CN105060656B - Biochemical system auxiliary device and application thereof - Google Patents

Abstract

The invention discloses a biochemical system auxiliary device. The biochemical system auxiliary device comprises a power supply controller, insulation tubes, and at least two parallel positive and negative electrodes and/or zero, one or multiple pairs of positive and negative fuel cell electrodes; each electrode comprises a tank body, electrode pore plates vertical to a water inlet direction are inserted in the tank body, at least three rows of electrode pore plates, which are made from piezoelectric/contact alloy, are arranged at a sewage feeding end, and at least twenty rows of electrode pore plates, which are made from rare-earth alloy, are arranged at a sewage discharging end; the fuel cell electrodes are mesh-shaped; the power supply controller is respectively connected with the electrodes and the fuel cell electrode. The biochemical auxiliary device not only can perform a high-performance-cost pre-treatment on sewage, but also can culture targeting bacteria online in a biochemical system; a fuel cell can eliminate charge accumulation toxicity of the biochemical system, so that the biochemical system efficiently and stably runs, the digestion ability to COD is improved by more than two times, and the biochemical effluent index is improved by more than 50%.

Description

A kind of biochemical system auxiliary equipment and its application

Technical field

The present invention relates to a kind of biochemical system auxiliary equipment and its in sewage pretreatment tank, anaerobic pond, oxygen compatibility pool, Aerobic Pond With the application of biochemical sludge concentration basin, belong to environmental technology field.

Background technology

At present, cost performance highest sewage water treatment method, first elects biochemical treatment, and process is：1. it is multiple with the breeding of microorganism Make to be converted into organic matter (microorganism containing hydrocarbon nitrogen oxygen sulfur phosphorus and a small amount of inorganic salt etc. is labeled as A), 2. and/or with microorganism Metabolism clearing up, come out with form of heat, and/or release biogas (methane, nitrogen, carbon dioxide, sulfuration Hydrogen, volatile acid etc. are labeled as B), 3. and/or by microorganism adsorption (polysaccharide of microorganism secretion can optionally, by difficult degradation Adsorption of Organic simultaneously drops its low aqueous solubility, and separates with sewage, and water quality is purified (be labeled as C), and becomes biochemical sludge A part, cooperatively becomes biochemical sludge and is labeled as D with A, because absorption of the microorganism to Organic substance has certain limit, pin Different C values are had to different sewage operating modes.

Biochemical system needs certain activated sludge recoverable amount (mainly considering the amount of Biomass, i.e. A), and unnecessary part is (main consideration system normally runs the maximum bearing value of C to biochemical excess sludge, is labeled as D_{It is remaining}), it is necessary to biochemical system is discharged, no The harm of row or the biochemical excess sludge of few row is for well known to industry.

That is, the load (in terms of COD) that biochemical system is really removed only has part B, the life of general sanitary sewage Change system is all less, only preliminary sedimentation tank and Aerobic Pond, and the heat and biogas of generation is less, and surplus sludge volume accounts for total load (in terms of COD) more than 80%, chemical industry trade effluent, because of difficult degradation, though biochemical system is larger, the heat of generation and biogas Also less, biochemical surplus sludge volume accounts for total load (in terms of COD) 70% or so to yield；With natural animal and/or plant as raw material Industrial undertaking biochemical system, anaerobism produce heat and biogas amount it is larger, biochemical surplus sludge volume account for total load (with COD is counted) except 60% or so, but microbiological pharmacy (production of antibiotics enterprise), because of traditional antibiotic biochemical sewage system only Have aerobic, cause biochemical surplus sludge volume to account for total load (in terms of COD) more than 80%.

Excess sludge compost treatment is that industry is generally acknowledged, extraordinary method for sludge treatment, because a variety of factors affect, meets The biochemical excess sludge of compost standard is pitiably little；Safest processing mode is burning decrement, then fills, it can be seen that：① The activated sludge process of sewage disposal there is also fatal defect：Substantial amounts of biochemical excess sludge is to manufacturing enterprise, society and the mankind The environment of existence causes huge burden；2. it is same, it is very important, biochemical system because of salt accumulation, electrical conductivity raise and Affect the osmotic pressure of microorganism, and/or charge accumulation affects biochemical reaction process, and/or organic nitrogen, and/or nitrate nitrogen and/ Or ammonia nitrogen, and/or organophosphors, and/or total phosphorus, and/or cyanide, and/or hydrogen sulfide, and/or heavy metal etc. are even more and allow sewage Biochemical treatment is difficult.

Since real elimination capacity (in terms of COD), only " come out with heat, and/or release biogas (first Alkane, nitrogen, carbon dioxide, hydrogen sulfide, volatile acid etc.) " so：1. it is optimal path to increase microbial biomass；2. increase simultaneously dirty The biodegradability of dye thing, then be necessary, so many trade effluents need pretreatment, but, current preprocess method is all It is double-edged sword, cost performance is all problematic, in addition to ozone and wet oxidation process do not cause secondary pollution, others are not very Perfection, but, its cost performance is not high, rare application；3. it is directed to Recalcitrant chemicals culture targeting engineering bacteria, it is possible to reduce pre- place Reason expense, many scientific research institutions are all in effort, but link is numerous, and interest relations are complicated, huge because putting into, almost unfeasible Property；4. biochemical reaction also oxidation-reduction reaction, catalytic action of the rare earth element to biochemical reaction has had research, but The laboratory stage is at, practice have shown that, because there is biochemical toxicity when rare earth element concentration is larger, how Based Intelligent Control addition is It is crucial；5. electrolysis processes sewage and has problems in principle：Cationic substance is poisonous to microorganism, and should try one's best removal, But cationic substance and/or other pollutant are facts have proved, is that hydrated ion state is present in sewage, electrolysis is simply in electrolysis The decomposition of water, the oxygen of generation, and/or chlorine to stable organic nitrogen, organophosphors, complicated Organic substance, benzene and its derivative etc. Almost do not act on, and simply play modified effect, then materialized mud is formed by flocculation sediment, play the mesh of pollution transportation , and, materialized mud typically belongs to danger and gives up, and disposal costs are very high.

The content of the invention

The technical problem to be solved is：It is a kind of can make biochemical system efficiently, the auxiliary equipment of stable operation.

To solve above-mentioned technical problem, the technical solution used in the present invention is：A kind of biochemical system auxiliary equipment, the equipment Including：Power-supply controller of electric, insulation tube, at least two be arranged in parallel and electrode positive and negative each other, and/or zero pair, it is one or more pairs of Fuel cell electrode positive and negative each other；Described electrode, including casing, are symmetrically arranged with several cards on described cabinet wall Groove, draw-in groove with water inlet direction it is vertical, the draw-in groove on same inwall be parallel to each other it is evenly distributed, be provided with described draw-in groove with The electrode orifice plate that draw-in groove is engaged, at least three rows are arranged by pressing/get an electric shock electrode orifice plate made by alloy end is flowed near sewage (purpose is：The alloy orifice plate fixed is consistent with water (flow) direction in thickness direction, and width and length direction hang down with water (flow) direction Directly, the foundation of setting is：The organic nitrogen or when 10% during low organic tp removal rate (100 side's water 12 hours) in pretreatment, then need Increase, the amount of increase, it is minimum to increase by a row, and require that two electrodes increase simultaneously), arranging at least near sewage outflow end 20 rows by made by rare earth alloy electrode orifice plate (installation warrants are：When sludge concentration tank runs, salinity, and/or COD Clearance when being less than 20% (100 side's water 12 hours), then need to increase, the minimum row of amount of increase, and require two electrodes Increase simultaneously)；The sewage stream entry/exit end of described casing is both provided with flange；

Described two be arranged in parallel and one in electrode positive and negative each other is connected by flange with one end of insulation tube, The other end of the insulation tube is connected by flange with another electrode；Described two be arranged in parallel and electrode positive and negative each other The distance between be 0.1m-50m, preferably 4m-6m；

Described power-supply controller of electric is provided with power input and power output end, described power output end be connected with to Few two main control lines, described power-supply controller of electric is connected by main control line with electrode；Described power input is external The alternating current of 220V or 380V；

Described fuel cell electrode is network structure, and it is handed over industrial pure titanium metal silk and microporous catalyst fiber shuffling Knit and obtain；Described fuel cell electrode is arranged in the anaerobic pond in biochemical system and/or oxygen compatibility pool and/or Aerobic Pond, often Identical to electrode size, arrangement mode is：Both positive and negative polarity is parallel to each other, and is connected by wire, and power consumption device is accessed in wire (such as：Bulb), described fuel cell electrode is connected with power-supply controller of electric outfan, is provided with described fuel cell electrode Electric resistance sensor, electric resistance sensor be connected with power-supply controller of electric (when resistance raise more than 10% when, power-supply controller of electric is exported automatically Incrustation scale on the voltage dielectric breakdown electrode of twice or higher), it is also possible to generation is played to the microorganism in pond using high voltage The electric mutation of targeting bacterium, is that, to electric shock/piezoelectric electrode, the assosting effect that plays of rare earth alloy electrode (facilitates, the present invention for statement Equipment, referred to as：Biochemical treasured (goldscull)).

Described power-supply controller of electric, insulation tube, at least two be arranged in parallel and electrode positive and negative each other constitutes biochemical system Outer part, in pretreatment section high performance-price ratio sewage is processed, and is cultivated online and oxygen targeting in anoxia section, simultaneous oxygen section, aerobic section Bacterium, while eliminating the cumulative toxicity of biochemical system；In biochemical sludge processing section, with biochemical excess sludge as nutrition, targeting is cultivated Bacterium, returns again to biochemical system；Described power-supply controller of electric, fuel cell electrode constitute the part in biochemical system：Effectively eliminate Charge accumulation toxicity in biochemical system, the inorganic salt accumulation in reduction system in the form of electrode condensation incrustation scale, and aid in life Part outside change system finally, makes biochemical sludge decrement more than 90% to biochemical systematic collaboration potentiation, and makes biochemical system pair The ability of clearing up of COD improves more than 2 times, and bio-chemical effluent index improves more than 50%.

Arrange on described electrode by electric resistance sensor, electric resistance sensor is connected with power-supply controller of electric by wire, works as electricity When resistance raises more than 10%, power-supply controller of electric exports the incrustation scale on the voltage dielectric breakdown electrode of twice or higher automatically.

Described biochemical system auxiliary equipment also includes：Rose Box, incrustation scale collection device and electric blowdown valve；Described mistake Filter box is arranged on sewage and flows into end；Described incrustation scale collection device and electric blowdown valve is arranged on the sewage outflow end of electrode；Institute The incrustation scale collection device stated is funnel-form, and incrustation scale collection device and electric blowdown valve puncture action linkage with incrustation scale.

Described power-supply controller of electric is exchange input, and the way of output is：Frequency conversion square-wave pulse, frequency conversion direct impulse, frequency conversion The group of one or more in negative pulse, frequency conversion commutating pulse, forward dc output, negative sense direct current output or communicating DC output Close.

The output frequency of described power-supply controller of electric is 10-1000Hz, preferably 10-40Hz；Output voltage is 60- 999V, preferably 300-600V, the intermittent time is 10s-12h.

Described power-supply controller of electric being capable of the interelectrode resistance data of automatic data collection and intelligent dielectric breakdown pressure/electric shock on demand The Determination of multiple metal elements for separating out and condensing on alloy electrode, multiple level rare earth alloy electrode, self-cleaning function fuel cell electrode Compound difficulty soluble salt (incrustation scale), it is ensured that equipment nominal situation run.

Described pressure/electric shock alloy electrode (trade name：Piezoelectricity/electric shock alloy), make by the following method ：With metal acid-salt compositionss as base material, add rare earth oxide, mass ratio is 4.0～4.5：1 mix homogeneously, grinds to form 80 The powder body of ± 5 mesh, under the conditions of 1600 DEG C, with hydrogen reducing 300h, must get an electric shock/piezoelectricity functional material；It is (excellent with corrosion resistant metal Elect Hastelloy C alloys system as) according to mass ratio it is 2-4 with described electric shock/piezoelectricity functional material for dispersant:1, it is cast into conjunction Ingot, then the orifice plate for 300mm*100mm*8mm is finish-machined to, aperture is 6-10mm, and open-work rate is 20%-40%, preferably 30%, and it is assembled into the electrode area of needs；Described metal acid-salt compositionss are Barium metatitanate., barium chromate, barium molybdate, aluminic acid The metal acid-salt compositionss that barium, Manganese green, nickel acid barium are formed；Described Barium metatitanate., Manganese green and barium molybdate quality sum account for gold The 60% of category hydrochlorate compositionss gross mass, remaining is barium aluminate, barium chromate and nickel acid three kinds of metal acid-salts of barium；Described metatitanic acid Barium, Manganese green and barium molybdate mass ratio are 3-4：2-3：1-2, the mass ratio of the barium aluminate, barium chromate and nickel acid barium is 1-2： 1-2：1；Described rare earth oxide is one or more in following rare earth highest oxides：Dysprosium, erbium, thorium, samarium, europium, Gadolinium, promethium, neodymium.

Described pressure/electric shock alloy electrode is the free electron e using its generation, and cation and nonionic pollutant are entered Row is modified, and so that selectively poisonous organic nitrogen organophosphors are adsorbed onto into anode the nutrition that Institute of Micro-biology needs is oxidized to；By It is in totally elecrtonegativity in activated sludge, electronics e plays the role of to protect microorganism well.

Described multiple level rare earth alloy electrode (trade name：Multiple level rare earth alloy), by the following method It is obtained：According to the mass fraction, component A intermediate alloy is consisted of：15 ± 1 parts of lanthanum, 15 ± 1 parts of cerium, 3 ± 0.1 parts of thorium, samarium 3 ± 0.1 Part, 1 ± 0.01 part of europium, 0.5 ± 0.001 part of gadolinium, 10 ± 1 parts of praseodymium, 5 ± 0.1 parts of neodymium, 1 ± 0.01 part of vanadium, 20 ± 1 parts of manganese, nickel 17 ± 1 part, 5 ± 1 parts of carbon, 4.5 ± 0.5 parts of ferrum；B component：Pure iron；A intermediate alloys are added in the B component of melting, are closed in the middle of A Gold is 600 ± 3 with the mass ratio of B component：1400 ± 10, molten steel stably after hot investment casting into 300*100*8 orifice plate, it is a diameter of 6-10mm, open-work rate is 20%-40%, preferably 30%, and be assembled into the electrode area of needs.

When rare earth element is entered in sewage：In pretreatment stage, promote the carrying out of redox reaction, increase to pretreatment Effect；In biochemical reaction section, promote the redox reaction of microorganism, and controlled by electrode adsorption rare earth element it is excessive when Biochemical toxicity.

Described fuel cell electrode (trade name：Electrode of microbial fuel cell) it is to use industrially pure titanium Ta₂Tinsel interweaves with microporous catalyst fiber shuffling and obtains fishnet shape fuel cell electrode；Described microporous catalyst fiber, Comprise the following steps：According to the mass fraction, component A is consisted of：30 ± 1 parts of ball-type graphite, 45 ± 1 parts of manganese dioxide, metal 3 ± 0.1 parts of gallium, 1 ± 0.1 part of silver oxide, 1 ± 0.01 part of LiFePO 4,20 ± 1 parts of ethylene glycol；B component polyether sulfone is cut into slices； In mass ratio it is 150 ± 1 by component A and B component：After 450 ± 1 fully mix, melt spinning afterwards, is washed with water except ethylene glycol, Then obtain microporous catalyst fiber, then with commercially available industrially pure titanium Ta₂Shuffling forms self-cleaning function fuel cell electrode；This electrode Good corrosion resistance, intensity are high, mass transfer effect is good, fouling or it is contaminated after, can be by described power supply in the method for dielectric breakdown Inorganic pollution (incrustation scale) is removed, while removing organic contamination by the redox reaction of electrode, automatically cleaning purpose is reached, and is made Fuel cell electrode normal work, it should be pointed out that under power-supply controller of electric effect, fuel cell electrode can also provide target Stimulate to the mutation of bacterium, if necessary, biochemical treasured (goldscull) culture targeting bacterium can be aided in.

Second technical problem to be solved by this invention be：A kind of application of biochemical system auxiliary equipment is provided.

To solve above-mentioned technical problem, the technical solution used in the present invention is：The application of biochemical system auxiliary equipment：By institute State by power-supply controller of electric, insulation tube at least two be arranged in parallel and positive and negative each other electrode composition biochemical system auxiliary equipment (" biochemical treasured (goldscull) ") is arranged on after sludge concentration tank shell pump, after anaerobic sludge reflux pump, simultaneous oxygen sludge reflux pump Afterwards, after aerobic sludge backflow and/or nitrification liquid reflux pump, by reflux pump by pending sewage and/or mud through " biochemical precious (goldscull) " self-loopa operates more than 72 hours, carries out pretreatment, then is added thereto to account for treatment sewage and/or mud body The microbial inoculum of product 0.1-5%, preferred 0.1-1% is then back to sludge concentration tank or in anaerobic pond, oxygen compatibility pool, Aerobic Pond Interior self-loopa；Annual to add a microorganism on demand, such as system stability Effec-tive Function then need not be added；In high-leveled and difficult and/or height Install additional after the pretreatment pool reflux pump of malicious sewage, make treatment sewage flow through " biochemical treasured (goldscull) " and return again to pretreatment Pond, reciprocation cycle determines pretreatment time according to pre-processing requirements.The described fuel cell electrode being connected with power-supply controller of electric In the anaerobic pond being arranged in biochemical system and/or oxygen compatibility pool and/or Aerobic Pond.

The described fuel cell electrode being connected with power-supply controller of electric is arranged on the anaerobic pond in biochemical system and/or and oxygen In pond and/or Aerobic Pond.

Described microbial inoculum for Jing high voltage mutation possess gene grafting potential quality female bacterium (Microbial bacteria Liquid), viable count is more than 100,000,000 in every milliliter of bacterium solution.

Described biochemical system auxiliary equipment (" biochemical precious ") is for during pretreatment, method to be：According to live water quality and water Pool volume sets electrode area, allows high-leveled and difficult, and/or high poison sewage, back and forth flows through biochemical treasured equipment, it is desirable to (water pump is installed after pump Lift is not less than 20 meters), into next stage process after detection.

Principle analysis is：High voltage low current is electrolysed, and can produce under piezoelectricity/pressure of the electric shock alloy more than two kilograms big Amount free electron e, free electron e can be modified to the pollutant in sewage so as to anode is easily adsorbed onto, by high oxidation Also original position is aoxidized, meanwhile, high potential and pulse also easily breaks the hydration status of pollutant, makes absorption and is decomposed by electrode Efficiency increase substantially；Meanwhile, multiple level rare earth element is easier also redox reaction, and chemical intermediate is in air Can be by its ultimate oxidation under effect.

When described biochemical system auxiliary equipment (" biochemical precious ") is for anaerobism section, method is：It is connected on anaerobic sludge backflow After pump.

Adjustment method：Biochemical treasured equipment is added after anaerobic pond operates 72 hours(the body of microbial inoculum 0.1% Product ratio), normal operation.

It is power using sludge reflux pump, anaerobic system is transformed into into the baterial cultivation pool of targeted microorganisms population, while eliminates Cumulative toxicity and increase biodegradability, further improve anaerobism efficiency, fast decoupled organic nitrogen, organophosphors, reduction COD, nitre state Nitrogen, ammonia nitrogen, hydrogen sulfide, inorganic salt content, and provide necessary nutrition for aerobic section.

Principle analysis is：(organic nitrogen, organophosphors, salinity, hydrogen sulfide, ammonia nitrogen, cell age exceed the cumulative toxicity of anaerobic pond 100 days microorganism etc.), it is eliminated in the presence of the functions such as " biochemical precious " high-pressure electrolysis, the freedom that electric shock material is provided Electronics, effective protection cell age is short, the strong microorganism of activity, in the presence of the 60-999V pulse voltages and rare earth catalyst, mutation Go out to decompose the targeting bacterium of Recalcitrant chemicals, make biochemical system potentiation.

When described biochemical system auxiliary equipment (" biochemical precious ") is for aerobic section, using method is：It is connected on aerobic sludge After reflux pump, and/or after nitrification liquid reflux pump.

Adjustment method：Biochemical treasured equipment is added after Aerobic Pond operates 72 hours(the body of microbial inoculum 0.1% Product ratio), normal operation.

It is power using sludge reflux pump, aerobic system is transformed into into the baterial cultivation pool of targeted microorganisms population, while eliminates Cumulative toxicity and increase biodegradability, further improve aerobic efficiency, reduce surplus sludge volume, reduce ammonia nitrogen, the nitre state of water outlet Nitrogen, COD.

Principle analysis is：Biochemical treasured (goldscull) has decomposed to be gone out by the Recalcitrant chemicals of microorganism adsorption, and mutation Decompose the facultative targeting bacterium of Recalcitrant chemicals, the aerobic bacteria with system defines aerobic particle mud, defines autotrophy Type microbial population, while the catalytic action of rare earth accelerates oxidation reaction.So oxygen demand is greatly lowered, the utilization rate of oxygen Increase substantially.

When described biochemical system auxiliary equipment (" biochemical treasured goldscull ") is for biochemical sludge concentration basin, user Method is：After being connected on sludge concentration tank shell pump, the biochemical treasured equipment of Jing returns sludge concentration tank.

Adjustment method：Biochemical treasured equipment is added after sludge concentration tank operates 72 hoursMicrobial inoculum 1% (volume ratio), after reruning 72 hours, returns anaerobic system and clears up, later just can all biochemical remaining dirts every 72 hours Mud is converted into efficient targeting bacterium, so as to increase substantially anaerobism efficiency high.

Principle analysis is：Biochemical excess sludge, in the sterilization section of " biochemical precious ", givesMicroorganism is created preferably Breeding copying surroundings, and under high-voltage square-wave impulse action, mutation has gone out targeted microorganisms, remaining after add-back biochemical system Part is far longer than at that time 1% inoculum concentration, so only need to " biochemical precious " effect online on sludge concentration tank just can be with, Without inoculating.

Beneficial effect：The application can overcome biochemical system generally existing that ability is cleared up to load (in terms of COD) is low, raw Change surplus sludge volume is big, system is unable to the defects such as stable and high effective operation because of cumulative toxicity, at the high performance-price ratio of pretreatment section Reason sewage increase biodegradability cultivates online simultaneous oxygen targeting bacterium with sterilization, in anoxia section, simultaneous oxygen section, aerobic section, while eliminating The cumulative toxicity of biochemical system, makes biochemical system stable, efficient；In biochemical sludge processing section, by being with biochemical excess sludge Nutrition, culture targeting bacterium returns to anoxia section, simultaneous oxygen section, aerobic section, and makes biochemical sludge decrement more than 90%, system pair The ability of clearing up of COD improves more than 2 times, and effluent index improves more than 50%, and economic benefit and social benefit are obvious.Specifically Performance is as follows：

1) anaerobic and aerobic efficiency is greatly improved, the less defect of biochemical system relative emission requirement can be made up, saved More than one times of infrastructure construction and its operating cost；

2) because of quick, reduction oxygen demand (COD) in a large number, and the power consumption of aerobic section is greatly reduced；

3) residual active sludge amount is greatly decreased；

4) highly difficult pollutant can be solved with low cost：1. the problem that biodegradability is poor, pretreatment cost is high；2. divide Solution, the Organic substance that cannot be decomposed with traditional method for oxidation, and the nutritional benefit of microorganism is converted into, and do not increase salinity； 3. efficiently solve fuel cell technology and process highly concentrated, the high-leveled and difficult contaminant waters of industry such as chemical industry, medicine, pesticide, dyestuff, oil field A difficult problem for pretreatment high cost；

5) sterilization of high toxicity organic wastewater can at lower cost be completed：Eliminate organic nitrogen, organophosphors, aminoglycoside (anti- Raw element), cyanide, the biochemical toxicity of fluoride etc.；

6) cumulative toxicity of biochemical system, electro-adsorption demineralization therein, and/or high voltage low current are fundamentally solved Electrolysis, and/or nonionic and the anode that is adsorbed onto of cationic substance uniform design are oxidized, so as to become biochemical reaction Nutrition, also, because the absorption of Organic substance is such that it is able to suppressing the loss of electrode；

7) technology disclosed in the present application, when applying in anaerobism, the return-flow system of aerobic system, it is not necessary to which extra is dynamic Power, in microampere to milliampere level, power consumption almost can be ignored electric current, and operating cost is low；

8) present techniques also have in addition：There are fabulous antiscale, anticorrosion to plumbing drain, aerating system, filler etc. Function, the life-span of several times of prolongation sewage disposal systems.

Description of the drawings：

Fig. 1 is biochemical system auxiliary equipment structural representation；

Fig. 2 is electrode structure schematic diagram；

Fig. 3 is pressure/electric shock alloy electrode or multiple level rare earth alloy electrode orifice plate；

Fig. 4 is that biochemical sludge carries out handling principle flow chart；

Fig. 5 is that the biochemical sludge installed after biochemical system auxiliary equipment carries out process chart.

In Fig. 1 to 3,1, electrode, 2, draw-in groove, 3, electrode orifice plate, 4, casing, 5, flange, 6, power-supply controller of electric, 7, power supply it is defeated Go out end, 8, main control line, 9, power input, 10, electric resistance sensor, 11, sewage inlet, 12, outlet of sewer, 13, incrustation scale receives Acquisition means, 14, electric blowdown valve, 15, Rose Box, 16, insulation tube.

Specific embodiment：

Present invention below will be described in further detail in conjunction with specific embodiments, technical staff is clearly understood Advantages of the present invention.It should be understood that content therein is used merely as explanation, and protection scope of the present invention is constituted limit absolutely not System.

A kind of biochemical system auxiliary equipment, the equipment includes：Power-supply controller of electric 6, insulation tube 16, at least two be arranged in parallel Electrode 1 positive and negative each other, and multipair fuel cell electrode positive and negative each other；Described electrode 1, including casing 4, described casing Several vertical draw-in grooves 2 are symmetrically arranged with 4 inwalls, the draw-in groove 2 on same inwall be parallel to each other it is evenly distributed, in described card The electrode orifice plate 3 being engaged with draw-in groove 2 is provided with groove 2, three rows are set by pressing/get an electric shock alloy to make end is flowed near sewage Electrode orifice plate 3, near sewage outflow end, at least 20 rows electrode orifice plate 3 by made by rare earth alloy is being set；Described case The sewage stream entry/exit end of body 4 is both provided with flange 5；

Described electrode 1 is connected by flange 5 with insulation tube 16, and the insulation tube 16 is by flange 5 and another electrode 1 Connection, described two be arranged in parallel and the distance between electrode 1 positive and negative each other is 6m；

Described sewage flows into end and is provided with Rose Box 15；The Rose Box 15 is connected by flange 5 with insulation tube 16, and this is exhausted Edge pipe 16 is connected by flange 5 with casing 4；Funnel-form incrustation scale collection device is provided with the sewage outflow end of described electrode 1 13 and electric blowdown valve 14；

Described fuel cell electrode is network structure, and it is by titanium silk and microporous catalyst fiber shuffling intertexture Into；Each pair electrode size is identical, and arrangement mode is：Both positive and negative polarity is parallel to each other, and is connected by wire, and power consumption is accessed in wire Device；Described fuel cell electrode is connected with the outfan of power-supply controller of electric 6；Described fuel cell electrode is arranged on department of biochemistry In anaerobic pond and/or oxygen compatibility pool and/or Aerobic Pond in system.

Two electrodes 1 for be arrangeding in parallel positive and negative each other are identical setting, two be arranged in parallel each other positive and negative electrode 1 it Between connected with 6m insulation tubes 16.The import and export internal diameter of electrode 1 is DN150, and arranges the electric resistance sensor 10 of electrode 1 and electronic The sensor of blowoff valve 14.

Power supply is selected：The input of power supply is AC220, is output as 60-999V output waveforms for square-wave pulse, or positive arteries and veins Punching, or negative pulse, or commutating pulse, or forward dc output, or negative sense direct current output, or 7 kinds of outputs such as communicating DC output Pattern is optional, and the intermittent time, 10s-12h was adjustable.

Electric resistance sensor is provided with described fuel cell electrode, electric resistance sensor is connected with power-supply controller of electric, works as electricity When resistance raises more than 10%, power-supply controller of electric exports the incrustation scale on the voltage dielectric breakdown electrode of twice or higher automatically.

Described pressure/electric shock alloy electrode, comprises the following steps：With metal acid-salt compositionss as base material, add rare earth Oxide, mass ratio is 4.0～4.5：1 mix homogeneously, grinds to form the powder body of 80 ± 5 mesh, under the conditions of 1600 DEG C, with hydrogen also Former 300h, must get an electric shock/piezoelectricity functional material；With corrosion resistant metal (preferably Hastelloy C alloys system) as dispersant, touch with described Electricity/piezoelectricity functional material is 2-4 according to mass ratio:1, alloy pig is cast into, then it is finish-machined to the hole for 300mm*100mm*8mm Plate, aperture is 10mm, and open-work rate is 30%, and is assembled into the electrode area of 300mm*300mm, and is arranged in each electrode case 3 rows.

Described metal acid-salt compositionss are Barium metatitanate., and barium chromate, barium molybdate, barium aluminate, Manganese green, nickel acid barium is formed Metal acid-salt compositionss；Described Barium metatitanate., Manganese green and barium molybdate quality sum account for metal acid-salt compositionss gross mass 60%, remaining is barium aluminate, barium chromate and nickel acid three kinds of metal acid-salts of barium；Described Barium metatitanate., Manganese green and barium molybdate quality Than for 3-4：2-3：1-2, the mass ratio of the barium aluminate, barium chromate and nickel acid barium is 1-2：1-2：1；Described rare earth oxide For one or more in following rare earth highest oxides：Dysprosium, erbium, thorium, samarium, europium, gadolinium, promethium, neodymium.

Described multiple level rare earth alloy electrode, comprises the following steps：According to the mass fraction, component A intermediate alloy group Become：15 parts of lanthanum, 15 parts of cerium, 3 parts of thorium, 3 parts of samarium, 1 part of europium, 0.5 part of gadolinium, 10 parts of praseodymium, 5 parts of neodymium, 1 part of vanadium, 20 parts of manganese, nickel 17 Part, 5 parts of carbon, 4.5 parts of ferrum；B component：Pure iron；By 600 kilograms of A intermediate alloys, in being added to 1400 kilograms of B components of melting, steel Liquid stably after hot investment casting into 300*100*8 orifice plate, aperture is 10mm, and open-work rate is 30%, and is assembled into 300mm*300mm Electrode area, and 20 rows are set in each electrode case.

It is as follows biochemical treatment experiment to be carried out using described biochemical treatment auxiliary equipment：

Embodiment 1

Certain pesticidal preparations company processes pesticidal preparations brush tank sewage 30m³

Using biochemical system efficiently, stable operation auxiliary equipment (biochemical treasured (goldscull)), adjust voltage 300v, work Operation mode is commutating pulse output, and frequency is 40Hz, and run time is 90s, and the intermittent time is 10s, shows electric current 0.1A, Jing Run within 208 hours, COD drops to 3333mg/L, clearance 48%, (power consumption 5.4kw.h, dropped 90kgCOD) by 6400mg/L COD becomes and turns to into after aerobic section：108mg/L is dropped to first, sterilization, increase biodegradability of this explanation present invention in pretreatment The high performance-price ratio of aspect.

Embodiment 2

Certain insecticide factory's biochemical sludge：100m³,

Using biochemical system efficiently, stable operation auxiliary equipment (biochemical treasured (goldscull)), adjust voltage 300v, work Operation mode is square-wave pulse output, and frequency is 28Hz, and run time is 60s, and the intermittent time is 30s, and display electric current is 0.15A

Jing runs for 48 hours, and COD drops to 4480mg/L, clearance 83% by 26750mg/L；Ammonia nitrogen by 765mg/L, under It is down to 145mg/L, clearance 78.5%,.Power consumption 1.44kw.h eliminates 2227kgCOD, and this illustrates the present invention program in drop Solution COD aspect cost performances are high.

Embodiment 3

Certain pesticide high-concentration waste water 100m³：

Using biochemical system efficiently, stable operation auxiliary equipment (biochemical treasured (goldscull)), adjust voltage 300v, work Operation mode is commutating pulse output, and frequency is 40Hz, and run time is 90s, and the intermittent time is 10s, shows electric current：0.15A：

Jing test of many times, substantially, the technical scheme of the application is to sterilizing, urging for COD, ammonia nitrogen, kjeldahl nitrogen, total nitrogen downward trend Change oxidation Decomposition complexity Organic substance aspect effectively.

Embodiment 4

Install simultaneously on the anaerobic sludge reflux pipe of certain insecticide factory's biochemical system and on nitrification liquid reflux pipe,

Biochemical system is efficient, stable operation auxiliary equipment (biochemical treasured (goldscull)), adjusts voltage 300v, Working mould Formula is square-wave pulse output, and frequency is 20Hz, and run time is 90s, and the intermittent time is 30s voltages, and the biochemistry of anaerobism backflow is precious (goldscull) electric current is shown：0.15A, aerobic nitrification liquid backflow shows that electric current is 0.17A：

After operation 30 days：Bio-chemical effluent COD drops to 200mg/L or so by original 300mg/L, and ammonia nitrogen is by 100mg/L Drop to below 40mg/L；

Again, after running 6 months, bio-chemical effluent COD is down to 80mg/L or so, and ammonia nitrogen drops to below 10mg/L, in 1.5- Between 6mg/L, and substantially observe that anaerobism section ammonia nitrogen is raised, illustrating to be generated in biochemical system using present device can Decompose the targeted microorganisms population of antibiotic (organic nitrogen), this is domestic outside in the sewerage of pesticide original medicine manufacturing enterprise It is secondary, it is also that the COD of bio-chemical effluent is stably dropped to less than 100 by pesticide intermediate sewage for the first time.

Embodiment 5

Install on sludge concentration tank of certain insecticide factory containing pesticide and the sewerage of pesticide intermediate

Using technical scheme disclosed in the present application, the data statisticss beginning and ending time is 2014.07.26～2014.11.10, raw Changing sludge does not have to be arranged outside any form, and biochemical sludge amount in system, does not increase (SV30 keeps stable 40% or so), sludge Reduction rate more than 90%；Meanwhile, because increasing substantially anaerobism efficiency, the oxygen demand of aerobic section is greatly lowered, temperature 30～ When 35 DEG C or so, aerobic blower fan is cut off, only jet pump maintains stirring and faint oxygen supply；2014.10.11 start, temperature drop During to 18～20 DEG C, aerobic blower fan is opened, and continuous 30 days, is removed, and bio-chemical effluent COD brings up to 300mg/L or so, biochemical remaining dirty Still without outer row, system sludge amount remains in that normal level (SV30 keeps stable 40% or so) to mud, this explanation application The biochemical system of the present invention program can significantly economize on electricity, and still accomplish biochemical sludge reduced training not after temperature drop Become.

Embodiment 6

The biochemical sludge concentration basin of the Wastewater treating biochemical system of certain penicillin production marketing enterprises

Using biochemical system efficiently, stable operation auxiliary equipment (biochemical treasured (goldscull)), adjust voltage 400v, work Operation mode is square-wave pulse output, and frequency is 30Hz, and run time is 90s, and the intermittent time is 30s voltages, shows electric current： 0.15A：

Start to count on July 25th, 2015 from June 10th, 2015 accumulative by the biochemistry of 1450 tons of solid contents 4% or so Excess sludge, with aerobic section is added to after present device process, three on measuring frequency section observation station is observed：

1st, by 1000 tons of biochemical excess sludge in the presence of biochemical system auxiliary equipment (biochemical treasured (goldscull)) After adding biochemical system, the mud amount of possessing of system does not increase, on the contrary in downward trend；

2nd, observe from 3# sections：The COD and ammonia nitrogen in tri- ponds of A, B, C is all downward trend；

3rd, the shock proof ability of system is increased substantially：System water inlet COD from 1549mg/L-20798mg/L significantly In the case of fluctuation, the COD and ammonia nitrogen in tri- ponds of A, B, C of 3# sections is almost without big fluctuation (this explanation：Big biology Amount, increases substantially can biochemical system impact resistance).

Embodiment 7

200 tons of water of certain pesticidal preparations factory (useless pesticide is mixed with brush tank water), COD3800mg/L is aided in biochemical system Equipment (biochemical treasured (goldscull)) does pretreatment：

1, voltage 500V, power work mode is that commutating pulse is exported, frequency 40Hz, electric current 0.3A, run time 90S, Dwell time 10S, 100 sides of flow/hour, Jing runs for 96 hours, and COD drops to 10000mg/L or so；

2, the side of above-mentioned water 100 is taken, plus clear water dilutes 1 times, COD is 5000mg/L, the aeration in the pond of another 1 200 side, gas Water ratio is 0.5:1, after 24 hours, it is found that COD drops to 2000mg/L or so.

Analysis principle is：Biochemical system auxiliary equipment (biochemical treasured (goldscull)) has rare earth element to enter when " 1 " is run Enter in water, participate in enhanced reaction of modification, and in " 2 ", the high-pressure electrolysis without biochemical system auxiliary equipment (biochemical treasured (goldscull)) During effect, the ultimate oxidation of organic compounds in air presence of the rare earth element in water, and COD is quickly reduced, demonstrate again that, this The effect of bright multiple level rare earth alloy.

Claims (9)

1. a kind of biochemical system auxiliary equipment, it is characterised in that：The equipment includes：Power-supply controller of electric（6）, insulation tube（16）, extremely Few two be arranged in parallel and electrode positive and negative each other（1）With zero pair, one or more pairs of fuel cell electrodes positive and negative each other；It is described It is arranged in parallel and electrode positive and negative each other（1）Including casing（4）, the casing（4）Some row's draw-in grooves are symmetrically arranged with inwall （2）, the draw-in groove（2）It is vertical with water inlet direction, in described draw-in groove（2）Inside it is provided with and draw-in groove（2）The electrode orifice plate being engaged （3）, near casing（4）Sewage flow into end at least three rows be set by pressing/get an electric shock electrode orifice plate made by alloy（3）, leaning on Nearly casing（4）Sewage outflow end arrange at least 20 rows electrode orifice plate by made by rare earth alloy（3）；Described casing（4） Sewage stream entry/exit end be both provided with flange（5）；

Described two be arranged in parallel and electrode positive and negative each other（1）In one pass through flange（5）With insulation tube（16）One End connection, the insulation tube（16）The other end pass through flange（5）With another electrode（1）Connection；Described two parallel to set Put and electrode positive and negative each other（1）The distance between be 0.1m-50m；

Described power-supply controller of electric（6）It is provided with power input（9）And power output end（7）, described power output end（7） It is connected with least two main control lines（8）, described power-supply controller of electric（6）By corresponding main control line（8）Be arranged in parallel And electrode positive and negative each other（1）Connection；

Described fuel cell electrode is network structure, and it is interwoven by titanium silk with microporous catalyst fiber shuffling；Often Equivalently-sized to fuel cell electrode, arrangement mode is：Both positive and negative polarity is parallel to each other, and is connected by wire, and electric energy is accessed in wire Consumers；Described fuel cell electrode and power-supply controller of electric（6）Outfan connects.

2. a kind of biochemical system auxiliary equipment according to claim 1, it is characterised in that：It is described to be arranged in parallel and each other just Negative electrode（1）On be provided with electric resistance sensor（10）, electric resistance sensor（10）With power-supply controller of electric（6）It is connected by wire.

3. a kind of biochemical system auxiliary equipment according to claim 1, it is characterised in that：On described fuel cell electrode It is provided with electric resistance sensor, electric resistance sensor and power-supply controller of electric（6）Connected by wire.

4. a kind of biochemical system auxiliary equipment according to claim 1,2 or 3, it is characterised in that：Described biochemical system Auxiliary equipment also includes：Rose Box（15）, incrustation scale collection device（13）And electric blowdown valve（14）；Described Rose Box（15）If Put and flow into end in sewage；Described incrustation scale collection device（13）And electric blowdown valve（14）It is arranged on casing（4）Sewage flow out End.

5. a kind of biochemical system auxiliary equipment according to claim 1,2 or 3, it is characterised in that：Described power supply Device（6）It is input into for exchange, the way of output is：Frequency conversion square-wave pulse, frequency conversion direct impulse, frequency conversion negative-going pulse, frequency conversion commutation arteries and veins The combination of one or more in punching, forward dc output, negative sense direct current output or communicating DC output；

The output frequency of described power-supply controller of electric is 10-1000Hz；Output voltage is 60-999V, and the intermittent time is 10s- 12h。

6. a kind of biochemical system auxiliary equipment according to claim 1,2 or 3, it is characterised in that：It is described by pressure/get an electric shock Electrode orifice plate made by alloy（3）, its preparation method is：With metal acid-salt compositionss as base material, add rare earth oxide, quality Than for 4.0 ~ 4.5：1 mix homogeneously, grinds to form the powder body of 80 ± 5 mesh, under the conditions of 1600 DEG C, with hydrogen reducing 300h, obtains Electric shock/piezoelectricity functional material；With corrosion resistant metal as dispersant, it is according to mass ratio with described electric shock/piezoelectricity functional material 2-4:1, alloy pig is cast into, orifice plate is reprocessed into, aperture is 6-10mm, and open-work rate is 20%-40%, and is assembled into the electricity of needs Pole-face is accumulated；

Described metal acid-salt compositionss are Barium metatitanate., barium chromate, barium molybdate, barium aluminate, Manganese green, the metal of nickel acid barium formation Hydrochlorate compositionss；Described Barium metatitanate., Manganese green and barium molybdate quality sum account for the 60% of metal acid-salt compositionss gross mass, its It is remaining for barium aluminate, barium chromate and nickel acid barium three kinds of metal acid-salts；Described Barium metatitanate., Manganese green and barium molybdate mass ratio are 3-4： 2-3：1-2, the mass ratio of the barium aluminate, barium chromate and nickel acid barium is 1-2：1-2：1；Described rare earth oxide is following dilute One or more in native highest oxides：Dysprosium, erbium, samarium, europium, gadolinium, promethium, neodymium.

7. a kind of biochemical system auxiliary equipment according to claim 1,2 or 3, it is characterised in that：Described is closed by rare earth Electrode orifice plate made by gold（3）, its preparation method is：According to the mass fraction, component A intermediate alloy is consisted of：15 ± 1 parts of lanthanum, 15 ± 1 parts of cerium, 3 ± 0.1 parts of thorium, 3 ± 0.1 parts of samarium, 1 ± 0.01 part of europium, 0.5 ± 0.001 part of gadolinium, 10 ± 1 parts of praseodymium, neodymium 5 ± 0.1 Part, 1 ± 0.01 part of vanadium, 20 ± 1 parts of manganese, 17 ± 1 parts of nickel, 5 ± 1 parts of carbon, 4.5 ± 0.5 parts of ferrum；B component：Pure iron；By in component A Between alloy be added in the B component of melting, the mass ratio of component A intermediate alloy and B component is 600 ± 3：1400 ± 10, molten steel Orifice plate is cast as after stable, aperture is 6-10mm, and open-work rate is 20%-40%, and is assembled into the electrode area of needs.

8. a kind of biochemical system auxiliary equipment according to claim 1,2 or 3, it is characterised in that：Described fuel cell Electrode, comprises the following steps：According to the mass fraction, component A is consisted of：30 ± 1 parts of spherical graphite, 45 ± 1 parts of manganese dioxide, 3 ± 0.1 parts of gallium, 1 ± 0.1 part of silver oxide, 1 ± 0.01 part of LiFePO 4,20 ± 1 parts of ethylene glycol；B component is polyether sulfone Section；By component A and B component in mass ratio 150 ± 1：After 450 ± 1 fully mix, melt spinning is washed with water except ethylene glycol, Microporous catalyst fiber is obtained, the microporous catalyst fiber of gained forms fuel cell electrode with titanium silk Ta2 shufflings again.

9. the application of biochemical system auxiliary equipment, it is characterised in that step is：By described in claim 1 or 2 by power supply Device（6）, insulation tube（16）, at least two be arranged in parallel and electrode positive and negative each other（1）The biochemical system auxiliary equipment peace of composition Be mounted in after biochemical sludge concentration basin shell pump, after anaerobic sludge reflux pump, and oxygen sludge reflux pump after, aerobic sludge reflux pump And/or after nitrification liquid reflux pump, pending sewage and/or mud are allowed through biochemical system auxiliary equipment self-loopa by reflux pump Operating more than 72 hours, carries out pretreatment, then is added thereto to the microbial bacteria for accounting for treatment sewage and/or mud volume 0.1-5% Liquid, is then back to sludge concentration tank or the self-loopa in anaerobic pond, oxygen compatibility pool, Aerobic Pond；High-leveled and difficult and/or high poison sewage pre- Install after processing pond reflux pump, run time is determined according to the requirement of pretreatment；

Described and power-supply controller of electric（6）The fuel cell electrode of connection is arranged on the anaerobic pond in biochemical system and/or and oxygen In pond and/or Aerobic Pond.