CN105176276A - Scrubbing-resistant and antifouling interior wall emulsion paint - Google Patents
Scrubbing-resistant and antifouling interior wall emulsion paint Download PDFInfo
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- CN105176276A CN105176276A CN201510546674.6A CN201510546674A CN105176276A CN 105176276 A CN105176276 A CN 105176276A CN 201510546674 A CN201510546674 A CN 201510546674A CN 105176276 A CN105176276 A CN 105176276A
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Abstract
The invention discloses a scrubbing-resistant and antifouling interior wall emulsion paint. The paint comprises the following components by weight: 30 to 60 parts of silicon acrylic emulsion, 2 to 15 parts of vac-veova emulsion, 3 to 15 parts of fluorocarbon emulsion, 3 to 10 parts of waterborne epoxy resin, 10 to 35 parts of deionized water, 3 to 15 parts of lightweight calcium carbonate, 2 to 15 parts of talcum powder, 2 to 10 parts of sericite powder, 20 to 35 parts of calcined kaolin, 2 to 12 parts of nanometer titanium dioxide, 2 to 15 parts of tourmaline, 0.5 to 3 parts of a film-forming auxiliary agent, 0.3 to 1.5 parts of 2-amino-2-methyl-1-propanol, 0.1 to 1 part of dimethylethanolamine and 5 to 20 parts of an auxiliary agent. The scrubbing-resistant and antifouling interior wall emulsion paint provided by the invention has strong antifouling property and good water resistance and scrubbing-resistant performance, can be applied in painting of an office, a classroom, side walls of a house, etc., and has good comprehensive performance and long service life.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to the antifouling emulsion paint of a kind of washability interior wall.
Background technology
Emulsion paint is inner-outer wall brushing building coating popular at present.In daily life, metope after covering with paint can be polluted by various household stains unavoidably, serious also can have influence on the attractive in appearance of coating, destroys its decorative effect, but interiro wall latex paint conventional in the market exists the problem of stain resistance difference mostly, once stain or dirty spot print are on the wall, be difficult to clean out, and not scrubbing resistance, duration of service is short, often need the replacing carrying out emulsion paint, so just make cost up.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes the antifouling emulsion paint of a kind of washability interior wall, its pollution resistance is strong, water tolerance and wash-resistant property good, can be used for the application of office, classroom, family's flank wall etc., and good combination property, long service life.
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 30-60 part, vac-veova emulsion 2-15 part, fluorine carbon emulsion 3-15 part, aqueous epoxy resins 3-10 part, deionized water 10-35 part, light calcium carbonate 3-15 part, talcum powder 2-15 part, sericite in powder 2-10 part, calcined kaolin 20-35 part, nano titanium oxide 2-12 part, tourmalinite 2-15 part, film coalescence aid 0.5-3 part, 2-amino-2-methyl-1-propanol 0.3-1.5 part, dimethylethanolamine 0.1-1 part, auxiliary agent 5-20 part;
Wherein, described auxiliary agent is added in 15-30 parts by weight of propylene glycol by 10-25 weight part calcined kaolin, 10-25 parts by weight of bentonite, 4-12 weight account polyethylene alcohol, 3-15 weight part nano silicon, 1-2 weight part defoamer, 2-5 weight part Sodium dodecylbenzene sulfonate, 1-5 weight part fluorocarbon surfactant, and after stirring, grinding distribution obtains.
In a particular embodiment, the antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, in its raw material, the weight part of organosilicon crylic acid latex can be 30,32,34,35,36,38,39,42,45,46,48,48.6,49,52,53,56,58,58.6,60 parts; The weight part of vac-veova emulsion can be 2,3,4,5,6,6.3,7,8,8.5,9,9.4,10,12,13,13.6,14,14.5,15 parts; The weight part of fluorine carbon emulsion can be 3,4,5,6,8,9,9.3,12,13,13.5,14,14.6,15 parts; The weight part of aqueous epoxy resins can be 3,4,5,6,6.3,7,8,9,9.5,10 parts; The weight part of deionized water can be 10,12,13,15,16,18,19,19.3,21,23,25,28,29,29.3,31,32,34,34.6,35 parts; The weight part of light calcium carbonate can be 3,4,5,6,8,9,9.3,10,12,13,14,14.6,15 parts, talcous weight part can be 2,3,4,5,5.6,6,6.3,7,8,9,9.3,10,12,13,13.5,14,14.6,15 parts; The weight part of sericite in powder can be 2,3,4,5,6,7,8,9,9.3,10 parts; The weight part of calcined kaolin can be 20,23,24,25,26,28,29,29.3,31,32,34,34.6,35 parts; The weight part of nano titanium oxide can be 2,3,4,5,6,6.3,7,8,8.5,9,9.3,11,11.3,12 parts; The weight part of tourmalinite can be 2,3,4,5,6,7,8,8.5,9,9.3,12,13,13.4,14,14.6,15 parts; The weight part of film coalescence aid can be 0.5,0.6,0.8,0.9,1,1.2,1.3,1.35,1.8,1.9,2,2.1,2.3,2.8,3 part; The weight part of 2-amino-2-methyl-1-propanol can be 0.3,0.5,0.8,1,1.2,1.3,1.38,1.42,1.5 part; The weight part of dimethylethanolamine can be 0.1,0.2,0.3,0.5,0.8,0.95,1 part; The weight part of auxiliary agent can be 5,6,7,8,9,9.3,10,10.6,11,11.3,12,12.6,15,18,19,19.3,20 parts.
Preferably, in its raw material, the weight ratio of organosilicon crylic acid latex, vac-veova emulsion, fluorine carbon emulsion is 40-50:5-12:8-13.
Preferably, its raw material comprises following component by weight: organosilicon crylic acid latex 45-48 part, vac-veova emulsion 8-10 part, fluorine carbon emulsion 10-12 part, aqueous epoxy resins 5-8 part, deionized water 25-30 part, light calcium carbonate 9-12 part, talcum powder 8-13 part, sericite in powder 5-9 part, calcined kaolin 25-30 part, nano titanium oxide 7-10 part, tourmalinite 8-12 part, film coalescence aid 1.8-2.2 part, 2-amino-2-methyl-1-propanol 0.8-1.2 part, dimethylethanolamine 0.5-0.8 part, auxiliary agent 11-14 part.
Preferably, its raw material comprises following component by weight: organosilicon crylic acid latex 46 parts, vac-veova emulsion 9 parts, fluorine carbon emulsion 11 parts, aqueous epoxy resins 7 parts, deionized water 28 parts, light calcium carbonate 10 parts, talcum powder 12 parts, sericite in powder 7 parts, calcined kaolin 28 parts, nano titanium oxide 9 parts, 10 parts, tourmalinite, film coalescence aid 2 parts, 2-amino-2-methyl-1-propanol 1 part, dimethylethanolamine 0.7 part, auxiliary agent 12 parts.
Preferably, described film coalescence aid is one or more the mixture in propylene glycol, glycerol, propandiol butyl ether, propylene glycol phenylate, propylene glycol monomethyl ether, dipropylene glycol methyl ether, butyl, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrates.
Preferably, the calcining temperature of described calcined kaolin is 820-900 DEG C; The mean particle size of calcined kaolin is 2000-3500 order; The oil-absorption(number) of calcined kaolin is 80-90g/100g; Water content≤the 5wt% of calcined kaolin.
Preferably, described auxiliary agent is added in 22-26 parts by weight of propylene glycol by 16-20 weight part calcined kaolin, 17-22 parts by weight of bentonite, 6-10 weight account polyethylene alcohol, 9-12 weight part nano silicon, 1.3-1.8 weight part defoamer, 3.2-3.5 weight part Sodium dodecylbenzene sulfonate, 2.8-3.5 weight part fluorocarbon surfactant, and after stirring, grinding distribution obtains.
Preferably, described auxiliary agent is added in 25 parts by weight of propylene glycol by 17 weight part calcined kaolins, 20 parts by weight of bentonite, 8 weight account polyethylene alcohol, 10 weight part nano silicons, 1.6 weight part defoamers, 3.3 weight part Sodium dodecylbenzene sulfonatees, 3 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains.
The antifouling emulsion paint of washability interior wall of the present invention can emulsion paint preparation technology conveniently be prepared from.
In the present invention, using organosilicon crylic acid latex as main filmogen, coordinate and with the addition of vac-veova emulsion and fluorine carbon emulsion as auxiliary filmogen, by the compatibleness between main film forming substance and auxiliary film forming matter, the performance of three is worked in coordination with, the antifouling emulsion paint of washability interior wall obtained has the character of three simultaneously, gives the excellent specific property such as weather-proof, resistant, the scratch resistance of emulsion paint paint film excellence, wear-resisting, water-fast, acid-and base-resisting, nano titanium oxide adds in system, there is extremely strong activity, in emulsion paint, with the surface reaction of filmogen and water, form powerful interaction force, thus obviously can change over rheological and the suspension of membrane substance, nano titanium oxide is at light calcium carbonate simultaneously, talcum powder, sericite in powder, calcined kaolin, activated adsorption center is defined between tourmalinite particle, bonding is produced in film coated surface, substantially increase the compactness of film, toughness, hardness, scrub resistance and contamination resistance, with tourmalinite, there is synergy, improve the germ resistance of emulsion paint.
The antifouling emulsion paint of washability interior wall of the present invention, with organosilicon crylic acid latex, vac-veova emulsion, fluorine carbon emulsion for filmogen, and with the addition of multiple color stuffing and its compatibility, the sticking power of the antifouling emulsion paint paint film of the washability interior wall obtained and ground is good, strong covering power, water-fast, contamination resistance, abrasion resistance and good weatherability, can be used for the application of office, classroom, family's flank wall etc.
Carry out performance test to the antifouling emulsion paint of washability interior wall of the present invention, its surface drying time is 0.9-1.5h, and the time of doing solid work is 10-18h; Alkali resistance 24h is without exception, and acid resistance 24h is without exception; Abrasion resistance is more than 300 times.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 30 parts, vac-veova emulsion 15 parts, fluorine carbon emulsion 3 parts, aqueous epoxy resins 10 parts, deionized water 10 parts, light calcium carbonate 15 parts, talcum powder 2 parts, sericite in powder 10 parts, calcined kaolin 20 parts, nano titanium oxide 12 parts, 2 parts, tourmalinite, propylene glycol 0.2 part, glycerol 0.5 part, propandiol butyl ether 0.3 part, propylene glycol phenylate 0.2 part, propylene glycol monomethyl ether 0.3 part, dipropylene glycol methyl ether 0.7 part, butyl 0.4 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 0.4 part, 2-amino-2-methyl-1-propanol 0.3 part, dimethylethanolamine 1 part, auxiliary agent 5 parts,
Wherein, described auxiliary agent is added in 30 parts by weight of propylene glycol by 10 weight part calcined kaolins, 25 parts by weight of bentonite, 4 weight account polyethylene alcohol, 15 weight part nano silicons, 1 weight part defoamer, 5 weight part Sodium dodecylbenzene sulfonatees, 1 weight part fluorocarbon surfactant, and after stirring, grinding distribution obtains;
The calcining temperature of described calcined kaolin is 820 DEG C; The mean particle size of calcined kaolin is 3500 orders; The oil-absorption(number) of calcined kaolin is 80g/100g; The water content of calcined kaolin is 3wt%.
Embodiment 2
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 60 parts, vac-veova emulsion 2 parts, fluorine carbon emulsion 15 parts, aqueous epoxy resins 3 parts, deionized water 35 parts, light calcium carbonate 3 parts, talcum powder 15 parts, sericite in powder 2 parts, calcined kaolin 35 parts, nano titanium oxide 2 parts, 15 parts, tourmalinite, butyl 0.2 part, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 0.3 part, 2-amino-2-methyl-1-propanol 1.5 parts, dimethylethanolamine 0.1 part, auxiliary agent 20 parts;
Wherein, described auxiliary agent is added in 15 parts by weight of propylene glycol by 25 weight part calcined kaolins, 10 parts by weight of bentonite, 12 weight account polyethylene alcohol, 3 weight part nano silicons, 2 weight part defoamers, 2 weight part Sodium dodecylbenzene sulfonatees, 5 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains;
The calcining temperature of described calcined kaolin is 900 DEG C; The mean particle size of calcined kaolin is 2000 orders; The oil-absorption(number) of calcined kaolin is 80g/100g; The water content of calcined kaolin is 4wt%.
Embodiment 3
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 45 parts, vac-veova emulsion 10 parts, fluorine carbon emulsion 10 parts, aqueous epoxy resins 8 parts, deionized water 25 parts, light calcium carbonate 12 parts, talcum powder 8 parts, sericite in powder 9 parts, calcined kaolin 25 parts, nano titanium oxide 10 parts, 12 parts, tourmalinite, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.8 parts, 2-amino-2-methyl-1-propanol 1.2 parts, dimethylethanolamine 0.5 part, auxiliary agent 14 parts;
Wherein, described auxiliary agent is added in 22 parts by weight of propylene glycol by 20 weight part calcined kaolins, 17 parts by weight of bentonite, 10 weight account polyethylene alcohol, 9 weight part nano silicons, 1.8 weight part defoamers, 3.2 weight part Sodium dodecylbenzene sulfonatees, 3.5 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains;
The calcining temperature of described calcined kaolin is 850 DEG C; The mean particle size of calcined kaolin is 3000 orders; The oil-absorption(number) of calcined kaolin is 85g/100g; The water content of calcined kaolin is 5wt%.
Embodiment 4
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 48 parts, vac-veova emulsion 8 parts, fluorine carbon emulsion 12 parts, aqueous epoxy resins 5 parts, deionized water 30 parts, light calcium carbonate 9 parts, talcum powder 13 parts, sericite in powder 5 parts, calcined kaolin 30 parts, nano titanium oxide 7 parts, 8 parts, tourmalinite, propandiol butyl ether 0.6 part, propylene glycol phenylate 0.4 part, propylene glycol monomethyl ether 1.2 parts, 2-amino-2-methyl-1-propanol 0.8 part, dimethylethanolamine 0.8 part, auxiliary agent 11 parts;
Wherein, described auxiliary agent is added in 26 parts by weight of propylene glycol by 16 weight part calcined kaolins, 22 parts by weight of bentonite, 6 weight account polyethylene alcohol, 12 weight part nano silicons, 1.3 weight part defoamers, 3.5 weight part Sodium dodecylbenzene sulfonatees, 2.8 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains;
The calcining temperature of described calcined kaolin is 870 DEG C; The mean particle size of calcined kaolin is 2800 orders; The oil-absorption(number) of calcined kaolin is 88g/100g; The water content of calcined kaolin is 5wt%.
Embodiment 5
The antifouling emulsion paint of a kind of washability interior wall that the present invention proposes, its raw material comprises following component by weight: organosilicon crylic acid latex 46 parts, vac-veova emulsion 9 parts, fluorine carbon emulsion 11 parts, aqueous epoxy resins 7 parts, deionized water 28 parts, light calcium carbonate 10 parts, talcum powder 12 parts, sericite in powder 7 parts, calcined kaolin 28 parts, nano titanium oxide 9 parts, 10 parts, tourmalinite, propylene glycol 2 parts, 2-amino-2-methyl-1-propanol 1 part, dimethylethanolamine 0.7 part, auxiliary agent 12 parts;
Wherein, described auxiliary agent is added in 25 parts by weight of propylene glycol by 17 weight part calcined kaolins, 20 parts by weight of bentonite, 8 weight account polyethylene alcohol, 10 weight part nano silicons, 1.6 weight part defoamers, 3.3 weight part Sodium dodecylbenzene sulfonatees, 3 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains;
The calcining temperature of described calcined kaolin is 840 DEG C; The mean particle size of calcined kaolin is 2800 orders; The oil-absorption(number) of calcined kaolin is 83g/100g; The water content of calcined kaolin is 5wt%.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. the antifouling emulsion paint of washability interior wall, it is characterized in that, its raw material comprises following component by weight: organosilicon crylic acid latex 30-60 part, vac-veova emulsion 2-15 part, fluorine carbon emulsion 3-15 part, aqueous epoxy resins 3-10 part, deionized water 10-35 part, light calcium carbonate 3-15 part, talcum powder 2-15 part, sericite in powder 2-10 part, calcined kaolin 20-35 part, nano titanium oxide 2-12 part, tourmalinite 2-15 part, film coalescence aid 0.5-3 part, 2-amino-2-methyl-1-propanol 0.3-1.5 part, dimethylethanolamine 0.1-1 part, auxiliary agent 5-20 part;
Wherein, described auxiliary agent is added in 15-30 parts by weight of propylene glycol by 10-25 weight part calcined kaolin, 10-25 parts by weight of bentonite, 4-12 weight account polyethylene alcohol, 3-15 weight part nano silicon, 1-2 weight part defoamer, 2-5 weight part Sodium dodecylbenzene sulfonate, 1-5 weight part fluorocarbon surfactant, and after stirring, grinding distribution obtains.
2. the antifouling emulsion paint of washability interior wall according to claim 1, it is characterized in that, in its raw material, the weight ratio of organosilicon crylic acid latex, vac-veova emulsion, fluorine carbon emulsion is 40-50:5-12:8-13.
3. the antifouling emulsion paint of washability interior wall according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: organosilicon crylic acid latex 45-48 part, vac-veova emulsion 8-10 part, fluorine carbon emulsion 10-12 part, aqueous epoxy resins 5-8 part, deionized water 25-30 part, light calcium carbonate 9-12 part, talcum powder 8-13 part, sericite in powder 5-9 part, calcined kaolin 25-30 part, nano titanium oxide 7-10 part, tourmalinite 8-12 part, film coalescence aid 1.8-2.2 part, 2-amino-2-methyl-1-propanol 0.8-1.2 part, dimethylethanolamine 0.5-0.8 part, auxiliary agent 11-14 part.
4. the antifouling emulsion paint of washability interior wall according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: organosilicon crylic acid latex 46 parts, vac-veova emulsion 9 parts, fluorine carbon emulsion 11 parts, aqueous epoxy resins 7 parts, deionized water 28 parts, light calcium carbonate 10 parts, talcum powder 12 parts, sericite in powder 7 parts, calcined kaolin 28 parts, nano titanium oxide 9 parts, 10 parts, tourmalinite, film coalescence aid 2 parts, 2-amino-2-methyl-1-propanol 1 part, dimethylethanolamine 0.7 part, auxiliary agent 12 parts.
5. the antifouling emulsion paint of washability interior wall according to any one of claim 1-4, it is characterized in that, described film coalescence aid is propylene glycol, glycerol, propandiol butyl ether, propylene glycol phenylate, propylene glycol monomethyl ether, dipropylene glycol methyl ether, butyl, 2,2, one or more mixture in 4-trimethylammonium-1,3-pentanediol mono isobutyrate.
6. the antifouling emulsion paint of washability interior wall according to any one of claim 1-5, is characterized in that, the calcining temperature of described calcined kaolin is 820-900 DEG C; The mean particle size of calcined kaolin is 2000-3500 order; The oil-absorption(number) of calcined kaolin is 80-90g/100g; Water content≤the 5wt% of calcined kaolin.
7. the antifouling emulsion paint of washability interior wall according to any one of claim 1-6, it is characterized in that, described auxiliary agent is added in 22-26 parts by weight of propylene glycol by 16-20 weight part calcined kaolin, 17-22 parts by weight of bentonite, 6-10 weight account polyethylene alcohol, 9-12 weight part nano silicon, 1.3-1.8 weight part defoamer, 3.2-3.5 weight part Sodium dodecylbenzene sulfonate, 2.8-3.5 weight part fluorocarbon surfactant, and after stirring, grinding distribution obtains.
8. the antifouling emulsion paint of washability interior wall according to any one of claim 1-7, it is characterized in that, described auxiliary agent is added in 25 parts by weight of propylene glycol by 17 weight part calcined kaolins, 20 parts by weight of bentonite, 8 weight account polyethylene alcohol, 10 weight part nano silicons, 1.6 weight part defoamers, 3.3 weight part Sodium dodecylbenzene sulfonatees, 3 weight part fluorocarbon surfactants, and after stirring, grinding distribution obtains.
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| CN201510546674.6A CN105176276A (en) | 2015-08-31 | 2015-08-31 | Scrubbing-resistant and antifouling interior wall emulsion paint |
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| CN107384053A (en) * | 2017-06-30 | 2017-11-24 | 天长市巨龙车船涂料有限公司 | A kind of anti-soil water paint |
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| JP2018145359A (en) * | 2017-03-08 | 2018-09-20 | 旭化成株式会社 | Aqueous composition, aqueous coating material, coating film, composite coating film, and coated product |
| CN109723191A (en) * | 2018-11-21 | 2019-05-07 | 温州市东日建筑装饰工程有限公司 | A kind of finishing wall finiss coating method and preparation method |
| CN111004574A (en) * | 2019-12-19 | 2020-04-14 | 佛山市南海双维水性材料有限公司 | Scrubbing-resistant antifouling emulsion paint for interior walls |
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