CN105165891A - Chlorine dioxide tablet disinfector and preparing method thereof - Google Patents
Chlorine dioxide tablet disinfector and preparing method thereof Download PDFInfo
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- CN105165891A CN105165891A CN201510606726.4A CN201510606726A CN105165891A CN 105165891 A CN105165891 A CN 105165891A CN 201510606726 A CN201510606726 A CN 201510606726A CN 105165891 A CN105165891 A CN 105165891A
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- chlorine dioxide
- sodium
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- acid
- activator
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 35
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000012190 activator Substances 0.000 claims abstract description 13
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229960002218 sodium chlorite Drugs 0.000 claims abstract description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 8
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011975 tartaric acid Substances 0.000 claims abstract description 8
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 8
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 6
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims abstract description 5
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 4
- 239000000645 desinfectant Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 9
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical group [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 9
- 238000005260 corrosion Methods 0.000 claims description 8
- 230000007797 corrosion Effects 0.000 claims description 8
- 239000002274 desiccant Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 235000011008 sodium phosphates Nutrition 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000011667 zinc carbonate Substances 0.000 claims description 3
- 235000004416 zinc carbonate Nutrition 0.000 claims description 3
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 239000011686 zinc sulphate Substances 0.000 claims description 3
- 235000009529 zinc sulphate Nutrition 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 abstract 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 abstract 1
- 229950009390 symclosene Drugs 0.000 abstract 1
- 239000003826 tablet Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 206010023126 Jaundice Diseases 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- -1 chlorate anions Chemical class 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000007939 sustained release tablet Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a chlorine dioxide tablet disinfector. The chlorine dioxide tablet disinfector is prepared from, by weight, 15 parts to 20 parts of sodium chlorite, 10 parts to 15 parts of stabilizers, 25 parts to 30 parts of activators and 2 parts to 5 parts of instantizers. The stabilizers are one or more kinds of magnesium chloride, anhydrous sodium sulfate and magnesium sulfate. The activators are one or more kinds of sodium hydrogen sulfate, citric acid and tartaric acid. The instantizers are one or more kinds of sodium carbonate, lauryl sodium sulfate and trichloroisocyanuric acid. According to the chlorine dioxide tablet disinfector, the disinfection time is long, chlorine dioxide can be evenly generated for 3 h to 6 h under the indoor temperature condition of 20 DEG C, the concentration is controlled to be about 50 pp to 300 pp, the pH is mild, a drastic reaction is avoided, and the chlorine dioxide tablet disinfector is completely suitable for disinfection in the civilian aspect, the family environment aspect and the like.
Description
Technical field
The invention belongs to disinfectant preparing technical field, be specifically related to a kind of chlorine dioxide tablet disinfectant and preparation method thereof.
Background technology
Chlorine dioxide is current safety generally acknowledged in the world, the sterilization of wide spectrum, fresh-keeping and deodorant, is the optimal substitute of chlorinated product, is widely used in developed country.The U.S., Canada, Japan, West Europe etc. have been ratified and have been recommended chlorine dioxide to be used for the anti-corrosive fresh-keeping etc. of the sterilization of food, food processing industry, pharmacy industry, hospital, public environment etc., deodorizing, mildew-resistant and food.Chlorine dioxide is also classified as Al level security high effect disinfectants by the World Health Organization (WHO).For controlling the generation of " three cause material " in drinking water (teratogenesis, carcinogenic, mutagenesis), European and American developed countries wide popularization and application chlorine dioxide substitute the sterilization that chlorine carries out drinking water.In recent years since, China also starts to pay attention to the promotion and application to chlorine dioxide, and product constantly comes out, and it is that disinfectant and novel foodstuff add drug that health ministry has also ratified chlorine dioxide.But because current stability chlorine dioxide product is mostly two-component packaging (being made up of stabilized chlorine solutions of chlorine and solid or liquid activating agent two parts), in use need again to activate sterilized stock solution with acidic activator, not only complex operation.Operating personnel are required high, transport, storage inconvenience; And activation efficiency lower (only reaching 10-15%), make the chlorine dioxide of nearly 85-90% because do not have activate and cannot use, cause the significant wastage of product, also substantially increase working concentration and the disinfection cost of product, seriously limit the extensive use of Chlorine dioxide production.Traditional chlorine dioxide tablet is all carry out compressing tablet by adding adhesive, makes its utilization rate of active components low.
According to the NaClO of product professional standard (ZBG12015-89) its Grade A
2content>=82%, sodium chlorate (Na2ClO3) content≤3.5%, sodium chloride (NaCl) content≤13.5%.Prepare in chlorine dioxide and also produce chlorate anions, wherein chlorate anions mainly ClO
2disproportionated reaction produce.Cl
-then ClO
2, ClO
-catabolite.
Prepare chlorine dioxide ClO
2method a lot, use sodium chlorite NaClO
2adding hcl acidifying is conventional method, but the accessory substance of above-mentioned reaction can produce; Chemical method prepares chlorine dioxide also useful sodium chlorite NaClO
2acidifying is produced, and the difference of pH value is very large on activation effect impact.The composition worked in disinfecting process is chlorine dioxide, if acidity is inadequate, soak time is short, and activation all may be made incomplete, and affect Disinfection Effect, undue acidity is also unfavorable to water treatment, because can bring much useless or harmful composition.In many analyses, conventional general iodimetric titration measures ClO
2concentration, often can by ClO
2 -survey into ClO by mistake
2, cause ClO
2the illusion that activation rate is very high.Sodium chlorite solution contains a certain amount of free ClO dissolved in because of decomposition
2, solution is turned to be yellow, and has pungent taste, and usual ClO
3 -content also higher.
Temperature also has considerable influence, ClO to preparing chlorine dioxide
2place 14 days when it is generally acknowledged 54 DEG C, be equivalent to ambient temperatare and put 1 year.If adopt sodium carbonate Na
2cO
3make basic materials, ClO in general stable ClO 2 solution
2content lower, be only 2% ~ 8%.
Summary of the invention
The present invention seeks to, solve the technical problem existed, provide a kind of product safety to stablize, chlorine dioxide tablet disinfectant that utilization rate of active components is high and preparation method thereof.
Technical problem to be solved by this invention realizes by the following technical solutions, a kind of chlorine dioxide tablet disinfectant, it is characterized in that described disinfectant is made up of the component of following weight, sodium chlorite 15-20, stabilizing agent 10-15, activator 25-30, quick-dissolving agent 2-5; Described stabilizing agent is magnesium chloride, anhydrous sodium sulfate, magnesium sulfate one or more 10-15 wherein.
Described activator is niter cake, citric acid, tartaric acid one or more 25-30 wherein.
Described quick-dissolving agent is sodium carbonate, lauryl sodium sulfate, trichlorine isocyanide are urinated acid one or more 2-5 wherein.
Especially also lubricant 0.5-3 can be adopted, glidant 5-15, desiccant 5-10, corrosion inhibiter 3-4 (these four kinds have very great help to compressing tablet); Described lubricant is sodium chloride, dolomol, fumaric acid wherein one or more.Described glidant is talcum powder, silica, boric acid wherein one or more, described desiccant is one or more mixtures in anhydrous calcium chloride, anhydrous magnesium sulfate or anhydrous sodium sulfate, and described corrosion inhibiter is one or more mixtures in sodium acetate, sodium phosphate, zinc sulphate, zinc carbonate.
The preparation method of chlorine dioxide tablet disinfectant, all auxiliary material mixing are carried out drying, stabilizing agent 10-15, quick-dissolving agent 2-5 weight portion, at temperature 50-60 DEG C, carry out mixing heat drying 3 hours, detect after moisture content (≤1.5wt%) meets the requirements and cool; Add sodium chlorite 15-20 weight portion again to add in mixing kettle with dry auxiliary material and mix, be uniformly mixed 30-60 minute at 30-40 DEG C of temperature after, under finally adding activator 30-40 DEG C temperature, be uniformly mixed 30-40 minute.
Auxiliary material mixing is carried out drying and is comprised the materials such as stabilizing agent, quick-dissolving agent, lubricant, glidant.
Be less than 28 DEG C in temperature, humidity carries out compressing tablet lower than under the environment of 30%, and sheet is heavy can be required to be adjusted to 1g/ sheet, 1.5g/ sheet, 2g/ sheet etc. according to user.Manufactured tablet does not have jaundice and swollen bag phenomenon for 24 hours in 70 DEG C of baking ovens.
Beneficial effect of the present invention: the material of all moisture content more than 5% all carries out drying and dewatering process; This disinfection tablet is sustained release tablets, after niter cake, citric acid, tartaric acid wherein one or more under suitable pH value condition, pH value is best when about 3 react, and from the addition of sodium chlorite, almost can change into chlorine dioxide completely and discharge in water.With hcl acidifying Method compare, disinfecting time of the present invention is long (can evenly produce chlorine dioxide 3-6h under 20 DEG C of room temperature conditions, concentration controls at about 50-300pp), pH value not harsh (gentleer), do not produce intense reaction, be applicable to the disinfection of the aspects such as civilian and home environment completely; Add composite trichlorine isocyanide urinate acid itself there is collaborative disinfective action, be also conducive to the adjustment of pH value.This disinfectant tablet adopts antioxidation aluminium moulding material to carry out single packaging, is very easy to the use of product, improves the safety of product. and this product content is high, and stability is good, is convenient to store and transport, and it is extremely convenient to use.
Embodiment
The present invention has following formula (weight portion): stabilizing agent is magnesium chloride, anhydrous sodium sulfate, magnesium sulfate wherein one or more.Described activator is niter cake, citric acid, tartaric acid wherein one or more.Acid wherein one or more that described quick-dissolving agent is sodium carbonate, lauryl sodium sulfate, trichlorine isocyanide are urinated.
Especially also lubricant 0.5-3 can be adopted, glidant 5-15, desiccant 5-10, corrosion inhibiter 3-4.Sodium chlorite niter cake citric acid stabilizing agent quick-dissolving agent lubricants glidants desiccant corrosion inhibiter
Or tartaric acid
In the 14-18 of formula: totally 28 (30) niter cakes and citric acid (or tartaric acid) are identical weight, and the effect of totally 28 or 30 parts is best, reaction evenly discharges chlorine dioxide; Especially also 20 lubricant 0.5-3 can be adopted, glidant 5-15, desiccant 5-10, corrosion inhibiter 3-4;
Described stabilizing agent is magnesium chloride (routine 1-5), anhydrous sodium sulfate (routine 6-10), magnesium sulfate add magnesium chloride (routine 11-18), one wherein or two kinds of indistinctions.
Described quick-dissolving agent is sodium carbonate (routine 1-5), lauryl sodium sulfate (routine 6-9), trichlorine isocyanide are urinated acid (routine 10-11, effect is especially good) work wherein one or more, routine 12-18 is lauryl sodium sulfate, trichlorine isocyanide is urinated, and acid two kinds is mixed.
Described lubricant is sodium chloride (routine 1-5), dolomol (routine 6-8), fumaric acid (routine 9-11,17-18) one or more indistinctions wherein.Described glidant is talcum powder (routine 10-12), silica, boric acid (routine 13-17) one or more indistinctions wherein, described desiccant is one or more mixtures in anhydrous calcium chloride (routine 11-15), example 17 anhydrous magnesium sulfate or anhydrous sodium sulfate, and described corrosion inhibiter is the equal indistinction of one or more mixtures in sodium acetate, sodium phosphate, zinc sulphate, zinc carbonate.
The embodiment of the preparation method of chlorine dioxide tablet disinfectant of the present invention, drying is carried out in all auxiliary material mixing, stabilizing agent anhydrous sodium sulfate 10, quick-dissolving agent lauryl sodium sulfate, trichlorine isocyanide are urinated acid 5 weight portions totally, at temperature 50-60 DEG C, carry out mixing heat drying 3 hours, detect after moisture content (≤1.5wt%) meets the requirements and cool; Add sodium chlorite 15-20 weight portion to add in mixing kettle with dry auxiliary material and mix, be uniformly mixed 30-60 minute at 30-40 DEG C of temperature after, finally add activator niter cake and citric acid totally 28 parts at 30-40 DEG C of temperature, be uniformly mixed 30-40 minute.Be less than 28 DEG C in temperature, humidity carries out compressing tablet lower than under the environment of 30%, and sheet is heavy can be required to be adjusted to 1g/ sheet, 1.5g/ sheet, 2g/ sheet etc. according to user.Manufactured tablet does not have jaundice and swollen bag phenomenon for 24 hours in 70 DEG C of baking ovens.
Have in technical field of the present invention and usually know the knowledgeable, without departing from the spirit and scope of the present invention, when doing various changes and retouching.Therefore, protection scope of the present invention is when being as the criterion depending on those as defined in claim.
Claims (5)
1. a chlorine dioxide tablet disinfectant, is characterized in that being made up of the component of following weight, sodium chlorite 15-20, stabilizing agent 10-15, activator 25-30, quick-dissolving agent 2-5;
Described stabilizing agent is magnesium chloride, anhydrous sodium sulfate, magnesium sulfate wherein one or more;
Described activator is niter cake, citric acid, tartaric acid wherein one or more;
Acid wherein one or more that described quick-dissolving agent is sodium carbonate, lauryl sodium sulfate, trichlorine isocyanide are urinated.
2. chlorine dioxide tablet disinfectant, is characterized in that also adding lubricant 0.5-3, glidant 5-15, desiccant 5-10, corrosion inhibiter 3-4; Described lubricant is sodium chloride, dolomol, fumaric acid wherein one or more; Described glidant is talcum powder, silica, boric acid wherein one or more, described desiccant is one or more mixtures in anhydrous calcium chloride, anhydrous magnesium sulfate or anhydrous sodium sulfate, and described corrosion inhibiter is one or more mixtures in sodium acetate, sodium phosphate, zinc sulphate, zinc carbonate.
3. chlorine dioxide tablet disinfectant, is characterized in that activator adopts niter cake 14-15 part and citric acid 14-15 part, or niter cake 14-15 part and tartaric acid 14-15 part, jointly adds as activator.
4. according to the preparation method of the chlorine dioxide tablet disinfectant one of claim 1-3 Suo Shu, it is characterized in that with following steps: drying is carried out in all auxiliary material mixing, at temperature 50-60 DEG C, carry out mixing heat drying 3 hours, detect after moisture content (≤1.5wt%) meets the requirements and cool; Add sodium chlorite 15-20 weight portion again to add in mixing kettle with dry auxiliary material and mix, be uniformly mixed 30-60 minute at 30-40 DEG C of temperature after, under finally adding activator 30-40 DEG C temperature, be uniformly mixed 30-40 minute.
5. the preparation method of chlorine dioxide tablet disinfectant according to claim 4, it is characterized in that being less than 28 DEG C in temperature, humidity carries out compressing tablet lower than under the environment of 30%.
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| CN201510606726.4A CN105165891A (en) | 2015-09-22 | 2015-09-22 | Chlorine dioxide tablet disinfector and preparing method thereof |
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| CN201510606726.4A CN105165891A (en) | 2015-09-22 | 2015-09-22 | Chlorine dioxide tablet disinfector and preparing method thereof |
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| CN105668730A (en) * | 2016-03-22 | 2016-06-15 | 江苏祥豪实业有限公司 | Novel chlorine dioxide material for treating water and method for preparing novel chlorine dioxide material |
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| CN106614557A (en) * | 2016-10-19 | 2017-05-10 | 上海普吉生物科技有限公司 | Chlorine dioxide powder and preparation method |
| CN108030705A (en) * | 2017-12-25 | 2018-05-15 | 河北科技大学 | A kind of compound sodium chlorite effervesce for oral care is gargled tablet and preparation method |
| CN108719321A (en) * | 2018-08-06 | 2018-11-02 | 山东华实药业有限公司 | A kind of stability disinfection tablet and its manufacture craft |
| CN108849973A (en) * | 2018-08-06 | 2018-11-23 | 山东华实药业有限公司 | A kind of stability chlorine dioxide disinfectant powder and its manufacture craft |
| CN109819999A (en) * | 2019-04-04 | 2019-05-31 | 开封恩科生物科技有限公司 | Chlorine dioxide solid releasing agent and preparation method thereof |
| CN110550981A (en) * | 2019-09-24 | 2019-12-10 | 杨宇 | Production method of chlorine dioxide disinfectant |
| CN111226980A (en) * | 2020-03-28 | 2020-06-05 | 晋玮璘 | Reactive chlorine dioxide solid preparation and preparation method thereof |
| CN111436456A (en) * | 2020-05-09 | 2020-07-24 | 南京协心健康科技有限公司 | Chlorine dioxide solution spray and preparation method thereof |
| CN111567555A (en) * | 2020-06-24 | 2020-08-25 | 珠海佰俐生物科技有限公司 | Slow-release disinfectant, slow-release disinfection bag and preparation method thereof |
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| CN108719321A (en) * | 2018-08-06 | 2018-11-02 | 山东华实药业有限公司 | A kind of stability disinfection tablet and its manufacture craft |
| CN108849973A (en) * | 2018-08-06 | 2018-11-23 | 山东华实药业有限公司 | A kind of stability chlorine dioxide disinfectant powder and its manufacture craft |
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| CN110550981A (en) * | 2019-09-24 | 2019-12-10 | 杨宇 | Production method of chlorine dioxide disinfectant |
| CN110550981B (en) * | 2019-09-24 | 2021-09-28 | 上海汉今医疗科技有限公司 | Production method of chlorine dioxide disinfectant |
| CN111226980A (en) * | 2020-03-28 | 2020-06-05 | 晋玮璘 | Reactive chlorine dioxide solid preparation and preparation method thereof |
| CN111436456A (en) * | 2020-05-09 | 2020-07-24 | 南京协心健康科技有限公司 | Chlorine dioxide solution spray and preparation method thereof |
| CN111567555A (en) * | 2020-06-24 | 2020-08-25 | 珠海佰俐生物科技有限公司 | Slow-release disinfectant, slow-release disinfection bag and preparation method thereof |
| CN111567555B (en) * | 2020-06-24 | 2021-09-28 | 珠海佰俐生物科技有限公司 | Slow-release disinfectant, slow-release disinfection bag and preparation method thereof |
| CN112352785A (en) * | 2020-10-29 | 2021-02-12 | 青岛翼科新程生物科技有限公司 | Chlorine dioxide nano zinc disinfection and bacteriostasis tablet |
| KR102417750B1 (en) * | 2022-03-11 | 2022-07-05 | 이지희 | Composition for disinfecting and sterilizing sand and method for preparing the same |
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