CN105199828B - A kind of environment-friendly water-soluble machining of metals liquid - Google Patents
A kind of environment-friendly water-soluble machining of metals liquid Download PDFInfo
- Publication number
- CN105199828B CN105199828B CN201510618269.0A CN201510618269A CN105199828B CN 105199828 B CN105199828 B CN 105199828B CN 201510618269 A CN201510618269 A CN 201510618269A CN 105199828 B CN105199828 B CN 105199828B
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- Prior art keywords
- water
- environment
- machining
- metals
- monoethanolamine
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- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 15
- 239000002184 metal Substances 0.000 title claims abstract description 15
- 238000003754 machining Methods 0.000 title claims abstract description 13
- 150000002739 metals Chemical class 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 7
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012964 benzotriazole Substances 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 7
- 235000019441 ethanol Nutrition 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 5
- 239000008158 vegetable oil Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000005555 metalworking Methods 0.000 abstract description 4
- 241001074085 Scophthalmus aquosus Species 0.000 abstract description 2
- 230000002421 anti-septic effect Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract description 2
- 238000003801 milling Methods 0.000 abstract description 2
- 239000003973 paint Substances 0.000 abstract description 2
- 239000008399 tap water Substances 0.000 abstract description 2
- 235000020679 tap water Nutrition 0.000 abstract description 2
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 239000002173 cutting fluid Substances 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000010808 liquid waste Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000012224 working solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- -1 use scope is wide Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention discloses a kind of environment-friendly water-soluble machining of metals liquid, component by weight percentage is：Triethanolamine 12 15%, vegetable oil acid 20 30%, 6 10%, 11 carbon diacid 4 6% of sodium sulfonate, monoethanolamine 2 3%, glycerine 10 15%, benzotriazole 2 3%, ethyl alcohol 6 10%, water surplus.Use of the invention has extremely strong antiseptic and rustproof property, preferable compatibilization, lubricity, cleaning, cooling performance in machining of metals process.Free from extraneous odour, it is non-stimulated to personal skin, machinery paint is adapted to, to dilution water without particular/special requirement, general underground water, tap water, hot water, cold water, use scope is wide, the manufacturing procedures such as vehicle, milling, plane, brill, mill adapt to, and are multifunctional environment protection metal working fluids.
Description
Technical field
The present invention is to be related to a kind of environment-friendly water-soluble machining of metals liquid.
Background technology
Current market sales of emulsion cutting fluid product is mostly that mineral oil produces, and a other product contains nitrous
Sour sodium, the waste liquid after the work of oil base emulsion cutting fluid is difficult, and not environmentally, waste liquid is scattered damage to the environment, and sodium nitrite is toxic, with
Personal skin contact damage health, with the raising that Environmental is protected, increasingly proposes the requirements such as health of human body, safety in production
It is high.Using rear liquid waste processing difficulty, and there is environmentally friendly hidden danger.
Invention content
It is difficult using rear liquid waste processing to solve emulsion cutting fluid, and there is environmental protection, the present invention carries
A kind of environment-friendly water-soluble machining of metals liquid has been supplied, on the basis of environment protection metal processing cutting fluid production technology is completed,
It is formed using environment-friendly type raw material, it is harmless in the person, with water-soluble metal processing cutting fluid that is environmental-friendly, increasing economic efficiency.
To achieve these goals, the present invention adopts the following technical scheme that.
A kind of environment-friendly water-soluble machining of metals liquid, component by weight percentage are：Triethanolamine 12-
15%, vegetable oil acid 20-30%, sodium sulfonate 6-10%, 11 carbon diacid 4-6%, monoethanolamine 2-3%, glycerine 10-
15%, benzotriazole 2-3%, ethyl alcohol 6-10%, water surplus.
Triethanolamine, vegetable oil acid, sodium sulfonate, 11 carbon diacid and water are added in reaction kettle in order, heated up 90 degree
Stirring adds in monoethanolamine in kettle, and stirring neutralizes, and glycerine, benzotriazole and ethyl alcohol are added in, stirs evenly, filter,
Up to product.
The beneficial effects of the invention are as follows：Using in machining of metals process, there is extremely strong antiseptic and rustproof property, preferably
Compatibilization, lubricity, cleaning, cooling performance.Free from extraneous odour, it is non-stimulated to personal skin, machinery paint is adapted to, to dilute
Water is released without particular/special requirement, general underground water, tap water, hot water, cold water, use scope is wide, and vehicle, milling, plane, brill, mill etc. add
Work process adapts to, and is multifunctional environment protection metal working fluid.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1：The environment-friendly water-soluble machining of metals liquid of the present embodiment, component include：Triethanolamine 12% is planted
Object oleic acid 30%, sodium sulfonate 6%, 11 carbon diacid 6%, monoethanolamine 2%, glycerine 15%, benzotriazole 2%, ethyl alcohol
10%, water 17%.
Any of the above raw material passes through technological requirement, is combined with each other and is reacted by heating, produces water-soluble metalworking liquid production
Product, with this product weight ratio 1:20 are watered, and convert into emulsifying working solution, using in machining of metals process.
The product quality of the present embodiment such as following table.
| Project | Experimental result | Experimental method |
| Appearance | Brownish red transparent oily liquid | Range estimation |
| PH value (5% concentration) | 7-9 | Extensive pH value test paper |
| Stability (- 5 DEG C) | Resilient | Frozen process experiment |
| Rust-preventing characteristic (summer/cast iron) | 30 days or more | Practical application |
| Anti-corrosive properties | 6 months or more | Practical application |
Embodiment 2：The environment-friendly water-soluble machining of metals liquid of the present embodiment, component include：Triethanolamine 15% is planted
Object oleic acid 20%, sodium sulfonate 10%, 11 carbon diacid 4%, monoethanolamine 3%, glycerine 10%, benzotriazole 3%, ethyl alcohol
6%, water 29%.
Any of the above raw material passes through technological requirement, is combined with each other and is reacted by heating, produces water-soluble metalworking liquid production
Product, with this product weight ratio 1:20 are watered, and convert into emulsifying working solution, using in machining of metals process.
The product quality of the present embodiment such as following table.
| Project | Experimental result | Experimental method |
| Appearance | Brownish red transparent oily liquid | Range estimation |
| PH value (5% concentration) | 7-9 | Extensive pH value test paper |
| Stability (- 5 DEG C) | Resilient | Frozen process experiment |
| Rust-preventing characteristic (summer/cast iron) | 20 days or more | Practical application |
| Anti-corrosive properties | 5 months or more | Practical application |
Although the above-mentioned specific embodiment to the present invention is described, not to the limit of the scope of the present invention
System, those skilled in the art should understand that, based on the technical solutions of the present invention, those skilled in the art do not need to pay
Go out various modifications or changes that creative work can be made still within protection scope of the present invention.
Claims (1)
1. a kind of environment-friendly water-soluble machining of metals liquid, it is characterized in that, component by weight percentage is：Triethanolamine
12-15%, vegetable oil acid 20-30%, sodium sulfonate 6-10%, 11 carbon diacid 4-6%, monoethanolamine 2-3%, glycerine 10-
15%, benzotriazole 2-3%, ethyl alcohol 6-10%, water surplus；
And in order add in triethanolamine, vegetable oil acid, sodium sulfonate, 11 carbon diacid and water in reaction kettle, 90 degree of heating is stirred
It mixes, monoethanolamine is added in kettle, stirring neutralizes, and glycerine, benzotriazole and ethyl alcohol are added in, stirs evenly, filter, i.e.,
Obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510618269.0A CN105199828B (en) | 2015-09-25 | 2015-09-25 | A kind of environment-friendly water-soluble machining of metals liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510618269.0A CN105199828B (en) | 2015-09-25 | 2015-09-25 | A kind of environment-friendly water-soluble machining of metals liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105199828A CN105199828A (en) | 2015-12-30 |
| CN105199828B true CN105199828B (en) | 2018-07-03 |
Family
ID=54947791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510618269.0A Active CN105199828B (en) | 2015-09-25 | 2015-09-25 | A kind of environment-friendly water-soluble machining of metals liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105199828B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107090344A (en) * | 2017-03-30 | 2017-08-25 | 上海希勒化学有限公司 | A kind of water-soluble metal lubricant |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013087896A1 (en) * | 2011-12-16 | 2013-06-20 | Total Raffinage Marketing | Grease composition |
| CN104450105A (en) * | 2014-12-29 | 2015-03-25 | 长沙艾森设备维护技术有限公司 | Low-odor and low-toxicity glass cutting fluid |
-
2015
- 2015-09-25 CN CN201510618269.0A patent/CN105199828B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013087896A1 (en) * | 2011-12-16 | 2013-06-20 | Total Raffinage Marketing | Grease composition |
| CN104450105A (en) * | 2014-12-29 | 2015-03-25 | 长沙艾森设备维护技术有限公司 | Low-odor and low-toxicity glass cutting fluid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105199828A (en) | 2015-12-30 |
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| CB02 | Change of applicant information |
Address after: 262500 Qingzhou North Road, Weifang, Shandong (North 309 National Road, 393K) Applicant after: Shandong Hao Mark oil Polytron Technologies Inc Address before: 262500 Qingzhou North Road, Weifang, Shandong (North 309 National Road, 393K) Applicant before: SHANDONG HIMARK PETROLEUM TECHNOLOGY CO., LTD. |
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