CN105086045A - Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor - Google Patents
Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000005260 corrosion Methods 0.000 title claims abstract description 12
- 230000007797 corrosion Effects 0.000 title abstract description 3
- 230000003064 anti-oxidating effect Effects 0.000 title abstract 2
- -1 polyethylene Polymers 0.000 claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 15
- 229920000573 polyethylene Polymers 0.000 claims abstract description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004698 Polyethylene Substances 0.000 claims abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000012188 paraffin wax Substances 0.000 claims abstract description 8
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 5
- 239000004203 carnauba wax Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 230000000694 effects Effects 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 6
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 229960002447 thiram Drugs 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000000748 compression moulding Methods 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- 238000000967 suction filtration Methods 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- APIRFTQFMATPRA-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol octadecanamide Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)N.OCC(CO)(CO)CO APIRFTQFMATPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 239000006247 magnetic powder Substances 0.000 abstract 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract 1
- 238000004891 communication Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- CXURGFRDGROIKG-UHFFFAOYSA-N 3,3-bis(chloromethyl)oxetane Chemical compound ClCC1(CCl)COC1 CXURGFRDGROIKG-UHFFFAOYSA-N 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an antioxidation corrosion-resistant cable material with a shielding action and a preparation method therefor. The cable material is characterized by being prepared from the following raw materials in parts by weight: 90-100 parts of polyethylene, 10-15 parts of red phosphorus, 3-5 parts of paraffin, 0.5-1 part of silane coupling agent kh570, 15-25 parts of nano calcium carbonate, 0.8-1.6 parts of polyvinyl alcohol, 2-4 parts of copper powder, 5-8 parts of polystyrene resin, 1-3 parts of zinc borate, 5-10 parts of pentaerythritol stearic amide, 1-2 parts of methyl thiuram disulfide, 3-5 parts of palm wax, 3-5 parts of carbonyl magnetic powder and a proper amount of anhydrous ethanol. The cable material is simple in preparation method, wide in material source and little in environmental pollution, is suitable for large-scale production and is worthy of popularization.
Description
Technical field
The present invention relates to cable material field, particularly relate to a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof.
Background technology
Communication, electric power are the development in the emphasis of nation-building, whichever place, and communication, power construction are always leading, so communication, electric utility development are very fast.The development of communication, electric utility, working in coordination of all respects is wanted in spontaneous combustion, wherein CABLE MATERIALS is exactly an aspect, general electric wire is coating expects mainly plastics casing rubber, as long as electric wire thermoplastics has polyvinyl chloride, polyethylene, polypropylene, fluoroplastics, penton and polymeric amide, wherein widely used is polyethylene and polyvinyl chloride.In China's polyvinyl chloride cable material development comparatively early, kind model is more, for the manufacture of wire cable insulating and the sheath of various temperature classification.Because density of pe is little, electrical property is excellent, be easy to forming process.Polyethylene is the large kind of one in thermoplastics, there is the features such as light weight, nontoxic, chemical resistance is excellent, but poly oxygen index is very low, belong to inflammable material, polyethylene can produce serious melting drippage behavior when burning, this brings very large difficulty to flame retardant resistance, except inflammable, poly volume specific resistance and surface resistivity are very high, this just makes it once bring electrostatic to be just difficult to eliminate in processing and use procedure, and two above shortcomings bring very large potential safety hazard and reduce use range to poly use.Red phosphorus is the efficient flame-retarding agent of the superpolymer such as plastics, rubber, resin and synthon, and red phosphorus itself is inflammable, badly influences the flame retardant effect of red phosphorus.Calcium carbonate filling modification high density polyethylene(HDPE), research emphasis comparatively early concentrates on and how to realize filling to greatest extent, reduce costs, although improve the rigidity of material, but intensity and the fracture toughness property of material is greatly reduced, and be not suitable for carrying high density polyethylene(HDPE) sheath material, the present invention adopts special process modified nano calcium carbonate to not only improve filler dispersion effect in the base and enhances the two cohesive strength, improve intensity and the toughness of polythene material, enhance bearing capacity greatly, mechanical property is improved greatly.
Summary of the invention
The object of this invention is to provide a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, is made up of the raw material of following weight part: polyethylene 90-100, red phosphorus 10-15, paraffin 3-5, silane coupling agent kh5700.5-1, nano-calcium carbonate 15-25, polyvinyl alcohol 0.8-1.6, copper powder 2-4, polystyrene resin 5-8, zinc borate 1-3, tetramethylolmethane hard esteramides 5-10, curing methyl thiuram 1-2, palm wax 3-5, carbonyl magnetic 3-5, dehydrated alcohol are appropriate;
A kind of antioxygen anti-corrosion cable material with shielding effect of the present invention and preparation method thereof, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 70-90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.5-1h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, raised temperature stirs to during 50-60 ° of C again, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 160-170 ° of C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
Advantage of the present invention is: the present invention adopts silane coupler modified nano-calcium carbonate, calcium carbonate surface is made to have certain hydrophobicity, enhance the consistency in polyethylene and dispersiveness, and add in modifying process copper powder adhere to its surface, improve poly antistatic property, by the coated polystyrene resin of red phosphorus and paraffin combination cooling rear surface, solve the problem that red phosphorus is inflammable, greatly improve flame retardant properties, and do not affect poly physical and mechanical property, during fire-retardant product burning, the amount of being fuming is low, no asphyxia gas is released, health environment-friendly, the curing methyl thiuram added, palm wax and carbonyl magnetic interact, greatly improve the antioxygen protection against corrosion of CABLE MATERIALS and the effect of electromagnetic radiation shielding, great minimizing radiation is on the interference between the impact of environment and cable, ensure the normal of signal, preparation method of the present invention is simple, material source is extensive, environmental pollution is little, suitable for mass production, be worthy to be popularized.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, is made up of the raw material of following weight part (kilogram): polyethylene 100, red phosphorus 13, paraffin 4, silane coupling agent kh5700.8, nano-calcium carbonate 21, polyvinyl alcohol 0.8, copper powder 3, polystyrene resin 7, zinc borate 2, the hard esteramides of tetramethylolmethane 8, curing methyl thiuram 1, palm wax 4, carbonyl magnetic 5, dehydrated alcohol are appropriate;
A kind of antioxygen anti-corrosion cable material with shielding effect of the present invention and preparation method thereof, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.7h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, then stir during raised temperature to 50 ° C, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 170 ° C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
Produce polythene material according to embodiment preparation, performance index are as follows: tensile strength >=15MPa, tensile strength >=30MPa, dielectric strength >=32MV/m, fracture extension rate >=310%, elongation at break velocity of variation 12%, oxygen index >=30%.
Claims (2)
1. antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, it is characterized in that, be made up of the raw material of following weight part: polyethylene 90-100, red phosphorus 10-15, paraffin 3-5, silane coupling agent kh5700.5-1, nano-calcium carbonate 15-25, polyvinyl alcohol 0.8-1.6, copper powder 2-4, polystyrene resin 5-8, zinc borate 1-3, tetramethylolmethane hard esteramides 5-10, curing methyl thiuram 1-2, palm wax 3-5, carbonyl magnetic 3-5, dehydrated alcohol are appropriate.
2. a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof according to claim 1, is characterized in that, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 70-90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.5-1h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, raised temperature stirs to during 50-60 ° of C again, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 160-170 ° of C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
Priority Applications (1)
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CN201510442321.1A CN105086045A (en) | 2015-07-27 | 2015-07-27 | Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor |
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CN201510442321.1A CN105086045A (en) | 2015-07-27 | 2015-07-27 | Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105655000A (en) * | 2016-01-15 | 2016-06-08 | 熊小辉 | Double-core electric power wire |
CN105679432A (en) * | 2016-02-02 | 2016-06-15 | 安徽万博电缆材料有限公司 | High-performance cable added with hydroxyl methyl fatty amine |
CN105694256A (en) * | 2016-02-02 | 2016-06-22 | 安徽幸福电器电缆有限公司 | Magnetic shielding cable |
CN106893313A (en) * | 2017-01-17 | 2017-06-27 | 江西伟普科技有限公司 | Nanometer multipolymer and preparation method for being molded magnetic material modification |
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CN103724777A (en) * | 2014-01-10 | 2014-04-16 | 安徽瑞升电气科技有限公司 | Low-smoke flame retardant polyethylene cable material |
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2015
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CN103724777A (en) * | 2014-01-10 | 2014-04-16 | 安徽瑞升电气科技有限公司 | Low-smoke flame retardant polyethylene cable material |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105655000A (en) * | 2016-01-15 | 2016-06-08 | 熊小辉 | Double-core electric power wire |
CN105679432A (en) * | 2016-02-02 | 2016-06-15 | 安徽万博电缆材料有限公司 | High-performance cable added with hydroxyl methyl fatty amine |
CN105694256A (en) * | 2016-02-02 | 2016-06-22 | 安徽幸福电器电缆有限公司 | Magnetic shielding cable |
CN106893313A (en) * | 2017-01-17 | 2017-06-27 | 江西伟普科技有限公司 | Nanometer multipolymer and preparation method for being molded magnetic material modification |
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