CN105118600A - Magnetic powder alloy material - Google Patents
Magnetic powder alloy material Download PDFInfo
- Publication number
- CN105118600A CN105118600A CN201510566984.4A CN201510566984A CN105118600A CN 105118600 A CN105118600 A CN 105118600A CN 201510566984 A CN201510566984 A CN 201510566984A CN 105118600 A CN105118600 A CN 105118600A
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- China
- Prior art keywords
- percent
- alloy material
- magnetic powder
- magnetic
- vanadium
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- 239000000956 alloy Substances 0.000 title claims abstract description 16
- 239000006247 magnetic powder Substances 0.000 title claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 11
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 11
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 239000011733 molybdenum Substances 0.000 claims abstract description 7
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 7
- 239000010955 niobium Substances 0.000 claims abstract description 7
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910052742 iron Inorganic materials 0.000 claims abstract description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 4
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 4
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 239000010703 silicon Substances 0.000 claims abstract description 4
- 239000010936 titanium Substances 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 8
- 229910001004 magnetic alloy Inorganic materials 0.000 claims description 3
- 239000000696 magnetic material Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000005347 demagnetization Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
Landscapes
- Soft Magnetic Materials (AREA)
Abstract
The invention relates to a magnetic powder alloy material, which is the basic material of FEC0MSiBTi, wherein each of constituted components comprises by atom percent (at %): 20 to 25 percent of cobalt, 3 to 5 percent of M, 8 to 12 percent of silicon, 10 to 15 percent of boron, 1 to 3 percent of titanium, 1 to 3 percent of scandium and 1 to 3 percent of ruthenium, and the rest percent is iron and few amount of inevitable impurities; the combination is M copper and one or more of niobium, molybdenum, vanadium, and zirconium.
Description
Technical field
The invention belongs to field of functional materials, refer to a kind of magnetic powder alloy material especially.
Background technology
In prior art, magnetic material particularly magnetic material is used as producing high frequency transformer, magnetic head etc. and needs to utilize the product of magnetic material properties.Magnetic material refers to that the magnetic material with demagnetization performance compared by same permanent magnetic material.The now production of main magnetic material is prepared with Ferrite Material substantially, and the key property of this kind of Ferrite Material is the advantages such as resistivity is high, and high frequency eddy current losses is little.But the saturation induction density of magnetic product prepared by this material is on the low side, temperature characterisitic is poor, only can be used in temperature lower than the scope of 100 DEG C, when temperature exceedes this scope, its performance even magnetic that sharply declines disappears, and therefore this kind of material is not suitable for the application under hot conditions.
In metal smelt process, through melting, cooling, the processes such as reprocessing, complex procedures, and all need to consume the generation that a large amount of energy also has pernicious gas in each operation, technology has now been had to adopt alloy powder die casting mode to produce alloy product, passable like this
Summary of the invention
The object of the invention is by improvements over the prior art, also can improve the demagnetization performance of this kind of magnetic material in the temperature characterisitic and storage magnetic property that ensure magnetic material.
The present invention is achieved by the following technical solutions:
A kind of magnetic powder alloy material, described magnetic alloy material is FeCOMSiBTi base material, each composition composition comprising by atomic percentage conc (at%): the cobalt of 20-25, the silicon of the M of 3-5,8-12, the boron of 10-15, the titanium of 1-3, the scandium of 1-3%, the ruthenium of 1-3%, all the other are iron and a small amount of inevitably impurity; Described M is one or more combination in copper and niobium, molybdenum, vanadium, zirconium.
The atomic percentage conc (at%) of described copper is 0.8-1.2; The atomic percentage conc (at%) of one or more combination in described niobium, molybdenum, vanadium, zirconium is 3-5.
Further improvement, described M is the combination of copper and vanadium.
The invention has the beneficial effects as follows:
Compared with the existing technology, this magnetic material alloy has good hot properties and storage magnetic property, is the preferred magnetic material for making magnetic head.
Further improvement, described M is the combination of copper and vanadium.
Embodiment
Below in conjunction with specific embodiment so that the present invention is described in detail, select many group embodiments also by drawing the performance of each component to the detection of each embodiment in this application.6 groups of embodiments are selected in this application altogether.
A kind of magnetic powder alloy material, described magnetic alloy material is FeCOMSiBTi base material, each composition composition comprising by atomic percentage conc (at%): the cobalt of 20-25, the silicon of the M of 3-5,8-12, the boron of 10-15, the titanium of 1-3, the scandium of 1-3%, the ruthenium of 1-3%, all the other are iron and a small amount of inevitably impurity; One or more combination in described M copper and niobium, molybdenum, vanadium, zirconium.
The atomic percentage conc (at%) of described copper is 0.8-1.2; The atomic percentage conc (at%) of one or more combination in described niobium, molybdenum, vanadium, zirconium is 3-5.
Described M is the combination of copper and vanadium.
The preparation of embodiment carries out melting in vaccum sensitive stove, is first evacuated to 10 by stove
-3more than Pa; then be filled with 1 atmospheric argon gas, melting is in employing argon shield and is cast into alloy base substrate after sufficient electromagnetic agitation, then is carried out according to need by base substrate being processed into semi-finished product; again through 500-520 DEG C and the insulation annealing of 30 minutes, then to product test.
The testing experiment of product
The measurement of magnetic permeability Bs (T) is 10 in vacuum degree
-3carry out in Pa vacuum furnace, metering system employing heating rate is that the linear temperature increase of 3.5 DEG C/min is measured.Through measuring, the technical program has good temperature characterisitic.
The concrete composition of embodiment 1-6 is in table 1
Composition (table 1) the unit atomic percent at% of various embodiments of the present invention
Can be shown by above measurement result, technical scheme of the present invention is similar with the performance of the magnetic material rolling up cobalt content in prior art, but cost reduces in a large number.
Claims (3)
1. a magnetic powder alloy material, it is characterized in that: described magnetic alloy material is FeCOMSiBTi base material, each composition composition comprising by atomic percentage conc (at%): the cobalt of 20-25, the silicon of the M of 3-5,8-12, the boron of 10-15, the titanium of 1-3, the scandium of 1-3%, the ruthenium of 1-3%, all the other are iron and a small amount of inevitably impurity; One or more combination in described M copper and niobium, molybdenum, vanadium, zirconium.
2. magnetic powder alloy material according to claim 1, is characterized in that: the atomic percentage conc (at%) of described copper is 0.8-1.2; The atomic percentage conc (at%) of one or more combination in described niobium, molybdenum, vanadium, zirconium is 3-5.
3. magnetic powder alloy material according to claim 1, is characterized in that: described M is the combination of copper and vanadium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510566984.4A CN105118600A (en) | 2015-09-08 | 2015-09-08 | Magnetic powder alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510566984.4A CN105118600A (en) | 2015-09-08 | 2015-09-08 | Magnetic powder alloy material |
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| Publication Number | Publication Date |
|---|---|
| CN105118600A true CN105118600A (en) | 2015-12-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510566984.4A Pending CN105118600A (en) | 2015-09-08 | 2015-09-08 | Magnetic powder alloy material |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105244132A (en) * | 2015-11-03 | 2016-01-13 | 顾建 | Weakly-magnetic alloy material |
| CN106409460A (en) * | 2016-08-22 | 2017-02-15 | 吴雅萍 | Magnetically soft alloy |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102867604A (en) * | 2012-09-10 | 2013-01-09 | 任静儿 | Magnetically soft alloy |
| CN103123842A (en) * | 2012-10-22 | 2013-05-29 | 虞海香 | Magnetic powdered alloy material |
| CN103123841A (en) * | 2012-09-10 | 2013-05-29 | 顾建 | Magnetic alloy material |
| CN103540872A (en) * | 2007-03-20 | 2014-01-29 | Nec东金株式会社 | Soft magnetic alloy, magnetic component using the same, and their production methods |
-
2015
- 2015-09-08 CN CN201510566984.4A patent/CN105118600A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103540872A (en) * | 2007-03-20 | 2014-01-29 | Nec东金株式会社 | Soft magnetic alloy, magnetic component using the same, and their production methods |
| CN102867604A (en) * | 2012-09-10 | 2013-01-09 | 任静儿 | Magnetically soft alloy |
| CN103123841A (en) * | 2012-09-10 | 2013-05-29 | 顾建 | Magnetic alloy material |
| CN103123842A (en) * | 2012-10-22 | 2013-05-29 | 虞海香 | Magnetic powdered alloy material |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105244132A (en) * | 2015-11-03 | 2016-01-13 | 顾建 | Weakly-magnetic alloy material |
| CN106409460A (en) * | 2016-08-22 | 2017-02-15 | 吴雅萍 | Magnetically soft alloy |
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