CN105038488B - Possess offset printing transfer coatings of high anti-scratch performance and preparation method thereof - Google Patents
Possess offset printing transfer coatings of high anti-scratch performance and preparation method thereof Download PDFInfo
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- CN105038488B CN105038488B CN201510471596.8A CN201510471596A CN105038488B CN 105038488 B CN105038488 B CN 105038488B CN 201510471596 A CN201510471596 A CN 201510471596A CN 105038488 B CN105038488 B CN 105038488B
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- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 238000007645 offset printing Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000011347 resin Substances 0.000 claims abstract description 21
- 229920005989 resin Polymers 0.000 claims abstract description 21
- -1 aldehyde ketone Chemical class 0.000 claims abstract description 16
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 229920002678 cellulose Polymers 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000000654 additive Substances 0.000 claims abstract description 3
- 230000000996 additive effect Effects 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 6
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 239000011342 resin composition Substances 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 4
- 229920008347 Cellulose acetate propionate Polymers 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- FZENGILVLUJGJX-UHFFFAOYSA-N acetaldehyde oxime Chemical compound CC=NO FZENGILVLUJGJX-UHFFFAOYSA-N 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- CJTRGWNHVKRZEB-UHFFFAOYSA-N cyclohexanone;formaldehyde Chemical class O=C.O=C1CCCCC1 CJTRGWNHVKRZEB-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 2
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- 239000004743 Polypropylene Substances 0.000 claims 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229960004756 ethanol Drugs 0.000 claims 1
- 125000004494 ethyl ester group Chemical group 0.000 claims 1
- 239000003595 mist Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 150000003349 semicarbazides Chemical class 0.000 claims 1
- 229920005573 silicon-containing polymer Polymers 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 229920002635 polyurethane Polymers 0.000 abstract description 2
- 239000004814 polyurethane Substances 0.000 abstract description 2
- 229920002125 Sokalan® Polymers 0.000 abstract 1
- 239000004584 polyacrylic acid Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 230000007547 defect Effects 0.000 description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical group CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JKCRGAPZVZSCPC-UHFFFAOYSA-N C1(CCCCCC1)=O.C=O Chemical compound C1(CCCCCC1)=O.C=O JKCRGAPZVZSCPC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- UGZICOVULPINFH-UHFFFAOYSA-N acetic acid;butanoic acid Chemical compound CC(O)=O.CCCC(O)=O UGZICOVULPINFH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
The invention provides a kind of offset printing transfer coatings for possessing high anti-scratch performance, it is made up of the following component of weight percent：Polyurethane-modified polyacrylic acid tree 10~15%；Modified aldehyde ketone resin 5~12%；Cellulose ester resin 5~8%；Siliceous smooth auxiliary agent 0.2~0.5%；Wax powder additive 0.8~1.5%；Solvent 63~79%.Compared with prior art, the present invention has following beneficial effect：1st, the present invention, using polyurethane modified acrylic resin and modified aldehyde ketone resin, makes coating have more preferable hardness and elastoplasticity by preferred resin system；Coating surface smoothness is improved by siliceous slipping agent；By adding wax powder, the scratch resistance anti-wear performance of coating is further improved.Production prepares simple, low cost.
Description
Technical field
The present invention relates to a kind of offset printing transfer coatings for possessing high anti-scratch performance and preparation method thereof, belong to coating technology neck
Domain.
Background technology
Because transfer aluminum plated paper relative to PET coating cards or aluminium foil composite card paper has obvious cost, environment-friendly advantage, institute
With, at present, domestic packaging industry is generally upgraded to transfer aluminum plated technique, using the technique productions wrapping paper not only
It is economic and environment-friendly, and with it is nonpoisonous and tasteless the characteristics of.Prevailing with shifting process, follow-up typography is to transfer coatings
It is required that also more and more higher.Particularly in offset printing technique, due to special transfering process, paper coating surface is particularly easy to
Scratch, causes product rejection.And the excellent thermosetting transfering system of anti-scratch performance, its offset printing performance is unable to reach printing will
Ask.The common practice that offset printing anti-scratch is solved the problems, such as in packaging industry is the last layer water varnish again on transfer coated, it is ensured that
The anti-scratch performance of coating.Although can so solve the problems, such as offset printing anti-scratch, due to many processes varnished together, life can be made
Produce cost significantly raised.At present, on the market also without a kind of offset printing transfer coatings for possessing high anti-scratch performance.
The content of the invention
For defect of the prior art, shift and apply it is an object of the invention to provide a kind of offset printing for possessing high anti-scratch performance
Material and preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of offset printing transfer coatings for possessing high anti-scratch performance, it is made up of the following component of weight percent：
The use of polyurethane-modified polyacrylic resin can avoid coating from not possessing elastoplasticity, can make the anti-scratch performance of formula
The defect of difference.If consumption is higher than 15% this scope, coating can be made partially soft, there is viscous leeward danger；If less than 10%, bullet will do not had
The effect of plasticity.
The use of modified aldehyde ketone resin can avoid coating hardness not high, the defect being easily scratched.If consumption is higher than 12%, meeting
Make coating partially crisp, cause in coating wrapup procedure, coating shedding；If less than 5%, not having the effect for improving coating hardness.
The use of cellulose ester resin can avoid the defect that coating will not possess offset printing performance.If consumption is higher than 8%,
The anti-scratch performance of coating can be influenceed；If less than 5%, will be unable to ensure printing performance.
Siliceous smooth auxiliary agent can avoid coating from not possessing smoothness, surface easily abrasive defect.If consumption is higher than 0.5%,
Coated film is excessively smooth, can produce winding slippage problems；If less than 0.2%, not having smooth effect.
Wax powder additive can avoid the reduction of coating abrasion performance and resistance to marring.If consumption is higher than 1.5%, it will influence is applied
The transparency of layer；If less than 0.8%, not having the effect of wearability and resistance to marring.
Preferably, the polyurethane-modified polyacrylic resin refers to methyl acrylate, ethyl acrylate, propylene
Any group of acid butyl ester, methyl methacrylate, butyl methacrylate and the copolymer of urethane monomer or their copolymers
Close, urethane monomer composition is not less than 10%, and the homopolymer or copolymer 50<Tg<90 DEG C, molecular weight is 5~80,000.
Modified acrylic acid has more preferable elastoplasticity, makes coating be less susceptible to be scratched, and modified acrylic acid can carry for coating
For more excellent adhesive force.
Preferably, the modified aldehyde ketone resin refer to ethylidene azanol, amido urea, maleic anhydride to hexamethylene
Ketone-formaldehyde resin is modified, and makes it have higher Tg, its Tg>130℃.Modified high Tg aldehyde ketone resins, with higher hard
Degree, can make coating harder, more resistant to wiping.
Preferably, the cellulose ester resin includes cellulose acetate, cellulose acetate propionate, acetate butyrate fibre
One or more in dimension element, the molecular weight of cellulose esters is 7000~20000.
Preferably, the siliceous smooth auxiliary agent includes organosiloxane, polyether-modified polysiloxanes, poly- diformazan
Radical siloxane etc., but be not limited to above-mentioned several.The addition of siliceous smooth auxiliary agent, can significantly improve the smooth of coating surface
Property, the coefficient of friction of coating surface is reduced, the effect of anti-scratch is reached.
Preferably, the solvent is ethyl acetate, n-propyl acetate, ethanol, propylene glycol monomethyl ether, isopropanol, third
At least one in glycol ether.
A kind of preparation method of the offset printing transfer coatings of high anti-scratch performance as described in the present invention, it comprises the following steps：
Solvent is placed in reactor, stirring and heater is opened, solvent is well mixed, temperature is kept for 50 DEG C；
Resin Composition is put into reactor, it is 150~250rpm to control stir speed (S.S.), stirs 1~5h, makes resin Composition
Dissolving is abundant；
After resin Composition is completely dissolved, auxiliary agent is put into reactor, it is 100~150rpm to control stir speed (S.S.),
20min is fully dispersed to auxiliary agent, finally, and final products are obtained using 250 mesh filter-cloth filterings.
Compared with prior art, the present invention has following beneficial effect：
1st, the present invention increases the elastoplasticity of coating using polyurethane modified acrylic resin by preferred resin system,
Using modified aldehyde ketone resin, coating is set to have higher hardness；Coating surface smoothness is improved by siliceous slipping agent, hard thing is drawn
Cross, be difficult scratch；By adding wax powder, the scratch resistance anti-wear performance of coating is further improved.The effect of synthesis resin and auxiliary agent, makes
Transfer coated to have certain elastoplasticity and hardness, surface is smooth, is difficult to be scratched by hard thing.
2nd, common transfer coatings that anti-scratch performance poor good compared to offset printing performance, due to preferred resin system and helping
Agent, makes it have preferable elastoplasticity, hardness and surface smoothness, with excellent anti-scratch performance, can not varnish directly
Printing；
3rd, it is good compared to anti-scratch performance, can not direct offset printing thermosetting transfer coatings, the present invention improving erasibility
On the premise of energy, while with preferable offset printing, can direct offset printing, be not scratched.
4th, compared to the guarantee anti-scratch technique of varnishing generally used at present, it can not be varnished, saved using this coating
Production cost；
5th, production prepares simple, low cost.
Embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that to the ordinary skill of this area
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Heretofore described polyurethane-modified polyacrylic resin refers to methyl acrylate, ethyl acrylate, acrylic acid fourth
Any combination of ester, methyl methacrylate, butyl methacrylate and the copolymer of urethane monomer or their copolymers, gathers
Urethane monomer composition is not less than 10%, and the homopolymer or copolymer 50<Tg<90 DEG C, molecular weight is 5~80,000.It is modified
Acrylic acid there is more preferable elastoplasticity, make coating be less susceptible to be scratched, and modified acrylic acid can provide more excellent for coating
Adhesive force.Referring to ethylidene azanol, amido urea, maleic anhydride to cyclohexanone-formaldehyde resin modification for aldehyde ketone resin is modified,
Higher Tg is made it have, its Tg>130℃.Modified high Tg aldehyde ketone resins, with higher hardness, can make coating harder, more
It is resistance to wipe.
Heretofore described cellulose ester resin includes cellulose acetate, cellulose acetate propionate, acetylbutyrylcellulose
In one or more, the molecular weight of cellulose esters is 7000~20000.
Embodiment 1
A kind of component for offset printing transfer coatings for possessing high anti-scratch performance that the present embodiment is related to is as shown in the table：
Embodiment 2
A kind of component for offset printing transfer coatings for possessing high anti-scratch performance that the present embodiment is related to is as shown in the table：
Embodiment 3
A kind of component for offset printing transfer coatings for possessing high anti-scratch performance that the present embodiment is related to is as shown in the table：
Comparative example
A kind of component for offset printing transfer coatings for possessing high anti-scratch performance that this comparative example is related to is as shown in the table：
Contrast effect：
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substance of the present invention.
Claims (6)
1. a kind of offset printing transfer coatings for possessing high anti-scratch performance, it is characterised in that by the following component group of weight percent
Into：
The modified aldehyde ketone resin refers to be modified cyclohexanone-formaldehyde resin with ethylidene azanol, semicarbazides, maleic anhydride, makes
It has higher Tg, its Tg>130℃；
The cellulose ester resin includes one kind or several in cellulose acetate, cellulose acetate propionate, acetylbutyrylcellulose
Kind, the molecular weight of cellulose esters is 7000~20000.
2. possess the offset printing transfer coatings of high anti-scratch performance as claimed in claim 1, it is characterised in that described polyurethane-modified
Polyacrylic resin refers to methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, methacrylic acid fourth
The copolymer of ester and urethane monomer, urethane monomer composition is not less than 10%, and the copolymer 50<Tg<90 DEG C, molecule
Measure as 5~80,000.
3. possess the offset printing transfer coatings of high anti-scratch performance as claimed in claim 1, it is characterised in that described siliceous smooth to help
Agent includes polyether-modified polysiloxanes, dimethyl silicone polymer.
4. possess the offset printing transfer coatings of high anti-scratch performance as claimed in claim 1, it is characterised in that the wax powder additive
Including polyethylene wax micro mist, polyamide wax, ptfe micropowder or polypropylene wax.
5. possess the offset printing transfer coatings of high anti-scratch performance as claimed in claim 1, it is characterised in that the solvent is acetic acid
At least one in ethyl ester, n-propyl acetate, ethanol, propylene glycol monomethyl ether, isopropanol, propylene-glycol ethyl ether.
6. a kind of preparation method for the offset printing transfer coatings for possessing high anti-scratch performance as claimed in claim 1, it is characterised in that
This method comprises the following steps：
Solvent is placed in reactor, stirring and heater is opened, solvent is well mixed, temperature is kept for 50 DEG C；
Resin Composition is put into reactor, it is 150~250rpm to control stir speed (S.S.), stirs 1~5h, dissolves resin Composition
Fully；
After resin Composition is completely dissolved, auxiliary agent is put into reactor, it is 100~150rpm to control stir speed (S.S.), and 20min is extremely
Auxiliary agent is fully dispersed, finally, and final products are obtained using 250 mesh filter-cloth filterings.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510471596.8A CN105038488B (en) | 2015-08-04 | 2015-08-04 | Possess offset printing transfer coatings of high anti-scratch performance and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510471596.8A CN105038488B (en) | 2015-08-04 | 2015-08-04 | Possess offset printing transfer coatings of high anti-scratch performance and preparation method thereof |
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| CN106928417A (en) * | 2017-04-21 | 2017-07-07 | 苏州雄鹰笔墨科技有限公司 | A kind of modified aldehyde ketone resin, preparation method and the application in writing ink |
| CN111978837B (en) * | 2020-07-13 | 2022-01-07 | 惠州宝柏包装有限公司 | Matte coating with soft and smooth touch feeling |
| CN112662227A (en) * | 2020-12-11 | 2021-04-16 | 上海美美良虹印刷有限公司 | Carbon-free environment-friendly offset printing black ink and preparation method thereof |
| CN114155780A (en) * | 2021-12-22 | 2022-03-08 | 松裕印刷包装有限公司 | Dustproof label |
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| CN101760091A (en) * | 2009-12-14 | 2010-06-30 | 上海维凯化学品有限公司 | Single-coating type matt transferring aluminum-plating paint and preparation method thereof |
| CN101747685A (en) * | 2009-12-27 | 2010-06-23 | 浙江桐乡新东方油墨有限公司 | Composite alcohol water plastic printing ink and preparation method thereof |
| JP6090657B2 (en) * | 2013-02-22 | 2017-03-08 | 荒川化学工業株式会社 | Paper-making surface sizing agent and paper coated with the sizing agent |
| CN103555105B (en) * | 2013-10-24 | 2016-01-27 | 上海维凯光电新材料有限公司 | The holographic transfer coatings composition and method of making the same of environment-friendly type anti-copying |
| CN104404819B (en) * | 2014-09-28 | 2017-11-10 | 上海维凯光电新材料有限公司 | A kind of multifunctional coating for wine box outer packing and preparation method thereof |
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