CN105213237A - A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof - Google Patents
A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof Download PDFInfo
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- CN105213237A CN105213237A CN201410237423.5A CN201410237423A CN105213237A CN 105213237 A CN105213237 A CN 105213237A CN 201410237423 A CN201410237423 A CN 201410237423A CN 105213237 A CN105213237 A CN 105213237A
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- cucumber
- beauty
- cucumidis sativi
- skin protection
- fructus cucumidis
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- 235000010799 Cucumis sativus var sativus Nutrition 0.000 title claims abstract description 26
- 238000000605 extraction Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 244000299906 Cucumis sativus var. sativus Species 0.000 title 1
- 240000008067 Cucumis sativus Species 0.000 claims abstract description 25
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims description 9
- 229920000858 Cyclodextrin Polymers 0.000 claims description 8
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 claims description 6
- 239000003205 fragrance Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 229930003231 vitamin Natural products 0.000 claims description 5
- 239000011782 vitamin Substances 0.000 claims description 5
- 229940088594 vitamin Drugs 0.000 claims description 5
- 235000013343 vitamin Nutrition 0.000 claims description 5
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 claims description 3
- 241000579895 Chlorostilbon Species 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 229930002875 chlorophyll Natural products 0.000 claims description 3
- 235000019804 chlorophyll Nutrition 0.000 claims description 3
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims description 3
- 229910052876 emerald Inorganic materials 0.000 claims description 3
- 239000010976 emerald Substances 0.000 claims description 3
- 229960003471 retinol Drugs 0.000 claims description 3
- 235000020944 retinol Nutrition 0.000 claims description 3
- 239000011607 retinol Substances 0.000 claims description 3
- 229930091371 Fructose Natural products 0.000 claims description 2
- 239000005715 Fructose Substances 0.000 claims description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- UPYKUZBSLRQECL-UKMVMLAPSA-N Lycopene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1C(=C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=C)CCCC2(C)C UPYKUZBSLRQECL-UKMVMLAPSA-N 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 229930006000 Sucrose Natural products 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 150000001746 carotenes Chemical class 0.000 claims description 2
- 235000005473 carotenes Nutrition 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 150000002972 pentoses Chemical class 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- NCYCYZXNIZJOKI-UHFFFAOYSA-N vitamin A aldehyde Natural products O=CC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C NCYCYZXNIZJOKI-UHFFFAOYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 229940088710 antibiotic agent Drugs 0.000 description 3
- 239000004599 antimicrobial Substances 0.000 description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 229930014626 natural product Natural products 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000007850 degeneration Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- MBDOYVRWFFCFHM-SNAWJCMRSA-N (2E)-hexenal Chemical compound CCC\C=C\C=O MBDOYVRWFFCFHM-SNAWJCMRSA-N 0.000 description 1
- ZHHYXNZJDGDGPJ-BSWSSELBSA-N (2e,4e)-nona-2,4-dienal Chemical compound CCCC\C=C\C=C\C=O ZHHYXNZJDGDGPJ-BSWSSELBSA-N 0.000 description 1
- BSAIUMLZVGUGKX-BQYQJAHWSA-N (E)-non-2-enal Chemical compound CCCCCC\C=C\C=O BSAIUMLZVGUGKX-BQYQJAHWSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 241001515806 Stictis Species 0.000 description 1
- JZRWCGZRTZMZEH-UHFFFAOYSA-N Thiamine Natural products CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N JZRWCGZRTZMZEH-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- KYMBYSLLVAOCFI-UHFFFAOYSA-N thiamine Chemical compound CC1=C(CCO)SCN1CC1=CN=C(C)N=C1N KYMBYSLLVAOCFI-UHFFFAOYSA-N 0.000 description 1
- 229960003495 thiamine Drugs 0.000 description 1
- 235000019157 thiamine Nutrition 0.000 description 1
- 239000011721 thiamine Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof, (1) clean fresh cucumber is blended, squeeze the juice and filter, obtained Fructus Cucumidis sativi natural juice, then (2) add beta-schardinger dextrin-(β-CD) or derivatives thereof list 2-HP-β-CD in obtained Fructus Cucumidis sativi natural juice, make compound Sucus Cucumidis sativi, then (3) compound Sucus Cucumidis sativi is dewatered under vacuum, dry obtained solid skin protection and beauty-care extraction from cucumber.
Description
Technical field
The invention belongs to daily-use chemical industry technical field.
Background technology
Green cucumber product on domestic and international Cosmetic Market is still confined to the liquid forms such as " milk ", " dew " of water quality.This based article is large except volume, and exist during use outside the many inconvenience of storage and limitation, all containing certain antiseptic and antibiotic agent, and the existence of antiseptic and antibiotic agent more or less always has certain ill effect.Delicate fragrance element (2 is anti-, and 6 is a suitable) nonadienal in addition in fresh cucumber, the material such as α-nonenyl aldehyde and hexenal is very unstable in water quality is dissolved, and very easily by the dioxygen oxidation in air, this is also the main cause that broken Fructus Cucumidis sativi is easily turned sour.For the Fructus Cucumidis sativi matter cosmetics preventing above-mentioned change from causing are spoiled, they all need to allocate one or more fragrant elements into.Obviously, existing Fructus Cucumidis sativi matter cosmetics stricti jurise is said can't can be regarded as natural product.In order to develop the skin-protecting face nursing performance of Fructus Cucumidis sativi better, needing preparation a kind ofly to have Fructus Cucumidis sativi pure natural composition and proportioning, not containing various anti-rotten antibacterial and the natural product of stable performance.
Summary of the invention
Object of the present invention is exactly the shortcoming of unstable properties existed to solve existing Fructus Cucumidis sativi matter cosmetics, utilizes supermolecular theory, makes a kind of stable performance, possesses the natural product of Fructus Cucumidis sativi pure natural composition and proportioning.
Of the present invention to the effect that by means of supermolecular theory, using beta-schardinger dextrin-(β-CD) and derivant list 2-HP-β-CD thereof as function body, obtained possess Fructus Cucumidis sativi pure natural composition and proportioning, not containing various antiseptic and antibiotic agent and stable performance, in emerald pulverulent solids skin protection and beauty-care extraction from cucumber, it is soluble in water, and its Main Components is:
Cyclodextrin 40% ~ 60%
Fructus Cucumidis sativi protein 5% ~ 8%
Fructus Cucumidis sativi fat 0.8% ~ 1.2%
Fructus Cucumidis sativi delicate fragrance element 0.8% ~ 1.5%
Vitamin 0.1% ~ 0.2%
(wherein, retinol 0.05% ~ 0.1%, sulfur peace element 0.02% ~ 0.08%, Buddhist nun's gram element 0.02% ~ 0.08%)
Sugar 10% ~ 14%
Cellulose 2% ~ 4%
Chlorophyll 6% ~ 8%
Metallic element 0.4% ~ 0.8%
Vitamin contained in skin protection and beauty-care extraction from cucumber is mainly Vc, carotene etc.
Sugar in skin protection and beauty-care extraction from cucumber is glucose, sucrose, pentose, fructose, pectin etc. mainly.
Metallic element K, Ca, Na, Mg, Fe, Mn, Zn, Cu etc. are main metal element contained in skin protection and beauty-care extraction from cucumber.
By means of supermolecular theory, we know that cyclodextrin molecular has " amphiphilic " performance hydrophilic outside intracavity oleophylic, chamber.When cyclodextrin molecular is with when comprising each organic molecular species of Fructus Cucumidis sativi protein or have the inorganic molecule of certain hydrophobic performance to interact, both can form master---the guest complexes of enclose type in the multiple supermolecular mechanism power of release etc. of the forming process cyclodextrin ring skeleton tension force energy of clathrate by the hydrogen bond action (3) between the hydroxyl of VanderWaals effect (2) cyclodextrin at the hydrophobic position of (1) cyclodextrin cavity and guest molecule and the polarity gene of guest molecule.The formation of this clathrate produces except certain water soluble characteristic except making hydrophobic guest molecule, oxidizable guest molecule also can be made to produce certain antioxygenic property, the guest molecule of easy moldy metamorphism is made to produce certain anti-mildew degeneration energy, the guest molecule of easy light modification is produced and certain anti-lightly causes degeneration energy, make volatile guest molecule produce certain anti-volatile performance etc.The formation of this complex can not affect the metabolism performance of guest molecule in human body and physiological action, this just cyclodextrin be widely used in the reason of daily chemical industry.
The preparation technology of skin protection and beauty-care extraction from cucumber, concrete steps are as follows:
(1) clean fresh cucumber is blended, squeezes the juice, adopt P100 type glass filtration instrument to filter at reduced pressure conditions, obtained Fructus Cucumidis sativi natural juice,
(2) in obtained Fructus Cucumidis sativi natural juice, β-CD is added or single 2-HP-β-CD makes compound Sucus Cucumidis sativi, this step at normal temperatures and pressures, carry out in magnetic stirring apparatus, the object adding β-CD or single 2-HP-β-CD is the oxidation, volatilization etc. that fully control the organic substances such as Fructus Cucumidis sativi delicate fragrance element, Vc, also effectively can increase the stability of Fructus Cucumidis sativi organic substance
(3) compound Sucus Cucumidis sativi is dewatered under vacuum, dry final obtained in emerald skin protection and beauty-care extraction from cucumber pressed powder.This step completes in vacuum distillation apparatus, and distillation, baking temperature should control at 40 DEG C/below 5mmHg.
Embodiment:
200g is cleaned the fresh cucumber after airing to blend, squeeze the juice and filter obtained Fructus Cucumidis sativi natural juice, in obtained Fructus Cucumidis sativi natural juice, add 2.5g β-CD to match obtained compound Sucus Cucumidis sativi, compound Sucus Cucumidis sativi is placed in vacuum distillation apparatus, dehydration, drying, distillation, baking temperature should control at 40 DEG C/below 5mmHg, and finally obtained 4.0g is emerald green skin protection and beauty-care extraction from cucumber pressed powder.Main Components is: cyclodextrin 2.45g, Fructus Cucumidis sativi protein 0.25g, Fructus Cucumidis sativi fat 0.05g, Fructus Cucumidis sativi delicate fragrance element 0.05g, sugar 0.45g, cellulose 0.15g, chlorophyll 0.30g, vitamin retinol, thiamine, Buddhist nun gram plain 0.05g, ash, moisture etc. are about 0.25g.Use adjustable 1 ~ 2 liter of Fructus Cucumidis sativi facial cleanser of 1g skin protection and beauty-care extraction from cucumber in use, 5 ~ 10 liters of Fructus Cucumidis sativi bath lotion.
Claims (4)
1. a skin protection and beauty-care extraction from cucumber, it is characterized in that this skin protection and beauty-care extraction from cucumber is a kind of in emerald powdery solid, its main composition part is: cyclodextrin 40% ~ 60% Fructus Cucumidis sativi protein 5% ~ 8% Fructus Cucumidis sativi fat 0.8% ~ 1.2% Fructus Cucumidis sativi delicate fragrance element 0.8% ~ 1.5% vitamin 0.1% ~ 0.2% wherein, retinol 0.05% ~ 0.1%, sulfur peace element 0.02% ~ 0.08%, Buddhist nun's gram element 0.02% ~ 0.08% sugar 10% ~ 14% cellulose 2% ~ 4% chlorophyll 6% ~ 8% metallic element 0.4% ~ 0.8%.
2. the preparation technology of a skin protection and beauty-care extraction from cucumber, it is characterized in that the step of this technique is divided into: clean fresh cucumber blends by (1), squeeze the juice and filter, obtained Fructus Cucumidis sativi natural juice, then (2) add beta-schardinger dextrin-(β-CD) or derivatives thereof list 2-HP-β-CD in obtained Fructus Cucumidis sativi natural juice, make compound Sucus Cucumidis sativi, then (3) compound Sucus Cucumidis sativi is dewatered under vacuum, dry obtained solid skin protection and beauty-care extraction from cucumber.
3. skin protection and beauty-care extraction from cucumber according to claim 1, is characterized in that vitamin contained in skin protection and beauty-care extraction from cucumber is mainly Vc, carotene.
4. skin protection and beauty-care extraction from cucumber according to claim 1, is characterized in that sugar mainly glucose, sucrose, pentose, fructose, the pectin contained by skin protection and beauty-care extraction from cucumber.
Priority Applications (1)
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CN201410237423.5A CN105213237A (en) | 2014-05-31 | 2014-05-31 | A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof |
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CN201410237423.5A CN105213237A (en) | 2014-05-31 | 2014-05-31 | A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof |
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CN201410237423.5A Pending CN105213237A (en) | 2014-05-31 | 2014-05-31 | A kind of skin protection and beauty-care extraction from cucumber and preparation technology thereof |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1154238A (en) * | 1996-09-02 | 1997-07-16 | 山东大学 | Skin protection and beauty-care extraction from cucumber and method for preparing same |
WO2009085472A1 (en) * | 2007-12-19 | 2009-07-09 | Elc Management Llc | Compositions and methods for treating skin with extract from trametes |
-
2014
- 2014-05-31 CN CN201410237423.5A patent/CN105213237A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1154238A (en) * | 1996-09-02 | 1997-07-16 | 山东大学 | Skin protection and beauty-care extraction from cucumber and method for preparing same |
WO2009085472A1 (en) * | 2007-12-19 | 2009-07-09 | Elc Management Llc | Compositions and methods for treating skin with extract from trametes |
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