CN105272344A - Foamed wall building material manufactured through recycling of solid waste and method - Google Patents
Foamed wall building material manufactured through recycling of solid waste and method Download PDFInfo
- Publication number
- CN105272344A CN105272344A CN201510790991.2A CN201510790991A CN105272344A CN 105272344 A CN105272344 A CN 105272344A CN 201510790991 A CN201510790991 A CN 201510790991A CN 105272344 A CN105272344 A CN 105272344A
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- CN
- China
- Prior art keywords
- solid waste
- building material
- wall building
- waste
- flyash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002910 solid waste Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims description 13
- 239000004566 building material Substances 0.000 title abstract description 14
- 238000004064 recycling Methods 0.000 title abstract 3
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000002699 waste material Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 16
- 238000005266 casting Methods 0.000 claims abstract description 8
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 8
- 238000005187 foaming Methods 0.000 claims abstract description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 239000010881 fly ash Substances 0.000 claims description 13
- 238000010276 construction Methods 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 235000006408 oxalic acid Nutrition 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 230000008929 regeneration Effects 0.000 claims description 7
- 238000011069 regeneration method Methods 0.000 claims description 7
- 230000002940 repellent Effects 0.000 claims description 7
- 239000005871 repellent Substances 0.000 claims description 7
- 238000013329 compounding Methods 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- -1 industrial residue Substances 0.000 claims description 3
- 239000011499 joint compound Substances 0.000 claims description 2
- 230000004044 response Effects 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 239000011449 brick Substances 0.000 description 6
- 239000004567 concrete Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Building Environments (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to the technical field of building materials, in particular to a lightweight foamed wall building material manufactured through recycling of solid waste and a manufacturing method. The foamed wall building material is a large block wall building material manufactured by applying a physical principle through instant foaming expansion, boiler heating is not needed, the wall building material is heated through magnesium chloride water, high-speed stirring is conducted, and the wall building material is formed through integral casting by pouring the materials into a large mold. The lightweight foamed wall building material manufactured through recycling of the solid waste and the manufacturing method have the advantages that specific investment is less, a boiler does not need to be installed, atmospheric pollution is reduced, the cost is low, the solid waste is utilized, the heat preservation effect is good, and the strength is higher than that of an aerated building block and reaches above 8.2 mpa; the waste is turned into treasure, and the silicate component in the solid waste is recycled.
Description
[technical field]
The present invention relates to building material technical field, is using the technology of construction wall packing material waste material as regeneration stopping composition, and solid waste regeneration utilizes the light-weight foam wall body building material and making method made specifically.
[background technology]
At present, high buildings and large mansions are built higher and higher, generally all adopt skeleton construction, need a large amount of partition wall building materials, and in order to alleviate the weight in building, the demand of light filling materials for wall body is increasing.Construction method is widely known by the people.Meanwhile, along with the continuous transformation in city, industry is greatly developed, and increasing building waste, industrial slag, cinder, slag the like waste are badly in need of solving.Containing gold in these wastes, silver, copper, iron, phosphorus comprises a large amount of flyash containing silicate, if arbitrarily wasted, not only contaminate environment, waste soil, has also wasted wherein favourable valuable composition.These waste materials above-mentioned can be used as the packing material of construction wall completely, and can be good at solving the prejudice that people cannot recycle for industrial residue.
Before this, had many people for developing in this respect and attempting, concrete aerated foam building block brick is in widespread use, but the investment of this manufacture method is large, boiler must be installed, steam, need to burn coal, waste resource, air is polluted, and intensity is poor, cannot nail be bored.
The patent that a castoff regenerative of China Patent No. to be 201210084892.9 be the applicant's earlier application utilizes, it discloses concrete grammar is under machine,massing or material distributing machine stir, add above-mentioned content light-burning magnesium powder, organosilicon, tertiary sodium phosphate, composite modifier, Aminosulfonic-acid high-efficiency water reducer, stir ten minutes, after making its uniform decomposition, batching is sent into full automatic brick making machine, the automatic compression moulding of hopper.
[summary of the invention]
The object of the invention is to produce a kind of lightweight building wall material of novelty, technique is advanced, need not install boiler, without steam, without maintenance, rapid shaping, and all adopt waste as stopping composition, through research, in industrial waste, building waste, especially flyash, containing a large amount of silicate component in slag, specifically has good modifying function.
To achieve these goals, design a kind of solid waste regeneration and utilize the foaming wall material of construction made, comprise rectangular tiles body and body of wall, the base material formula of this bulk one-piece casting and weight ratio as follows: building waste or solid industrial abandoned mine slag 65% ~ 75%, light-burning magnesium powder 8% ~ 10%, magnesium chloride, change water and be heated to 70 degree Celsius 3% ~ 6%, phosphoric acid 0.5% ~ 1%, oxalic acid 0.3% ~ 0.6%, inorganic compounding water repellent agent 0.3% ~ 0.5%, terra alba 2% ~ 4%, aluminium powder 0.3% ~ 0.5%, flyash 20% ~ 30%, wherein solid waste comprises building waste, industrial residue, flyash, slag and mud.
A kind ofly prepare the one-piece casting method that above-mentioned solid waste regeneration utilizes the foaming wall material of construction made, comprise rectangular tiles body and body of wall, one-piece construction casting method adopts the design of large mould, bulk is built, 70 degrees Celsius are warmed to by after the magnesium chloride water of above-mentioned content, the light-burning magnesium powder of above-mentioned content is added under strong stirring, phosphoric acid, oxalic acid, inorganic compounding water repellent agent, terra alba, aluminium powder, flyash, building waste or abandoned mine slag strong stirring made base material uniform decomposition after 6 minutes, reach instantaneous expansion, then pour in large-scale mould, after question response fully solidifies, building block and the large-sized sheet material of various desired shape can be cut into, base material hardness after shaping is more than 8.2mpa.
The present invention compared with the existing technology, its advantage is: structure is different, and technique is different, and technique effect is different, the wall body building material adopting this proportioning and method to make is higher than concrete aerated fly ash building block intensity, and heat-insulating property is also higher than concrete aerated fly ash building block, thermal conductivity can reach 0.27, greatly reduces the consumption of the energy, the minimizing of work personnel and the reduction of cost, because aerating need not be heated, without boiler, decrease the pollution of environment.
[embodiment]
The invention will be further described below, and the proportioning of this material and principle are very clearly concerning the people of this specialty.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1: every cube of base material formula per-cent of thorough piece of this entirety casting is as follows:
This entirety is cast building block and is provided with large mould, the magnesium chloride water of above-mentioned content is heated to 70 DEG C of degree, under the stirring of machine,massing, add the light-burning magnesium powder of above-mentioned content, phosphoric acid, oxalic acid, compound water repellent agent, terra alba, aluminium powder, flyash, building waste (or solid abandoned mine slag) strong stirring 6 minutes, make base material uniform decomposition, instantaneous expansion, then pour that to make it solidify physics voluntarily in pre-designed mould shaping into, shaping rear intensity is more than 8.2mpa, ultimate compression strength is high, thermal conductivity reaches 0.27, good heat insulating, lightweight, good endurance, long service life, easy processing, can cut, can certificate, can follow closely.
Embodiment 2
This entirety cast every cubic metre of base material formula of building block and weight percent as follows: building waste (or solid abandoned mine slag) 55% ~ 65%, light-burning magnesium powder 8% ~ 10%, magnesium chloride (change water and be heated to 70 degrees Celsius) 3% ~ 6%, phosphoric acid 0.5% ~ 1%, oxalic acid 0.3% ~ 0.6%, inorganic compounding water repellent agent 0.3% ~ 0.5%, terra alba 2% ~ 4%, aluminium powder 0.3% ~ 0.5%, flyash 20% ~ 30%.
This integral cast building block is fixed by mould, is heated by the magnesium chloride water of above-mentioned content to 70 DEG C of degree under the stirring of machine,massing, adds the light-burning magnesium powder of above-mentioned content, phosphoric acid, oxalic acid, inorganic compounding water repellent agent, terra alba, aluminium powder, flyash or building waste strong stirring 6 minutes.Make base material uniform decomposition, instantaneous expansion, then to pour after making it fully expand in pre-designed mould curing molding voluntarily into.Then the shaping building materials such as required plate, building block, brick are cut into.Its product performance: one, physique is light, every cube of 459kg, two, good heat insulating, thermal conductivity reaches 0.27, and three, intensity reaches more than 8.2mpa, four, fire resistance is good, reach non-fire material A level, five, good endurance, 20 years anti-aging detection dust one-levels through national building materials test center, color is constant, and six, water resisting property is good, seven, easily process, can cutting processing arbitrarily, eight, can saw, can bore, bore when following closely not broken, do not loosen, and cheap.
This product is desirable in sum, light wall material.
Example 1
The specification of wall brick is long 24mm, wide 11.5mm, and thick is 5.1mm.
Example 2
The specification of large-scale wall brick is long 1200mm, wide 1200mm, and thick is 400mm.
Example 3
The specification of sea base stone walling brick is long 1200mm, wide 1200mm, and thick is 500mm.
Example 4
The specification of wallboard is long 500mm, wide 500mm, and thick is 12mm.
Claims (2)
1. a solid waste regeneration utilizes the foaming wall material of construction made, comprise rectangular tiles body and body of wall, it is characterized in that base material formula and the weight ratio of this bulk one-piece casting are as follows: building waste or solid industrial abandoned mine slag 65% ~ 75%, light-burning magnesium powder 8% ~ 10%, magnesium chloride, change water and be heated to 70 degree Celsius 3% ~ 6%, phosphoric acid 0.5% ~ 1%, oxalic acid 0.3% ~ 0.6%, inorganic compounding water repellent agent 0.3% ~ 0.5%, terra alba 2% ~ 4%, aluminium powder 0.3% ~ 0.5%, flyash 20% ~ 30%, wherein solid waste comprises building waste, industrial residue, flyash, slag and mud.
2. prepare the one-piece casting method that solid waste regeneration as claimed in claim 1 utilizes the foaming wall material of construction made for one kind, comprise rectangular tiles body and body of wall, it is characterized in that one-piece construction casting method adopts the design of large mould, bulk is built, 70 degrees Celsius are warmed to by after the magnesium chloride water of above-mentioned content, the light-burning magnesium powder of above-mentioned content is added under strong stirring, phosphoric acid, oxalic acid, inorganic compounding water repellent agent, terra alba, aluminium powder, flyash, building waste or abandoned mine slag strong stirring made base material uniform decomposition after 6 minutes, reach instantaneous expansion, then pour in large-scale mould, after question response fully solidifies, building block and the large-sized sheet material of various desired shape can be cut into, base material hardness after shaping is more than 8.2mpa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510790991.2A CN105272344B (en) | 2015-11-17 | 2015-11-17 | A kind of one-piece casting method for preparing foaming wall construction material made of solid waste regeneration utilization |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510790991.2A CN105272344B (en) | 2015-11-17 | 2015-11-17 | A kind of one-piece casting method for preparing foaming wall construction material made of solid waste regeneration utilization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105272344A true CN105272344A (en) | 2016-01-27 |
| CN105272344B CN105272344B (en) | 2017-11-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510790991.2A Active CN105272344B (en) | 2015-11-17 | 2015-11-17 | A kind of one-piece casting method for preparing foaming wall construction material made of solid waste regeneration utilization |
Country Status (1)
| Country | Link |
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| CN (1) | CN105272344B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108117341A (en) * | 2016-11-28 | 2018-06-05 | 广东帝亿建材科技有限公司 | A kind of preparation method of environment friendly wall material and environment friendly wall material |
| CN108516790A (en) * | 2018-04-28 | 2018-09-11 | 赤水市瑞泰建材有限公司 | A kind of solid waste regeneration materials for wall and preparation method thereof |
| CN114096344A (en) * | 2019-06-03 | 2022-02-25 | 贝托拉尔公司 | Arrangement and method for mixing paste at waste disposal site |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225345A (en) * | 1998-11-30 | 1999-08-11 | 韩敏芳 | Artificial stone products |
| EP2119866A1 (en) * | 2004-10-26 | 2009-11-18 | Halliburton Energy Services, Inc. | Casing strings and methods of using such strings in subterranean cementing operations |
-
2015
- 2015-11-17 CN CN201510790991.2A patent/CN105272344B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1225345A (en) * | 1998-11-30 | 1999-08-11 | 韩敏芳 | Artificial stone products |
| EP2119866A1 (en) * | 2004-10-26 | 2009-11-18 | Halliburton Energy Services, Inc. | Casing strings and methods of using such strings in subterranean cementing operations |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108117341A (en) * | 2016-11-28 | 2018-06-05 | 广东帝亿建材科技有限公司 | A kind of preparation method of environment friendly wall material and environment friendly wall material |
| CN108516790A (en) * | 2018-04-28 | 2018-09-11 | 赤水市瑞泰建材有限公司 | A kind of solid waste regeneration materials for wall and preparation method thereof |
| CN114096344A (en) * | 2019-06-03 | 2022-02-25 | 贝托拉尔公司 | Arrangement and method for mixing paste at waste disposal site |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105272344B (en) | 2017-11-24 |
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