CN105084818A - Heat-preserving fireproof decorating wall material made of FBZ nanometer ceramics - Google Patents
Heat-preserving fireproof decorating wall material made of FBZ nanometer ceramics Download PDFInfo
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Abstract
The invention discloses a heat-preserving fireproof decorating wall material made of FBZ nanometer ceramics. The material is prepared from, by weight, 1-5 parts of floating beads, 5-10 parts of artificial vermiculite, 5-10 parts of brucite fibers, 10-30 parts of nanometer ceramic powder, 0-5 parts of color sand, 5-10 parts of brucite fibers, 5-10 parts of phenolic resin powder, 0.2-0.4 part of organic silicon water repellent powder, 1-5 parts of inorganic adhesive cement, 1-5 parts of loadable dispersity emulsion powder, 2-5 parts of hydroxy propyl cellulose, 2-5 parts of sodium alginate, 0.5-5 parts of chemical resistant modifiers, 2-6 parts of flame-retardant synergist and 5-10 parts of brominated flame retardant. The material prevents leakage, preserves heat, insulates the heat, saves energy, has weather resistance, fireproof performance and durability, and meets the requirement of a building for overall attractiveness.
Description
Technical field
The present invention relates to building material field, be specifically related to a kind of FBZ nano ceramics insulated fire decorating wall material.
Background technology
China's building energy conservation wall thermal insulation technology and applying of product are started in the latter stage eighties, mainly contain the inorganic heat insulation material such as perlite, composition silicate at that time.Within 1996, in order to accelerate Developing Energy-saving Construction, country has promulgated the energy conservation standard of energy-conservation 50%.Because inorganic heat insulation material thermal conductivity is high, constructing operation cannot ensure.And its poor thermal insulation property, the phenomenon such as fire retardant performance is good, hollowing, cracking come off.Therefore, the energy saving requirement of energy-conservation 50% cannot be met.Like this, organic polystyrene heat-preservation cystose enters energy-saving heat preserving market.Subsequently, the organic insulation material such as extruded sheet, polyurathamc enters application in succession.Within 2003, Minstry of Housing and Urban-Rural Development of People Republic of China (MOHURD) has formulated the standard-required of polystyrene foam plate, standard No. JG149-2003 " expansion polyphenyl Lamb wave plastering exterior wall outer heat preservation system ", within 2007, China Institute of Building Standard Design & Research has worked out (external wall outer insulation building structure atlas), within 2008, has worked out industry standard (external wall outer insulation engineering code) JGJ144-2008.
Go through for many years, expansion joints bellows external thermal insulation system, substantially occupy the market share in domestic external wall outer insulation market 80%.As time goes on, the use drawback of organic insulation material on buildings more and more highlights.In Beijing, Shanghai, the ground such as Shenyang, several the concrete on fire occurred due to organic heat-insulating plate.State ministry of public security has issued (public affairs disappear 2011) No. 65 files, wherein a regulation " covil construction external-wall heat-insulation material employing combustionproperty is the material of A level ".But the lagging material that lagging material can reach the A level of the power conservation requirement of 50% is very few.At present, the rock cotton board applied at home, apparent availability also with regard to 5% market.And the organic heat-insulating plate be quite received by the market, can make its heat-insulation system fire-retardant fireproof by adding fire retardant, when there being naked light, molten of organic insulation material, when temperature reaches more than 250 DEG C, still can burn on fire.And the drawback such as the supply of inorganic rock cotton board and construction and installation makes organic insulation material pass through to add fire retardant, become the main insulation supply product in lagging material market, still in a large amount of use.
Polyphenyl plate thin plastering exterior wall external insulation system, service condition of putting into practice through the several years shows, exterior insulation system for polyphenyl plate thin plastering exterior wall design Shortcomings, the thermal conductivity of polystyrene foam plate is 0.042W (M ° of K), and the thermal conductivity of outer anticracking grout is 0.93W (M ° of K), two material thermal conductivities differ 22 times, anticracking grout layer only after 3-5MM, heat not easily passs through conduction diffusion, accumulate in anticracking grout layer, surface temperature will up to 50 DEG C-70 DEG C, the highest withstand temp of styrofoam is 70 DEG C, can STRESS VARIATION be there is in polyphenyl plate heat preserving layer, shrinkage strain.Meet then surface temperature of raining suddenly and can sharply drop to about 15 DEG C, difference variation reaches 35-60 DEG C, in the course of time, spreads upon the outer finishing coat on anticracking grout layer, and continuous change also can occur for putty material, coating material, tile material stress.Between each material, interfacial layer is many, and stress relief is uneven, causes serious outer finishing coat craze and transfiguration.Crack generation can develop into be split larger and larger.Rainwater enters, and becomes a fine day temperature and raises, and water becomes again water vapour release.Crack is split larger and larger, produces the body of wall that leaks and goes mouldy.Winter due to the excellent heat-insulating property of heat-insulation system, and then extends the time of drying of the moisture infiltrated in thermal insulation layer, provides favourable life condition to mould.There is the phenomenon that condensation is mouldy in interior of building.Outer finishing coat peeling, come off, layering, have a strong impact on the attractive in appearance of buildings and security.
To sum up: a good exterior wall heat-preserving system, buildings must be met and possess insulation, heat-insulating and energy-saving, permanent work-ing life, complementing one another property between good load and each material forming exterior wall heat-preserving system, fire prevention, water leakage, weathering resistance, weather resistance and Wind-Pressure Resistance ability, the integrated beauty perception etc. of buildings.
Summary of the invention
The invention provides a kind of FBZ nano ceramics insulated fire decorating wall material, both antiseep, insulation, heat-insulating and energy-saving, had weathering resistance again, fire line, weather resistance, and the requirement meeting the overall aesthetics of buildings.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of FBZ nano ceramics insulated fire decorating wall material, is prepared from by the component of following weight part:
Float pearl 1-5 part, synthetic vermiculite 5-10 part, brucite fiber 5-10 part, nano-ceramic powder 10-30 part, colored sand 0-5 part, brucite fiber 5-10 part, Phenolic resin powder 5-10 part, organosilicon moisture repellent powder 0.2-0.4 part, inorganic adhesive cement 1-5 part, dispersed latex powder 1-5 part, hydroxypropylcellulose 2-5 part, sodium alginate 2-5 part, chemicals-resistant properties-correcting agent 0.5-5 part, fire retarding synergist 2-6 part, bromide fire retardant 5-10 part can be carried.
Preferably, described chemicals-resistant properties-correcting agent is fluorinated additive.
Preferably, described fluorinated additive is the acrylic acid series additive containing perfluoroalkyl.
Preferably, described fire retarding synergist is the one in zinc borate, antimonous oxide, antimony peroxide.
Preferably, described bromide fire retardant is the one in tetrabromo-bisphenol, ethylidene-(two tetrabromo phthalimide), brominated epoxy.
The present invention has following beneficial effect:
There is fire line, weathering resistance, weather resistance, overall aesthetics, insulation and thermal insulation, float pearl by inorganic heat insulation material, synthetic vermiculite, brucite fiber, nano ceramic powder solve thermal insulation layer and anticracking grout layer is too large because of thermal conductivity deviation, and the crack caused, layering, to come off, solve that outer finishing coat fades by colored sand, variable color, peeling, the problem that comes off, thermal insulation layer interface can be painted on during use, decrease material because of interfacial layer many, stress relief is uneven, and produce layering, obscission, make whole building effect consistent, improve its aesthetic appearance of buildings, by the use of nano ceramics, brucite fiber, Phenolic resin powder, fire retardant and fire retarding synergist, improve the fire resistance of material monolithic, by organosilicon moisture repellent powder, strengthen the water resistance of material, solve the Seepage that rainwater infiltrates buildings, by inorganic adhesive cement, dispersed latex powder can be carried, hydroxypropylcellulose, the use of sodium alginate, improve the weathering resistance of buildings, weather resistance, security, introduce the acrylic acid series additive of perfluoroalkyl as chemicals-resistant properties-correcting agent, the transport efficiency of this additive is high, surface can be moved to completely form a kind of protective membrane in the process that product is shaping, this layer of protective membrane is incompatible with water and have the performance of stronger acid and alkali-resistance, thus the material that with the addition of such additive run into exterior trim paint etc. comparatively deep-etching paint time, huge surface tension can be there is in surface, deep-etching paint is prevented to enter into material internal, can greatly reduce cracking situation, improve spraying yield.
Embodiment
In order to make objects and advantages of the present invention clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
In following examples, the chemicals-resistant properties-correcting agent used is the acrylic acid series additive containing perfluoroalkyl; Fire retarding synergist is the one in zinc borate, antimonous oxide, antimony peroxide; Bromide fire retardant is the one in tetrabromo-bisphenol, ethylidene-(two tetrabromo phthalimide), brominated epoxy.
Embodiment 1
A kind of FBZ nano ceramics insulated fire decorating wall material, is prepared from by the component of following weight part:
Float 1 part, pearl, synthetic vermiculite 5 parts, brucite fiber 5 parts, nano-ceramic powder 10 parts, brucite fiber 5 parts, Phenolic resin powder 5 parts, 0.2 part, organosilicon moisture repellent powder, inorganic adhesive cement 1 part, dispersed latex powder 1 part, hydroxypropylcellulose 2 parts, sodium alginate 2 parts, chemicals-resistant properties-correcting agent 0.5 part, fire retarding synergist 2 parts, bromide fire retardant 5 parts can be carried.
Embodiment 2
A kind of FBZ nano ceramics insulated fire decorating wall material, is prepared from by the component of following weight part:
Float 5 parts, pearl, synthetic vermiculite 10 parts, brucite fiber 10 parts, nano-ceramic powder 30 parts, colored sand 5 parts, brucite fiber 10 parts, Phenolic resin powder 10 parts, 0.4 part, organosilicon moisture repellent powder, inorganic adhesive cement 5 parts, dispersed latex powder 5 parts, hydroxypropylcellulose 5 parts, sodium alginate 5 parts, chemicals-resistant properties-correcting agent 5 parts, fire retarding synergist 6 parts, bromide fire retardant 10 parts can be carried.
Embodiment 3
A kind of FBZ nano ceramics insulated fire decorating wall material, is prepared from by the component of following weight part:
Float 3 parts, pearl, synthetic vermiculite 7.5 parts, brucite fiber 7.5 parts, nano-ceramic powder 20 parts, colored sand 2.5 parts, brucite fiber 7.5 parts, Phenolic resin powder 7.5 parts, 0.3 part, organosilicon moisture repellent powder, inorganic adhesive cement 3 parts, dispersed latex powder 3 parts, hydroxypropylcellulose 3.5 parts, sodium alginate 3.5 parts, chemicals-resistant properties-correcting agent 2.75 parts, fire retarding synergist 4 parts, bromide fire retardant 7.5 parts can be carried.
This is concrete when implementing to use, and is that the ratio of 1: 4 directly adds tap water and stirs by volume, then, is painted on thermal insulation layer, thickness 8-12 millimeter, after epidermis drying, and brushing epidermis gloss solidifying agent.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (5)
1. a FBZ nano ceramics insulated fire decorating wall material, is characterized in that, is prepared from by the component of following weight part:
Float pearl 1-5 part, synthetic vermiculite 5-10 part, brucite fiber 5-10 part, nano-ceramic powder 10-30 part, colored sand 0-5 part, brucite fiber 5-10 part, Phenolic resin powder 5-10 part, organosilicon moisture repellent powder 0.2-0.4 part, inorganic adhesive cement 1-5 part, dispersed latex powder 1-5 part, hydroxypropylcellulose 2-5 part, sodium alginate 2-5 part, chemicals-resistant properties-correcting agent 0.5-5 part, fire retarding synergist 2-6 part, bromide fire retardant 5-10 part can be carried.
2. a kind of FBZ nano ceramics insulated fire decorating wall material according to claim 1, it is characterized in that, described chemicals-resistant properties-correcting agent is fluorinated additive.
3. a kind of FBZ nano ceramics insulated fire decorating wall material according to claim 2, it is characterized in that, described fluorinated additive is the acrylic acid series additive containing perfluoroalkyl.
4. a kind of FBZ nano ceramics insulated fire decorating wall material according to claim 1, it is characterized in that, described fire retarding synergist is the one in zinc borate, antimonous oxide, antimony peroxide.
5. a kind of FBZ nano ceramics insulated fire decorating wall material according to claim 1, is characterized in that, described bromide fire retardant is the one in tetrabromo-bisphenol, ethylidene-(two tetrabromo phthalimide), brominated epoxy.
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Cited By (3)
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| CN104877249A (en) * | 2015-04-26 | 2015-09-02 | 吉林大学 | Dielectric microwave attenuation material and preparation method thereof |
| CN105565367A (en) * | 2016-01-25 | 2016-05-11 | 延安大学 | Preparation method of nanometer zinc oxide powder material |
| CN109554943A (en) * | 2018-12-30 | 2019-04-02 | 山东莱威新材料有限公司 | A kind of wear-resisting mine fireproof hawser and its processing method |
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| CN109554943A (en) * | 2018-12-30 | 2019-04-02 | 山东莱威新材料有限公司 | A kind of wear-resisting mine fireproof hawser and its processing method |
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Application publication date: 20151125 |