CN105105387B - Moisture absorption ultra-fine fiber leather and manufacturing method thereof - Google Patents
Moisture absorption ultra-fine fiber leather and manufacturing method thereof Download PDFInfo
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- CN105105387B CN105105387B CN201510581793.5A CN201510581793A CN105105387B CN 105105387 B CN105105387 B CN 105105387B CN 201510581793 A CN201510581793 A CN 201510581793A CN 105105387 B CN105105387 B CN 105105387B
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Abstract
The invention relates to the field of materials for clothing and discloses moisture absorption ultra-fine fiber leather. The moisture absorption ultra-fine fiber leather comprises a dyeing layer, a composite film, a base layer and an anti-wrinkle net layer, wherein the upper surface of the dyeing layer is coated with the composite film, the base layer is arranged on the lower surface of the dyeing layer, and the anti-wrinkle net layer is arranged on the lower surface of the base layer. The dyeing layer is made of micro-fiber materials. The anti-wrinkle net layer is a reticulate body woven from PTT fibers. The invention further discloses a manufacturing method of the ultra-fine fiber leather. The ultra-fine fiber leather has the windproof performance, moisture permeability, waterproof performance, oil-dirt resistance and warmth retention performance and excellent chemical resistance and low temperature resistance, and the peel strength, moisture permeability and elastic recovery rate of the ultra-fine fiber leather are all high. The ultra-fine fiber leather can be effectively recovered from wrinkles through the anti-wrinkle net layer; the dyeing layer is arranged, so that only the dyeing layer needs to be dyed in the dyeing process, dyeing cost is reduced, resources are saved, and the dyeing layer made of ultra-fine fiber materials is not likely to fade.
Description
Technical field
The present invention relates to dress material field, more particularly to a kind of moisture absorption superfiber leather and its manufacture method.
Background technology
At present, the existing dress material for making medicated clothing mainly goes to attract the eyeball of consumer with the durable and outward appearance of dress material,
And dress material major part is monolayer, for example, monolayer dress material is made by textile material, the monolayer dress material by made by polyester fiber material.
These dress materials all have certain feature performance benefit, while also having certain performance deficiency.For example, although textile dress material has very
Strong moisture absorption sweat discharging functions, but its crease resistance is poor.With the increasingly raising of people's living standard, requirement of the people to dress material
More and more higher, it is attractive in appearance not require nothing more than outward appearance, and moisture absorption air permeable effect will be got well, moreover it is possible to heat-insulated, insulation, has functions that beauty
Etc. function.For example：
Existing dress material air permeable effect is poor, wears uncomfortable defect, and people are when motion, easily a large amount of to perspire, if
Perspiration cannot be discharged in time, and people can be allowed to feel sultry uncomfortable, affect sense comfortable and easy to wear.Thicker dress material is overall when dyeing
Dyeing, dyeing is high pollution, very high energy consumption industry, water wasting, waste of resource, improves production cost；After dyeing, dress material easily fades；Clothing
Material does not possess the characteristic such as Water-proof and oil-proof, crease-resistant, and easy crumple reduces the service life of dress material, especially corresponds to used in curtain, sand
The dress material of issue.The dress material having in addition can coat one layer of polyurethane coating, easily occur blister phenomenon when coating, affect clothing
The quality of material.
The content of the invention
The present invention is for disadvantages mentioned above in prior art, there is provided one kind is provided with dye layer, grease proofing, crease-resistant, be difficult to fade
Moisture absorption superfiber leather and its manufacture method.
In order to solve above-mentioned technical problem, the present invention is addressed by following technical proposals：
Moisture absorption superfiber leather, including dye layer, be coated in the composite membrane of dye layer upper surface, be arranged on dye layer following table
The basic unit in face, the crease-resistant stratum reticulare for being arranged on basic unit's lower surface, composite membrane coat a strata using in PolytetrafluoroethylFilm Film
Urethane film is made；Dye layer lower surface coats one layer of water repellent layer, and dye layer is made using woven fabric material, and crease-resistant stratum reticulare is that PTT is fine
The reticulate body that dimension is made into, the mesh size of crease-resistant stratum reticulare is 4-6mm.
Preferably, dye layer upper surface is uneven, dye layer upper surface is provided with groove, the cross section face of groove bottom
Cross-sectional area of the product more than groove top.
Preferably, basic unit is formed by weaving using spandex yarn, spandex yarn forms some coils in lower surface, and two or more connects
Continuous coil forms a salient point.
The manufacture method of moisture absorption superfiber leather, comprises the following steps：
A. dye layer is dyeed in staining machine；
B. dewatering process is carried out to dye layer；
C. carry out silicone oil to dye layer after being dehydrated to wash；
D. dried after silicone oil is washed；
E. the method in dye layer lower surface roll marks coats one layer of drying agent solution, then is dried, and forms water repellent layer；
F. the making of composite membrane：
1）By politef adhesive coated in dye layer upper surface, politef adhesive is in dye layer upper surface
Form polytetrafluoroethylene film；
2）The polyurethane of solid-state and dimethyl formamide solution mixed dissolution are formed into adhesive for polyurethane, solution containing solid
Amount is between 18%-20%；
3）Using dry fabrication composite membrane：The polyurethane adhesive scraper got ready is applied directly to into politef thin
On film；
4）Composite membrane is placed in baking oven to evaporate the solvent on adhesive for polyurethane；
G. the preparation of basic unit：Basic unit is formed by weaving using spandex yarn, and spandex yarn forms some coils in lower surface, two with
Upper continuous coil forms a salient point；
H. the mixing liquid of antistatic oil preparation is sprayed in basic unit by spray pattern, balances 12h or 24h or 36h；
I. dye layer is fitted in into basic unit's upper surface by the way of wet method laminating；
J. the preparation of crease-resistant stratum reticulare：Reticulate body is made into using ptt fiber；And crease-resistant stratum reticulare is bonded in into basic unit's lower surface,
Salient point in basic unit is exposed outside by mesh.
Preferably, in step f 4）, concrete mode is as follows：First heated up with the programming rate of 2 DEG C/min, evaporated
Fall some impurity solvents, baking 5-15min is persistently incubated when the boiling point of secondary solvent is warmed up to, is continued with the liter of 2 DEG C/min afterwards
Warm speed heats up, and is finally persistently incubated at 150 DEG C and dries 20-60min.
Preferably, step i dye layer lower surface sprays one layer of tack coat, dye layer lower surface is fitted with tack coat, base
Layer upper surface is fitted with tack coat, and during laminating, temperature is 150 DEG C -170 DEG C, forms gapless laminating, and with the speed of 5m/min
Operation, adopt low-pressure and dye layer and basic unit dipped for 2.5t, after respectively through 105 DEG C -110 DEG C, 110 DEG C -115 DEG C, 115
DEG C -120 DEG C, 120 DEG C -125 DEG C, 125 DEG C -130 DEG C, 130 DEG C -135 DEG C, 135 DEG C -140 DEG C of temperature section progressively dried,
The holdup time in each stage is 2-15min.
Preferably, toward in staining machine adding CD-1000N to carry out moisture absorbable and breathable finishing to dye layer after the dyeing of step a.
Preferably, hydrophilic softener is added during silicone oil is washed in step c, its consumption compares 0.5%- for weight
1.5%。
Preferably, in step f 2）, dimethyl formamide solution is the primary solvent for dissolving polyurethane, can be added auxiliary
Cosolvent, secondary solvent is acetone, the secondary solvent that butanone, ethyl acetate, toluene are mixed to form, primary solvent and secondary solvent
Mass ratio be 3:2.
The present invention as a result of above technical scheme, with significant technique effect：It is provided with using in politef
Film surface coats composite membrane made by one layer of polyurethane film, polytetrafluoroethylene film have Radix Saposhnikoviae, moisture-inhibiting, Water-proof and oil-proof it is dirty,
Thermal property and excellent chemical resistance and resistance to low temperature, and polyurethane film improves what polytetrafluoroethylene film was lacked
Elasticity, the peel strength of composite membrane, poisture-penetrability, elastic recovery rate are higher；Ptt fiber antifouling property is good, and high resilience has
Excellent elongation is restorative（Elongation 20% can still recover its original length）, superfiber leather is recovered from fold；
Dye layer is provided with, therefore only dye layer need to be dyeed when dyeing, reduced dyeing cost, economize on resources,
Dye layer made by super-fine fiber material is difficult to fade.
Description of the drawings
Fig. 1 is the simple schematic diagram of fragmentary longitudinal section structure for amplifying of the embodiment of the present invention 1.
Fig. 2 is the enlarged drawing of basic unit.
Fig. 3 is the enlarged drawing of crease-resistant stratum reticulare.
In the accompanying drawing toponym referred to by each number designation is as follows：Wherein 1-dye layer, 2-composite membrane, 3-basic unit,
4-crease-resistant stratum reticulare, 5-groove, 6-coil, 7-salient point, 8-tack coat, 9-mesh, 10-water repellent layer.
Specific embodiment
The present invention is described in further detail with embodiment below in conjunction with the accompanying drawings.
Embodiment 1
Moisture absorption superfiber leather, as shown in Figure 1 to Figure 3, including dye layer 1, is coated in the composite membrane of 1 upper surface of dye layer
2nd, the crease-resistant stratum reticulare 4 for being arranged on 3 lower surface of basic unit, composite membrane 2 is using in polytetrafluoro for the basic unit 3 for being arranged on 1 lower surface of dye layer
Ethylene (PTFE) film surface coats strata urethane (PU) film and makes.1 lower surface of dye layer coats one layer of water repellent layer 10.Dyeing
Layer 1 is made using woven fabric material, and 1 upper surface of dye layer is uneven, and 1 upper surface of dye layer is provided with groove 5,5 bottom of groove
Cross-sectional area of the cross-sectional area more than 5 top of groove.Basic unit 3 is formed by weaving using spandex yarn, and spandex yarn is in lower surface shape
Into some coils 6, the continuous coil 6 of two or more forms a salient point 7；It is viscous by tack coat 8 between basic unit 3 and dye layer 1
Knot.
Using dye layer 1 made by super-fine fiber material, with advantages below：Easy cleaning, super-fine fiber material is dirt
It is adsorbed between fiber, fibre number is high in addition, density is big, therefore high adsorption capacity, clear water or slightly need to be used using rear
Detergent is cleaned；Do not fade：Make which not bring the trouble of pollution of decolourizing when superfiber leather surface is cleaned completely；It is long
Life-span：Superfine fibre intensity is big, and toughness is strong, still invariance after repeatedly washing, and the not dry in the sun even with after also will not be mouldy, rotten
It is rotten, with extra long life；Tear-resistant, wearability, tension intensity etc. preferably, resist cold, acidproof；Light weight, flexible, breathable are good,
Smooth and soft handle；With antibacterial, mould proof, mothproof characteristic.
The reticulate body that crease-resistant stratum reticulare 4 is made into for ptt fiber, 9 size of mesh of crease-resistant stratum reticulare 4 is 2-6mm, ptt fiber tool
There is excellent elongation restorative, the size of mesh 9 can effectively recover folded region, in the present embodiment, crease-resistant stratum reticulare for 2-6mm
49 size of mesh is 4mm.Salient point 7 is superfiber leather body, is changed in the past using rubber matrix, Maifanitum filling etc.
Grain material salient point 7 pro-skin comfortableness, ruggedness the problems such as.The setting of salient point 7 so that contact of the skin with superfiber leather
Area is little, and the surface area of the whole moisture evaporation on superfiber leather is significantly expanded, and has spread the rapid evaporation of moisture,
Evaporate so as to quickly derive sweat so that dry and comfortable inside superfiber leather, its moisture pick-up properties preferably, make human body and clothing it
Between micro climate remain comfortable.
Embodiment 2
The manufacture method of moisture absorption superfiber leather, comprises the following steps：
A. dye layer 1 is dyeed；
Dyeing is entered water and is in charge of at normal temperatures using the O-shaped low tension type dyeing machine of Italy Ba Zuoni environmental protection, staining machine
Enter cloth, and add CD-1000N, which is stirred and issued automatic feeding system in staining machine pair cylinder, which is pumped into dyeing automatically
In machine, the pH value in staining machine is controlled between 3 and 6；Then technological parameter is input in computer system：Tension force 20N, rotating speed
150m/min, nozzle exit pressure 0.21MP/cm2, main pump rotating speed 1005r/min, bath raio 1:5,98 DEG C of pre-treatment temperature, programming rate
For 2 DEG C/min, temperature retention time 20min；Room temperature is cooled to the speed of 1.5 DEG C/min afterwards, is washed 2 times, and is added CD-1000N；
50 DEG C of post-processing temperature, temperature retention time 20min are being warming up to the speed of 2 DEG C/min.In computer system input process above ginseng
Number, computer automatically form technology establishment.Computer is set as automatically, whole process operation be automatically brought into operation after the completion of by go out cloth.
Wherein, when dye layer 1 carries out moisture absorbable and breathable finishing using CD-1000N after dyeing, pH value is controlled between 3 and 6.
Temperature control during arrangement is most important, slow during intensification（2℃/min）Control lower temperature is reacted, in case
The unstable precipitation of CD-1000N.
B. dewatering process is carried out after washing；
It is dehydrated using centrifuge, is dehydrated parameter：Rotating speed 500r/min, working time 5min.
C. carry out silicone oil to dye layer 1 after being dehydrated to wash；
Silicone oil adds hydrophilic softener during washing, and its consumption compares 0.5%-1.5% for weight.In the present embodiment,
The consumption of hydrophilic softener compares 1% for weight.
D. dried after silicone oil is washed, drying time is 2h-4h, and drying temperature is 110 DEG C -130 DEG C；In the present embodiment
In, drying time is 3h, and drying temperature is 120 DEG C；
E. heat treatment is carried out to dye layer 1 after drying；
Setting process is to be managed using Korea and heat setting machine, technological parameter：Frame amplitude 155cm, 160 DEG C of temperature, machine speed
30r/min, nip pressure 2.5t, overfeeding 28, cabinet air quantity：Windward 500r/min, leeward 800r/min；Operation：Entering cloth
Roll is turned down pressure and dips 1 surface of dye layer for 2.5t；160 DEG C of setting control computer box temperature；Adjustment overfeeding 28；Dye layer
1 passes through forming machine with the cloth machine speed that enters of 30m/min, goes out cloth measurement cloth fabric width 155cm.
Using CD-1000N as nanometer finishing agent, and by controlling nano finishing technical matters main points, and in silicone oil
Middle addition hydrophilic softener is washed, soft warm property, moisture absorbing and sweat releasing and the frivolous heat-preserving function of superfiber leather is enhanced, which is fixed
Ability is higher.
F. the method in 1 lower surface roll marks of dye layer coats one layer of drying agent solution, then is dried, and forms water repellent layer
10；
Due to there is water repellent layer 10, the surface tension of 1 lower surface of dye layer is which reduced, checked capillary effect and pressure differential
Formation, make shipwreck to enter from 1 lower surface of dye layer so that the exchange of the water in the follow-up solvent when composite membrane 2 is coated
Only carry out in 1 upper surface of dye layer, it is to avoid the generation of blister, it is ensured that the quality of composite membrane 2, and the setting of water repellent layer 10
So that dye layer 1 has certain moisture protection.
G. the making of composite membrane 2：
1）On dye layer 1 by politef adhesive coated after being shaped, part politef adhesive
Penetrate into groove 5 and be full of groove 5, politef adhesive forms polytetrafluoroethylene film in 1 upper surface of dye layer；
Politef adhesive adopts normal temperature cure, that is, after being coated in dye layer 1, be placed at a temperature of 15 DEG C -32 DEG C
10h, or 5h or 24h, it would however also be possible to employ the mode of drying is carried out.After the solidification of politef adhesive, in groove 5
Politef with 1 surface of dye layer politef be integral type structure, so as to polytetrafluoroethylene film is arranged
It is on dye layer 1, difficult for drop-off.
2）By the polyurethane of solid-state and dimethyl formamide solution mixed dissolution, the solid content of solution is between 18%-20%；
In the present embodiment, by polyurethane formulations into the polyurethane adhesive that solid content is 18%, it is also possible to which it is 20% to make solid content
Polyurethane adhesive makes the polyurethane adhesive that solid content is 19%.
Dimethyl formamide solution is the primary solvent for dissolving polyurethane, can add secondary solvent, secondary solvent be acetone,
The mass ratio of the secondary solvent that butanone, ethyl acetate, toluene are mixed to form, primary solvent and secondary solvent is 3:2.
Polyurethane is real in dimethyl formamide solution to be dissolved, and polyurethane chain is in curly wherein, and interchain can
Can mutually wind, there is the dynamic balancing of " winding and unwrapping " state, with the reduction of concentration, the winding of interchain is progressively opened；
It is clearly as the winding of interchain, exacerbates the viscosity of solution, unfavorable to film, thus from solution solid content in 18%-20%
Between.
3）Using dry fabrication composite membrane 2：The polyurethane adhesive scraper got ready is applied directly to into politef
On thin film；
4）Composite membrane 2 is placed in baking oven to evaporate the solvent on adhesive for polyurethane；
Concrete mode is as follows：First heated up with the programming rate of 2 DEG C/min, evaporated some impurity solvents, heated up
To secondary solvent boiling point when be persistently incubated baking 10min, continue to heat up with the programming rate of 2 DEG C/min, finally continue at 150 DEG C
30min is dried in insulation.
H. the preparation of basic unit 3：Basic unit 3 is formed by weaving using spandex yarn, and spandex yarn forms some coils 6 in lower surface, and two
More than individual, continuous coil 6 forms a salient point 7；
I. the mixing liquid of antistatic oil preparation is sprayed in basic unit 3 by spray pattern, balances 24h, it is also possible to balance
12h or 36h；
J. dye layer 1 is fitted in into 3 upper surface of basic unit by the way of wet method laminating；
Concrete operations are as follows：1 lower surface of dye layer sprays one layer of tack coat 8, and 1 lower surface of dye layer is fitted with tack coat 8,
3 upper surface of basic unit is fitted with tack coat 8, and during laminating, temperature is 150 DEG C -170 DEG C, forms gapless laminating, and with 5m/min's
Speed run, adopt low-pressure and dye layer 1 and basic unit 3 dipped for 2.5t, after respectively through 105 DEG C -110 DEG C, 110 DEG C -115
DEG C, 115 DEG C -120 DEG C, 120 DEG C -125 DEG C, 125 DEG C -130 DEG C, 130 DEG C -135 DEG C, 135 DEG C -140 DEG C of temperature section carry out by
Step drying, the holdup time in each stage is 5min.
Tack coat 8 is mainly made up of primary raw material of vinylacetate, acrylate, ethylene etc., using EVA application formula
Form, with binding speed it is fast, original viscosity is good, bonding force is strong, film formation at low temp performance is good.
K. it is placed in room temperature after drying to be conserved, curing time is at least 24h；
L. the preparation of crease-resistant stratum reticulare 4：Reticulate body is made into using ptt fiber, 9 size of mesh of crease-resistant stratum reticulare 4 is 2-6mm,
In the present embodiment, the size of mesh 9 is 4mm；And crease-resistant stratum reticulare 4 is bonded in into 3 lower surface of basic unit, the salient point 7 in basic unit 3 leads to
Cross mesh 9 exposed outside.
In a word, presently preferred embodiments of the present invention, all equalizations made according to scope of the present invention patent be the foregoing is only
Change and modification, should all belong to the covering scope of patent of the present invention.
Claims (7)
1. moisture absorption superfiber leather, it is characterised in that：Including dye layer（1）, be coated in dye layer（1）The composite membrane of upper surface
（2）, be arranged on dye layer（1）The basic unit of lower surface（3）, be arranged on basic unit（3）The crease-resistant stratum reticulare of lower surface（4）, composite membrane（2）
Made using one layer of polyurethane film is coated in PolytetrafluoroethylFilm Film；Dye layer（1）Lower surface coats one layer of water repellent layer
（10）, dye layer（1）Made using woven fabric material, crease-resistant stratum reticulare（4）For the reticulate body that ptt fiber is made into, crease-resistant stratum reticulare（4）'s
Mesh（9）Size is 4-6mm, dye layer（1）Upper surface is provided with groove（5）, groove（5）The cross-sectional area of bottom is more than groove
（5）The cross-sectional area on top, basic unit（3）It is formed by weaving using spandex yarn, spandex yarn forms some coils in lower surface（6）,
The continuous coil of two or more（6）Form a salient point（7）.
2. it is used for preparing the manufacture method of the moisture absorption superfiber leather in claim 1, it is characterised in that comprise the following steps：
A. to dye layer in staining machine（1）Dyeed；
B. to dye layer（1）Carry out dewatering process；
C. to dye layer after being dehydrated（1）Carry out silicone oil to wash；
D. dried after silicone oil is washed；
E. in dye layer（1）The method of lower surface roll marks coats one layer of drying agent solution, then is dried, and forms water repellent layer
（10）；
F. composite membrane（2）Making：
1）By politef adhesive coated in dye layer（1）Upper surface, politef adhesive is in dye layer（1）Upper table
Face forms polytetrafluoroethylene film；
2）The polyurethane of solid-state is formed into adhesive for polyurethane with dimethyl formamide solution mixed dissolution, the solid content of solution exists
Between 18%-20%；
3）Using dry fabrication composite membrane（2）：The polyurethane adhesive scraper got ready is applied directly to into politef thin
On film；
4）By composite membrane（2）It is placed in baking oven to evaporate the solvent on adhesive for polyurethane；
G. basic unit（3）Preparation：Basic unit（3）It is formed by weaving using spandex yarn, spandex yarn forms some coils in lower surface（6）,
The continuous coil of two or more（6）Form a salient point（7）；
H. the mixing liquid of antistatic oil preparation is sprayed in basic unit by spray pattern, balances 12h or 24h or 36h；
I. by dye layer by the way of wet method laminating（1）It is fitted in basic unit（3）Upper surface；
J. crease-resistant stratum reticulare（4）Preparation：Reticulate body is made into using ptt fiber；And by crease-resistant stratum reticulare（4）It is bonded in basic unit（3）Under
Surface, basic unit（3）On salient point（7）By mesh（9）It is exposed outside.
3. the manufacture method of moisture absorption superfiber leather according to claim 2, it is characterised in that：In step f 4）, specifically
Mode is as follows：First heated up with the programming rate of 2 DEG C/min, evaporate some impurity solvents, be warmed up to secondary solvent
Baking 5-15min is persistently incubated during boiling point, continues afterwards to heat up with the programming rate of 2 DEG C/min, finally in 150 DEG C of persistently insulation bakings
20-60min。
4. the manufacture method of moisture absorption superfiber leather according to claim 2, it is characterised in that：In step i, dye layer
（1）Lower surface sprays one layer of tack coat（8）, dye layer（1）Lower surface and tack coat（8）Laminating, basic unit（3）Upper surface and bonding
Layer（8）Laminating, during laminating, temperature is 150 DEG C -170 DEG C, forms gapless laminating, and is run with the speed of 5m/min, using low
Pressure dips dye layer for 2.5t（1）And basic unit（3）, after respectively through 105 DEG C -110 DEG C, 110 DEG C -115 DEG C, 115 DEG C -120
DEG C, 120 DEG C -125 DEG C, 125 DEG C -130 DEG C, 130 DEG C -135 DEG C, 135 DEG C -140 DEG C of temperature section progressively dried, each rank
The holdup time of section is 2-15min.
5. the manufacture method of moisture absorption superfiber leather according to claim 2, it is characterised in that：Toward dye after the dyeing of step a
CD-1000N is added in color machine to dye layer（1）Carry out moisture absorbable and breathable finishing.
6. the manufacture method of moisture absorption superfiber leather according to claim 2, it is characterised in that：In step c, silicone oil is washed
During add hydrophilic softener, its consumption compares 0.5%-1.5% for weight.
7. the manufacture method of moisture absorption superfiber leather according to claim 2, it is characterised in that：In step f 2）, diformazan
Base formamide solution be dissolve polyurethane primary solvent, add secondary solvent, secondary solvent be acetone, butanone, ethyl acetate,
The mass ratio of the secondary solvent that toluene is mixed to form, primary solvent and secondary solvent is 3:2.
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| JP4402153B1 (en) * | 2008-11-19 | 2010-01-20 | ハニー化成株式会社 | Aqueous matte surface treating agent composition and polyvinyl chloride resin product having coating layer thereof |
| CN103009741A (en) * | 2011-09-21 | 2013-04-03 | 昆山华富合成皮革有限公司 | Polyurethane composite film |
| CN203188024U (en) * | 2013-03-12 | 2013-09-11 | 天守(福建)超纤科技股份有限公司 | Abrasion-resistant, waterproof and breathable leather |
| CN203923570U (en) * | 2013-12-10 | 2014-11-05 | 浙江航艇针织有限公司 | The woven cloth of pro-skin, band heating massage convex point |
| CN103741350B (en) * | 2014-01-20 | 2015-07-29 | 浙江航艇针织有限公司 | A kind of massage convex point braided fabric of pro-skin and weaving process thereof |
| CN203844360U (en) * | 2014-04-14 | 2014-09-24 | 天守(福建)超纤科技股份有限公司 | Anti-fouling and anti-wrinkle fabric |
| CN104708878B (en) * | 2015-02-25 | 2017-03-08 | 昆山华阳新材料股份有限公司 | The composite microporous thin film of high resiliency double-component |
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