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CN105086045A - Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor - Google Patents

Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor Download PDF

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Publication number
CN105086045A
CN105086045A CN201510442321.1A CN201510442321A CN105086045A CN 105086045 A CN105086045 A CN 105086045A CN 201510442321 A CN201510442321 A CN 201510442321A CN 105086045 A CN105086045 A CN 105086045A
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parts
preparation
cable material
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CN201510442321.1A
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Inventor
尚广东
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HEFEISHI SHENZHAO ELECTRONIC Co Ltd
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HEFEISHI SHENZHAO ELECTRONIC Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/01Magnetic additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antioxidation corrosion-resistant cable material with a shielding action and a preparation method therefor. The cable material is characterized by being prepared from the following raw materials in parts by weight: 90-100 parts of polyethylene, 10-15 parts of red phosphorus, 3-5 parts of paraffin, 0.5-1 part of silane coupling agent kh570, 15-25 parts of nano calcium carbonate, 0.8-1.6 parts of polyvinyl alcohol, 2-4 parts of copper powder, 5-8 parts of polystyrene resin, 1-3 parts of zinc borate, 5-10 parts of pentaerythritol stearic amide, 1-2 parts of methyl thiuram disulfide, 3-5 parts of palm wax, 3-5 parts of carbonyl magnetic powder and a proper amount of anhydrous ethanol. The cable material is simple in preparation method, wide in material source and little in environmental pollution, is suitable for large-scale production and is worthy of popularization.

Description

A kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof
Technical field
The present invention relates to cable material field, particularly relate to a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof.
Background technology
Communication, electric power are the development in the emphasis of nation-building, whichever place, and communication, power construction are always leading, so communication, electric utility development are very fast.The development of communication, electric utility, working in coordination of all respects is wanted in spontaneous combustion, wherein CABLE MATERIALS is exactly an aspect, general electric wire is coating expects mainly plastics casing rubber, as long as electric wire thermoplastics has polyvinyl chloride, polyethylene, polypropylene, fluoroplastics, penton and polymeric amide, wherein widely used is polyethylene and polyvinyl chloride.In China's polyvinyl chloride cable material development comparatively early, kind model is more, for the manufacture of wire cable insulating and the sheath of various temperature classification.Because density of pe is little, electrical property is excellent, be easy to forming process.Polyethylene is the large kind of one in thermoplastics, there is the features such as light weight, nontoxic, chemical resistance is excellent, but poly oxygen index is very low, belong to inflammable material, polyethylene can produce serious melting drippage behavior when burning, this brings very large difficulty to flame retardant resistance, except inflammable, poly volume specific resistance and surface resistivity are very high, this just makes it once bring electrostatic to be just difficult to eliminate in processing and use procedure, and two above shortcomings bring very large potential safety hazard and reduce use range to poly use.Red phosphorus is the efficient flame-retarding agent of the superpolymer such as plastics, rubber, resin and synthon, and red phosphorus itself is inflammable, badly influences the flame retardant effect of red phosphorus.Calcium carbonate filling modification high density polyethylene(HDPE), research emphasis comparatively early concentrates on and how to realize filling to greatest extent, reduce costs, although improve the rigidity of material, but intensity and the fracture toughness property of material is greatly reduced, and be not suitable for carrying high density polyethylene(HDPE) sheath material, the present invention adopts special process modified nano calcium carbonate to not only improve filler dispersion effect in the base and enhances the two cohesive strength, improve intensity and the toughness of polythene material, enhance bearing capacity greatly, mechanical property is improved greatly.
Summary of the invention
The object of this invention is to provide a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, is made up of the raw material of following weight part: polyethylene 90-100, red phosphorus 10-15, paraffin 3-5, silane coupling agent kh5700.5-1, nano-calcium carbonate 15-25, polyvinyl alcohol 0.8-1.6, copper powder 2-4, polystyrene resin 5-8, zinc borate 1-3, tetramethylolmethane hard esteramides 5-10, curing methyl thiuram 1-2, palm wax 3-5, carbonyl magnetic 3-5, dehydrated alcohol are appropriate;
A kind of antioxygen anti-corrosion cable material with shielding effect of the present invention and preparation method thereof, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 70-90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.5-1h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, raised temperature stirs to during 50-60 ° of C again, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 160-170 ° of C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
Advantage of the present invention is: the present invention adopts silane coupler modified nano-calcium carbonate, calcium carbonate surface is made to have certain hydrophobicity, enhance the consistency in polyethylene and dispersiveness, and add in modifying process copper powder adhere to its surface, improve poly antistatic property, by the coated polystyrene resin of red phosphorus and paraffin combination cooling rear surface, solve the problem that red phosphorus is inflammable, greatly improve flame retardant properties, and do not affect poly physical and mechanical property, during fire-retardant product burning, the amount of being fuming is low, no asphyxia gas is released, health environment-friendly, the curing methyl thiuram added, palm wax and carbonyl magnetic interact, greatly improve the antioxygen protection against corrosion of CABLE MATERIALS and the effect of electromagnetic radiation shielding, great minimizing radiation is on the interference between the impact of environment and cable, ensure the normal of signal, preparation method of the present invention is simple, material source is extensive, environmental pollution is little, suitable for mass production, be worthy to be popularized.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, is made up of the raw material of following weight part (kilogram): polyethylene 100, red phosphorus 13, paraffin 4, silane coupling agent kh5700.8, nano-calcium carbonate 21, polyvinyl alcohol 0.8, copper powder 3, polystyrene resin 7, zinc borate 2, the hard esteramides of tetramethylolmethane 8, curing methyl thiuram 1, palm wax 4, carbonyl magnetic 5, dehydrated alcohol are appropriate;
A kind of antioxygen anti-corrosion cable material with shielding effect of the present invention and preparation method thereof, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.7h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, then stir during raised temperature to 50 ° C, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 170 ° C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
Produce polythene material according to embodiment preparation, performance index are as follows: tensile strength >=15MPa, tensile strength >=30MPa, dielectric strength >=32MV/m, fracture extension rate >=310%, elongation at break velocity of variation 12%, oxygen index >=30%.

Claims (2)

1. antioxygen anti-corrosion cable material with shielding effect and preparation method thereof, it is characterized in that, be made up of the raw material of following weight part: polyethylene 90-100, red phosphorus 10-15, paraffin 3-5, silane coupling agent kh5700.5-1, nano-calcium carbonate 15-25, polyvinyl alcohol 0.8-1.6, copper powder 2-4, polystyrene resin 5-8, zinc borate 1-3, tetramethylolmethane hard esteramides 5-10, curing methyl thiuram 1-2, palm wax 3-5, carbonyl magnetic 3-5, dehydrated alcohol are appropriate.
2. a kind of antioxygen anti-corrosion cable material with shielding effect and preparation method thereof according to claim 1, is characterized in that, be made up of following concrete steps:
(1) silane coupling agent kh570 is added to is placed in the flask of water-bath, add appropriate dehydrated alcohol and be slowly warming up to and dissolve completely, the nano-calcium carbonate adding oven dry again stirs, control temperature is within the scope of 70-90 ° of C, add polyvinyl alcohol, copper powder heated and stirred backflow 0.5-1h again, carry out repeatedly suction filtration after reaction terminates, alcohol wash circulation repeatedly, then is placed in baking oven and dries under 110 ° of C, grind for subsequent use;
(2) by red phosphorus and paraffin mixing, raised temperature stirs to during 50-60 ° of C again, be added in the polystyrene resin of melting after being cooled to rapidly room temperature, then add product mixing and stirring prepared by zinc borate and step (1) naturally cool to room temperature after for subsequent use;
(3) by open type plastic purificating set raised temperature to 160-170 ° of C, polyethylene, the hard esteramides of tetramethylolmethane are added to two roller intermediate melt and plasticate, material prepared by step (2) is added after it mixes, the two roller spacing of adjustment, roller refining, thin-pass repeatedly make the two mix, add all the other remaining materials again and continue mixing and stirring, after naturally cooling to room temperature, mixture is transferred to compression moulding under 180 ° of C in vulcanizing press.
CN201510442321.1A 2015-07-27 2015-07-27 Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor Pending CN105086045A (en)

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Application Number Priority Date Filing Date Title
CN201510442321.1A CN105086045A (en) 2015-07-27 2015-07-27 Antioxidation corrosion-resistant cable material with shielding action and preparation method therefor

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105655000A (en) * 2016-01-15 2016-06-08 熊小辉 Double-core electric power wire
CN105679432A (en) * 2016-02-02 2016-06-15 安徽万博电缆材料有限公司 High-performance cable added with hydroxyl methyl fatty amine
CN105694256A (en) * 2016-02-02 2016-06-22 安徽幸福电器电缆有限公司 Magnetic shielding cable
CN106893313A (en) * 2017-01-17 2017-06-27 江西伟普科技有限公司 Nanometer multipolymer and preparation method for being molded magnetic material modification

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509229A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 Irradiation crosslinking low-smoke halogen-free flame-retardant polyolefin cable material for photovoltaic cables
CN103724777A (en) * 2014-01-10 2014-04-16 安徽瑞升电气科技有限公司 Low-smoke flame retardant polyethylene cable material
CN104610634A (en) * 2015-01-15 2015-05-13 安徽科正新材料有限公司 Silane crosslinked-polyethylene insulation material adopting one-step method and preparation technology of silane crosslinked-polyethylene insulation material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103509229A (en) * 2013-10-12 2014-01-15 绿宝电缆(集团)有限公司 Irradiation crosslinking low-smoke halogen-free flame-retardant polyolefin cable material for photovoltaic cables
CN103724777A (en) * 2014-01-10 2014-04-16 安徽瑞升电气科技有限公司 Low-smoke flame retardant polyethylene cable material
CN104610634A (en) * 2015-01-15 2015-05-13 安徽科正新材料有限公司 Silane crosslinked-polyethylene insulation material adopting one-step method and preparation technology of silane crosslinked-polyethylene insulation material

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王大全、李凤生等: "《微纳米技术与精细化工》", 31 January 2009, 中国石化出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105655000A (en) * 2016-01-15 2016-06-08 熊小辉 Double-core electric power wire
CN105679432A (en) * 2016-02-02 2016-06-15 安徽万博电缆材料有限公司 High-performance cable added with hydroxyl methyl fatty amine
CN105694256A (en) * 2016-02-02 2016-06-22 安徽幸福电器电缆有限公司 Magnetic shielding cable
CN106893313A (en) * 2017-01-17 2017-06-27 江西伟普科技有限公司 Nanometer multipolymer and preparation method for being molded magnetic material modification

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Application publication date: 20151125

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