CN105177788B - A kind of terylene tyre cord, its preparation method and its application in cross-ply - Google Patents
A kind of terylene tyre cord, its preparation method and its application in cross-ply Download PDFInfo
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- CN105177788B CN105177788B CN201510683244.9A CN201510683244A CN105177788B CN 105177788 B CN105177788 B CN 105177788B CN 201510683244 A CN201510683244 A CN 201510683244A CN 105177788 B CN105177788 B CN 105177788B
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- 229920004933 Terylene® Polymers 0.000 title claims abstract description 99
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 99
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000004744 fabric Substances 0.000 claims abstract description 82
- 238000009987 spinning Methods 0.000 claims abstract description 49
- 238000000034 method Methods 0.000 claims abstract description 41
- 238000007598 dipping method Methods 0.000 claims abstract description 27
- 239000002243 precursor Substances 0.000 claims description 45
- 238000001035 drying Methods 0.000 claims description 24
- 238000009826 distribution Methods 0.000 claims description 12
- 238000005470 impregnation Methods 0.000 claims description 12
- 238000004513 sizing Methods 0.000 claims description 12
- 238000003860 storage Methods 0.000 claims description 12
- 238000004804 winding Methods 0.000 claims description 12
- 229920002994 synthetic fiber Polymers 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 abstract description 20
- 239000004677 Nylon Substances 0.000 abstract description 18
- 229920001778 nylon Polymers 0.000 abstract description 18
- 238000012360 testing method Methods 0.000 description 18
- 239000000835 fiber Substances 0.000 description 17
- 229920002292 Nylon 6 Polymers 0.000 description 14
- 230000006835 compression Effects 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- 241000168096 Glareolidae Species 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Tires In General (AREA)
Abstract
The invention provides a kind of preparation method of terylene tyre cord, it is characterised in that：Comprise the following steps：(1) spinning technique flow；(2) gum dipping process flow.Preparation method of the present invention can effectively improve the ultimate strength and extension at break of conventional polyester cord fabric thread, so as to improve the impact resistance of terylene tyre cord.Present invention also offers terylene tyre cord made from a kind of preparation method using terylene tyre cord of the present invention, fracture strength >=6.5cN/dtex of the terylene tyre cord, elongation at break is up to 19~25%, its work to break is far above the work to break of conventional polyester cord fabric thread, its dimensional stability (DSI) is compared with the dimensional stability (DSI) of nylon curtain line, and tool improves a lot.The present invention still further provides application of the obtained terylene tyre cord in cross-ply.
Description
Technical field
The invention belongs to tire manufacturing techniques field, more particularly, to a kind of terylene tyre cord, its preparation method and its
Application in cross-ply.
Background technology
At present, it is in tire to use synthetic fibers as carcass reinforcing material more, wherein with terylene, nylon, artificial silk and
Aramid fiber is most widely used；And in the cross-plies such as motorcycle, bicycle, all-terrain vehicle and agricultural vehicle, carcass enhancing
Material is basic based on nylon curtain line, and the using area that its reason is mainly motorcycle, bicycle and agricultural vehicle etc. is mostly
Road conditions are poor, more based on country road, hill path etc., it is desirable to which tire has good shock resistance.But nylon curtain line
The shortcomings of there is high hygroscopic, pre- shrinkage factor, poor dimensional stability, and easily there is the defect of flat spot in nylon enhancing tire.Wash
The features such as synthetic fibre cord fabric thread has low water absorption rate, good stability of the dimension, therefore it is used for the carcass material of meridian tyres for passenger cars.
Effect --- anti-impact of the nylon curtain line in the oblique wheel tire such as motorcycle, bicycle, all-terrain vehicle and agricultural vehicle
Hitting property is good, and impact resistance can be weighed with the energy of rupture of tire, be found by research, the work to break and tire of the cord fabric thread of nylon 6
Energy of rupture between there is linear approximate relationship, as shown in Figure 1.The work to break computational methods of cord fabric thread, as shown in Figure 2.Work as curtain
During the work to break increase of sub-line, the energy of rupture that tire is made of the cord fabric thread also increases, the impact resistance enhancing of tire, therefore can
Tire impact resistance is improved by improving the work to break of cord fabric thread.The work to break of cord fabric thread can be calculated by formula (1)：
W=∫ F*dL ... ... ... ... ... ... ... ... ... ... ... (1)
W-work to break, J；
F-ultimate strength, N；
Elongation under L-ultimate strength effect, m.
As can be seen here, the elongation under the higher effect with ultimate strength of the ultimate strength of cord fabric thread is longer, the fracture of cord fabric thread
Work(is bigger.
The intensity of cord fabric thread be cord fabric thread ultimate strength divided by cord fabric thread nominal fiber number business, formula (2) can be passed through
Calculate：
UTS=BS/LD ... ... ... ... ... ... ... ... ... ... ... ... (2)
The intensity of UTS-cord fabric thread, cN/dtex；
The ultimate strength of BS-cord fabric thread, N；
The nominal fiber number of LD-cord fabric thread, dtex.
The content of the invention
It is an object of the invention to provide a kind of preparation method of terylene tyre cord, the preparation method can effectively improve
The ultimate strength and elongation at break of conventional polyester cord fabric thread, so as to improve the impact resistance of terylene tyre cord；The present invention is also carried
Supply using terylene tyre cord made from the preparation method, the terylene tyre cord not only remains the excellent of conventional polyester cord fabric thread
Point, its work to break and fatigue performance, which also have, to improve a lot；The present invention still further provides the terylene tyre cord in oblique
Application in tire, has given full play to the advantage of terylene tyre cord, and combines the advantage of the good impact resistance of nylon curtain line, keeps away
Its shortcoming.
The technical solution adopted by the present invention is：
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor；
Its technological parameter is：Spinning speed：4800-5200mpm；Annealer temperature：230-365℃；Draw ratio：1.95-
2.23 and inherent viscosity：0.98-1.06g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Obtain terylene tyre cord.
The preparation method of terylene tyre cord of the present invention, wherein, the gum dipping process flow described in step (2), its work
Skill parameter is：First 160 DEG C of area's drying temperature and dry tension force 520-700g；230 DEG C of draft temperature and tensile stress 1150-
1300g, second 160 DEG C of area's drying temperature and dry tension force 520-700g, 110~250g of 230 DEG C of setting temperature and sizing tension force.
Present invention also offers one kind using terylene tyre cord made from above-mentioned preparation method.
Fracture strength >=6.5cN/dtex of the terylene tyre cord produced by the present invention, elongation at break up to 19~
25%.
The present invention still further provides application of the obtained terylene tyre cord in cross-ply.
Beneficial effect of the present invention：
The preparation method of terylene tyre cord of the present invention, can effectively improve the ultimate strength of conventional polyester cord fabric thread
And extension at break, so as to improve the impact resistance of terylene tyre cord.
The terylene tyre cord produced by the present invention, the advantage except remaining conventional polyester cord fabric thread, such as dimensionally stable
Property good, water absorption rate is low and price is low outer, its work to break and fatigue performance tool improve a lot, the terylene tyre cord it is disconnected
Resistance to spalling >=6.5cN/dtex, elongation at break uses precursor fiber number for 1000 daniers and 1300 daniers up to 19~25%
Work to break difference >=the 3.5J (specification is 1000DX2) and >=4.7J (specification is 1300DX2) of obtained terylene tyre cord, it breaks
Work(is split respectively far above conventional polyester cord fabric thread 2.7J (specification is 1000DX2) and the 3.9J (rule used made from identical fiber number
Lattice are 1300DX2)；Its dimensional stability (DSI) is compared with the dimensional stability (DSI) of nylon curtain line, is carried with very big
Height, precursor fiber number is the dimensional stability (DSI) of the nylon curtain line of 1260 daniers and 840 daniers respectively up to 15% (rule
Lattice are 1260DX2) and 16.4% (specification is 840DX2), precursor fiber number is used made from 1000 daniers and 1300 daniers
The DSI of the terylene tyre cord of the present invention is then respectively smaller than 11% (specification is 1300DX2) and 9.5% (specification is 1000DX2), can
To be compared favourably with nylon curtain line.In addition, the terylene tyre cord produced by the present invention, it processes curing temperature can be original
More than 10 DEG C are improved on the curing temperature of the cord fabric thread of nylon 6, at least reduces by 25% cure time, and can be without rear inflator
Sequence realizes the dimensionally stable of tire；The flat spot defect of nylon curtain line tire is can greatly improve, while the rolling resistance of its tire
Power reduces 7% than nylon curtain line tire, and its tire is riding and handling test result is also superior to nylon curtain line tire；Energy
It is enough not increase the enhanced cross-ply apparatus for production line of existing nylon curtain line and do not doing the bar of big adjustment to production technology
Under part, industrialization production is realized.
Application of the terylene tyre cord produced by the present invention in cross-ply, in motorcycle, bicycle, all-terrain vehicle
In the cross-ply such as agricultural vehicle, the advantage of terylene tyre cord is given full play to, with reference to the good impact resistance of nylon curtain line
Advantage, keeps away its shortcoming.
Brief description of the drawings
Fig. 1 is the work to break of the cord fabric thread of nylon 6 in the prior art and the graph of a relation of tire energy of rupture；
Fig. 2 calculates schematic diagram for the work to break of cord fabric thread in the prior art；
In Fig. 31 be conventional polyester cord fabric thread (specification is 1000DX2) stress strain curve figure；2 be washing that embodiment 8 is obtained
The stress strain curve figure of synthetic fibre cord fabric thread (specification is 1000DX2)；3 be the stress strain curve of nylon66 fiber cord fabric thread (specification is 840DX2)
Figure；4 be the stress strain curve figure of the cord fabric thread of nylon 6 (specification is 840DX2)；
In Fig. 41 be conventional polyester cord fabric thread (specification is 1300DX2) stress strain curve figure；2 be the cord fabric thread (specification of nylon 6
For 1260DX2) stress strain curve figure；3 be the stress strain curve figure of nylon66 fiber cord fabric thread (specification is 1260DX2)；4 be embodiment 3
The stress strain curve figure of obtained terylene tyre cord (specification is 1300DX2)；
In Fig. 51 be the terylene tyre cord (specification is 1300DX2) that embodiment 3 is obtained compression endurance test result figure；
2 be the compression endurance test result figure of the cord fabric thread of nylon 6 (specification is 1260DX2)；3 be that (specification is conventional polyester cord fabric thread
Compression endurance test result figure 1300DX2)；
In Fig. 61 be conventional polyester cord fabric thread powder x-ray diffraction (XRD) figure；2 be the terylene curtain that embodiment 8 is obtained
Powder x-ray diffraction (XRD) figure of line；
Fig. 7 is that the terylene tyre cord that embodiment 8 is obtained and the cord fabric thread of nylon 6 (specification is 1260DX2) are oblique before and after the examination of road
Hand over tire performance comparison figure.
Below in conjunction with specific embodiments and the drawings, the invention will be further described.
Embodiment
Cord fabric thread in the terylene tyre cord according to made from embodiment 1-10 and comparative example 1-4 is measured by following method
Physical property：
1) according to standard ASTM-D885, draw speed：254mm/min, clamp distance：254mm；Drawn using universal material
Power machine Instron3367, fixture：The strength of 2714-006, measurement precursor and cord fabric thread, intensity, elongation at break and constant load
Elongation (EASL).
2) according to the method for testing of shrinkage factor in standard ASTM-D4974：177 DEG C, 2min, 0.05g/D；Test equipment is adopted
The shrinkage tester Mk6 produced with Testrite companies, measures the shrinkage factor of precursor and cord fabric thread.
3) X ' Pert PRO Multi-functional X ray diffractometers, 1/2 ° of divergent slit are used；Antiscatter slits 5mm；Easel mask
15mm；Receiver X ' Celerator；2 θ of scanning range=5-60 °；0.196603 °/Sec of sweep speed；Scanning step
0.0167113Sec；Specimen holder uses the specimen holder in patent ZL 201220475618.X, measures the XRD of cord fabric thread.
4) using conventional disk endurance (DISC) method of testing：Vulcanize 15 minutes in 11 tons of 168 DEG C of temperature and pressure
76mm (length) X12.7 (width) mmX11.2mm (height) rubber strip is made, the disc fatigue examination produced in B.F.Goodrich companies
Test machine to run 24 hours with 2500 revs/min, measure the conventional fatigue durability of cord fabric thread.
5) using disk endurance (DISC) method of testing of compression：Vulcanize 15 minutes in 11 tons of 168 DEG C of temperature and pressure
76mm (length) X12.7 (width) mmX11.2mm (height) rubber strip is made, the disc fatigue examination produced in B.F.Goodrich companies
Test machine to run more than 7 hours with 2000 revs/min, measure the compression fatigue durability of cord fabric thread.
6) dimensional stability (DSI) is the summation of continuous rating elongation rate (EASL) and the shrinkage factor measured by the above method.
Used raw material sources are as follows in the present embodiment 1-10 and comparative example 1-4：
Specification is respectively 840DX2 and 1260DX2 nylon66 fiber cord fabric thread, originates from China Shenma Group Co., Ltd；
Specification is respectively the 840DX2 and 1260DX2 cord fabric thread of nylon 6, originates from Jiangsu Co., Ltd of courser group；Specification is distinguished
It is our company's self-control for 1000DX2 and 1300DX2 conventional polyester cord fabric, using self-produced polyester industrial yarn (DSP) conduct
Synthesize the raw material of the present embodiment 1-10 terylene tyre cord.
Embodiment 1
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：4800mpm；Annealer temperature：335℃；Draw ratio：2.13 and inherent viscosity：
1.06g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 700g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 700g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1300g, second 160 DEG C of area's drying temperature and the secondth area
180g。
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 2
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor；, precursor is obtained, the performance of the precursor is such as
Shown in table 1；
Its technological parameter is：Spinning speed：4800mpm；Annealer temperature：260℃；Draw ratio：2.08 and inherent viscosity：
1.02g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 700g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 700g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1300g, second 160 DEG C of area's drying temperature and the secondth area
250g。
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 3
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：4800mpm；Annealer temperature：230℃；Draw ratio：2.09 and inherent viscosity：
1.00g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 700g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 700g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1300g, second 160 DEG C of area's drying temperature and the secondth area
140g。
As shown in figure 4, the terylene tyre cord (specification is 1300DX2) that the present embodiment is obtained, is strongly 201N, extension at break
Rate is 22.5%, and work to break is 5.17J.
Fig. 5 is terylene tyre cord, the conventional polyester curtain that the present embodiment measured using the DISC method of testings of compression is obtained
The stress strain curve figure of sub-line (specification is 1300DX2) and the cord fabric thread of nylon 6 (specification is 1260DX2), as shown in Figure 5, this implementation
The compression fatigue performance of example terylene tyre cord is substantially better than conventional polyester cord fabric thread, and can be resistance to the compression of the cord fabric thread of nylon 6
Fatigue behaviour compares favourably；Table 3 is the resistance to of the terylene tyre cord that the present embodiment measured using conventional DISC method of testings is obtained
Testing fatigue result, as shown in Table 3, the fatigue performance for the terylene tyre cord that the present embodiment is obtained are substantially better than specification and are
1300DX2 conventional polyester cord fabric thread and specification is the 1260DX2 cord fabric thread of nylon 6.
The precursor and the other performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 4
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5000mpm；Annealer temperature：365℃；Draw ratio：1.95 and inherent viscosity：
1.04g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 700g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 700g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1300g, second 160 DEG C of area's drying temperature and the secondth area
110g。
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 5
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5200mpm；Annealer temperature：280℃；Draw ratio：2.09 and inherent viscosity：
1.02g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 520g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 520g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1150g, second 160 DEG C of area's drying temperature and the secondth area
110g。
Embodiment 6
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：4900mpm；Annealer temperature：340℃；Draw ratio：2.23 and inherent viscosity：
1.04g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 520g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 520g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1150g, second 160 DEG C of area's drying temperature and the secondth area
200g。
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 7
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5000mpm；Annealer temperature：360℃；Draw ratio：1.98 and inherent viscosity：
1.06g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 520g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 520g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1150g, second 160 DEG C of area's drying temperature and the secondth area
160g。
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 8
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5000mpm；Annealer temperature：360℃；Draw ratio：2.08 and inherent viscosity：
1.04g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：Tension force 520g is dried in first 160 DEG C of area's drying temperature and the firstth area；230 DEG C of draft temperature and
Tension force 520g, 230 DEG C of setting temperature and sizing tension force are dried by tensile stress 1150g, second 160 DEG C of area's drying temperature and the secondth area
140g。
As shown in figure 3, the terylene tyre cord (specification is 1000DX2) that the present embodiment is obtained, is strongly 155N, extension at break
Rate is 21.0%, and work to break is 3.94J.
As shown in fig. 6, the XRD and conventional polyester cord fabric thread of the terylene tyre cord (specification is 1000DX2) of the present embodiment
(specification is 1000DX2) is compared, and the crystallinity of the terylene tyre cord of the present embodiment is 73%, and the size in three faces is respectivelyWithAnd the crystallinity of conventional polyester cord fabric thread (specification is 1000DX2) is 75%, the size point in three faces
It is notWithTherefore the terylene tyre cord (specification is 1000DX2) of the present embodiment has lower crystallinity
Bigger crystalline size, so as in the case where playing the superiority condition of conventional polyester cord fabric thread, improve the strong of the terylene tyre cord
Degree and elongation at break, so as to improve the riding and handling of cross-ply.
As shown in fig. 7, the motorcycle tyre being made of the present embodiment terylene tyre cord oblique before and after the examination of road 24000Km
The test result of warp shows that the performance of the present embodiment terylene tyre cord is better than the cord fabric thread 1260DX2 of nylon 6 performance,
And pass through 40000Km the examination of road test, as shown in table 5.
Tire 2.75-184PR, the 45P being made of the present embodiment terylene tyre cord, respectively in 172 DEG C, saturated vapour pressure
0.93Mpa, internal saturated vapour pressure 1.35Mpa, cure time 11 minutes and 185 DEG C, saturated vapour pressure 0.93Mpa, inside are full
With vapour pressure 1.35Mpa, cure time vulcanizes processing under conditions of 8 minutes, by Tire testing, as a result as shown in table 4, in table
As shown by data, curing temperature improves 13 DEG C, and cure time shortens 27%, and the performance on tire does not influence significantly.
The precursor and the other performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 9
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5000mpm；Annealer temperature：305℃；Draw ratio：2.09 and inherent viscosity：
0.98g/dl。
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：First 160 DEG C of area's drying temperature and dry tension force 520g；230 DEG C of draft temperature and stretching
Power 1150g, second 160 DEG C of area's drying temperature and dry tension force 520g, 230 DEG C of setting temperature and sizing tension force 250g.
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Embodiment 10
A kind of preparation method of terylene tyre cord, comprises the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-spinning group
Part-annealer-ring wind quenching-oils-drawing-off-winding, obtains precursor, the performance of the precursor is as shown in table 1；
Its technological parameter is：Spinning speed：5100mpm；Annealer temperature：330℃；Draw ratio：2.04 and inherent viscosity：
1.00g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area and does first
Dry-the-the two-bath gum dipping of stretching dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is batched；
Terylene tyre cord is obtained, the terylene tyre cord performance is as shown in table 2；
Its technological parameter is：First 160 DEG C of area's drying temperature and dry tension force 520g；230 DEG C of draft temperature and stretching
Power 1150g, second 160 DEG C of area's drying temperature and dry tension force 520g, 230 DEG C of setting temperature and sizing tension force 220g.
The precursor and the performance difference of terylene tyre cord that the present embodiment is obtained are as shown in Table 1 and Table 2.
Comparative example 1
Using above-mentioned drawing process, the precursor fiber number that the method for testing of shrinkage factor is measured is the nylon 6 of 1260 daniers
The performance of (specification is 1260DX2) is as shown in table 2.
Comparative example 2
Using above-mentioned drawing process, the precursor fiber number that the method for testing of shrinkage factor is measured is washed for the routine of 1300 daniers
The performance of synthetic fibre cord fabric thread (specification is 1300DX2) is as shown in table 2.
Comparative example 3
Using above-mentioned drawing process, the precursor fiber number that the method for testing of shrinkage factor is measured is the nylon 6 of 840 daniers
The performance of (specification is 840DX2) is as shown in table 2.
Comparative example 4
Using above-mentioned drawing process, the precursor fiber number that the method for testing of shrinkage factor is measured is washed for the routine of 1000 daniers
The performance of synthetic fibre cord fabric thread (specification is 1000DX2) is as shown in table 2.
The precursor performance table of table 1
The cord fabric thread performance table of table 2
From Tables 1 and 2, the fracture strength >=6.5cN/dtex for the terylene tyre cord that the present embodiment 1-10 is obtained breaks
Elongation is split up to 19~25%, uses the fracture of precursor fiber number terylene tyre cord made from 1000 daniers and 1300 daniers
Work(difference >=3.5J (specification is 1000DX2) and >=4.7J (specification is 1300DX2), its work to break are far above using identical respectively
Conventional polyester cord fabric thread 2.7J (specification is 1000DX2) and 3.9J made from fiber number (specification is 1300DX2)；Its dimensionally stable
Property (DSI) compared with the dimensional stability (DSI) of nylon curtain line, tool improves a lot, precursor fiber number be 1260 daniers
Dimensional stability (DSI) with the nylon curtain line of 840 daniers is respectively up to 15% (specification is 1260DX2) and 16.4% (rule
Lattice are 840DX2), use the DSI of precursor fiber number terylene tyre cord of the invention made from 1000 daniers and 1300 daniers
11% (specification is 1300DX2) and 9.5% (specification is 1000DX2) are then respectively smaller than, can be compared favourably with nylon curtain line.
The routine DISC endurance test results of table 3
Tyre performance table of the terylene tyre cord of the embodiment 8 of table 4 under different conditions of vulcanizations
The riding and handling test result of the tire of table 5
Embodiment described above is only that the preferred embodiment of the present invention is described, not to the model of the present invention
Enclose and be defined, on the premise of design spirit of the present invention is not departed from, technical side of the those of ordinary skill in the art to the present invention
In various modifications and improvement that case is made, the protection domain that claims of the present invention determination all should be fallen into.
Claims (4)
1. a kind of preparation method of terylene tyre cord, it is characterised in that：Comprise the following steps：
(1) spinning technique flow：Section-drying-Screw Extrusion-melt distribution pipe-spinning manifold-filament spinning component-delays
Cooler-ring wind quenching-oils-drawing-off-winding, obtains precursor；
Its technological parameter is：Spinning speed：4800-5200mpm；Annealer temperature：230-365℃；Draw ratio：1.95-2.23
And inherent viscosity：0.98-1.06g/dl；
(2) gum dipping process flow：Lead out-preceding storage cloth holder-first bath impregnation impregnate-aspirates the-the first area drying-drawing first
The-the two-bath gum dipping dipping-- the second area's drying-sizing-breaking knife of secondary suction-storing up cloth holder afterwards-is stretched to batch；Washed
Synthetic fibre cord fabric thread；
Gum dipping process flow described in step (2), its technological parameter is：First 160 DEG C of area's drying temperature and dry tension force 520-
700g；230 DEG C of draft temperature and tensile stress 1150-1300g, second 160 DEG C of area's drying temperature and dry tension force 520-700g,
110~250g of 230 DEG C of setting temperature and sizing tension force.
2. using terylene tyre cord made from the preparation method of the terylene tyre cord described in claim 1.
3. terylene tyre cord according to claim 2, it is characterised in that：Fracture strength >=6.5cN/ of the terylene tyre cord
Dtex, elongation at break is up to 19~25%.
4. application of the terylene tyre cord described in Claims 2 or 3 in cross-ply.
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| MX2017016675A (en) * | 2016-07-01 | 2018-07-06 | Kordsa Teknik Tekstil As | Novel bielastic polyester tire cord as cap ply. |
| CN106192121B (en) * | 2016-09-27 | 2019-08-06 | 联新（开平）高性能纤维有限公司 | High-intensitive high-dimensional stability polyester cord warp thread and its preparation method and application |
| CN107574670B (en) * | 2017-09-13 | 2019-11-19 | 联新（开平）高性能纤维有限公司 | The cord fabric warp thread and preparation method and application of cord fabric warp thread dipping solution and preparation |
| CN112281272A (en) * | 2020-10-15 | 2021-01-29 | 联新（开平）高性能纤维有限公司 | Polyester cord fabric warp with ultrahigh strength and dimensional stability as well as preparation method and application thereof |
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| IN167096B (en) * | 1985-04-04 | 1990-09-01 | Akzo Nv | |
| US4975326A (en) * | 1987-06-03 | 1990-12-04 | Allied-Signal Inc. | High strength polyester yarn for improved fatigue resistance |
| US4867936A (en) * | 1987-06-03 | 1989-09-19 | Allied-Signal Inc. | Process for producing high strength polyester yarn for improved fatigue resistance |
| JP4397207B2 (en) * | 2003-10-06 | 2010-01-13 | 株式会社ブリヂストン | Pneumatic radial tire |
| US7056461B2 (en) * | 2004-03-06 | 2006-06-06 | Hyosung Corporation | Process of making polyester multifilament yarn |
| CN100432306C (en) * | 2006-09-11 | 2008-11-12 | 江南大学 | Method for preparing high-modulus super low shrinkage industrial yarn using pyromellitic dianhydride |
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