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CN105220017A - A kind of nickel alloy wire and production method thereof - Google Patents

A kind of nickel alloy wire and production method thereof Download PDF

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Publication number
CN105220017A
CN105220017A CN201510781104.5A CN201510781104A CN105220017A CN 105220017 A CN105220017 A CN 105220017A CN 201510781104 A CN201510781104 A CN 201510781104A CN 105220017 A CN105220017 A CN 105220017A
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China
Prior art keywords
alloy wire
nickel alloy
cent
weight per
wire
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Pending
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CN201510781104.5A
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Chinese (zh)
Inventor
唐靖岚
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Wuxi Qingyang Machinery Manufacturing Co Ltd
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Wuxi Qingyang Machinery Manufacturing Co Ltd
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Priority to CN201510781104.5A priority Critical patent/CN105220017A/en
Publication of CN105220017A publication Critical patent/CN105220017A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of nickel alloy wire, does each constituent mass percentage composition of described alloy comprise: Si7-10%, Cu? 2-3%, Mg1-2%, Ag0.1-0.2%, Mo0.4-0.6%, Ti0.01-0.02%, La0.02-0.03%, Co0.01-0.03%, Mn, 0.01-0.02%, Sn0.03-0.04%, surplus is nickel and inevitable nonmetal inclusion.Provide corresponding preparation method, product belongs to the product innovation of novel uniqueness and scientific and reasonable formula simultaneously, not only has outstanding interior quality, also possesses excellent visual appearance simultaneously; Accomplish easy to operate, improve work efficiency, decreasing pollution, cost-saving.

Description

A kind of nickel alloy wire and production method thereof
Technical field
The present invention relates to a kind of nickel alloy wire, belong to nickel-base alloy and manufacture field.
Background technology
Ni-al alloyed wire not only increases thermal spraying material surface-treated state of the art, and its performance outclass galvanization coating, and effectively improves operating environment, and coating quality is more easily ensured, work efficiency improves greatly, and price more user accepts.Electric arc spraying ni-al alloyed wire expands the Application Areas of electric arc spraying, also play crucial effect in the surface coated treatment and decoration etc. such as its repair and intensify at the component easy to wear such as protection, axle class of anticorrosion and antirust, the big area component of high-class metal part, sintering metal and oxide ceramics, be widely used at numerous areas such as space flight, aviation, automobile, machinery, electric power, chemical industry, mine, geology, metallurgy.But along with metal spraying by electric arc Application Areas will expand gradually, improving constantly of technology, specification of quality, the internal performance of ni-al alloyed wire and visual appearance all await further raising.
Summary of the invention
The object of the invention is to, propose a kind of high-quality nickel alloy wire and production method thereof, according to described production method, can produce high tensile, high elongation rate, multi-field use, high-quality nickeline wire section product.
The invention provides a kind of nickel alloy wire for achieving the above object, each constituent mass percentage composition of described alloy comprises: Si7-10%, Cu2-3%, Mg1-2%, Ag0.1-0.2%, Mo0.4-0.6%, Ti0.01-0.02%, La0.02-0.03%, Co0.01-0.03%, Mn, 0.01-0.02%, Sn0.03-0.04%, and surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
The main performance index of nickel alloy wire finished product is as follows: tensile strength > 1400Mpa, elongation > 32%, voidage < 1.8%.
Described nickel alloy wire, chemical component weight per-cent is: Si8-9%.
Described nickel alloy wire, chemical component weight per-cent is: Si8.5%.
Described nickel alloy wire, chemical component weight per-cent is: Cu2.5%.
Described nickel alloy wire, chemical component weight per-cent is: Mg1.5%.
Described nickel alloy wire, chemical component weight per-cent is: Ag0.15%.
Described nickel alloy wire, chemical component weight per-cent is: Mo0.5%.
Described nickel alloy wire, chemical component weight per-cent is: Ti0.015%.
Described nickel alloy wire, chemical component weight per-cent is: La0.025%.
Described nickel alloy wire, chemical component weight per-cent is: Co0.02%.
Described nickel alloy wire, chemical component weight per-cent is: Mn0.015%.
Described nickel alloy wire, chemical component weight per-cent is: Sn0.035%.
Compared with prior art, the present invention has following beneficial effect:
Present invention process method, has fully taken into account the factor of each side, has both paid close attention to science, technical, and has also paid much attention to economy, practicality; Both extremely focus on the internal performance of product, be also particular about very much the visual appearance of product.By processing method of the present invention, the high-performance of metal thermal spraying ni-al alloyed wire solid silk section product high-quality is guaranteed, its feature is: product belongs to the product innovation of novel uniqueness and scientific and reasonable formula, not only has outstanding interior quality, also possesses excellent visual appearance simultaneously; Accomplish easy to operate, improve work efficiency, decreasing pollution, cost-saving.
Embodiment
Embodiment 1:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si7%, Cu2%, Mg1%, Ag0.1%, Mo0.4%, Ti0.01%, La0.02%, Co0.01%, Mn, 0.01%, Sn0.03%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
Embodiment 2:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si10%, Cu3%, Mg2%, Ag0.2%, Mo0.6%, Ti0.02%, La0.03%, Co0.03%, Mn, 0.02%, Sn0.04%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
Embodiment 3:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si9%, Cu3%, Mg2%, Ag0.2%, Mo0.6%, Ti0.02%, La0.03%, Co0.03%, Mn, 0.02%, Sn0.04%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
Embodiment 4:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si9%, Cu2.5%, Mg2%, Ag0.2%, Mo0.6%, Ti0.02%, La0.03%, Co0.03%, Mn, 0.02%, Sn0.04%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
Embodiment 5:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si9%, Cu3%, Mg1.5%, Ag0.2%, Mo0.6%, Ti0.02%, La0.03%, Co0.03%, Mn, 0.02%, Sn0.04%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
Embodiment 6:
Designed a kind of nickel alloy wire, each constituent mass percentage composition of described alloy comprises: Si9%, Cu3%, Mg1.5%, Ag0.15%, Mo0.6%, Ti0.02%, La0.03%, Co0.03%, Mn, 0.02%, Sn0.04%, surplus is nickel and inevitable nonmetal inclusion.
The production method of the above-mentioned nickel alloy wire of the present invention, its production technique comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.

Claims (8)

1. a nickel alloy wire, it is characterized in that: each constituent mass percentage composition of described alloy comprises: Si7-10%, Cu2-3%, Mg1-2%, Ag0.1-0.2%, Mo0.4-0.6%, Ti0.01-0.02%, La0.02-0.03%, Co0.01-0.03%, Mn, 0.01-0.02%, Sn0.03-0.04%, surplus is nickel and inevitable nonmetal inclusion.
2. nickel alloy wire as claimed in claim 1, chemical component weight per-cent is: Si8-9%.。
3. nickel alloy wire as claimed in claim 2, chemical component weight per-cent is: Si8.5%.
4. nickel alloy wire as claimed in claim 1, chemical component weight per-cent is: Cu2.5%.
5. nickel alloy wire as claimed in claim 1, chemical component weight per-cent is: Mg1.5%.
6. nickel alloy wire as claimed in claim 1, chemical component weight per-cent is: Ag0.15%.
7. nickel alloy wire as claimed in claim 1, chemical component weight per-cent is: Mo0.5%.
8. produce a method for nickel alloy wire as described in claim 1-7, it is characterized in that:
Described production method comprises following operation:
(1) by each component concentration batching of nickel alloy wire; (2) raw material is placed in feeder melting, adopts at high-frequency vacuum induction furnace, vacuumize, in stove, vacuum tightness will reach 3.34 × 10 -2kPa; Melt temperature 1680 DEG C, 2 hours; Stir aluminium alloy, be incubated to pouring temperature 1470 DEG C, casting nickelalloy billet; (3) by nickelalloy billet air forging press forging sub-one-tenth square billet; (4) with hot rolls, square billet is rolled into the rod of diameter 10mm; (5) with drawing wire machine, rod is first drawn into the B alloy wire of φ 3.0mm, (6) adopt annealing furnace electric furnace to anneal, and annealing temperature is 1000 DEG C, soaking time 5 hours; (7) finish draw: finish draw is shaping on drawing wire machine.
CN201510781104.5A 2015-11-13 2015-11-13 A kind of nickel alloy wire and production method thereof Pending CN105220017A (en)

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Application Number Priority Date Filing Date Title
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CN105220017A true CN105220017A (en) 2016-01-06

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486418A (en) * 2018-04-25 2018-09-04 常州市潞城慧热电子厂 A kind of B alloy wire and its preparation process for thermoelectric generator

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2051622A (en) * 1979-05-25 1981-01-21 Nippon Musical Instruments Mfg Method for manufacturing components for magnetic heads
US4668310A (en) * 1979-09-21 1987-05-26 Hitachi Metals, Ltd. Amorphous alloys
CN1804080A (en) * 2006-01-08 2006-07-19 丹阳市高频焊管厂 Nickel aluminium alloy and preparation method thereof
CN1849403A (en) * 2003-09-10 2006-10-18 德累斯顿协会莱布尼茨固体材料研究所 Nickel-based semi-finished product with recrystallized three-dimensional texture structure and its manufacturing method and application
CN101629255A (en) * 2009-07-22 2010-01-20 厦门钨业股份有限公司 Low-cost high-performance rare-earth-based AB5-type hydrogen storage alloy and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2051622A (en) * 1979-05-25 1981-01-21 Nippon Musical Instruments Mfg Method for manufacturing components for magnetic heads
US4668310A (en) * 1979-09-21 1987-05-26 Hitachi Metals, Ltd. Amorphous alloys
CN1849403A (en) * 2003-09-10 2006-10-18 德累斯顿协会莱布尼茨固体材料研究所 Nickel-based semi-finished product with recrystallized three-dimensional texture structure and its manufacturing method and application
CN1804080A (en) * 2006-01-08 2006-07-19 丹阳市高频焊管厂 Nickel aluminium alloy and preparation method thereof
CN101629255A (en) * 2009-07-22 2010-01-20 厦门钨业股份有限公司 Low-cost high-performance rare-earth-based AB5-type hydrogen storage alloy and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108486418A (en) * 2018-04-25 2018-09-04 常州市潞城慧热电子厂 A kind of B alloy wire and its preparation process for thermoelectric generator

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