CN105152579A - Stone slab with patterns - Google Patents
Stone slab with patterns Download PDFInfo
- Publication number
- CN105152579A CN105152579A CN201510480939.7A CN201510480939A CN105152579A CN 105152579 A CN105152579 A CN 105152579A CN 201510480939 A CN201510480939 A CN 201510480939A CN 105152579 A CN105152579 A CN 105152579A
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- Prior art keywords
- weight percent
- stone slab
- quartz
- powder
- decorative pattern
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- 239000004575 stone Substances 0.000 title claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 14
- 239000003365 glass fiber Substances 0.000 claims abstract description 13
- 239000010453 quartz Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 11
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 9
- 239000000956 alloy Substances 0.000 claims abstract description 9
- 239000007822 coupling agent Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 2
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 2
- 239000006004 Quartz sand Substances 0.000 claims description 2
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- FKMKNMHOYXAUAP-UHFFFAOYSA-N copper;naphthalene-1-carboxylic acid Chemical compound [Cu].C1=CC=C2C(C(=O)O)=CC=CC2=C1 FKMKNMHOYXAUAP-UHFFFAOYSA-N 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000005034 decoration Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract description 2
- 238000011161 development Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract description 2
- 239000007767 bonding agent Substances 0.000 abstract 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 238000013019 agitation Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- -1 rhombspar Inorganic materials 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000009775 high-speed stirring Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004579 marble Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a formula of a stone slab with artificial patterns. The formula comprises raw materials as follows: unsaturated polyester resin, a curing agent, quartz, glass fiber, color paste, an accelerant, a coupling agent, alloy powder, composite powder and water serving as a hydraulic bonding agent. The stone slab is energy-saving and environment-friendly due to the fact that the quartz and the glass fiber which are low in price and easy to obtain are taken as the raw materials of the formula and belongs to a novel environment-friendly building material, and various resources can be sufficiently used; the stone slab replaces natural quartz stone to serve as a high-grade decoration, over-exploitation of the natural quartz stone is effectively restrained, and environment protection and development of recycling economy and low-carbon economy are promoted; the stone slab has the advantages of non-toxic, tastelessness, non-radiation, no microcellular structure, dirt resistance, easiness in maintenance and high processability and can has a good lighting effect by the aid of projection of common light.
Description
Technical field
The present invention relates to Artificial construction material field, in particular to a kind of formula of Artificial grain's stone slab.
Background technology
Stone material is widely used in interior/exterior decoration design, curtain wall decoration and public facility construction as a kind of high-grade construction decoration material.Stone material common in the market is mainly divided into lithotome and artificial stone-like material.Lithotome refers to be exploited out from natural rock mass, and through being processed into the general name of bulk or board-like material.The lithotome of architectural decoration mainly contains grouan and marble two macrospecies.At present, the exploitation of natural stone resource is brought to the destruction of unrepairable to ecotope, also there is the problems such as construction intensity is large, transport difficult simultaneously.And artificial stone-like material can effectively address these problems, it take unsaturated polyester resin as cakingagent, be equipped with the inorganics powder such as natural marble or calcite, rhombspar, silica sand, glass powder, and appropriate fire retardant, staining agent etc., make through method forming and hardenings such as batching mixing, porcelain casting, vibrocompression, extruding.Compared with lithotome, it is consistent that artificial stone-like material has beautiful in colour, highly polished, color even, anti-pressure and abrasion-proof, good toughness, compact structure, sturdy and durable, light specific gravity, do not absorb water, resistant to corrosion weathering, the advantage such as aberration is little, colour-fast, radioactivity is low.Artificial stone-like material has the advantage of comprehensive utilization of resources, has immeasurable effect in environmental protection and energy saving, is also genuine building materials Green Product, progressively becomes the finishing material of modern architecture first-selection.
According to the needs of human consumer, can also produce figuratum artificial stone-like material, manufacture the method complex process of decorative pattern stone material at present, need to carry out twice cloth, production cost is high.
Summary of the invention
In order to solve the defect in order to overcome existing decorative pattern stone material technology of preparing, the invention provides a kind of preparation formula of with low cost, decorative pattern stone material that environmental protection is attractive in appearance, the present invention is realized by following technical proposal:
Unsaturated polyester resin;
Solidifying agent;
Quartz;
Glass fibre;
Mill base;
Promotor;
Coupling agent;
Alloy powder;
Composite powder;
And as the water of hydraulicaccumulator binder, wherein, the weight percent of described unsaturated polyester resin is 5 ~ 10%, the weight percent of solidifying agent is 0.01 ~ 0.5%, the weight percent of quartz is 30 ~ 60%, the weight percent of glass fibre is 20 ~ 40%, the weight percent of mill base is 0.05 ~ 0.3%, the weight percent of promotor is 0.05 ~ 0.3%, the weight percent of coupling agent is 0.01 ~ 0.5%, the weight percent of alloy powder is 0.01 ~ 0.5%, the weight percent of composite powder is 20 ~ 25%, remaining part is the water as hydraulicaccumulator binder, described weight percent is 100 listed as parts by weight by decorative pattern stone slab.
Wherein, solidifying agent is one or more in benzoyl peroxide, methylethyl ketone peroxide, peroxidized t-butyl perbenzoate;
Quartz is quartz sand or silica powder;
Promotor is one or more in different Rinmann's green, naphthoic acid copper, vinylbenzene;
Coupling agent is silane coupling agent;
The main component of alloy powder is iron alloy powder, includes a small amount of Al alloy powder and Titanium Powder simultaneously;
The main component of composite powder is calcium carbonate.
Further, the unsaturated polyester resin in above-mentioned raw materials formula consists of the following composition again:
Phthalic anhydride;
Cis-butenedioic anhydride;
Glycerine;
Glycol ether;
Ethylene glycol;
Phenylformic acid;
Vinylbenzene;
Wherein, the weight percent of described phthalic anhydride is 25%, the weight percent of cis-butenedioic anhydride is 20%, the weight percent of glycerine is 15%, the weight percent of glycol ether is 10%, and the weight percent of ethylene glycol is 10%, and benzoic weight percent is 2%, cinnamic weight percent is 18%, and described weight percent is 100 listed as parts by weight by unsaturated polyester resin.
Further, the size specification of described quartz is 120 orders.
Further, the size specification of described glass fibre is 6 ~ 8 orders.
The invention has the beneficial effects as follows:
(1) adopt quartz cheap and easy to get and glass fibre as raw material, energy-conserving and environment-protective, belong to novel green building material, various resource can be made full use of;
(2) substitute natural stone diamond stone and become high-grade ornament, effectively suppress the overexploitation to natural stone diamond stone, promote the development of environment protection, recycling economy and low-carbon economy;
(3) have nontoxic, tasteless, radiationless by this decorative pattern stone slab made of filling a prescription, pore-free structure, stain resistance, easily maintains, the advantage that processibility is strong; By the projection of common light, produce good effect of shadow;
(4) by this decorative pattern stone slab of making of filling a prescription have beautiful in colour, highly polished, color even is consistent, anti-pressure and abrasion-proof, good toughness, compact structure, sturdy and durable, light specific gravity, do not absorb water, resistant to corrosion weathering, the advantage such as aberration is little, colour-fast, radioactivity is low, there is immeasurable effect in environmental protection and energy saving, progressively become the finishing material of modern architecture first-selection.
Obtained decorative pattern stone slab has excellent performance, as shown in the table:
Table 1 is for soaking the performance test results of front sample
Illustrate: wherein 1# novel artificial decorative pattern stone slab, 2# is conventional stone slab.Table is visible thus, and this novel decorative pattern stone slab M11 made that fills a prescription compares with M21, and water-intake rate is starkly lower than M21, and under equal quality condition, dry compressive strength and dry flexural strength are obviously better than M21.Mohs' hardness is greater than conventional stone slab equally.
Embodiment
embodiment 1
Get raw material by weight as follows:
Unsaturated polyester resin 8kg, solidifying agent methylethyl ketone peroxide 0.4kg, silica powder 40kg, glass fibre 25kg, mill base 0.2kg, coupling agent 0.3kg, alloy powder 0.1kg, composite powder 24kg, water 2kg.
Unsaturated polyester resin being added in agitation vat, in high-speed agitating process, add composite powder, stir 16min, mix, continuing to stir 15min to mixing.Add in agitation vat by mill base and promotor, high-speed stirring 5min mixes.Waiting for 10min, add solidifying agent, continuing to stir 10min to mixing.The raw material mixed is put into and makes Hua Jizhong and carry out making flower process, then glass fibre is required to cut according to mold surface dimensions, be placed in inside mould.Poured into fast in mould by the raw material mixed having carried out making flower process, ambient cure 20min, makes it to become blank, carry out vacuum-treat to blank, vacuum tightness is 0.06MPa, the air in removing blank, then suppress, compacting specification is 100 Dun/㎡, and the press time is 10min.The blank obtained is taken out, puts into the oven for baking 100min of 100 DEG C, finally polish, after polishing, obtain finished product.
embodiment 2
Get raw material by weight as follows:
Unsaturated polyester resin 9kg, solidifying agent methylethyl ketone peroxide 0.4kg, silica powder 40kg, glass fibre 24kg, mill base 0.2kg, coupling agent 0.3kg, alloy powder 0.1kg, composite powder 25kg, water 1kg.
Unsaturated polyester resin being added in agitation vat, in high-speed agitating process, add composite powder, stir 18min, mix, continuing to stir 16min to mixing.Add in agitation vat by mill base and promotor, high-speed stirring 8min mixes.Waiting for 10min, add solidifying agent, continuing to stir 12min to mixing.The raw material mixed is put into and makes Hua Jizhong and carry out making flower process, then glass fibre is required to cut according to mold surface dimensions, be placed in inside mould.Poured into fast in mould by the raw material mixed having carried out making flower process, ambient cure 20min, makes it to become blank, carry out vacuum-treat to blank, vacuum tightness is 0.08MPa, the air in removing blank, then suppress, compacting specification is 120 tons/m2, and the press time is 15min.The blank obtained is taken out, puts into the oven for baking 120min of 120 DEG C, finally polish, after polishing, obtain finished product.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, the amendment made, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. a decorative pattern stone slab, is characterized in that, is made up of following raw material:
Unsaturated polyester resin;
Solidifying agent;
Quartz;
Glass fibre;
Mill base;
Promotor;
Coupling agent;
Alloy powder;
Composite powder;
And as the water of hydraulicaccumulator binder, wherein, the weight percent of described unsaturated polyester resin is 5 ~ 10%, the weight percent of solidifying agent is 0.01 ~ 0.5%, the weight percent of quartz is 30 ~ 60%, the weight percent of glass fibre is 20 ~ 40%, the weight percent of mill base is 0.05 ~ 0.3%, the weight percent of promotor is 0.05 ~ 0.3%, the weight percent of coupling agent is 0.01 ~ 0.5%, the weight percent of alloy powder is 0.01 ~ 0.5%, the weight percent of composite powder is 20 ~ 25%, remaining part is the water as hydraulicaccumulator binder, described weight percent is 100 listed as parts by weight by decorative pattern stone slab,
Wherein, solidifying agent is one or more in benzoyl peroxide, methylethyl ketone peroxide, peroxidized t-butyl perbenzoate;
Quartz is quartz sand or silica powder;
Promotor is one or more the mixing in different Rinmann's green, naphthoic acid copper, vinylbenzene;
Coupling agent is silane coupling agent;
Alloy powder includes iron alloy powder, Al alloy powder and Titanium Powder;
The main component of composite powder is calcium carbonate.
2. decorative pattern stone slab according to claim 1, is characterized in that, described unsaturated polyester resin is made up of following raw material:
Phthalic anhydride;
Cis-butenedioic anhydride;
Glycerine;
Glycol ether;
Ethylene glycol;
Phenylformic acid;
Vinylbenzene;
Wherein, the weight percent of described phthalic anhydride is 25%, the weight percent of cis-butenedioic anhydride is 20%, the weight percent of glycerine is 15%, the weight percent of glycol ether is 10%, and the weight percent of ethylene glycol is 10%, and benzoic weight percent is 2%, cinnamic weight percent is 18%, and described weight percent is 100 listed as parts by weight by unsaturated polyester resin.
3. a kind of decorative pattern stone slab according to claim 1, is characterized in that, the size specification of described quartz is 120 orders.
4. a kind of decorative pattern stone slab according to claim 1, is characterized in that, the size specification of described glass fibre is 6 ~ 8 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510480939.7A CN105152579A (en) | 2015-08-07 | 2015-08-07 | Stone slab with patterns |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510480939.7A CN105152579A (en) | 2015-08-07 | 2015-08-07 | Stone slab with patterns |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105152579A true CN105152579A (en) | 2015-12-16 |
Family
ID=54793701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510480939.7A Pending CN105152579A (en) | 2015-08-07 | 2015-08-07 | Stone slab with patterns |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105152579A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106495566A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of imitation natural stone diamond stone decorative pattern sheet material and preparation method thereof |
| CN106495560A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of artificial jade slabstone and its manufacture craft |
| CN106495564A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of Snow Flower White quartzite slate and preparation method thereof |
| CN106542768A (en) * | 2016-11-08 | 2017-03-29 | 唐山金信人造板业有限公司 | A kind of OK a karaoke club crystobalite stone slab and its manufacture craft |
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
| CN107512870A (en) * | 2017-09-21 | 2017-12-26 | 成都新柯力化工科技有限公司 | A kind of environment friendly light building decoration artificial stone and preparation method |
| CN109279816A (en) * | 2018-10-26 | 2019-01-29 | 广东博瑞格新材料科技股份有限公司 | A kind of natural reticulate pattern hilllock stone and preparation method thereof |
| CN111393136A (en) * | 2020-03-25 | 2020-07-10 | 山东天马泰山机械集团有限公司 | Artificial stone and preparation method thereof |
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| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
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| CN104291734A (en) * | 2014-09-24 | 2015-01-21 | 湖北硅金凝健康石材有限公司 | Artificial stone and preparation method thereof |
| CN104478293A (en) * | 2014-12-15 | 2015-04-01 | 田忠和 | Synthetic quartzite plate and preparation method thereof |
| CN104556826A (en) * | 2015-01-12 | 2015-04-29 | 黄明超 | Process for producing artificial stone |
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- 2015-08-07 CN CN201510480939.7A patent/CN105152579A/en active Pending
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| CN101337805A (en) * | 2008-08-25 | 2009-01-07 | 张璐 | Artificial quartz in lump and fabrication technology thereof |
| CN102219882A (en) * | 2011-05-04 | 2011-10-19 | 肇庆福田化学工业有限公司 | Method for synthesizing unsaturated polyester resin by utilizing glycerol |
| CN103833265A (en) * | 2014-01-23 | 2014-06-04 | 王舒怡 | High-strength artificial quartz stone plate and its preparation method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106495566A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of imitation natural stone diamond stone decorative pattern sheet material and preparation method thereof |
| CN106495560A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of artificial jade slabstone and its manufacture craft |
| CN106495564A (en) * | 2016-11-08 | 2017-03-15 | 唐山金信人造板业有限公司 | A kind of Snow Flower White quartzite slate and preparation method thereof |
| CN106542768A (en) * | 2016-11-08 | 2017-03-29 | 唐山金信人造板业有限公司 | A kind of OK a karaoke club crystobalite stone slab and its manufacture craft |
| CN106866030A (en) * | 2017-03-22 | 2017-06-20 | 佛山市蓝瑞欧特信息服务有限公司 | A kind of water-fast artificial quartz in lump and preparation method thereof |
| CN107512870A (en) * | 2017-09-21 | 2017-12-26 | 成都新柯力化工科技有限公司 | A kind of environment friendly light building decoration artificial stone and preparation method |
| CN107512870B (en) * | 2017-09-21 | 2019-12-31 | 佛山市欧泊石业有限公司 | Environment-friendly light building decoration artificial stone and preparation method thereof |
| CN109279816A (en) * | 2018-10-26 | 2019-01-29 | 广东博瑞格新材料科技股份有限公司 | A kind of natural reticulate pattern hilllock stone and preparation method thereof |
| CN111393136A (en) * | 2020-03-25 | 2020-07-10 | 山东天马泰山机械集团有限公司 | Artificial stone and preparation method thereof |
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Application publication date: 20151216 |
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