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CN105104375A - Glycerine-containing herbicidal composition - Google Patents

Glycerine-containing herbicidal composition Download PDF

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Publication number
CN105104375A
CN105104375A CN201510498485.6A CN201510498485A CN105104375A CN 105104375 A CN105104375 A CN 105104375A CN 201510498485 A CN201510498485 A CN 201510498485A CN 105104375 A CN105104375 A CN 105104375A
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Prior art keywords
oil
glycerine
grams
ester
glyphosate
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CN201510498485.6A
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CN105104375B (en
Inventor
王成
宋妍
许兴志
韦能春
赵艳龙
吴磊
岳秀利
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Shandong Jingbo Agrochemical Technology Co ltd
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Jingbo Agrochemicals Technology Co Ltd
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Abstract

The present invention relates to the field of application of agricultural herbicides, in particular to glycerine-containing herbicidal composition and a preparation method. The glycerine-containing herbicidal composition comprises the following main components in percentage by mass: 8-97% of glycerine, 2-60% of a herbicide A, 0.1-20% of a surfactant, and 0.5-30% of a filler B. According to the glycerine-containing herbicidal composition, the application amount of pesticides is reduced while the prevention effect is improved; the national future pesticide reduction application requirements are met; and harms of the herbicide to the environment are reduced.

Description

A kind of glycerinated Herbicidal combinations
Technical field
The invention belongs to pesticide herbicide application, relate to a kind of glycerinated Herbicidal combinations, prevent and treat for weeds cauline leaf.
Background technology
Between weed killer herbicide different cultivars, mixture is to improve control efficiency and expanding prevention collection of illustrative plates, has a lot of patent and report, improves control efficiency be also all in daily use by different surfaces activating agent; Reduce pesticide dosage in current country, reduce pollutant and use, background under, how adopting clean nontoxic material to improve control efficiency has become the problem of pendulum in face of everybody, and this is also the certainty of Future Social Development.
Summary of the invention
The present invention provides a kind of novel high-efficiency environment friendly type weed killer herbicide according to Problems Existing, is used for improving control of weeds effect, reduces the using, to adapt to national development demand of dosage and other harmful substance.
To achieve these goals, the technical solution used in the present invention is as follows:
Containing a Herbicidal combinations for glycerine synergist, its raw material composition is counted by mass fraction:
Glycerine 8 ~ 97%, weed killer herbicide A2 ~ 60%, surfactant 0.1 ~ 20%, filler B0.5 ~ 30%.
As technique scheme further preferably, described Herbicidal combination raw material composition is counted by mass fraction:
Glycerine 30 ~ 90%, weed killer herbicide A2 ~ 60%, surfactant 0.1 ~ 20%, filler B0.5 ~ 30%.
Glycerine makes again glycerine be that odorless, has warm sweet taste without color and taste sweet clear and bright thick liquid, relative density: 1.26362, boiling point: 290.0 DEG C, the content of the present invention's glycerine used is 90 ~ 98.5%, be a kind of nontoxic material good with Environmental compatibility, moisture can be absorbed from air.Because its height boils and moisture absorption performance, make liquid on blade, have better moisture retention with mixture of herbicides, to carry absorbing of agricultural chemicals.
Described weed killer herbicide A is selected from one or more in following material: bentazone, the acid of chlorine Fampridine, glyphosate, ammonium glyphosate, glyphosate isopropyl amine salt, glyphosate potassium, sodium glyphosate, grass ammonium phosphine, fomesafen, diquat, imazapyr, 2 first 4 chlorine sodium, acifluorfen, ametryn, iodosulfuron-methyl-sodium, mesotrione, prometryn, thifensulfuronmethyl, clopyralid, nicosulfuron, atrazine, Pendimethalin, S-metolachlor, Quizalotop-ethyl, sethoxydim, Acetochlor, fluoroglycofen-ethyl, fluroxypyr, fluroxypyr ester, florasulam, flucarbazone, mesosulfuron, pyrrole grass ether, flumioxazin, azoles humulone, azoles quinoline grass ester, Flumetsulam, diflufenican, single phonetic sulphur ester, fluorine pyrazosulfuron, clodinafop-propargyl, the different monooctyl ester of methoxone, flufenacet, fluorine chloropyridine ester, pyridine sulphur grass amine, pyrrole penoxsulam, flurtamone, azoles quinoline grass ester, oxadiargyl, two careless ether, metamifop, KIH 6127, mefenacet, pyribenzoxim, cyhalofop-butyl, pyrazosulfuron, penoxsuam, S-metolachlor, benzene azoles humulone, amicarbazone, halosulfuronmethyl, 2,4 d butyl esters.
Described filler B is selected from: one or more in water, soya-bean oil, corn oil, methyl oleate, rapeseed oil, turpentine oil, waste oil, aromatic hydrocarbon solvent, mineral oil, diesel oil, machine oil, sec-butyl acetate, solvent naphtha, the following monohydric alcohol of 10 carbon or polyalcohol.The effect of these fillers is mainly used for adjusting product content.
Described surfactant is selected from anion surfactant, cationic surfactant, non-ionic surface active agent, anion surfactant has the fatty acid salts such as alkylbenzenesulfonate, lignin sulfonate, alkyl sulfate, Alkyl ethoxy carboxylate acid salt, also has one or more in phosphate ester salt, sulfosuccinate ester salt, naphthalene sulfonate, polycarboxylate, sulfonate and formaldehyde condensation product etc.; Cationic surfactant has amine salt, quaternary amine, amine oxide etc.; Amphoteric surfactant has one or more in betain, imidazoline type, Amino acid, phosphine ester etc.; Non-ionic surface active agent has the aliphatic alcohol esters such as fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, OPEO, alkylamine oxygen vinethene, special phenethyl phenol polyethenoxy ether, phenethyl phenol mela mine-formaldehyde resin APEO, tallow amine APEO, polyol ester; Also have fatty acid alkane ester, alkylamide etc.; Also has the mixed surfactant of alcohol ether type
The formulation that described composition can be processed into has: aqua, missible oil, micro emulsion, water and milk, suspending agent (water is outstanding, oil is outstanding, hang breast) and soluble liquid, preparation method is prepared according to the common process of each formulation, needs to add some auxiliary addition agents during preparation.
Selected auxiliary addition agent has: the organobentonite in thickener, xanthans, aluminium-magnesium silicate, sodium carboxymethyl starch, cellulose attapulgite.Emulsifier refers to wherein can accept surfactant.Other auxiliary agent such as cosolvent has acetone, N methyl pyrrolidone, DMF, cyclohexanone, DMSO, different fluorine that ketone, toluene, dimethylbenzene, solvent naphtha.
Select glycerine and above-mentioned each weed killer herbicide and additive compound to use, improve effective absorption of agricultural chemicals, good synergistic effect is played to the control of grass blade leaf.
The invention has the beneficial effects as follows: Herbicidal combinations provided by the invention is for cauline leaf process management of weeds of spraying, in formula, add glycerine in a large number, utilize the moisture absorption performance of keeping humidity of glycerine to soak to absorb thus play in despot's target and reduce dosage to improve effective ingredient and improve the effect of control efficiency.Reduce dosage and improve control efficiency, adapt to national requirements for environmental protection, meet the following policy requirements reducing Pesticide use amount of country.
Embodiment
Further illustrate the present invention below in conjunction with embodiment, those skilled in the art can be made more fully to understand the present invention, but do not limit the present invention in any way.
Embodiment 1
Mass fraction is the glyphosate isopropylamine salt water solution of 41%, and its formula composition is for 100 grams of samples:
Glyphosate isopropyl amine salt 41 grams, tallow amine APEO 1 gram, glycerine 50 grams, water supplements 100 grams.
Preparation method: according to above-mentioned consumption, after glyphosate isopropyl amine salt, glycerine, tallow amine APEO, water are mixed 15 minutes, obtains filtrate after filtration, is finished product.
The gyphosate solution sample prepared by which and commercial available quality mark 41% glyphosate isopropylamine salt water solution carry out reed comparative trial, and experimental result is in table 1:
Table 1
Sample Mu consumption gram/acre 10 days preventive effects 15 days preventive effects 20 days preventive effects
Commercially available glyphosate isopropylamine salt water solution 200 60% 85% 92%
Embodiment 1 sample 150 70% 90% 95%
Can be found out by table 1: said composition is after the consumption of reduction by 25%, and control efficiency is also good than control sample, particularly in quick-acting, plays good synergistic effect.
Embodiment 2
Concentration is the careless ammonium phosphine aqua of 200 grams per liters, and formula composition is for 100 grams of samples:
Grass ammonium phosphine 20 grams, glycerine 55 grams, water supplement 100 grams.
Preparation method: according to above-mentioned consumption, by after soluble in water for careless ammonium phosphine, after glycerol adding mixes 15 minutes, after filtration filtrate, be finished product.
Carry out eleusine indica preventive effect comparative trial with the careless ammonium phosphine aqua aqua of the concentration of which preparation to be the careless ammonium phosphine water sample of 200 grams per liters and commercial concentration be 200 grams per liters, result of the test is in table 2:
Table 2
Sample Mu consumption gram/acre 3 days preventive effects 5 days preventive effects 7 days preventive effects
Commercially available 200 grams per liter grass ammonium phosphine aquas 200 61% 86% 93%
Embodiment 2 sample 160 72% 88% 95%
Can be found out by table 2: said composition is after the consumption reducing careless ammonium phosphine effective ingredient 20%, and control efficiency is also good than control sample, particularly in quick-acting, plays good synergistic effect.
Embodiment 3
Mass fraction is the nicosulfuron oil suspending agent of 4%, and formula composition is for 100 grams of samples:
Nicosulfuron 4 grams, calcium dodecyl benzene sulfonate 5 grams, OPEO 3 grams, mela mine-formaldehyde resin APEO 2 grams, special phenethyl phenol APEO 1 gram, organobentonite 1.5 grams, glycerine 60 grams, methyl oleate supplements 100 grams.
Preparation method: according to above-mentioned consumption, sucks each liquid material in still and adds solid material after mixing, shears grinding after mixing in 1 hour, detects qualifiedly to get final product packing and obtain finished product.
Carry out lady's-grass preventive effect comparative trial with outstanding oily the hanging of nicosulfuron being 4% with commercial available quality mark of nicosulfuron oil that the mass fraction which is prepared is 4%, test situation is in table 3:
Table 3
Sample Mu consumption gram/acre 7 days preventive effects 10 days preventive effects 15 days preventive effects
Commercially available nicosulfuron oil is outstanding 90 52% 79% 91%
Embodiment 3 sample 70 59% 85% 95%
Can find out that said composition is after the consumption reducing nicosulfuron 30% by test, control efficiency is also good than control sample, particularly in quick-acting.
Embodiment 4
Mass fraction is the Quizalotop-ethyl missible oil of 5%, and formula composition is for 100 grams of samples:
Quizalotop-ethyl 5 grams, calcium dodecyl benzene sulfonate 4 grams, OPEO 4 grams, fatty alcohol-polyoxyethylene ether 3 grams, special phenethyl phenol APEO 1 gram, glycerine 40 grams, N methyl pyrrolidone 10 grams, 5 grams, acetone, C10 solvent naphtha supplement 100 grams.
Preparation method: according to above-mentioned consumption, sucks each liquid material in still and adds solid material after mixing, stirs after within 1 hour, dissolving, and detects qualifiedly to get final product packing and obtain finished product.
The 5% Quizalotop-ethyl missible oil prepared by which and commercially available 5% Quizalotop-ethyl missible oil carry out green foxtail preventive effect comparative trial, and test situation is in table 4:
Table 4
Sample Mu consumption gram/acre 7 days preventive effects 10 days preventive effects 15 days preventive effects
Commercially available 40% nicosulfuron oil is outstanding 80 51% 78% 90%
Embodiment 4 sample 60 61% 84% 95%
Can find out that said composition is after the consumption reducing Quizalotop-ethyl 20% by test, control efficiency is also good than control sample, particularly in quick-acting.
Embodiment 5
Mass fraction be 15% mesotrione water hang, formula composition for 100 grams of samples:
Mesotrione 15 grams, calcium dodecyl benzene sulfonate 1 gram, OPEO 1 gram, special phenethyl phenol APEO 1 gram, naphthalenesulfonatedispersant dispersant 1 gram, xanthans 0.1 gram, aluminium-magnesium silicate 1 gram, glycerine 40 grams, water supplement 100 grams.
Preparation method: according to above-mentioned consumption, sucks each liquid material in still and adds solid material after mixing, shears grinding after mixing in 1 hour, detects qualifiedly to get final product packing and obtain finished product.
With the mesotrione water that the mass fraction of which preparation is 15% hang with commercial available quality mark be 15% mesotrione water outstanding carry out barnyard grass preventive effect comparative trial, test situation is in table 5:
Table 5
Sample Mu consumption gram/acre 3 days preventive effects 5 days preventive effects 7 days preventive effects
Commercially available 15% mesotrione hangs 100 42% 77% 88%
Embodiment 5 sample 70 51% 84% 94%
Can find out that said composition is after the consumption reducing mesotrione effective ingredient 30% by test, control efficiency is also good than control sample, particularly in quick-acting.
Embodiment 6
Mass fraction is the different monooctyl ester water and milk of fluroxypyr of 20%, formula composition is for 100 grams of samples: the different monooctyl ester of fluroxypyr 20 grams, and dimethylbenzene 25 grams, OPEO 1 gram, mela mine-formaldehyde resin APEO 1 gram, xanthans 0.03 gram, glycerine 30 grams, water supplement 100 grams.
Preparation method: according to above-mentioned consumption, first use the different monooctyl ester of xylene soluble fluroxypyr, emulsifier OPEO, mela mine-formaldehyde resin APEO is added after dissolving completely, glycerine and xanthans is added after mixing, water is added under shearing condition, shear 60 minutes, detect qualified can packing obtain finished product.
The 20% fluroxypyr different monooctyl ester water and milk prepared by which and the different monooctyl ester water and milk of commercially available 20% fluroxypyr carry out field bindweed preventive effect comparative trial, and result of the test is in table 6:
Table 6
Sample Mu consumption gram/acre 5 days preventive effects 7 days preventive effects 10 days preventive effects
The different monooctyl ester water and milk of commercially available fluroxypyr 100 44% 79% 91%
Embodiment 6 sample 70 52% 81% 92%
Can find out that said composition is after the consumption reducing the different monooctyl ester effective ingredient 30% of fluroxypyr by test, control efficiency is also good than control sample, particularly in quick-acting.
Embodiment 7
Mass fraction is 30% 2,4 d butyl ester microemulsions, and formula composition is for 100 grams of samples:
2,4 d butyl esters 30 grams, dimethylbenzene 5 grams, calcium dodecyl benzene sulfonate 3 grams, OPEO 3 grams, mela mine-formaldehyde resin APEO 3 grams, glycerine 30 grams, N methyl pyrrolidone 5 grams, water supplement 100 grams.
Preparation method: according to above-mentioned consumption, first by 2, adds emulsifier OPEO, mela mine-formaldehyde resin APEO and glycerine after the mixing of 4 d butyl esters, dimethylbenzene, N methyl pyrrolidone, adds water after again mixing, then shear 60 minutes; Detect qualified can packing obtain finished product.
Be 30% 2,4 d butyl ester micro emulsions and commercial available quality mark be that 30% 2,4 d butyl ester missible oil carry out clearvers preventive effect comparative trial with the mass fraction of which preparation, result of the test is in table 7:
Table 7
Sample Mu consumption gram/acre 10 days preventive effects 15 days preventive effects 20 days preventive effects
Commercially available 30%%2,4 d butyl ester missible oil 100 43% 80% 90%
Embodiment 7 sample 80 57% 82% 93.1%
Can find out that said composition is after the consumption of reduction by 2,4 d butyl ester effective ingredient 20% by test, control efficiency is also good than control sample, particularly in quick-acting.
Embodiment 8
Mass fraction is the fomesafen soluble liquor of 10%, and formula composition is for 100 grams of samples:
Fomesafen 10 grams, dimethylbenzene 5 grams, triethylamine 1.5 grams, calcium dodecyl benzene sulfonate 1 gram, OPEO 2 grams, mela mine-formaldehyde resin APEO 1 gram, glycerine 50 grams, N methyl pyrrolidone 10 grams, acetone supplement 100 grams.
Preparation method: according to above-mentioned consumption, first adds fomesafen, dimethylbenzene, N methyl pyrrolidone, acetone in still and adds triethylamine again after mixing, add emulsifier and glycerine again after stirring and dissolving, and mixing detects and qualifiedly packing can obtain finished product.
With which preparation mass fraction be 10% fomesafen soluble concentrate and commercial available quality mark be that 10% Fluosulfonamide oxalether cream carries out acalypha copperleaf preventive effect comparative trial, result of the test is in table 8:
Table 8
Sample Mu consumption gram/acre 3 days preventive effects 5 days preventive effects 7 days preventive effects
Commercially available 10% Fluosulfonamide oxalether cream 80 62% 85% 93%
Embodiment 8 sample 60 67% 89% 95%
Can find out that said composition is after the consumption reducing fomesafen effective ingredient 25% by test, control efficiency is also good than control sample, particularly in quick-acting.
By above-described embodiment can illustrate in formula, add glycerine after can reduce dosage improve preventive effect, adapt to national pesticide reduction requirement.

Claims (5)

1. a glycerinated Herbicidal combinations, is characterized in that:
Raw material Main Ingredients and Appearance is counted by mass fraction:
Glycerine 8 ~ 97%, weed killer herbicide A2 ~ 60%, surfactant 0.1 ~ 20%, filler B0.5 ~ 30%;
The formulation that composition can be processed into has: aqua or missible oil or micro emulsion or water and milk or suspending agent or soluble liquid.
2. Herbicidal combinations according to claim 1, is characterized in that:
Raw material Main Ingredients and Appearance is counted by mass fraction:
Glycerine 30 ~ 90%, weed killer herbicide A2 ~ 60%, surfactant 0.1 ~ 20%, filler B0.5 ~ 30%.
3. Herbicidal combinations according to claim 1, is characterized in that: weed killer herbicide A is selected from one or more in following material: bentazone, the acid of chlorine Fampridine, glyphosate, ammonium glyphosate, glyphosate isopropyl amine salt, glyphosate potassium, sodium glyphosate, grass ammonium phosphine, fomesafen, diquat, imazapyr, 2 first 4 chlorine sodium, acifluorfen, ametryn, iodosulfuron-methyl-sodium, mesotrione, prometryn, thifensulfuronmethyl, clopyralid, nicosulfuron, atrazine, Pendimethalin, S-metolachlor, Quizalotop-ethyl, sethoxydim, Acetochlor, fluoroglycofen-ethyl, fluroxypyr, fluroxypyr ester, florasulam, flucarbazone, mesosulfuron, pyrrole grass ether, flumioxazin, azoles humulone, azoles quinoline grass ester, Flumetsulam, diflufenican, single phonetic sulphur ester, fluorine pyrazosulfuron, clodinafop-propargyl, the different monooctyl ester of methoxone, flufenacet, fluorine chloropyridine ester, pyridine sulphur grass amine, pyrrole penoxsulam, flurtamone, azoles quinoline grass ester, oxadiargyl, two careless ether, metamifop, KIH 6127, mefenacet, pyribenzoxim, cyhalofop-butyl, pyrazosulfuron, penoxsuam, S-metolachlor, benzene azoles humulone, amicarbazone, halosulfuronmethyl.
4. Herbicidal combinations according to claim 1, is characterized in that: filler B is selected from: one or more in water, soya-bean oil, corn oil, methyl oleate, rapeseed oil, turpentine oil, waste oil, aromatic hydrocarbon solvent, mineral oil, diesel oil, machine oil, sec-butyl acetate, solvent naphtha, the following monohydric alcohol of 10 carbon or polyalcohol.
5. Herbicidal combinations according to claim 1, is characterized in that: when formulation is suspending agent, is selected from outstanding or the oily outstanding or outstanding breast of water.
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CN105432633A (en) * 2015-12-18 2016-03-30 广东中迅农科股份有限公司 Rice-field weeding composition containing florasulam and cyhalofop-butyl
CN105432634A (en) * 2015-12-18 2016-03-30 广东中迅农科股份有限公司 Pesticide composition containing florasulam and pyriminobac-methyl
CN105475351A (en) * 2015-12-24 2016-04-13 安徽美兰农业发展股份有限公司 Glyphosate, clodinafop-propargyl and fluoroglycofen-ethyl compound wettable powder and preparation method thereof
CN105638673A (en) * 2016-03-21 2016-06-08 湖南农大海特农化有限公司 Weeding composition containing pyribenzoxim and fluroxypyr
CN105794835A (en) * 2016-03-31 2016-07-27 太仓市新进农场专业合作社 Agricultural seedbed herbicide and using method thereof
CN106305752A (en) * 2016-08-23 2017-01-11 安徽久易农业股份有限公司 Herbicide composition containing halauxifen-methyl and nicosulfuron
CN106376587A (en) * 2016-08-29 2017-02-08 广东中迅农科股份有限公司 Weeding composition for sugarcane field
CN106472515A (en) * 2016-10-13 2017-03-08 广东中迅农科股份有限公司 Herbicidal combinations containing bispyribac-sodium
CN106538559A (en) * 2016-10-31 2017-03-29 广东中迅农科股份有限公司 A kind of Herbicidal combinations containing topramezone and pyroxsulam
CN106538595A (en) * 2016-11-08 2017-03-29 青岛瀚生生物科技股份有限公司 The herbicidal composition of Glufosinate-ammoniumpesticideng, mesotrione and azoles humulone and its application
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CN106689147A (en) * 2017-03-06 2017-05-24 江苏莱科化学有限公司 Halauxifen-methyl/flufenacet-containing weedicide composition
CN106719759A (en) * 2017-01-16 2017-05-31 成都邦农化学有限公司 Smoke of gunpowder isopropyl first composition and its production technology
CN106942254A (en) * 2017-03-31 2017-07-14 山东滨农科技有限公司 A kind of herbicidal composition containing mesosulfuron
CN107279170A (en) * 2017-06-23 2017-10-24 北京科发伟业农药技术中心 The Herbicidal combinations of flufenacet, flucarbazone and amicarbazone
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CN108402063A (en) * 2018-03-27 2018-08-17 安徽圣丰生化有限公司 A kind of herbicide containing halosulfuronmethyl
CN108849870A (en) * 2018-06-22 2018-11-23 河北威远生物化工有限公司 Bentazone and florasulam Synergistic herbicide compositions and its dispersible oil-suspending agent
CN109221244A (en) * 2018-10-21 2019-01-18 江苏长青生物科技有限公司 Glufosinate-ammonium and the micro emulsion herbicide of fluoroglycofen-ethyl component and preparation method thereof
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Publication number Priority date Publication date Assignee Title
CN105432633A (en) * 2015-12-18 2016-03-30 广东中迅农科股份有限公司 Rice-field weeding composition containing florasulam and cyhalofop-butyl
CN105432634A (en) * 2015-12-18 2016-03-30 广东中迅农科股份有限公司 Pesticide composition containing florasulam and pyriminobac-methyl
CN105475351A (en) * 2015-12-24 2016-04-13 安徽美兰农业发展股份有限公司 Glyphosate, clodinafop-propargyl and fluoroglycofen-ethyl compound wettable powder and preparation method thereof
CN105638673A (en) * 2016-03-21 2016-06-08 湖南农大海特农化有限公司 Weeding composition containing pyribenzoxim and fluroxypyr
CN105794835A (en) * 2016-03-31 2016-07-27 太仓市新进农场专业合作社 Agricultural seedbed herbicide and using method thereof
WO2018028324A1 (en) * 2016-08-08 2018-02-15 江苏辉丰农化股份有限公司 Weeding composition having synergistic effects
CN106305752A (en) * 2016-08-23 2017-01-11 安徽久易农业股份有限公司 Herbicide composition containing halauxifen-methyl and nicosulfuron
CN106376587A (en) * 2016-08-29 2017-02-08 广东中迅农科股份有限公司 Weeding composition for sugarcane field
CN106472515A (en) * 2016-10-13 2017-03-08 广东中迅农科股份有限公司 Herbicidal combinations containing bispyribac-sodium
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