CN105239084B - A kind of metallic article anti-rust cleaning agent - Google Patents
A kind of metallic article anti-rust cleaning agent Download PDFInfo
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- CN105239084B CN105239084B CN201510815710.4A CN201510815710A CN105239084B CN 105239084 B CN105239084 B CN 105239084B CN 201510815710 A CN201510815710 A CN 201510815710A CN 105239084 B CN105239084 B CN 105239084B
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- Prior art keywords
- parts
- cleaning agent
- rust cleaning
- metallic article
- article anti
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- Expired - Fee Related
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 39
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 36
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 12
- 241000158728 Meliaceae Species 0.000 claims abstract description 12
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 12
- 239000011575 calcium Substances 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 10
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 8
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims abstract description 3
- XOGODJOZAUTXDH-UHFFFAOYSA-M (N-methylanilino)methanesulfonate Chemical group CN(CS([O-])(=O)=O)c1ccccc1 XOGODJOZAUTXDH-UHFFFAOYSA-M 0.000 claims abstract description 3
- -1 polyoxy Polymers 0.000 claims description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 16
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 16
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 4
- HVUMOYIDDBPOLL-UHFFFAOYSA-N 2-(3,4-Dihydroxyoxolan-2-yl)-2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)C1OCC(O)C1O HVUMOYIDDBPOLL-UHFFFAOYSA-N 0.000 claims description 3
- IJCWFDPJFXGQBN-UHFFFAOYSA-N 2-[4-Hydroxy-3-(octadecanoyloxy)oxolan-2-yl]-2-(octadecanoyloxy)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)C1OCC(O)C1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-UHFFFAOYSA-N 0.000 claims description 3
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims description 3
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 3
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 3
- PRXRUNOAOLTIEF-WUOFIQDXSA-N sorbitan trioleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C\CCCCCCCC)C1OCC(O)C1OC(=O)CCCCCCC\C=C\CCCCCCCC PRXRUNOAOLTIEF-WUOFIQDXSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims 2
- 238000001802 infusion Methods 0.000 claims 2
- 241000220324 Pyrus Species 0.000 claims 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 1
- 235000021017 pears Nutrition 0.000 claims 1
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 239000006260 foam Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 238000002347 injection Methods 0.000 abstract description 2
- 239000007924 injection Substances 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 150000003953 γ-lactams Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 230000002045 lasting effect Effects 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of metallic article anti-rust cleaning agent, belong to surface of metal product processing technology field, technical points include:It is made of the component of following parts by weight：5~7 parts of aliphatic amine polyoxyethylene ether, 4~8 parts of calcium mahogany sulfonate, 4~6 parts of 2 pyrrolidones of N methyl, 5~7 parts of sorbitan carboxylic esterses, 3~4 parts of defoamer, 15~20 parts of deionized water.The metallic article anti-rust cleaning agent cleansing power of the present invention is strong, can ensure preferable rust-preventing characteristic under high humidity conditions, hot conditions do not interfere with corrosion resistance yet, also, the low defoaming of product foam is fast, is easy to high-pressure injection to clean, safe and harmless, environmentally safe.The anti-rust cleaning agent antirust time length of the present invention, reaches more than 180 days.
Description
Technical field
The present invention relates to a kind of metallic article anti-rust cleaning agent.Belong to surface of metal product processing technology field.
Background technology
In mechanical processing process, part is often stained with various dirts, such as acid, alkali, salt, dust, sweat stain, lubricating oil
Deng may need to place for a long time after the completion of cleaning, this process can cause part to get rusty.The parts of some large scale equipments
Volume is big, and manufacturing process is various, is completed in a process, into before next process, needs first to clean up manufacture workpiece,
Otherwise the making precision of next procedure may be influenceed.Because parts volume is big, technique is relative complex, and manufacturing time is longer,
Using in general cleaning agent, after cleaning up, metal parts is completely exposed in air, and time slightly length will get rusty, to equipment
Parts have a negative impact.
In general cleaning agent only has cleaning function, without antirust function, it is necessary to do antirust treatment at once after the washing,
Waste time and energy, cost is higher.And metal material gets rusty quickly, placing several hours just occurs rusty stain, influences product quality.It is anti-
Become rusty oil can only antirust and without cleaning function.
Occur some oil removing anti-rust cleaning agents currently on the market, the antirust ability of these cleaning agents is by ambient temperature and humidity
Influence is very big, and its rust-preventing characteristic and corrosion resistance can not meet industry requirement.
The content of the invention
The purpose of the present invention is to overcome above-mentioned the deficiencies in the prior art, there is provided a kind of metallic article anti-rust cleaning agent.
To achieve the above object, the present invention uses following technical proposals：
A kind of metallic article anti-rust cleaning agent, it is made of the component of following parts by weight：
5~7 parts of aliphatic amine polyoxyethylene ether, 4~8 parts of calcium mahogany sulfonate, 4~6 parts of METHYLPYRROLIDONE, sorb
5~7 parts of alcohol acid anhydride fatty acid ester, 3~4 parts of defoamer, 15~20 parts of deionized water.
Preferably, it is made of the component of following parts by weight：
5~6 parts of aliphatic amine polyoxyethylene ether, 6~8 parts of calcium mahogany sulfonate, 5~6 parts of METHYLPYRROLIDONE, sorb
6~7 parts of alcohol acid anhydride fatty acid ester, 3~4 parts of defoamer, 17~19 parts of deionized water.
It is further preferred that it is made of the component of following parts by weight：
6 parts of aliphatic amine polyoxyethylene ether, 7 parts of calcium mahogany sulfonate, 5 parts of METHYLPYRROLIDONE, sorbitan fatty acid
6 parts of ester, 3 parts of defoamer, 18 parts of deionized water.
The sorbitan carboxylic esterses are any of span 20, sorbester p18, sorbester p38, sorbester p17, sorbester p37.
The defoamer is the mixture of polyoxyethylene polyoxy propyl alcohol amidogen ether and dimethyl silicone polymer, the mass ratio of the two
For 1：2~3.
Preferably, the two mass ratio is 1：2.
The preparation method of above-mentioned metallic article anti-rust cleaning agent, each component of formula ratio is weighed, 60 DEG C is heated to, persistently stirs
Mix, until mixing completely, produce.
The application method of the present invention：For general finding, the method that immersion can be used, pulled out after soaking several minutes, from
So dry, such as cleaned using ultrasonic wave, effect is more preferable；Large parts, the method that spray gun can be used to scrub are naturally dry
It is dry.
Beneficial effects of the present invention：
The metallic article anti-rust cleaning agent cleansing power of the present invention is strong, can ensure preferable antirust under high humidity conditions
Property, hot conditions do not interfere with corrosion resistance yet, also, the low defoaming of product foam is fast, are easy to high-pressure injection to clean, safe nothing
Evil, it is environmentally safe.The anti-rust cleaning agent antirust time length of the present invention, reaches more than 180 days.
Embodiment
With reference to specific embodiment, the present invention is described in further detail, but does not form to any of the present invention
Limitation.
With reference to embodiment, the present invention will be further elaborated, it should explanation, the description below merely to
The present invention is explained, its content is not defined.
Embodiment 1：
A kind of metallic article anti-rust cleaning agent of the present invention, is made of following components：
Aliphatic amine polyoxyethylene ether 5kg, calcium mahogany sulfonate 4kg, METHYLPYRROLIDONE 4kg, sorbitan fatty acid
Ester (span 20) 5kg, polyoxyethylene polyoxy propyl alcohol amidogen ether 1kg, dimethyl silicone polymer 2kg, deionized water 15kg.
Preparation method：The each component of formula ratio is weighed, is heated to 60 DEG C, lasting stirring, until mixing completely, is produced.
The performance of the metallic article anti-rust cleaning agent is as shown in table 1.
The embodiment 1 of table 1. prepares the performance parameter of metallic article anti-rust cleaning agent
Embodiment 2：
A kind of metallic article anti-rust cleaning agent of the present invention, is made of following components：
Aliphatic amine polyoxyethylene ether 7kg, calcium mahogany sulfonate 8kg, METHYLPYRROLIDONE 6kg, sorbitan fatty acid
Ester (sorbester p18) 7kg, polyoxyethylene polyoxy propyl alcohol amidogen ether 1kg, dimethyl silicone polymer 3kg, deionized water 20kg.
Preparation method：The each component of formula ratio is weighed, is heated to 60 DEG C, lasting stirring, until mixing completely, is produced.
The performance of the metallic article anti-rust cleaning agent is as shown in table 2.
The embodiment 2 of table 2. prepares the performance parameter of metallic article anti-rust cleaning agent
Embodiment 3：
A kind of metallic article anti-rust cleaning agent of the present invention, is made of following components：
Aliphatic amine polyoxyethylene ether 6kg, calcium mahogany sulfonate 6kg, METHYLPYRROLIDONE 5kg, sorbitan fatty acid
Ester (sorbester p38) 6kg, polyoxyethylene polyoxy propyl alcohol amidogen ether 1kg, dimethyl silicone polymer 2kg, deionized water 17kg.
Preparation method：The each component of formula ratio is weighed, is heated to 60 DEG C, lasting stirring, until mixing completely, is produced.
The performance of the metallic article anti-rust cleaning agent is as shown in table 3.
The embodiment 3 of table 3. prepares the performance parameter of metallic article anti-rust cleaning agent
Embodiment 4：
A kind of metallic article anti-rust cleaning agent of the present invention, is made of following components：
Aliphatic amine polyoxyethylene ether 6kg, calcium mahogany sulfonate 8kg, METHYLPYRROLIDONE 6kg, sorbitan fatty acid
Ester (sorbester p17) 7kg, polyoxyethylene polyoxy propyl alcohol amidogen ether 1kg, dimethyl silicone polymer 3kg, deionized water 19kg.
Preparation method：The each component of formula ratio is weighed, is heated to 60 DEG C, lasting stirring, until mixing completely, is produced.
The performance of the metallic article anti-rust cleaning agent is as shown in table 4.
The embodiment 4 of table 4. prepares the performance parameter of metallic article anti-rust cleaning agent
Embodiment 5：
A kind of metallic article anti-rust cleaning agent of the present invention, is made of following components：
Aliphatic amine polyoxyethylene ether 6kg, calcium mahogany sulfonate 7kg, METHYLPYRROLIDONE 5kg, sorbitan fatty acid
Ester (sorbester p37) 6kg, polyoxyethylene polyoxy propyl alcohol amidogen ether 1kg, dimethyl silicone polymer 2kg, deionized water 18kg.
Preparation method：The each component of formula ratio is weighed, is heated to 60 DEG C, lasting stirring, until mixing completely, is produced.
The performance of the metallic article anti-rust cleaning agent is as shown in table 5.
The embodiment 5 of table 5. prepares the performance parameter of metallic article anti-rust cleaning agent
From table 1~5 as can be seen that the metallic article anti-rust cleaning agent cleansing power of the present invention is strong, under high humidity conditions
Preferable rust-preventing characteristic can be ensured, hot conditions do not interfere with corrosion resistance yet, also, the low defoaming of product foam is fast, is easy to height
Jet cleaning is pressed, it is safe and harmless, it is environmentally safe.
4cm ﹡ 4cm 45 ﹟ steel discs are immersed respectively in the anti-rust cleaning agent of embodiment 1~5 10 seconds, taking-up hangs on room
It is interior, observation steel disc antirust time (occurring rusty stain on steel disc, be designated as end time), it the results are shown in Table 5.
The antirust time of the embodiment 1~5 of table 5.
| Sample | Antirust time (my god) |
| Embodiment 1 | 184 |
| Embodiment 2 | 183 |
| Embodiment 3 | 185 |
| Embodiment 4 | 184 |
| Embodiment 5 | 190 |
As can be seen from Table 5, anti-rust cleaning agent antirust time of the invention length, reaches more than 180 days.
Although the above-mentioned embodiment to the present invention is described, not to the limit of the scope of the present invention
System, on the basis of technical scheme, those skilled in the art need not pay creative work can make it is each
Kind modification is deformed still within protection scope of the present invention.
Claims (6)
1. a kind of metallic article anti-rust cleaning agent, it is characterised in that be made of the component of following parts by weight：Fatty amine polyoxy
5~7 parts of vinethene, 4~8 parts of calcium mahogany sulfonate, 4~6 parts of METHYLPYRROLIDONE, 5~7 parts of sorbitan carboxylic esterses,
3~4 parts of defoamer, 15~20 parts of deionized water.
2. a kind of metallic article anti-rust cleaning agent according to claim 1, it is characterised in that be by the group of following parts by weight
Made of point：5~6 parts of aliphatic amine polyoxyethylene ether, 6~8 parts of calcium mahogany sulfonate, 5~6 parts of METHYLPYRROLIDONE, sorb
6~7 parts of alcohol acid anhydride fatty acid ester, 3~4 parts of defoamer, 17~19 parts of deionized water.
3. a kind of metallic article anti-rust cleaning agent according to claim 1, it is characterised in that be by the group of following parts by weight
Made of point：6 parts of fat amine APEO, 7 parts of calcium mahogany sulfonate, 5 parts of METHYLPYRROLIDONE, sorbitan fatty acid
6 parts of ester, 3 parts of defoamer, 18 parts of deionized water.
4. according to a kind of metallic article anti-rust cleaning agent according to any one of claims 1 to 3, it is characterised in that the mountain
Pears alcohol acid anhydride fatty acid ester is any of span 20, sorbester p18, sorbester p38, sorbester p17, sorbester p37.
5. according to a kind of metallic article anti-rust cleaning agent according to any one of claims 1 to 3, it is characterised in that described to disappear
Infusion is the mixture of polyoxyethylene polyoxy propyl alcohol amidogen ether and dimethyl silicone polymer, and the mass ratio of the two is 1：2~3.
6. according to a kind of metallic article anti-rust cleaning agent according to any one of claims 1 to 3, it is characterised in that described to disappear
Infusion is the mixture of polyoxyethylene polyoxy propyl alcohol amidogen ether and dimethyl silicone polymer, and the two mass ratio is 1：2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510815710.4A CN105239084B (en) | 2015-11-20 | 2015-11-20 | A kind of metallic article anti-rust cleaning agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510815710.4A CN105239084B (en) | 2015-11-20 | 2015-11-20 | A kind of metallic article anti-rust cleaning agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105239084A CN105239084A (en) | 2016-01-13 |
| CN105239084B true CN105239084B (en) | 2017-12-19 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510815710.4A Expired - Fee Related CN105239084B (en) | 2015-11-20 | 2015-11-20 | A kind of metallic article anti-rust cleaning agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN105239084B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105780037A (en) * | 2016-04-07 | 2016-07-20 | 吴江市震宇缝制设备有限公司 | Cleaning agent for sewing machines |
| CN108677199A (en) * | 2018-04-10 | 2018-10-19 | 苏州捷德瑞精密机械有限公司 | Low bubble antibacterial metal cleaning agent of one kind and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5920754B2 (en) * | 1980-09-08 | 1984-05-15 | 日産自動車株式会社 | industrial metal cleaning agent |
| CN103540937B (en) * | 2013-10-21 | 2016-01-27 | 上海九盛实业有限公司 | A kind of solvent-borne type anti-rust cleaning agent for metallic element cleaning rust-proof |
| CN104073816A (en) * | 2014-06-26 | 2014-10-01 | 青岛启源振东电气有限公司 | Metal antirust detergent |
| CN104862713A (en) * | 2015-04-28 | 2015-08-26 | 安徽丹凤电子材料股份有限公司 | Metal surface eluant |
-
2015
- 2015-11-20 CN CN201510815710.4A patent/CN105239084B/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN105239084A (en) | 2016-01-13 |
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