CN105261731B - A kind of curing and dying process of anode plate for lead acid accumulator - Google Patents
A kind of curing and dying process of anode plate for lead acid accumulator Download PDFInfo
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- CN105261731B CN105261731B CN201510558431.4A CN201510558431A CN105261731B CN 105261731 B CN105261731 B CN 105261731B CN 201510558431 A CN201510558431 A CN 201510558431A CN 105261731 B CN105261731 B CN 105261731B
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- 239000002253 acid Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 40
- 230000003068 static effect Effects 0.000 claims abstract description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 4
- 239000001301 oxygen Substances 0.000 claims abstract description 4
- 238000010583 slow cooling Methods 0.000 claims abstract description 4
- 238000003860 storage Methods 0.000 claims description 4
- 230000009466 transformation Effects 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 230000000284 resting effect Effects 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
- H01M4/16—Processes of manufacture
- H01M4/20—Processes of manufacture of pasted electrodes
- H01M4/21—Drying of pasted electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
本发明涉及蓄电池的生产工艺领域,具体地说是一种铅酸蓄电池正极板的固化干燥工艺,包括固化、静止及干燥三个阶段,在固化阶段,将极板紧密靠拢,固化阶段设定温度为55‑60℃,固化湿度设置为90‑98%,固化时间设置为12‑24小时;静止阶段时间设置为8‑12小时,极板在慢慢冷却过程中将空气中的氧气吸入极板内部以达到游离铅转化所需的条件;干燥阶段温度设置为60℃,干燥湿度设置为30%以下,干燥时间设置为20小时。本发明可实现在较低固化温度的条件下,达到高温固化的效果,降低能耗和成本。The invention relates to the field of production technology of batteries, in particular to a curing and drying process for positive plates of lead-acid batteries, including three stages of curing, resting and drying. The temperature is 55-60°C, the curing humidity is set to 90-98%, the curing time is set to 12-24 hours; the static stage time is set to 8-12 hours, and the oxygen in the air is sucked into the plate during the slow cooling process. The interior is to achieve the conditions required for free lead conversion; the temperature of the drying stage is set to 60°C, the drying humidity is set to below 30%, and the drying time is set to 20 hours. The invention can realize the effect of high temperature curing under the condition of relatively low curing temperature, and reduce energy consumption and cost.
Description
技术领域technical field
本发明涉及蓄电池的生产工艺领域,具体地说是一种铅酸蓄电池正极板的固化干燥工艺。The invention relates to the field of storage battery production technology, in particular to a curing and drying process for the positive plate of a lead-acid storage battery.
背景技术Background technique
在制作铅酸电池的过程中,铅酸电池正极板铅膏中未转化的游离铅和水分含量过高,需要进行固化干燥使其下降到较低的水平,游离铅下降到4%以下,水分下降到1%以下。具体工艺流程如下:1、和膏;2、涂板;3湿正极板;4、固化、干燥;5、干正极板。目前铅酸电池正极板的固化工艺有高温固化和常温固化两种,高温固化温度为75~90℃,湿度为90~98%;常温固化温度为40~50℃,湿度为90-98%。干燥工艺中干燥温度为60~90℃,湿度为30%以下。上述的固化干燥工艺都是目前生产上较为常用的固化干燥工艺。In the process of making lead-acid batteries, the unconverted free lead and moisture content in the lead paste of the positive plate of the lead-acid battery are too high, and it needs to be cured and dried to reduce it to a lower level, and the free lead drops below 4%. dropped below 1%. The specific process flow is as follows: 1. Mixing the paste; 2. Coating the plate; 3. Wetting the positive plate; 4. Curing and drying; 5. Drying the positive plate. At present, the curing process of the positive plate of the lead-acid battery includes high temperature curing and room temperature curing. In the drying process, the drying temperature is 60-90°C, and the humidity is below 30%. The above-mentioned curing and drying processes are the more commonly used curing and drying processes in current production.
发明内容Contents of the invention
为解决上述存在的技术问题,本发明提供了一种铅酸蓄电池正极板的固化干燥工艺,在较低固化温度的条件下,达到高温固化的效果,降低能耗和成本。In order to solve the above-mentioned existing technical problems, the present invention provides a curing and drying process for the positive plate of a lead-acid battery, which achieves the effect of high-temperature curing under the condition of relatively low curing temperature, and reduces energy consumption and cost.
为达到上述目的,本发明所采用的技术方案是:In order to achieve the above object, the technical scheme adopted in the present invention is:
一种铅酸蓄电池正极板的固化干燥工艺,其特征在于,包括固化、静止及干燥三个阶段,在固化阶段,将极板紧密靠拢,固化阶段设定温度为55-60℃,固化湿度设置为90-98%,固化时间设置为12-24小时;静止阶段时间设置为8-12小时,极板在慢慢冷却过程中将空气中的氧气吸入极板内部以达到游离铅转化所需的条件;干燥阶段温度设置为60℃,干燥湿度设置为30%以下,干燥时间设置为20小时。A curing and drying process for the positive plate of a lead-acid battery, which is characterized in that it includes three stages of curing, resting and drying. In the curing stage, the polar plates are closely approached. 90-98%, the solidification time is set to 12-24 hours; the static stage time is set to 8-12 hours, the plate absorbs the oxygen in the air into the inside of the plate during the slow cooling process to achieve the required conversion of free lead Conditions; the drying stage temperature is set to 60°C, the drying humidity is set to below 30%, and the drying time is set to 20 hours.
本发明所阐述的铅酸蓄电池正极板固化干燥工艺,主要是在固化阶段将极板紧密靠拢在一起,利用极板自身放热反应的热量来提高极板固化阶段的温度,静止阶段使极板在慢慢冷却的过程中将空气中的氧气吸入极板内部以达到游离铅转化所需的条件,而干燥阶段温度仅需要60℃,这样使得固化阶段的温度在55-60℃时就可以达到固化75-90℃、干燥60-90℃的高温固化干燥效果,减少了整个工艺过程中的能源消耗,降低了生产成本,提高企业的经济效益。The curing and drying process of the positive plate of the lead-acid storage battery described in the present invention is mainly to close the pole plates together in the curing stage, use the heat of the exothermic reaction of the pole plate itself to increase the temperature of the pole plate in the curing stage, and make the pole plate dry in the static stage. In the process of slow cooling, the oxygen in the air is sucked into the inside of the plate to achieve the conditions required for the transformation of free lead, and the temperature in the drying stage only needs to be 60°C, so that the temperature in the solidification stage can be reached at 55-60°C The high-temperature curing and drying effect of curing at 75-90°C and drying at 60-90°C reduces energy consumption in the entire process, reduces production costs, and improves the economic benefits of the enterprise.
具体实施方式Detailed ways
下面结合具体实施例对本发明进行详细描述:The present invention is described in detail below in conjunction with specific embodiment:
实施例1:Example 1:
将正极板紧密靠拢,固化阶段温度为55℃,固化湿度为90~98%;静止阶段8小时;干燥温度为60℃,干燥湿度为30%以下。固化12~24小时,干燥20小时的实验结果如表1:Closely close the positive plates, the curing stage temperature is 55°C, and the curing humidity is 90-98%; the static stage is 8 hours; the drying temperature is 60°C, and the drying humidity is below 30%. The experimental results of curing for 12 to 24 hours and drying for 20 hours are shown in Table 1:
表1Table 1
实施例2:Example 2:
将正极板紧密靠拢,固化阶段温度为55℃,固化湿度为90~98%;静止阶段12小时;干燥温度为60℃,干燥湿度为30%以下。固化12~24小时,干燥20小时的实验结果如表2:Closely close the positive plates, the curing stage temperature is 55°C, and the curing humidity is 90-98%; the static stage is 12 hours; the drying temperature is 60°C, and the drying humidity is below 30%. The experimental results of curing for 12 to 24 hours and drying for 20 hours are shown in Table 2:
表2Table 2
实施例三:Embodiment three:
将正极板紧密靠拢,固化阶段温度为60℃,固化湿度为90~98%,静止阶段8小时;干燥温度为60℃,干燥湿度为30%以下。固化12~24小时,干燥20小时的实验结果如表3:Closely close the positive plates, the curing stage temperature is 60°C, the curing humidity is 90-98%, and the static stage is 8 hours; the drying temperature is 60°C, and the drying humidity is below 30%. The experimental results of curing for 12 to 24 hours and drying for 20 hours are shown in Table 3:
表3table 3
实施例四:Embodiment four:
一种铅酸电池正极板的固化干燥工艺,将正极板紧密靠拢,固化阶段温度为60℃,固化湿度为90~98%,静止阶段12小时;干燥温度为60℃,干燥湿度为30%以下。固化12~24小时,干燥20小时的实验结果如表4:A curing and drying process for the positive plate of a lead-acid battery, the positive plate is brought close together, the temperature in the curing stage is 60°C, the curing humidity is 90-98%, and the static stage is 12 hours; the drying temperature is 60°C, and the drying humidity is below 30% . The experimental results of curing for 12 to 24 hours and drying for 20 hours are shown in Table 4:
表4Table 4
从以上实施例中可以看出,极板经过固化干燥后都有高温固化的产物四碱式硫酸铅(4BS)生成。本发明在固化阶段将极板紧密地靠拢,利用极板自身放热反应的热量来提高极板固化阶段的温度,从而达到高温固化的效果。It can be seen from the above examples that tetrabasic lead sulfate (4BS), a product cured at high temperature, is produced after the plates are cured and dried. In the invention, the polar plates are closely approached in the curing stage, and the heat of the exothermic reaction of the polar plates is used to increase the temperature of the polar plates in the curing stage, so as to achieve the effect of high-temperature curing.
当然,上述说明并非是对本发明的限制,本发明也并不仅限于上述举例,本技术领域的技术人员在本发明的实质范围内所做出的变化、改型、添加或替换,也应属于本发明的保护范围。Of course, the above descriptions are not intended to limit the present invention, and the present invention is not limited to the above examples. Changes, modifications, additions or replacements made by those skilled in the art within the scope of the present invention shall also belong to the present invention. protection scope of the invention.
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CN102509777A (en) * | 2011-12-30 | 2012-06-20 | 江苏双登集团有限公司 | Curing and drying method applied to lead-acid storage battery plate |
CN102683651A (en) * | 2012-05-28 | 2012-09-19 | 江苏超威电源有限公司 | Intermittent sectional quick solidification method for cadmium-free internal formation storage battery |
CN103943832A (en) * | 2014-03-25 | 2014-07-23 | 超威电源有限公司 | Electrode plate solidification technology for energy storage lead-acid battery |
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CN102509777A (en) * | 2011-12-30 | 2012-06-20 | 江苏双登集团有限公司 | Curing and drying method applied to lead-acid storage battery plate |
CN102683651A (en) * | 2012-05-28 | 2012-09-19 | 江苏超威电源有限公司 | Intermittent sectional quick solidification method for cadmium-free internal formation storage battery |
CN103943832A (en) * | 2014-03-25 | 2014-07-23 | 超威电源有限公司 | Electrode plate solidification technology for energy storage lead-acid battery |
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Address after: 271400 Gangcheng Town Project Area, Ningyang County, Tai'an City, Shandong Province (West of Mengguan Highway, North of Xinzhou Highway) Patentee after: Shandong Mingde Power Supply Co.,Ltd. Country or region after: China Address before: 271405 Gangcheng Town Project Area, Ningyang County, Tai'an City, Shandong Province Patentee before: SHANDONG CHAOWEI POWER CO.,LTD. Country or region before: China |