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CN105077029A - Dinner replacing powder containing zinc-rich barley grass and preparation method of dinner replacing powder - Google Patents

Dinner replacing powder containing zinc-rich barley grass and preparation method of dinner replacing powder Download PDF

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CN105077029A
CN105077029A CN201510561152.3A CN201510561152A CN105077029A CN 105077029 A CN105077029 A CN 105077029A CN 201510561152 A CN201510561152 A CN 201510561152A CN 105077029 A CN105077029 A CN 105077029A
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barley seedling
powder
dinner
fruit
zinc
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宋新华
郝凯
阎建华
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Shandong University of Technology
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G31/00Soilless cultivation, e.g. hydroponics
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

本发明涉及一种富锌大麦苗晚餐代餐粉及其制备方法,属于保健功能食品技术领域。所述晚餐代餐粉由以下质量百分数的原料制成:富锌大麦苗微粉20-50%,水果酵素粉10-20%,菌菇酵素粉2-8%,果蔬粉10-30%,大米粉10-25%,魔芋微粉3-8%,熟坚果碎3-10%。其制备方法是先将果蔬粉、菌菇酵素粉、水果酵素粉、富锌大麦苗微粉充分混匀,密封备用;再将大米粉、魔芋微粉和熟坚果碎充分混匀,经干燥、粉碎、过筛,取筛下物;最后将密封备用的混合物与筛下物充分混匀,经分装、灭菌后制得。本发明解决了现有大麦苗固体饮料口感粗糙、青草味重、冲调后迅速分层的问题,具有代餐减肥、调节肠胃机能、增强免疫力的功效,其制备方法简单易行,易于实现产业化。The invention relates to a zinc-rich barley seedling dinner meal replacement powder and a preparation method thereof, belonging to the technical field of health-care functional foods. The dinner meal replacement powder is made of the following raw materials in mass percentage: 20-50% of zinc-rich barley seedling powder, 10-20% of fruit enzyme powder, 2-8% of mushroom enzyme powder, 10-30% of fruit and vegetable powder, large Rice flour 10-25%, konjac powder 3-8%, cooked nuts 3-10%. The preparation method is as follows: fully mix fruit and vegetable powder, mushroom enzyme powder, fruit enzyme powder, and zinc-rich barley seedling micropowder, and seal it for later use; Sieve, and take the undersize; finally, fully mix the sealed mixture with the undersize, subpackage and sterilize. The invention solves the problems of the existing barley seedling solid drink with rough taste, heavy grass flavor and rapid stratification after brewing, and has the effects of meal replacement, weight loss, gastrointestinal function regulation, and immunity enhancement, and its preparation method is simple and easy to implement. industrialization.

Description

富锌大麦苗晚餐代餐粉及其制备方法Zinc-rich barley seedling dinner meal replacement powder and preparation method thereof

技术领域technical field

本发明涉及一种富锌大麦苗晚餐代餐粉及其制备方法,属于保健功能食品技术领域。The invention relates to a zinc-rich barley seedling dinner meal replacement powder and a preparation method thereof, belonging to the technical field of health-care functional foods.

背景技术Background technique

研究发现,大麦苗的营养价值远高于大麦籽粒,株高在10-20cm的大麦苗幼嫩茎叶含有非常丰富的叶绿素、蛋白质、维生素、矿物质以及多种活性成分,如超氧化物歧化酶、过氧化物酶、细胞色素氧化酶、脂肪氧化酶、转羟酶等20多种酶。另外,大麦苗还富含膳食纤维,可以控制餐后血糖升高,减轻胰腺负担,是糖尿病人及高血脂患者的食用佳品。Studies have found that the nutritional value of barley seedlings is much higher than that of barley grains, and the young stems and leaves of barley seedlings with a plant height of 10-20cm contain very rich chlorophyll, protein, vitamins, minerals and various active ingredients, such as superoxide dismutation Enzyme, peroxidase, cytochrome oxidase, lipoxygenase, transhydroxylase and more than 20 kinds of enzymes. In addition, barley seedlings are also rich in dietary fiber, which can control the rise in blood sugar after meals and reduce the burden on the pancreas. It is a good food for diabetics and hyperlipidemia patients.

麦苗立体化无土栽培是不用天然土壤而用基质来固定植株,用营养液进行浇灌的栽培方法。无土栽培可以人工创造良好的根际环境,能有效防止土壤病害及土壤重金属污染,可以通过营养液来充分满足作物对矿物质、水分、气体等环境条件的需要,具有占地面积小,洁净无污染,种植采收可工厂化,产品质量优质可控,绿色无污染等特点。The three-dimensional soilless cultivation of wheat seedlings is a cultivation method in which the plants are fixed with substrates and watered with nutrient solution without using natural soil. Soilless cultivation can artificially create a good rhizosphere environment, which can effectively prevent soil diseases and soil heavy metal pollution. It can fully meet the needs of crops for minerals, water, gas and other environmental conditions through nutrient solution. It has a small footprint and is clean. No pollution, planting and harvesting can be industrialized, product quality is high-quality and controllable, green and pollution-free.

锌是人体必需的微量营养元素,生物体内已发现含锌酶约100多种,锌与机体发育、骨骼生长、免疫机能、蛋白质和核酸代谢、酶的活性等关系密切,机体锌的来源主要靠食物摄入,当前国内补锌类产品主要针对儿童研发生产,缺少其他人群的专属补锌产品。Zinc is an essential micronutrient element for the human body. More than 100 zinc-containing enzymes have been found in organisms. Zinc is closely related to body development, bone growth, immune function, protein and nucleic acid metabolism, and enzyme activity. The source of zinc in the body mainly depends on Food intake, the current domestic zinc supplement products are mainly developed and produced for children, and there is a lack of exclusive zinc supplement products for other groups of people.

水果酵素粉、菌菇酵素粉是指以一种或多种新鲜水果、一种或多种菌菇为原料,经多种有益菌发酵而产生的,含有丰富的维生素、酶、矿物质和有机酸等次生代谢产物的功能性微生物发酵产品。微生物酵素不但保存了发酵原料中所固有的营养物质,而且有效成分大量增加,并产生了一些新的生物活性成分和生物酶。蒋增良研究表明酵素产品具有良好的抗氧化性能,如树莓酵素对DPPH自由基、超氧自由基和ABTS自由基的清除能力,优于Vc对照。黑龙江八一农垦大学赵金凤研究发现植物酵素能够明显促进便秘小鼠的小肠推进运动,缩短便秘小鼠首次排便时间,因此认为酵素具有显著的润肠通便功能。Fruit enzyme powder and mushroom enzyme powder refer to one or more fresh fruits and one or more mushrooms as raw materials, which are fermented by a variety of beneficial bacteria, and are rich in vitamins, enzymes, minerals and organic Functional microbial fermentation products of secondary metabolites such as acids. Microbial enzymes not only preserve the inherent nutrients in the fermentation raw materials, but also increase the active ingredients in a large amount, and produce some new biologically active ingredients and biological enzymes. Jiang Zengliang's research shows that enzyme products have good antioxidant properties, such as raspberry enzyme's ability to scavenge DPPH free radicals, superoxide free radicals and ABTS free radicals, which is better than that of Vc control. Zhao Jinfeng of Heilongjiang Bayi Agricultural University found that plant enzymes can significantly promote the small intestine propulsion of mice with constipation and shorten the time for the first defecation of mice with constipation. Therefore, it is believed that enzymes have a significant laxative function.

现有技术中的大麦苗产品主要是大麦苗粉,其生产加工方式是通过大田种植大麦苗,当大麦苗高20-30cm时采收地上部分,经过清洗、晾干或烘干、粉碎、过筛而得,或者经过清洗、甩干、湿法粉碎提取、过滤、滤液浓缩、干燥而得到大麦苗粉。大田种植的大麦苗生长条件不易控制,易受病虫害或土壤重金属污染的影响,而且株高小于20cm时采收费时费力,株高大于20cm时,大麦苗产品口感粗糙、青草味重,适口性差。另外,市场上的大麦苗粉粉体粒径一般大于106μm,而且原料麦苗连收三茬。当大麦苗粉粉体粒径大于106μm时,冲调后的大麦苗粉混悬液口感粗糙,而且溶解性差,混匀后会迅速分层。第二茬、第三茬收割的麦苗青草味重,缺少一茬麦苗具有的麦香味。The barley seedling product in the prior art is mainly the barley seedling powder, and its production and processing method is to plant the barley seedlings in the field, and when the barley seedlings are 20-30cm high, the above-ground parts are harvested, cleaned, dried or dried, pulverized, and processed. It is obtained by sieving, or the barley grass powder is obtained by washing, drying, wet crushing and extracting, filtering, concentrating the filtrate and drying. The growth conditions of barley seedlings planted in the field are not easy to control, and are easily affected by diseases and insect pests or heavy metal pollution in the soil. Moreover, when the plant height is less than 20 cm, harvesting is labor-intensive. In addition, the particle size of barley grass powder on the market is generally larger than 106 μm, and the raw barley grass is harvested three times in a row. When the particle size of the barley grass powder is larger than 106 μm, the brewed barley grass powder suspension has a rough taste and poor solubility, and it will quickly stratify after mixing. The wheat seedlings harvested in the second and third crops have a strong grassy taste and lack the wheat aroma of the first crop.

发明内容Contents of the invention

本发明的目的是提供一种富锌大麦苗晚餐代餐粉,解决现有技术中的大麦苗固体饮料口感粗糙、青草味重、冲调后迅速分层的问题,富含短肽蛋白质、膳食纤维、维生素,富含锌和多种生物活性成分,具有代餐减肥、调节肠胃机能、增强免疫力的功效;本发明同时提供其制备方法。The purpose of the present invention is to provide a zinc-rich barley seedling dinner meal replacement powder, which solves the problems of the barley seedling solid drink in the prior art, which has a rough taste, a strong grassy taste, and rapid stratification after brewing. It is rich in short peptide protein, dietary Fiber and vitamins, rich in zinc and various bioactive components, have the effects of meal replacement for weight loss, regulation of gastrointestinal function, and enhancement of immunity; the invention also provides a preparation method thereof.

本发明所述的富锌大麦苗晚餐代餐粉,由以下质量百分数的原料制成:The zinc-rich barley seedling meal replacement powder for dinner of the present invention is made of the following raw materials in mass percentage:

其中,优选由以下质量百分数的原料制成:Wherein, it is preferably made of the raw materials of the following mass percentages:

所述的富锌大麦苗微粉的制备包括大麦苗栽培和大麦苗微粉加工两个步骤:The preparation of the zinc-rich barley seedling powder comprises two steps of barley seedling cultivation and barley seedling micropowder processing:

(1)大麦苗栽培:(1) Cultivation of barley seedlings:

采用蛭石做基质进行无土栽培,在大麦出苗生长过程中施加营养液,营养液中添加硫酸锌,从而在大麦苗中富集锌离子,大麦苗长至合适高度后,进行去根采收;Use vermiculite as the substrate for soilless cultivation, apply nutrient solution during the emergence and growth of barley, and add zinc sulfate to the nutrient solution to enrich zinc ions in the barley seedlings. After the barley seedlings grow to a suitable height, they are harvested by removing the roots. ;

(2)大麦苗微粉加工:(2) Micro-powder processing of barley seedlings:

用盐水浸泡采收的大麦苗,再用清水冲洗后进行甩干,然后进一步对其进行真空冷冻干燥、粗粉碎和超微粉碎,得到富锌大麦苗微粉。The harvested barley seedlings are soaked in salt water, rinsed with clear water, and then dried, and then subjected to vacuum freeze-drying, coarse crushing and ultrafine crushing to obtain zinc-rich barley seedling micropowder.

其中,优选的技术方案为:Wherein, preferred technical scheme is:

步骤(1)中硫酸锌的添加量为300-320mg/L;大麦苗长高至10-20cm时,大约需要10-15天的时间,进行去根采收。The amount of zinc sulfate added in the step (1) is 300-320 mg/L; when the barley seedlings grow to a height of 10-20 cm, it takes about 10-15 days to remove the roots and harvest.

营养液可以为常规营养液,也可以优选以下营养液:The nutrient solution can be a conventional nutrient solution, or the following nutrient solution can be preferred:

营养液由以下组分组成(毫克/升):硝酸钙1260,硫酸钾250,磷酸二氢钾350,硫酸镁537,硫酸铵237,EDTA铁钠盐20-40,硫酸亚铁15,硼酸2.86,硼砂4.5,硫酸锰2.13,硫酸铜0.05。The nutrient solution is composed of the following components (mg/L): calcium nitrate 1260, potassium sulfate 250, potassium dihydrogen phosphate 350, magnesium sulfate 537, ammonium sulfate 237, EDTA iron sodium salt 20-40, ferrous sulfate 15, boric acid 2.86 , borax 4.5, manganese sulfate 2.13, copper sulfate 0.05.

步骤(2)中盐水浓度为1.5-2.5%,浸泡时间为15-20min;粗粉碎后要过4目筛,取筛下物进行超微粉碎,超微粉碎采用水冷式高频振动超微粉碎机,经激光粒度仪检测,99%的粉体粒径﹤35μm,此种加工方式最大限度的保留了大麦苗中的营养成分。In step (2), the concentration of brine is 1.5-2.5%, and the soaking time is 15-20 minutes; after the coarse crushing, it is necessary to pass through a 4-mesh sieve, and the under-sieve is taken for ultra-fine grinding, and the ultra-fine grinding adopts water-cooled high-frequency vibration ultra-fine grinding Machine, through the laser particle size analyzer detection, 99% of the powder particle size <35μm, this processing method retains the nutritional content of the barley seedlings to the greatest extent.

所述的水果酵素粉的制备过程如下:The preparation process of described fruit enzyme powder is as follows:

选用新鲜的水果进行清洗去杂,之后对其进行切块,切块大小为1-2cm,然后将水果切块和紫苏叶交替分层放入发酵罐,接着在发酵罐中添加市售水果醋后进行密封发酵2-3个月。当发酵液pH值为2-4时,停止发酵,对其进行过滤,得到水果酵素液,对水果酵素液进行低温减压浓缩和真空冷冻干燥,得到水果酵素粉。Choose fresh fruit to wash and remove impurities, then cut it into pieces, the size of which is 1-2cm, then put the fruit pieces and perilla leaves into the fermentation tank alternately, and then add commercially available fruits to the fermentation tank Sealed fermentation after vinegar for 2-3 months. When the pH value of the fermented liquid is 2-4, stop the fermentation, filter it to obtain fruit enzyme liquid, carry out low-temperature decompression concentration and vacuum freeze-drying on the fruit enzyme liquid to obtain fruit enzyme powder.

其中,选用的水果可以是火龙果、蓝莓、猕猴桃、香蕉、葡萄、桑葚、山楂、苹果等中的一种或多种;以切块后的新鲜水果、紫苏叶和水果醋的总质量为100%计,紫苏叶占0.5-1.0%,水果醋占5.5-6.5%。Wherein, the fruit selected can be one or more in dragon fruit, blueberry, kiwi fruit, banana, grape, mulberry, hawthorn, apple etc.; On a 100% basis, perilla leaves account for 0.5-1.0%, and fruit vinegar accounts for 5.5-6.5%.

所述的菌菇酵素粉的制备过程如下:The preparation process of described mushroom enzyme powder is as follows:

选用新鲜或泡发的菌菇清洗去杂,再用煮沸的浓度为4-6wt%的姜粉水漂烫杀菌,然后切碎成大小为1-2cm的菌块,将菌块和紫苏叶交替分层放入发酵罐,最后加入蜂蜜浆,并接入乳酸菌液体菌种进行密封发酵,发酵时间为1-2个月。当发酵液pH值为2-4时,停止发酵,过滤得菌菇酵素液,菌菇酵素液经过低温减压浓缩和真空冷冻干燥,得到菌菇酵素粉。Choose fresh or soaked mushrooms to wash and remove impurities, then blanch and sterilize them with boiled ginger powder water with a concentration of 4-6wt%, then chop them into 1-2cm bacterial blocks, divide the bacterial blocks and perilla leaves alternately The layers are put into a fermenter, and finally the honey slurry is added, and the liquid strain of lactic acid bacteria is added for sealed fermentation, and the fermentation time is 1-2 months. When the pH value of the fermented liquid is 2-4, the fermentation is stopped, the mushroom enzyme liquid is obtained by filtration, and the mushroom enzyme liquid is concentrated under low temperature and reduced pressure and vacuum freeze-dried to obtain the mushroom enzyme powder.

其中,选用的菌菇可以是绣球菌、金针菇、蛹虫草、木耳、双孢菇、杏鲍菇等中的一种或多种;菌块、紫苏叶和蜂蜜浆的质量比为4-5:0.1:1,乳酸菌液体菌种的质量占发酵罐内物料总质量的0.5-1.2%。Wherein, the selected mushrooms can be one or more of hydrangea, Flammulina velutipes, Cordyceps militaris, fungus, Agaricus bisporus, Pleurotus eryngii, etc.; the mass ratio of bacteria block, perilla leaf and honey slurry is 4-5:0.1 1. The quality of the lactic acid bacteria liquid strain accounts for 0.5-1.2% of the total mass of the material in the fermenter.

所述的果蔬粉为市售的果蔬冻干粉,果蔬可以是芒果、蓝莓、猕猴桃、香蕉、葡萄、苹果、西兰花、菠菜、海苔、螺旋藻、盐藻等。The fruit and vegetable powder is a commercially available freeze-dried fruit and vegetable powder, and the fruits and vegetables can be mango, blueberry, kiwi, banana, grape, apple, broccoli, spinach, seaweed, spirulina, salina and the like.

所述的大米粉是市售产品。Described rice flour is a commercially available product.

所述的魔芋微粉为魔芋粗粉经超微粉碎后过160目筛,取筛下物而制得,魔芋微粉也可以是市售产品。The konjac micropowder is obtained by passing the konjac coarse powder through a 160-mesh sieve after ultrafine pulverization, and taking the under-sieve. The konjac micropowder can also be a commercially available product.

所述的熟坚果碎的制备过程是将杏仁、核桃、榛子、板栗或者花生中的任意一种,在110-120℃下烘焙2-3h,然后用冷式切粒机挤压切粒过筛而得到,冷式切粒机配有14目直线振动筛。The preparation process of the crushed cooked nuts is to bake any one of almonds, walnuts, hazelnuts, chestnuts or peanuts at 110-120°C for 2-3 hours, and then use a cold pelletizer to extrude, cut and sieve. To obtain, the cold granulator is equipped with a 14-mesh linear vibrating screen.

所述的富锌大麦苗晚餐代餐粉的制备方法,包括以下步骤:The preparation method of described zinc-rich barley seedling dinner meal replacement powder comprises the following steps:

(1)将配方量的果蔬粉、菌菇酵素粉、水果酵素粉、富锌大麦苗微粉充分混匀,密封备用;(1) Fully mix the fruit and vegetable powder, mushroom enzyme powder, fruit enzyme powder, and zinc-rich barley seedling micropowder in the prescribed amount, and seal it for later use;

(2)将配方量的大米粉、魔芋微粉和熟坚果碎在高效湿法混合机内充分混匀,再干燥、粉碎、过筛,取筛下物;(2) Fully mix the rice flour, konjac micropowder and cooked nut pieces in the high-efficiency wet mixer, then dry, pulverize, sieve, and get the under-sieve;

(3)将步骤(1)密封备用的混合物与步骤(2)的筛下物充分混匀,经分装、灭菌后得到富锌大麦苗晚餐代餐粉。(3) Fully mix the mixture sealed in step (1) for use with the sieved material in step (2), subpackage and sterilize to obtain zinc-rich barley seedling meal replacement powder for dinner.

其中:in:

高效湿法混合机内置搅拌桨与切刀,使得坚果碎和其他原料充分混匀;过筛用筛网目数为120目,避免了损失坚果中的不饱和脂肪酸,保留其营养价值;分装采用每袋10克的方式;灭菌方式采用钴60辐照。The high-efficiency wet mixer has a built-in stirring paddle and a cutter, so that the nuts and other raw materials are fully mixed; the mesh size of the sieve is 120 mesh, which avoids the loss of unsaturated fatty acids in the nuts and retains their nutritional value; The method of 10 grams per bag is adopted; the method of sterilization is irradiated with cobalt 60.

本发明中:In the present invention:

大麦苗粉营养物质种类齐全,含量丰富,是一种理想的保健食品原料。将大麦苗作为富锌对象,通过在营养液中添加硫酸锌,从而在大麦苗中富集锌离子。以大麦苗的良好功用为基础,通过大麦生长过程中对锌离子的富集作用,能够起到大麦苗自身营养价值和补充微量元素锌的双重功效,本发明可以作为老人、女性、成年男性等其他人群的专属补锌产品。Barley grass powder has a complete range of nutrients and rich content, and is an ideal raw material for health food. Taking barley seedlings as zinc-enriched objects, zinc ions are enriched in barley seedlings by adding zinc sulfate to the nutrient solution. Based on the good function of barley seedlings, through the enrichment of zinc ions in the growth process of barley, it can play the dual functions of barley seedlings' own nutritional value and supplementary trace element zinc. Exclusive zinc supplement products for other groups of people.

大麦苗粉和水果酵素粉、菌菇酵素粉的配伍,可以强化产品调节机体肠胃的功能,增强免疫力的功效,同时赋予产品适口的酸甜味道。The compatibility of barley grass powder, fruit enzyme powder and mushroom enzyme powder can strengthen the product's ability to regulate the body's gastrointestinal function and enhance immunity, and at the same time endow the product with a delicious sour and sweet taste.

由于魔芋含有丰富的水溶性膳食纤维,因此,魔芋微粉吸水性强,饱腹感高,是减肥代餐的佳品,魔芋还具有降低胆固醇、血糖和通便的功能。大麦苗粉和魔芋微粉的配伍,可以强化产品的代餐养生功效,而且两者混匀后的混悬液口感滑腻,不会出现分层。同时,本发明添加大米粉和熟坚果碎,满足人体对碳水化合物和不饱和脂肪酸的需要,为人体提供了能量和营养。Because konjac is rich in water-soluble dietary fiber, konjac powder has strong water absorption and high satiety, which is a good meal replacement for weight loss. Konjac also has the functions of lowering cholesterol, blood sugar and laxative. The combination of barley grass powder and konjac powder can strengthen the product’s meal replacement and health-preserving effect, and the suspension after mixing the two has a smooth taste without stratification. Simultaneously, the invention adds rice flour and cooked nut pieces to meet the needs of the human body for carbohydrates and unsaturated fatty acids, and provides energy and nutrition for the human body.

大麦苗粉见光或者接触空气,容易发生氧化。因此,在制备富锌大麦苗晚餐代餐粉时,首先将富锌大麦苗微粉和果蔬粉、菌菇酵素粉、水果酵素粉混匀备用。这是因为,果蔬粉、菌菇酵素粉、水果酵素粉中的多酚类、有机酸、维生素不仅可以防止富锌大麦苗微粉的氧化,而且利于锌元素的吸收利用。Barley grass powder is prone to oxidation when exposed to light or air. Therefore, when preparing zinc-rich barley seedling meal replacement powder for dinner, first mix the zinc-rich barley seedling powder with fruit and vegetable powder, mushroom enzyme powder, and fruit enzyme powder for later use. This is because the polyphenols, organic acids, and vitamins in fruit and vegetable powder, mushroom enzyme powder, and fruit enzyme powder can not only prevent the oxidation of zinc-rich barley seedling powder, but also facilitate the absorption and utilization of zinc.

本发明的有益效果如下:The beneficial effects of the present invention are as follows:

本发明的富锌大麦苗晚餐代餐粉溶解性好,食用时不分层,其营养物质种类齐全,含量丰富,能量低,适合晚餐代餐食用,富含短肽蛋白质、膳食纤维、维生素,富含锌和多种生物活性成分,具有代餐减肥、调节肠胃机能、增强免疫力的功效,且通过无土栽培种植大麦苗,具有绿色无污染的特点;本发明制备方法简单易行,易于实现产业化。The zinc-rich barley seedling dinner meal replacement powder of the present invention has good solubility, does not layer when eaten, has a complete range of nutrients, rich content, and low energy, is suitable for dinner meal replacements, and is rich in short peptide protein, dietary fiber, and vitamins. Rich in zinc and various biologically active ingredients, it has the effects of replacing meals for weight loss, regulating gastrointestinal function, and enhancing immunity, and grows barley seedlings through soilless cultivation, which has the characteristics of green and pollution-free; the preparation method of the present invention is simple and easy to implement Realize industrialization.

具体实施方式Detailed ways

以下结合实施例对本发明做进一步描述。The present invention is further described below in conjunction with embodiment.

实施例1Example 1

富锌大麦苗晚餐代餐粉,由以下质量百分数的原料制成:Zinc-rich barley seedling dinner meal replacement powder is made of the following raw materials in mass percentage:

制备过程如下:The preparation process is as follows:

1、富锌大麦苗微粉:1. Zinc-rich barley seedling powder:

包括两个步骤:It consists of two steps:

(1)大麦苗栽培:(1) Cultivation of barley seedlings:

采用蛭石做基质进行无土栽培,在大麦出苗生长过程中施加营养液,营养液中添加硫酸锌300mg/L,从而在大麦苗中富集锌离子,大麦苗长至10-20cm时,进行去根采收;Use vermiculite as the substrate for soilless cultivation, apply nutrient solution during the emergence and growth of barley, and add 300mg/L of zinc sulfate to the nutrient solution to enrich zinc ions in the barley seedlings. When the barley seedlings grow to 10-20cm, carry out root harvesting;

营养液由以下组分组成(毫克/升):硝酸钙1260,硫酸钾250,磷酸二氢钾350,硫酸镁537,硫酸铵237,EDTA铁钠盐30,硫酸亚铁15,硼酸2.86,硼砂4.5,硫酸锰2.13,硫酸铜0.05。The nutrient solution is composed of the following components (mg/L): calcium nitrate 1260, potassium sulfate 250, potassium dihydrogen phosphate 350, magnesium sulfate 537, ammonium sulfate 237, EDTA iron sodium salt 30, ferrous sulfate 15, boric acid 2.86, borax 4.5, manganese sulfate 2.13, copper sulfate 0.05.

(2)大麦苗微粉加工:(2) Micro-powder processing of barley seedlings:

用浓度为2%的盐水浸泡采收的大麦苗20min,再用清水冲洗后进行甩干,然后进一步对其进行真空冷冻干燥、粗粉碎,粗粉碎后过4目筛,取筛下物再进行超微粉碎,得到富锌大麦苗微粉,经激光粒度仪检测,99%的粉体粒径﹤35μm。Soak the harvested barley seedlings in 2% salt water for 20 minutes, rinse them with clean water and dry them, then further vacuum freeze-dry them, coarsely crush them, pass through a 4-mesh sieve after coarse crushing, and take the under-sieves for further processing. The zinc-rich barley seedling micropowder is obtained by ultrafine pulverization, and the particle size of 99% of the powder is less than 35 μm after detection by a laser particle size analyzer.

2、水果酵素粉:2. Fruit enzyme powder:

选用新鲜的水果进行清洗去杂,之后对其进行切块,切块大小为1-2cm,然后将水果切块和紫苏叶交替分层放入发酵罐,接着在发酵罐中添加市售水果醋后进行密封发酵2个月。当pH值为3时,停止发酵,对其进行过滤,得到水果酵素液,对水果酵素液进行低温减压浓缩和真空冷冻干燥,得到水果酵素粉。Choose fresh fruit to wash and remove impurities, then cut it into pieces, the size of which is 1-2cm, then put the fruit pieces and perilla leaves into the fermentation tank alternately, and then add commercially available fruits to the fermentation tank Sealed fermentation after vinegar for 2 months. When the pH value is 3, stop the fermentation, filter it to obtain fruit enzyme liquid, carry out low-temperature decompression concentration and vacuum freeze-drying on the fruit enzyme liquid to obtain fruit enzyme powder.

以切块后的新鲜水果、紫苏叶和水果醋的总质量为100%计,紫苏叶占1%,水果醋占6%。Based on the total mass of the diced fresh fruit, perilla leaves and fruit vinegar as 100%, the perilla leaves account for 1% and the fruit vinegar accounts for 6%.

3、菌菇酵素粉:3. Mushroom enzyme powder:

选用新鲜或泡发的菌菇清洗去杂,再用煮沸的浓度为5wt%的姜粉水漂烫杀菌,然后切碎成大小为1-2cm的菌块,将菌块和紫苏叶交替分层放入发酵罐,最后加入蜂蜜浆,并接入乳酸菌液体菌种进行密封发酵,发酵时间为2个月。发酵液pH值为3时,停止发酵,过滤得菌菇酵素液,菌菇酵素液经过低温减压浓缩和真空冷冻干燥,得到菌菇酵素粉。Choose fresh or soaked mushrooms to wash and remove impurities, then blanch and sterilize them with boiled ginger powder water with a concentration of 5wt%, then chop them into 1-2cm-sized mushroom blocks, put the mushroom blocks and perilla leaves in layers alternately Put it into the fermenter, and finally add honey slurry, and add lactic acid bacteria liquid strains for sealed fermentation. The fermentation time is 2 months. When the pH value of the fermented liquid is 3, the fermentation is stopped, the mushroom enzyme liquid is obtained by filtration, and the mushroom enzyme liquid is concentrated under reduced pressure at low temperature and vacuum freeze-dried to obtain the mushroom enzyme powder.

其中,菌块、紫苏叶和蜂蜜浆的质量比为4:0.01:1,乳酸菌液体菌种的质量占发酵罐内物料总质量的1%。Wherein, the mass ratio of bacteria block, perilla leaf and honey slurry is 4:0.01:1, and the mass of lactic acid bacteria liquid strain accounts for 1% of the total mass of materials in the fermentation tank.

4、果蔬粉:为市售产品。4. Fruit and vegetable powder: it is a commercially available product.

5、大米粉:为市售产品。5. Rice flour: it is a commercially available product.

6、魔芋微粉:为市售产品。6. Konjac powder: it is a commercially available product.

7、熟坚果碎:其制备过程是将杏仁、核桃、榛子、板栗或者花生中的任意一种,在120℃下进行低温烘焙2h,然后用冷式切粒机挤压切粒过筛而得到,冷式切粒机配有14目直线振动筛。本实施例选用熟核桃碎。7. Broken cooked nuts: the preparation process is to bake any one of almonds, walnuts, hazelnuts, chestnuts or peanuts at a low temperature of 120°C for 2 hours, and then extrude, cut and sieve with a cold pelletizer , The cold granulator is equipped with a 14-mesh linear vibrating screen. The present embodiment selects ripe walnut pieces for use.

8、混料:先将配方量的果蔬粉、菌菇酵素粉、水果酵素粉、富锌大麦苗微粉充分混匀,密封备用;再将配方量的大米粉、魔芋微粉和熟坚果碎在内置搅拌桨与切刀的高效湿法混合机中充分混匀,经红外干燥、粉碎、过筛,取筛下物;最后将密封备用的混合物与筛下物充分混匀,经分装、灭菌后得到富锌大麦苗晚餐代餐粉。8. Mixing ingredients: First mix the formula amount of fruit and vegetable powder, mushroom enzyme powder, fruit enzyme powder, and zinc-rich barley seedling powder, and seal it for later use; then put the formula amount of rice flour, konjac micro powder and cooked nuts into the built-in Fully mix in the high-efficiency wet mixer with stirring paddle and cutter, dry by infrared, crush and sieve, and take the undersize; finally, fully mix the sealed mixture with the undersize, pack and sterilize Finally, zinc-rich barley seedling dinner meal replacement powder was obtained.

高效湿法混合机内置的搅拌桨与切刀,目的是能够使配方的坚果碎和其他原料充分混匀;过筛用筛网目数为120目,以避免损失坚果中的不饱和脂肪酸,保留其营养价值;分装采用每袋10克的方式;灭菌方式采用钴60辐照。The purpose of the built-in stirring paddle and cutter in the high-efficiency wet mixer is to fully mix the nuts and other raw materials in the formula; the mesh size of the sieve is 120 mesh to avoid the loss of unsaturated fatty acids in the nuts and retain them. Its nutritional value; subpackage adopts the method of 10 grams per bag; sterilization method adopts cobalt 60 irradiation.

实施例2Example 2

富锌大麦苗晚餐代餐粉,由以下质量百分数的原料制成:Zinc-rich barley seedling dinner meal replacement powder is made of the following raw materials in mass percentage:

以下是制备过程:The following is the preparation process:

1、富锌大麦苗微粉包括两个步骤:1. Zinc-rich barley seedling powder includes two steps:

(1)大麦苗栽培:(1) Cultivation of barley seedlings:

采用蛭石做基质进行无土栽培,在大麦出苗生长过程中施加营养液,营养液中添加硫酸锌320mg/L,从而在大麦苗中富集锌离子,大麦苗长至10-20cm时,进行去根采收;Use vermiculite as the substrate for soilless cultivation, apply nutrient solution during the emergence and growth of barley, and add 320mg/L of zinc sulfate to the nutrient solution to enrich zinc ions in the barley seedlings. When the barley seedlings grow to 10-20cm, carry out root harvesting;

营养液由以下组分组成(毫克/升):硝酸钙1260,硫酸钾250,磷酸二氢钾350,硫酸镁537,硫酸铵237,EDTA铁钠盐30,硫酸亚铁15,硼酸2.86,硼砂4.5,硫酸锰2.13,硫酸铜0.05。The nutrient solution is composed of the following components (mg/L): calcium nitrate 1260, potassium sulfate 250, potassium dihydrogen phosphate 350, magnesium sulfate 537, ammonium sulfate 237, EDTA iron sodium salt 30, ferrous sulfate 15, boric acid 2.86, borax 4.5, manganese sulfate 2.13, copper sulfate 0.05.

(2)大麦苗微粉加工:(2) Micro-powder processing of barley seedlings:

用浓度为2.5%的盐水浸泡采收的大麦苗15min,再用清水冲洗后进行甩干,然后进一步对其进行真空冷冻干燥、粗粉碎,粗粉碎后过4目筛,取筛下物再进行超微粉碎,得到富锌大麦苗微粉,经激光粒度仪检测,99%的粉体粒径﹤35μm。Soak the harvested barley seedlings in 2.5% salt water for 15 minutes, then rinse them with clean water and dry them, then further vacuum freeze-dry them, coarsely crush them, pass through a 4-mesh sieve after coarse crushing, and take the under-sieve for further processing. The zinc-rich barley seedling micropowder is obtained by ultrafine pulverization, and the particle size of 99% of the powder is less than 35 μm after detection by a laser particle size analyzer.

2、水果酵素粉:2. Fruit enzyme powder:

选用新鲜的水果进行清洗去杂,之后对其进行切块,切块大小为1-2cm,然后将水果切块和紫苏叶交替分层放入发酵罐,接着在发酵罐中添加市售水果醋后进行密封发酵2个月。当pH值为4时,停止发酵,对其进行过滤,得到水果酵素液,对水果酵素液进行低温减压浓缩和真空冷冻干燥,得到水果酵素粉。Choose fresh fruit to wash and remove impurities, then cut it into pieces, the size of which is 1-2cm, then put the fruit pieces and perilla leaves into the fermentation tank alternately, and then add commercially available fruits to the fermentation tank Sealed fermentation after vinegar for 2 months. When the pH value is 4, stop the fermentation, filter it to obtain fruit enzyme liquid, carry out low-temperature decompression concentration and vacuum freeze-drying on the fruit enzyme liquid to obtain fruit enzyme powder.

以切块后的新鲜水果、紫苏叶和水果醋的总质量为100%计,紫苏叶占0.5%,水果醋占6.5%。Based on the total mass of the diced fresh fruit, perilla leaves and fruit vinegar as 100%, the perilla leaves account for 0.5%, and the fruit vinegar accounts for 6.5%.

3、菌菇酵素粉:3. Mushroom enzyme powder:

选用新鲜或泡发的菌菇清洗去杂,再用煮沸的浓度为6wt%的姜粉水漂烫杀菌,然后切碎成大小为1-2cm的菌块,将菌块和紫苏叶交替分层放入发酵罐,最后加入蜂蜜浆,并接入乳酸菌液体菌种进行密封发酵,发酵时间为1.5个月。发酵液pH值为4时,停止发酵,过滤得菌菇酵素液,菌菇酵素液经过低温减压浓缩和真空冷冻干燥,得到菌菇酵素粉。Choose fresh or soaked mushrooms to wash and remove impurities, then blanch and sterilize them with boiled ginger powder water with a concentration of 6wt%, then chop them into 1-2cm sized mushroom blocks, put the bacterial blocks and perilla leaves in layers alternately Put it into a fermenter, and finally add honey slurry, and add lactic acid bacteria liquid strains for sealed fermentation, and the fermentation time is 1.5 months. When the pH value of the fermented liquid is 4, the fermentation is stopped, the mushroom enzyme liquid is obtained by filtration, and the mushroom enzyme liquid is concentrated under low temperature and reduced pressure and vacuum freeze-dried to obtain the mushroom enzyme powder.

其中,菌块、紫苏叶和蜂蜜浆的质量比为5:0.01:1,乳酸菌液体菌种的质量占发酵罐内物料总质量的1.2%。Among them, the mass ratio of bacteria block, perilla leaf and honey pulp is 5:0.01:1, and the mass of lactic acid bacteria liquid strain accounts for 1.2% of the total mass of materials in the fermentation tank.

4、果蔬粉:为市售产品。4. Fruit and vegetable powder: it is a commercially available product.

5、大米粉:为市售产品。5. Rice flour: it is a commercially available product.

6、魔芋微粉:为市售产品。6. Konjac powder: it is a commercially available product.

7、熟坚果碎:其制备过程是将杏仁、核桃、榛子、板栗或者花生中的任意一种,在110℃下进行低温烘焙3h,然后用冷式切粒机挤压切粒过筛而得到,冷式切粒机配有14目直线振动筛。本实施例选用熟杏仁碎。7. Broken cooked nuts: the preparation process is to bake any one of almonds, walnuts, hazelnuts, chestnuts or peanuts at a low temperature of 110°C for 3 hours, and then extrude, cut and sieve with a cold pelletizer , The cold granulator is equipped with a 14-mesh linear vibrating screen. The present embodiment selects cooked almonds for use.

8、混料:先将配方量的果蔬粉、菌菇酵素粉、水果酵素粉、富锌大麦苗微粉充分混匀,密封备用;再将配方量的大米粉、魔芋微粉和熟坚果碎在内置搅拌桨与切刀的高效湿法混合机中充分混匀,经红外干燥、粉碎、过筛,取筛下物;最后将密封备用的混合物与筛下物充分混匀,经分装、灭菌后得到富锌大麦苗晚餐代餐粉。8. Mixing ingredients: First mix the formula amount of fruit and vegetable powder, mushroom enzyme powder, fruit enzyme powder, and zinc-rich barley seedling powder, and seal it for later use; then put the formula amount of rice flour, konjac micro powder and cooked nuts into the built-in Fully mix in the high-efficiency wet mixer with stirring paddle and cutter, dry by infrared, crush and sieve, and take the undersize; finally, fully mix the sealed mixture with the undersize, pack and sterilize Finally, zinc-rich barley seedling dinner meal replacement powder was obtained.

高效湿法混合机内置的搅拌桨与切刀,目的是能够使配方的坚果碎和其他原料充分混匀;过筛用筛网目数为120目,以避免损失坚果中的不饱和脂肪酸,保留其营养价值;分装采用每袋10克的方式;灭菌方式采用钴60辐照。The purpose of the built-in stirring paddle and cutter in the high-efficiency wet mixer is to fully mix the nuts and other raw materials in the formula; the mesh size of the sieve is 120 mesh to avoid the loss of unsaturated fatty acids in the nuts and retain them. Its nutritional value; subpackage adopts the method of 10 grams per bag; sterilization method adopts cobalt 60 irradiation.

实施例3Example 3

富锌大麦苗晚餐代餐粉,由以下质量百分数的原料制成:Zinc-rich barley seedling dinner meal replacement powder is made of the following raw materials in mass percentage:

除各组分的用量和种类不同之外,其余制备方法如实施例1。Except that the consumption and type of each component are different, all the other preparation methods are as in Example 1.

实施例4Example 4

富锌大麦苗晚餐代餐粉,由以下质量百分数的原料制成:Zinc-rich barley seedling dinner meal replacement powder is made of the following raw materials in mass percentage:

除各组分的用量和种类不同之外,其余制备方法如实施例2。Except that the consumption and type of each component are different, all the other preparation methods are as in Example 2.

应用实施例:Application example:

从淄博市张店区居民中,找到20名有便秘症状的35-60岁的中老年人。每天下午6点-8点期间服用本发明的10克富锌大麦苗晚餐代餐粉,除晚餐减量外,其他生活习惯不变,连续服用1个月。1个月后回访结果表明,服用富锌大麦苗晚餐代餐粉后,便秘症状即有明显改变,大部分居民口述,服用1周后感觉身体轻便了许多,睡眠质量得到提高。From the residents of Zhangdian District, Zibo City, 20 middle-aged and elderly people aged 35-60 with symptoms of constipation were found. Take 10 grams of zinc-rich barley seedling dinner meal replacement powder of the present invention during 6:00-8:00 pm every day, except for dinner reduction, other living habits remain unchanged, and take continuously for 1 month. One month later, the results of the follow-up visit showed that after taking the zinc-rich barley seedling meal replacement powder for dinner, the symptoms of constipation changed significantly. Most residents said that after taking it for a week, they felt much lighter and their sleep quality improved.

Claims (10)

1. a rich zinc barley seedling dinner generation meal powder, is characterized in that being made up of the raw material of following mass percent:
2. rich zinc barley seedling dinner generation meal powder according to claim 1, is characterized in that: the preparation of rich zinc barley seedling micro mist comprises barley seedling cultivation and two steps processed by barley seedling micro mist:
(1) barley seedling cultivation:
Adopt vermiculite to do matrix and carry out soilless culture, in barley emerges growth course, apply nutrient solution, in nutrient solution, add zinc sulfate, thus in barley seedling Zn accumulation ion, barley seedling grows tall to proper height, carries out root and gathers;
(2) barley seedling micro mist processing:
With the barley seedling that saline sook is gathered, then dry after rinsing with clear water, then carry out vacuum freeze drying, coarse crushing and ultramicro grinding, obtain rich zinc barley seedling micro mist.
3. rich zinc barley seedling dinner generation meal powder according to claim 2, is characterized in that: in step (1), the addition of zinc sulfate is 300-320mg/L; Barley seedling grows tall to 10-20cm, carries out root and gathers.
4. rich zinc barley seedling dinner generation meal powder according to claim 2, is characterized in that: in step (2), brine strength is 1.5-2.5wt%, and soak time is 15-20min; Cross 4 mesh sieves after coarse crushing, extracting screen underflow carries out ultramicro grinding.
5. rich zinc barley seedling dinner generation meal powder according to claim 1, is characterized in that: the preparation process of fruit ferment powder is as follows:
After fresh fruit cleaning impurity elimination, fruit stripping and slicing and perilla leaf alternatively layered to 1-2cm, then are put into fermentation tank by stripping and slicing, individual month of sealing and fermenting 2-3 after interpolation fruits vinegar; When zymotic fluid pH value is 2-4, stop fermentation, filter and obtain fruit enzyme liquid, after, vacuum freeze drying concentrated through low-temperature reduced-pressure, obtain fruit ferment powder; In the gross mass of the fruit after stripping and slicing, perilla leaf and fruits vinegar for 100%, perilla leaf accounts for 0.5-1.0%, and fruits vinegar accounts for 5.5-6.5%.
6. rich zinc barley seedling dinner generation meal powder according to claim 5, is characterized in that: fresh fruit is one or more in dragon fruit, blueberry, Kiwi berry, banana, grape, mulberries, hawthorn or apple.
7. rich zinc barley seedling dinner generation meal powder according to claim 1, is characterized in that: the preparation process of bacterium mushroom ferment powder is as follows:
To the bacterium mushroom cleaning impurity elimination that fresh or bubble are sent out, carry out blanching sterilization with the Jiang Fenshui that the concentration of boiling is 4-6wt% again, be then cut into the bacterium block of 1-2cm, bacterium block and perilla leaf alternatively layered are put into fermentation tank, finally add honey slurry, and after accessing lactic acid bacteria liquid spawn sealing and fermenting 1-2 month; When zymotic fluid pH value is 2-4, stop fermentation, filter and obtain bacterium mushroom enzyme liquid, vacuum freeze drying concentrated through low-temperature reduced-pressure obtains bacterium mushroom ferment powder; Wherein, the mass ratio of bacterium block, perilla leaf and honey slurry is 4-5:0.1:1; The quality of lactic acid bacteria liquid spawn accounts for the 0.5-1.2% of material gross mass in fermentation tank.
8. rich zinc barley seedling dinner generation meal powder according to claim 7, is characterized in that: bacterium mushroom is one or more in Sparassis crispa, asparagus, Cordyceps militaris, auricularia auriculajudae, White mushroom or pleurotus eryngii.
9. rich zinc barley seedling dinner generation meal powder according to claim 1, is characterized in that: the preparation process of ripe ground nut is as follows: by any one in almond, walnut, fibert, Chinese chestnut or peanut, carries out pelletizing after curing 2-3h at 110-120 DEG C.
10. a preparation method for the arbitrary described rich zinc barley seedling dinner generation meal powder of claim 1-9, is characterized in that comprising the following steps:
(1) fruit vegetable powder of formula ratio, bacterium mushroom ferment powder, fruit ferment powder, rich zinc barley seedling micro mist are fully mixed, seal for subsequent use;
(2) rice meal of formula ratio, konjaku micropowder and ripe ground nut are fully mixed, drier, pulverize, sieve, extracting screen underflow;
(3) screenings step (1) being sealed mixture for subsequent use and step (2) fully mixes, and obtains rich zinc barley seedling dinner generation meal powder after packing, sterilizing.
CN201510561152.3A 2015-09-07 2015-09-07 Dinner replacing powder containing zinc-rich barley grass and preparation method of dinner replacing powder Pending CN105077029A (en)

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CN106108015A (en) * 2016-06-29 2016-11-16 傅志勇 A kind of health product for intestinal maintenance and preparation method thereof
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CN106798331A (en) * 2017-01-16 2017-06-06 江南大学 It is a kind of to prepare the instant method for nursing one's health nanometer wheat seedling powder as raw material to freeze wheat seeding
CN106858345A (en) * 2017-02-21 2017-06-20 江南大学 A kind of processing method of the high-quality wheat seeding meal replacement powder rich in wheat seeding ferment
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CN107518392A (en) * 2017-09-25 2017-12-29 福清市火麒麟食用菌技术开发有限公司 The preparation method of Sparassis crispa solid ferment
CN107752003A (en) * 2017-10-17 2018-03-06 朱晓军 Five blue or green scattered preparation methods
CN108391785A (en) * 2018-02-13 2018-08-14 贵州理工学院 A kind of functionality meal replacement powder and its manufacture craft and application
CN108967801A (en) * 2018-08-28 2018-12-11 深圳易生原生物科技有限公司 A kind of fruit-vegetable plant solid beverage and preparation method thereof
WO2020151739A1 (en) 2019-01-24 2020-07-30 浙江医药股份有限公司新昌制药厂 Solid beverage containing barley leaves and preparation method therefor
CN110613088A (en) * 2019-03-12 2019-12-27 江苏省农业科学院 Recombinant barley seedling nutrition powder and production process thereof
CN112889920A (en) * 2019-12-03 2021-06-04 内蒙古蒙牛乳业(集团)股份有限公司 Stabilizer suitable for non-whole milk products, milk products made therefrom and preparation method thereof
CN112450431A (en) * 2020-11-27 2021-03-09 江南大学 Preparation method of freeze-dried konjac meal replacement powder based on enzyme prebiotics
CN112544962A (en) * 2020-12-21 2021-03-26 青岛农业大学 Processing method of pleurotus eryngii enzyme byproduct meal replacement powder
CN112544962B (en) * 2020-12-21 2023-02-07 青岛农业大学 Processing method of pleurotus eryngii enzyme byproduct meal replacement powder
CN115251284A (en) * 2022-06-15 2022-11-01 安徽宝楮生态农业科技有限公司 Preparation method of paper mulberry enzyme meal replacement powder

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