CN105255059A - High-temperature-resisting anti-aging interior decoration PVC modified material and preparation method thereof - Google Patents
High-temperature-resisting anti-aging interior decoration PVC modified material and preparation method thereof Download PDFInfo
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- CN105255059A CN105255059A CN201510762248.6A CN201510762248A CN105255059A CN 105255059 A CN105255059 A CN 105255059A CN 201510762248 A CN201510762248 A CN 201510762248A CN 105255059 A CN105255059 A CN 105255059A
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- 239000000463 material Substances 0.000 title claims abstract description 26
- 230000003712 anti-aging effect Effects 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 10
- 238000005034 decoration Methods 0.000 title abstract 3
- 239000000654 additive Substances 0.000 claims abstract description 14
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 7
- 239000004917 carbon fiber Substances 0.000 claims abstract description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 7
- 239000003549 soybean oil Substances 0.000 claims abstract description 7
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003381 stabilizer Substances 0.000 claims abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 31
- 239000004800 polyvinyl chloride Substances 0.000 claims description 31
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- 239000002994 raw material Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004159 Potassium persulphate Substances 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000011268 mixed slurry Substances 0.000 claims description 6
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 6
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 6
- 235000019394 potassium persulphate Nutrition 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 239000000230 xanthan gum Substances 0.000 claims description 6
- 229940082509 xanthan gum Drugs 0.000 claims description 6
- 235000010493 xanthan gum Nutrition 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 3
- 230000002745 absorbent Effects 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229960003742 phenol Drugs 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 abstract 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000473 propyl gallate Substances 0.000 abstract 1
- 229940075579 propyl gallate Drugs 0.000 abstract 1
- 235000010388 propyl gallate Nutrition 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 229910052845 zircon Inorganic materials 0.000 abstract 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-temperature-resisting and anti-aging interior decoration PVC modified material which is prepared from, by weight, 80-100 parts of PVC resin, 4-6 parts of zircon powder, 2-4 parts of graphite powder, 1-2 parts of carbon fiber, 1-2 parts of nano-zinc oxide, 0.2-0.4 part of propylgallate, 0.1-0.2 part of antioxidant 1010, 0.1-0.2 part of ultraviolet light absorber UV-531, 2-3 parts of a calcium-zinc stabilizer, 5-10 parts of epoxidized soybean oil, 20-30 parts of acetyl tributyl citrate, 0.5-1 part of oleamide and 5-10 parts of a performance additive. The interior decoration PVC modified material has the good mechanical performance and moisture absorption and humidifying performance, can effectively improve indoor environment comfort level, has the good high-temperature-resisting and anti-aging performance, is long in service life and high in stability, and has the high added value and practical value.
Description
Technical field
The present invention relates to the material modified technical field of PVC, particularly relate to a kind of high temperature resistant anti-aging upholstery PVC material modified and preparation method thereof.
Background technology
PVC and polyvinyl chloride are one of plastics varieties that Application Areas is the widest, have been widely used in the field such as pipe profile, building furniture, upholstery, sports equipment, medical material.But PVC product ubiquity poor mechanical property, to light, defect that thermostability is low, and along with the enhancing of people's environmental consciousness and the raising to indoor environment requirement, current PVC material is more and more difficult to accord with the demands of the market, and limits its application in upholstery field.Therefore, improve the over-all properties of PVC material, promoting the value added of PVC material, is the latency development direction of current PVC house decorative material.Easily there is decomposition and cause variable color in PVC, mechanical property declines rapidly, limits its range of application under high temperature or exposure condition.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of high temperature resistant anti-aging upholstery PVC material modified and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high temperature resistant anti-aging upholstery PVC is material modified, and it is obtained by the raw material of following weight parts:
Polyvinyl chloride resin 80-100, zirconium English powder 4-6, Graphite Powder 99 2-4, carbon fiber 1-2, nano zine oxide 1-2, Tenox PG 0.2-0.4, antioxidant 1010 0.1-0.2, ultraviolet absorbent UV-531 0.1-0.2, calcium zinc stabilizer 2-3, epoxy soybean oil 5-10, tributyl acetylcitrate 20-30, amine hydroxybenzene 0.5-1, modified additive 5-10;
Wherein modified additive is made up of the raw material of following weight part: vinylformic acid 6-8, methylene diacrylamide 0.1-0.15, Potassium Persulphate 0.2-0.4, nano aluminium oxide 3-5, diatomite 10-15, xanthan gum 1-2, silane resin acceptor kh-550 0.1-0.2, water 80-100; The preparation method of modified additive be diatomite, xanthan gum, nano aluminium oxide and Potassium Persulphate are added to the water 50-60 DEG C, 600-800r/min stirs 0.5-1h, then 2-3h is stirred under adding vinylformic acid and methylene diacrylamide similarity condition, cooled and filtered is washed, dry completely after under 100-120 DEG C of condition with all the other raw material mixing 10-15min, after cooling, grinding evenly, to obtain final product.
The preparation method that high temperature resistant anti-aging upholstery PVC is material modified, comprises the following steps:
(1) raw material is taken by weight, co-ground 10-15min after first zirconium English powder, Graphite Powder 99, carbon fiber, nano zine oxide being mixed with Tenox PG, then add epoxy soybean oil 60-80 DEG C, 1000-1200r/min stirs 5-10min, obtain mixed slurry;
(2) by the mixed slurry in polyvinyl chloride resin, modified additive and (1) prior to 50-60 DEG C, 1000-1500r/min stirs 5-10min, then add all the other raw materials and continue the blended 10-20min of high speed in 120-140 DEG C, finally add twin screw extruder and melt extrude granulation in 100-140 DEG C, namely obtain high temperature resistant anti-aging upholstery PVC after cooling material modified.
Advantage of the present invention is:
The present invention is by acrylic acid synthesizing, nano aluminium oxide, composite diatomite modified additive blended with the material such as polyvinyl chloride resin, then obtained PVC is melt extruded material modified, both mechanical property and the weathering resistance of material had been enhanced, which in turn improve the sucting wet air permeability of material, make that the upholstery PVC that obtains is material modified has good mechanical property and moisture absorption humidity, effectively can improve the comfort level of indoor environment, and there is good high temperature resistant ageing resistance, long service life, stability is high, has higher value added and practical value.
Embodiment
A kind of high temperature resistant anti-aging upholstery PVC is material modified, and it is obtained by the raw material of following weight parts:
Polyvinyl chloride resin 80, zirconium English powder 4, Graphite Powder 99 2, carbon fiber 1, nano zine oxide 1, Tenox PG 0.2, antioxidant 1010 0.1, ultraviolet absorbent UV-531 0.1, calcium zinc stabilizer 2, epoxy soybean oil 5, tributyl acetylcitrate 20, amine hydroxybenzene 0.5, modified additive 5;
Wherein modified additive is made up of the raw material of following weight part: vinylformic acid 6, methylene diacrylamide 0.1, Potassium Persulphate 0.2, nano aluminium oxide 3, diatomite 10, xanthan gum 1, Silane coupling agent KH550 0.1, water 80; The preparation method of modified additive be diatomite, xanthan gum, nano aluminium oxide and Potassium Persulphate are added to the water 50 DEG C, 600r/min stirs 0.5h, then 2h is stirred under adding vinylformic acid and methylene diacrylamide similarity condition, cooled and filtered is washed, dry completely after under 100 DEG C of conditions with all the other raw material mixing 10min, after cooling, grinding evenly, to obtain final product.
The preparation method that high temperature resistant anti-aging upholstery PVC is material modified, comprises the following steps:
(1) take raw material by weight, co-ground 10min after first zirconium English powder, Graphite Powder 99, carbon fiber, nano zine oxide being mixed with Tenox PG, then adds epoxy soybean oil 60 DEG C, 1000r/min stirs 5min, obtain mixed slurry;
(2) by the mixed slurry in polyvinyl chloride resin, modified additive and (1) prior to 50 DEG C, 1000r/min stirs 5min, then add all the other raw materials and continue the blended 10min of high speed in 120 DEG C, finally add twin screw extruder and melt extrude granulation in 100-140 DEG C, namely obtain high temperature resistant anti-aging upholstery PVC after cooling material modified.
The material modified the performance test results of above-mentioned obtained PVC is as follows:
| Test event | Unit | Result |
| Tensile strength | MPa | 24.6 |
| Elongation at break | ％ | 292 |
| Cantilever beam impact strength | kJ/m 2 | 13.9 |
| Ageing-resistant (158 DEG C, 168h) | Do not turn yellow, not embrittlement |
Claims (2)
1. a high temperature resistant anti-aging upholstery PVC is material modified, it is characterized in that, it is obtained by the raw material of following weight parts:
Polyvinyl chloride resin 80-100, zirconium English powder 4-6, Graphite Powder 99 2-4, carbon fiber 1-2, nano zine oxide 1-2, Tenox PG 0.2-0.4, antioxidant 1010 0.1-0.2, ultraviolet absorbent UV-531 0.1-0.2, calcium zinc stabilizer 2-3, epoxy soybean oil 5-10, tributyl acetylcitrate 20-30, amine hydroxybenzene 0.5-1, modified additive 5-10;
Described modified additive is made up of the raw material of following weight part: vinylformic acid 6-8, methylene diacrylamide 0.1-0.15, Potassium Persulphate 0.2-0.4, nano aluminium oxide 3-5, diatomite 10-15, xanthan gum 1-2, silane resin acceptor kh-550 0.1-0.2, water 80-100; The preparation method of modified additive be diatomite, xanthan gum, nano aluminium oxide and Potassium Persulphate are added to the water 50-60 DEG C, 600-800r/min stirs 0.5-1h, then 2-3h is stirred under adding vinylformic acid and methylene diacrylamide similarity condition, cooled and filtered is washed, dry completely after under 100-120 DEG C of condition with all the other raw material mixing 10-15min, after cooling, grinding evenly, to obtain final product.
2. the preparation method that a kind of high temperature resistant anti-aging upholstery PVC according to claim 1 is material modified, is characterized in that, comprise the following steps:
(1) raw material is taken by weight, co-ground 10-15min after first zirconium English powder, Graphite Powder 99, carbon fiber, nano zine oxide being mixed with Tenox PG, then add epoxy soybean oil 60-80 DEG C, 1000-1200r/min stirs 5-10min, obtain mixed slurry;
(2) by the mixed slurry in polyvinyl chloride resin, modified additive and (1) prior to 50-60 DEG C, 1000-1500r/min stirs 5-10min, then add all the other raw materials and continue the blended 10-20min of high speed in 120-140 DEG C, finally add twin screw extruder and melt extrude granulation in 100-140 DEG C, namely obtain high temperature resistant anti-aging upholstery PVC after cooling material modified.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510762248.6A CN105255059A (en) | 2015-11-10 | 2015-11-10 | High-temperature-resisting anti-aging interior decoration PVC modified material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510762248.6A CN105255059A (en) | 2015-11-10 | 2015-11-10 | High-temperature-resisting anti-aging interior decoration PVC modified material and preparation method thereof |
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| CN105255059A true CN105255059A (en) | 2016-01-20 |
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| CN201510762248.6A Pending CN105255059A (en) | 2015-11-10 | 2015-11-10 | High-temperature-resisting anti-aging interior decoration PVC modified material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280131A (en) * | 2016-08-31 | 2017-01-04 | 黄山豪泰塑胶有限公司 | A kind of PVC decorative Film of heat-proof combustion-resistant and its preparation method and application |
| CN106317703A (en) * | 2016-08-31 | 2017-01-11 | 黄山豪泰塑胶有限公司 | PVC (polyvinyl chloride) film as well as preparation method and application thereof |
| CN106380731A (en) * | 2016-08-31 | 2017-02-08 | 黄山豪泰塑胶有限公司 | PVC film for wallpaper and preparation method thereof |
| CN107176910A (en) * | 2017-05-17 | 2017-09-19 | 中国林业科学研究院林产化学工业研究所 | A kind of acetylation citric acid fatty acid ester plasticizer and its preparation method and application |
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| CN102453290A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Flame-retardant smoke-suppression PVC wood-plastic composite foaming material and manufacturing method thereof |
| CN103774813A (en) * | 2013-11-29 | 2014-05-07 | 淮北龙盘工贸有限责任公司 | Novel fire-retardant wallpaper |
| CN104324863A (en) * | 2014-09-30 | 2015-02-04 | 苏州博利迈新材料科技有限公司 | PVC (Polyvinyl Chloride) flocking composite material and preparation method thereof |
| CN104356545A (en) * | 2014-11-06 | 2015-02-18 | 安徽省三乐门窗幕墙工程有限公司 | High-weather-tolerance PVC wood-plastic composite material and preparation method thereof |
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2015
- 2015-11-10 CN CN201510762248.6A patent/CN105255059A/en active Pending
Patent Citations (4)
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| CN102453290A (en) * | 2010-10-22 | 2012-05-16 | 中国石油化工股份有限公司 | Flame-retardant smoke-suppression PVC wood-plastic composite foaming material and manufacturing method thereof |
| CN103774813A (en) * | 2013-11-29 | 2014-05-07 | 淮北龙盘工贸有限责任公司 | Novel fire-retardant wallpaper |
| CN104324863A (en) * | 2014-09-30 | 2015-02-04 | 苏州博利迈新材料科技有限公司 | PVC (Polyvinyl Chloride) flocking composite material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106280131A (en) * | 2016-08-31 | 2017-01-04 | 黄山豪泰塑胶有限公司 | A kind of PVC decorative Film of heat-proof combustion-resistant and its preparation method and application |
| CN106317703A (en) * | 2016-08-31 | 2017-01-11 | 黄山豪泰塑胶有限公司 | PVC (polyvinyl chloride) film as well as preparation method and application thereof |
| CN106380731A (en) * | 2016-08-31 | 2017-02-08 | 黄山豪泰塑胶有限公司 | PVC film for wallpaper and preparation method thereof |
| CN107176910A (en) * | 2017-05-17 | 2017-09-19 | 中国林业科学研究院林产化学工业研究所 | A kind of acetylation citric acid fatty acid ester plasticizer and its preparation method and application |
| CN107176910B (en) * | 2017-05-17 | 2019-10-22 | 中国林业科学研究院林产化学工业研究所 | A kind of acetylated citric acid fatty acid ester plasticizer and its preparation method and application |
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Application publication date: 20160120 |
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