temperature again, component pressure is that under the condition of 120 ~ 280bar, spinning forms strand, and strand is by cooling quench, cooling, solidification, package, formation hawser long filament;
4), by above-mentioned hawser long filament by rope-making equipment, according to actual needs, finished product hawser is woven into.
Embodiment three
A kind of boats and ships antibacterial flame-retardant hawser, it is characterized in that, described hawser is made up of the formulation ratio of following weight part:
PP：85％
PE：9.5％
Oily material: 4%
Antiseptic-germicide: 0.6%
Fire retardant: 0.8%
Auxiliary agent: 0.1%.
Described PP, PE are by the plastic casing of waste and old motorcycle, aircraft and household electrical appliance, and the junked tire recycling of automobile and motorcycle is extracted obtained.
Described oily material, mainly refers to acrylic acid esters co-polymer.
Described softening agent is epoxy plasticiser, comprises one or more in epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester.
Described auxiliary agent is one or more in photostabilizer, antioxidant.
A manufacture method for boats and ships antibacterial flame-retardant hawser, is characterized in that following steps:
According to above-mentioned weight part:
1), by oily material and auxiliary agent drop into mixing machine, with the speed of 1200 revs/min mixing, obtained mixture is for subsequent use;
2), single screw extrusion machine is passed through, adopt and quantitatively feed mode, logical and the step 1 by PP and PE) obtained mixture, in the ratio needed in fiber concentration feeding screw rod, melting, mixing, extrude, granulation, obtained masterbatch mix, extrusion temperature is set as 180-200 DEG C, and screw speed is 80 turns-120 revs/min;
3), by high-speed spinning colored terylene device for spinning, by above-mentioned masterbatch mix, add softening agent, by super-dry and Screw Extrusion, be melt into molten state spinning solution, be 200 DEG C-260 DEG C through filament spinning component at spinning temperature again, component pressure is that under the condition of 120 ~ 280bar, spinning forms strand, and strand is by cooling quench, cooling, solidification, package, formation hawser long filament;
4), by above-mentioned hawser long filament by rope-making equipment, according to actual needs, finished product hawser is woven into.
The foregoing describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (6)
1. a boats and ships antibacterial flame-retardant hawser, is characterized in that, described hawser is made up of the formulation ratio of following weight part:
PP：80-85％
PE：10-15％
Oily material: 1-5%
Antiseptic-germicide: 0.5-1.5%
Fire retardant: 0.5-1.5%
Auxiliary agent: 0.1-1%.
2. a kind of boats and ships antibacterial flame-retardant hawser according to claim 1, is characterized in that, described PP, PE are respectively by the plastic casing of waste and old motorcycle, aircraft and household electrical appliance, and the junked tire recycling of automobile and motorcycle is extracted obtained.
3. a kind of boats and ships antibacterial flame-retardant hawser according to claim 1, it is characterized in that, described oily material, mainly refers to acrylic acid esters co-polymer.
4. a kind of boats and ships antibacterial flame-retardant hawser according to claim 1, it is characterized in that, described softening agent is epoxy plasticiser, comprises one or more in epoxidized oil, epoxidized fat acid monoester and epoxidation tetrahydrophthalic acid ester.
5. a kind of boats and ships antibacterial flame-retardant hawser according to claim 1, it is characterized in that, described auxiliary agent is one or more in photostabilizer, antioxidant.
6. a boats and ships manufacture method for antibacterial flame-retardant hawser, is characterized in that following steps:
According to above-mentioned weight part:
1), by oily material and auxiliary agent drop into mixing machine, with the speed of 1200 revs/min mixing, obtained mixture is for subsequent use;
2), single screw extrusion machine is passed through, adopt and quantitatively feed mode, logical and the step 1 by PP and PE) obtained mixture, in the ratio needed in fiber concentration feeding screw rod, melting, mixing, extrude, granulation, obtained masterbatch mix, extrusion temperature is set as 180-200 DEG C, and screw speed is 80 turns-120 revs/min;
3), by high-speed spinning colored terylene device for spinning, by above-mentioned masterbatch mix, add softening agent, by super-dry and Screw Extrusion, be melt into molten state spinning solution, be 200 DEG C-260 DEG C through filament spinning component at spinning temperature again, component pressure is that under the condition of 120 ~ 280bar, spinning forms strand, and strand is by cooling quench, cooling, solidification, package, formation hawser long filament;
4), by above-mentioned hawser long filament by rope-making equipment, according to actual needs, finished product hawser is woven into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510727941.XA CN105273312A (en) | 2015-10-29 | 2015-10-29 | Shipborne antibacterial flame-retardant cable and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510727941.XA CN105273312A (en) | 2015-10-29 | 2015-10-29 | Shipborne antibacterial flame-retardant cable and manufacture method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105273312A true CN105273312A (en) | 2016-01-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510727941.XA Pending CN105273312A (en) | 2015-10-29 | 2015-10-29 | Shipborne antibacterial flame-retardant cable and manufacture method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163359A (en) * | 2017-07-18 | 2017-09-15 | 合肥万之景门窗有限公司 | A kind of antibacterial wear-resistant plastic and preparation method thereof |
| CN108659323A (en) * | 2018-06-21 | 2018-10-16 | 安徽鸿森塑业有限公司 | A method of preparing netting using plastic waste |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1873089A (en) * | 2005-05-30 | 2006-12-06 | 盐城神力制绳有限公司 | Method for fabricating rope of polypropylene meshwork threads in high strong |
| CN1918231A (en) * | 2004-01-22 | 2007-02-21 | 罗狄亚工业纱线股份公司 | Composition for yarns, yarns having improved properties and use thereof |
| CN102382372A (en) * | 2011-09-21 | 2012-03-21 | 深圳市科聚新材料有限公司 | Flame-retardant anti-bacteria polypropylene composite material and preparation method thereof |
-
2015
- 2015-10-29 CN CN201510727941.XA patent/CN105273312A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1918231A (en) * | 2004-01-22 | 2007-02-21 | 罗狄亚工业纱线股份公司 | Composition for yarns, yarns having improved properties and use thereof |
| CN1873089A (en) * | 2005-05-30 | 2006-12-06 | 盐城神力制绳有限公司 | Method for fabricating rope of polypropylene meshwork threads in high strong |
| CN102382372A (en) * | 2011-09-21 | 2012-03-21 | 深圳市科聚新材料有限公司 | Flame-retardant anti-bacteria polypropylene composite material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163359A (en) * | 2017-07-18 | 2017-09-15 | 合肥万之景门窗有限公司 | A kind of antibacterial wear-resistant plastic and preparation method thereof |
| CN108659323A (en) * | 2018-06-21 | 2018-10-16 | 安徽鸿森塑业有限公司 | A method of preparing netting using plastic waste |
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Application publication date: 20160127 |