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CN105028603A - Oligosaccharide water-retaining agent used for water retention of red shrimps and use method thereof - Google Patents

Oligosaccharide water-retaining agent used for water retention of red shrimps and use method thereof Download PDF

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CN105028603A
CN105028603A CN201510251900.8A CN201510251900A CN105028603A CN 105028603 A CN105028603 A CN 105028603A CN 201510251900 A CN201510251900 A CN 201510251900A CN 105028603 A CN105028603 A CN 105028603A
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water
shrimp
loss reducer
compound sugar
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谢超
裘晓华
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Zhejiang Ocean University ZJOU
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Zhejiang Ocean University ZJOU
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Abstract

The invention relates to an oligosaccharide water-retaining agent used for water retention of red shrimps, which is composed of following raw materials, by weight, 3-5% of gentiobiose, 25-30% of trehalose, 3-9% of a degradation product of konjac polysaccharide, 4.5-6.5% of alginate oligosaccharides, 2-3% of lactic acid, 5-8% of an anti-oxidizing agent and the balanced being dextrin. The water-retaining agent can maintain fresh degree of frozen shrimps. Volatile amino nitrogen and total bacteria are limited within a national standard range. The water-retaining agent can greatly reduce drying loss during freezing and greatly reduce drying loss of the red shrimps. Meanwhile, the water-retaining agent is prepared from natural fresh-keeping and water-retaining raw materials, thereby ensuring food safety and increasing economic benefit in aquatic product processing enterprises.

Description

一种用于红虾保水的低聚糖保水剂及其使用方法A kind of oligosaccharide water retaining agent for water retention of red shrimp and its application method

技术领域 technical field

本发明涉及海产品加工领域,特别涉及一种用于红虾保水的低聚糖保水剂及其使用方法。 The invention relates to the field of seafood processing, in particular to an oligosaccharide water-retaining agent for water retention of red shrimp and a use method thereof.

背景技术 Background technique

保水剂是有助于保持食品中的水分而加入的物质,多指用于肉类和水产品加工中增强其水分的稳定性和具有较高持水性的磷酸盐类物质。多聚磷酸盐就是这类物质中的一类,用于水产品时可以减少水产品在加工、运输和储藏过程中水分及营养成分的流失,保持制品嫩度,提高出品率,但多聚磷酸盐的过量添加,一方面会使得制品产生不愉快的金属涩味,组织粗糙及储藏过程中磷酸盐的沉淀作用导致表面出现雪花和晶化现象,另一方面消费者食用添加过量多聚磷酸盐的水产品后悔引起血液凝结,其降解产物磷酸盐也可能增大摄入者心脑血管疾病发生的可能性。 Water-retaining agent is a substance added to help maintain moisture in food. It mostly refers to phosphate substances that are used in the processing of meat and aquatic products to enhance their moisture stability and have high water holding capacity. Polyphosphate is one of these substances. When used in aquatic products, it can reduce the loss of water and nutrients during the processing, transportation and storage of aquatic products, maintain the tenderness of products, and increase the yield. However, polyphosphoric acid Excessive addition of salt will, on the one hand, cause an unpleasant metallic astringent taste, rough texture and phosphate precipitation during storage, resulting in snowflakes and crystallization on the surface; on the other hand, consumers eat products with excessive polyphosphate added Aquatic products regret causing blood coagulation, and its degradation product phosphate may also increase the possibility of cardiovascular and cerebrovascular diseases in the intake.

将红虾加工成虾仁,于冷冻条件下储藏、运输,已成为虾产业的重要组成部分,在冷冻贮藏过程中,虾仁中自由水冻结,水分经升华作用脱离虾体,在包装袋内形成冰晶,造成虾表面收缩、发白,不光减轻了产品重量,也降低了产品品质。 Red shrimp is processed into shrimp, stored and transported under freezing conditions, which has become an important part of the shrimp industry. During the frozen storage process, the free water in the shrimp freezes, and the water detaches from the shrimp body through sublimation, forming ice crystals in the packaging bag , causing the surface of the shrimp to shrink and turn white, which not only reduces the weight of the product, but also reduces the quality of the product.

为了延长虾仁的保鲜时间,降低干耗,一些企业违规添加含硫含磷成分,起到保鲜保水的作用,但含硫含磷的产品对人体有害,而且污染环境不环保。 In order to prolong the freshness of shrimp and reduce dry consumption, some companies illegally add sulfur and phosphorus ingredients to keep fresh and water. However, products containing sulfur and phosphorus are harmful to the human body and pollute the environment and are not environmentally friendly.

中国发明专利申请200810049209公开了一种冷鲜肉复合保水剂,该保水剂由以下重量份数的原料制成:乳化剂1-10份,食用油5-30份,防腐剂0.1-0.3份,水50-90份,其不足之处在于,对于水产品尤其是虾仁的保水作用较小。 Chinese invention patent application 200810049209 discloses a composite water-retaining agent for chilled fresh meat. The water-retaining agent is made of the following raw materials in parts by weight: 1-10 parts of emulsifier, 5-30 parts of edible oil, 0.1-0.3 parts of preservative, 50-90 parts of water, its disadvantage is that the water retention effect on aquatic products, especially shrimps, is relatively small.

发明内容 Contents of the invention

本发明的目的在于为了解决现有保水剂对水产品保水作用不大且不环保的缺陷而提供一种天然绿色,保水效果好降低虾仁干耗的用于红虾保水的低聚糖保水剂。 The purpose of the present invention is to provide a natural green oligosaccharide water-retaining agent for red shrimp that has a good water-retaining effect and reduces dry consumption of shrimps in order to solve the defects that existing water-retaining agents have little water-retaining effect on aquatic products and are not environmentally friendly.

本发明的另一个目的是为了提供该低聚糖保水剂的使用方法。 Another object of the present invention is to provide a method for using the oligosaccharide water retaining agent.

为了实现上述目的,本发明采用以下技术方案: In order to achieve the above object, the present invention adopts the following technical solutions:

一种用于红虾保水的低聚糖保水剂,由以下重量百分比的原料组成:龙胆二糖3-5%、海藻糖25-30%、魔芋多糖降解物3-9%、褐藻胶低聚糖4.5-6.5%、乳酸2-3%、抗氧化剂5-8%、余量为糊精。在本技术方案中,褐藻胶低聚糖能极大的改善虾仁肉质的保水性和组织状态,提高虾仁的吸水性、粘着性和凝胶性,使水界面张力降低,乳酸能提高褐藻胶低聚糖在其中的溶解性,还有防腐保鲜的作用。 An oligosaccharide water-retaining agent for water retention of red shrimp, which is composed of the following raw materials in weight percentage: gentiobiose 3-5%, trehalose 25-30%, konjac polysaccharide degradation products 3-9%, alginate low Polysaccharide 4.5-6.5%, lactic acid 2-3%, antioxidant 5-8%, and the balance is dextrin. In this technical solution, algin oligosaccharides can greatly improve the water retention and tissue state of shrimp meat, improve the water absorption, adhesion and gelation of shrimp, and reduce the interfacial tension of water, and lactic acid can improve the low The solubility of polysaccharides in it also has the function of antiseptic and fresh preservation.

作为优选,所述魔芋多聚糖降解物是在质量浓度6-10%的魔芋多糖溶液中添加魔芋多糖质量4-6%的酶,在45-50℃下水解8-12h,浓缩至固形物达到5-9%,喷雾干燥得到的。 As a preference, the konjac polysaccharide degradation product is added to the konjac polysaccharide solution with a mass concentration of 6-10% by adding an enzyme with a mass concentration of 4-6% konjac polysaccharide, hydrolyzed at 45-50°C for 8-12h, and concentrated to a solid To 5-9%, obtained by spray drying.

作为优选,所述的酶为甘露聚糖酶或葡聚糖酶。 Preferably, the enzyme is mannanase or glucanase.

作为优选,褐藻胶低聚糖的粘度为60-75MPa·s。 Preferably, the viscosity of the algin oligosaccharide is 60-75 MPa·s.

作为优选,所述抗氧化剂为维生素E、维生素C与茶多酚的混合物,维生素E、维生素C与茶多酚的质量比为1:2.5-4:5-7。 Preferably, the antioxidant is a mixture of vitamin E, vitamin C and tea polyphenols, and the mass ratio of vitamin E, vitamin C and tea polyphenols is 1:2.5-4:5-7.

一种用于红虾保水的低聚糖保水剂的使用方法,低聚糖保水剂的用法如下:将红虾冲洗,浸入冰水混合物中20-30min,取出后冲洗,去头去尾,排便,去壳后得到鲜虾仁,然后将虾仁浸泡于4-10℃的低聚糖保水剂中,料液比为1:5-6质量体积比,浸泡时间45-70min,每隔10min搅拌一次;捞出虾仁沥干,控干水分即可按照生产要求做进一步的加工。 A method of using an oligosaccharide water-retaining agent for water retention of red shrimp. The usage of the oligosaccharide water-retaining agent is as follows: wash the red shrimp, immerse in the ice-water mixture for 20-30 minutes, rinse after taking it out, remove the head and tail, and defecate , to obtain fresh shrimps after shelling, and then soak the shrimps in the oligosaccharide water-retaining agent at 4-10°C, the ratio of material to liquid is 1:5-6 mass volume ratio, the soaking time is 45-70min, and stir once every 10min; Take out the shrimps and drain, and control the moisture to make further processing according to the production requirements.

作为优选,在虾仁浸泡时,使用超声波震荡,超声频率为65-85kHz。 Preferably, when the shrimps are soaked, ultrasonic vibration is used, and the ultrasonic frequency is 65-85kHz.

本发明的有益效果是: The beneficial effects of the present invention are:

1)通过使用本发明保水剂,冷冻的虾仁新鲜度得到有效保持,挥发性氨基态氮,细菌总数在国家标准范围内,冷冻干耗大幅降低,极大的降低了红虾干耗损失,同时采用天然保鲜、保水原料,食品安全性得到保障,提高了水产品加工企业的经济效益; 1) By using the water-retaining agent of the present invention, the freshness of frozen shrimp is effectively maintained, the volatile amino nitrogen and the total number of bacteria are within the range of national standards, the freeze-dry consumption is greatly reduced, and the loss of dry consumption of red shrimp is greatly reduced. At the same time The use of natural fresh-keeping and water-retaining raw materials guarantees food safety and improves the economic benefits of aquatic product processing enterprises;

2)本发明提供的方法处理后的虾仁,蒸煮后虾仁口感好,汁多肉嫩,保持虾仁特有的口味。 2) The shrimps processed by the method provided by the present invention have a good taste after steaming, juicy and tender meat, and maintain the unique taste of shrimps.

具体实施方式 Detailed ways

以下通过具体实施例,对本发明作进一步的解释: Below by specific embodiment, the present invention is further explained:

本发明作用的原料均可从市场购得。 The raw materials of the present invention can be purchased from the market.

实施例1 Example 1

一种用于红虾保水的低聚糖保水剂,由以下重量百分比的原料组成:龙胆二糖3%、海藻糖25%、魔芋多糖降解物3%、褐藻胶低聚糖4.5%、乳酸2%、抗氧化剂5%、余量为糊精。其中,魔芋多聚糖降解物是在质量浓度6%的魔芋多糖溶液中添加魔芋多糖质量4%的甘露聚糖酶,在45℃下水解8h,浓缩至固形物达到5%,喷雾干燥得到的。褐藻胶低聚糖的粘度为60MPa·s。所述抗氧化剂为维生素E、维生素C与茶多酚的混合物,维生素E、维生素C与茶多酚的质量比为1:2.5:5。 An oligosaccharide water-retaining agent for water retention of red shrimp, which is composed of the following raw materials in weight percentage: gentiobiose 3%, trehalose 25%, konjac polysaccharide degradation product 3%, algin oligosaccharide 4.5%, lactic acid 2%, antioxidant 5%, and the balance being dextrin. Among them, the konjac polysaccharide degradation product is obtained by adding mannanase with 4% konjac polysaccharide mass to a konjac polysaccharide solution with a mass concentration of 6%, hydrolyzing it at 45°C for 8 hours, concentrating until the solid content reaches 5%, and spray drying . The viscosity of algin oligosaccharide is 60MPa·s. The antioxidant is a mixture of vitamin E, vitamin C and tea polyphenols, and the mass ratio of vitamin E, vitamin C and tea polyphenols is 1:2.5:5.

低聚糖保水剂的用法如下:将红虾冲洗,浸入冰水混合物中20min,取出后冲洗,去头去尾,排便,去壳后得到鲜虾仁,然后将虾仁浸泡于4-10℃的低聚糖保水剂中,料液比为1:5质量体积比,浸泡时间45min,每隔10min搅拌一次;捞出虾仁沥干,控干水分即可按照生产要求做进一步的加工。在虾仁浸泡时,使用超声波震荡,超声频率为65kHz。 The usage of oligosaccharide water-retaining agent is as follows: wash the red shrimp, immerse in the ice-water mixture for 20 minutes, take it out, rinse, remove the head and tail, defecate, get fresh shrimp after shelling, and then soak the shrimp in a low temperature of 4-10 ℃ In the polysaccharide water retaining agent, the ratio of material to liquid is 1:5 by mass to volume, the soaking time is 45 minutes, and it is stirred every 10 minutes; take out the shrimps and drain them, and control the water to make further processing according to production requirements. When the shrimps are soaked, ultrasonic vibration is used, and the ultrasonic frequency is 65kHz.

在此过程中,红虾虾仁的浸泡增重率为13.6%,冻藏45天后解冻损失率为-5.5%,蒸煮损失率为9.8%,出品率为93%。 During this process, the soaking weight gain rate of red shrimp was 13.6%, the thawing loss rate was -5.5% after 45 days of freezing, the cooking loss rate was 9.8%, and the yield rate was 93%.

实施例2 Example 2

一种用于红虾保水的低聚糖保水剂,由以下重量百分比的原料组成:龙胆二糖4%、海藻糖28%、魔芋多糖降解物6%、褐藻胶低聚糖55%、乳酸2.5%、抗氧化剂7%、余量为糊精。其中,魔芋多聚糖降解物是在质量浓度8%的魔芋多糖溶液中添加魔芋多糖质量5%的葡聚糖酶,在48℃下水解10h,浓缩至固形物达到8%,喷雾干燥得到的。褐藻胶低聚糖的粘度为70MPa·s。所述抗氧化剂为维生素E、维生素C与茶多酚的混合物,维生素E、维生素C与茶多酚的质量比为1:3:6。 An oligosaccharide water-retaining agent for water retention of red shrimp, which is composed of the following raw materials in weight percentage: gentiobiose 4%, trehalose 28%, konjac polysaccharide degradation product 6%, algin oligosaccharide 55%, lactic acid 2.5%, antioxidant 7%, and the balance dextrin. Among them, the konjac polysaccharide degradation product is obtained by adding 5% konjac polysaccharide dextranase to the konjac polysaccharide solution with a mass concentration of 8%, hydrolyzing it at 48°C for 10 hours, concentrating until the solid content reaches 8%, and spray drying . The viscosity of algin oligosaccharide is 70MPa·s. The antioxidant is a mixture of vitamin E, vitamin C and tea polyphenols, and the mass ratio of vitamin E, vitamin C and tea polyphenols is 1:3:6.

低聚糖保水剂的用法如下:将红虾冲洗,浸入冰水混合物中25min,取出后冲洗,去头去尾,排便,去壳后得到鲜虾仁,然后将虾仁浸泡于4-10℃的低聚糖保水剂中,料液比为1:5.5质量体积比,浸泡时间60min,每隔10min搅拌一次;捞出虾仁沥干,控干水分即可按照生产要求做进一步的加工。在虾仁浸泡时,使用超声波震荡,超声频率为70kHz。 The usage of oligosaccharide water-retaining agent is as follows: wash the red shrimp, immerse in the ice-water mixture for 25 minutes, take it out, rinse, remove the head and tail, defecate, get fresh shrimp after shelling, and then soak the shrimp in a low temperature of 4-10 ℃ In the polysaccharide water-retaining agent, the ratio of solid to liquid is 1:5.5 by mass to volume, the soaking time is 60 minutes, and it is stirred every 10 minutes; the shrimps are removed and drained, and the water can be controlled for further processing according to production requirements. When the shrimps are soaked, ultrasonic vibration is used, and the ultrasonic frequency is 70kHz.

在此过程中,红虾虾仁的浸泡增重率为14.6%,冻藏45天后解冻损失率为-5.6%,蒸煮损失率为9.2%,出品率为92%。 During this process, the soaking weight gain rate of red shrimp was 14.6%, the thawing loss rate was -5.6% after 45 days of freezing, the cooking loss rate was 9.2%, and the yield rate was 92%.

实施例3 Example 3

一种用于红虾保水的低聚糖保水剂,由以下重量百分比的原料组成:龙胆二糖5%、海藻糖30%、魔芋多糖降解物9%、褐藻胶低聚糖6.5%、乳酸3%、抗氧化剂8%、余量为糊精。其中,魔芋多聚糖降解物是在质量浓度10%的魔芋多糖溶液中添加魔芋多糖质量6%的甘露聚糖酶,在50℃下水解12h,浓缩至固形物达到9%,喷雾干燥得到的。褐藻胶低聚糖的粘度为75MPa·s。所述抗氧化剂为维生素E、维生素C与茶多酚的混合物,维生素E、维生素C与茶多酚的质量比为1:4:7。 An oligosaccharide water-retaining agent for water retention of red shrimp, which is composed of the following raw materials in weight percentage: gentiobiose 5%, trehalose 30%, konjac polysaccharide degradation product 9%, algin oligosaccharide 6.5%, lactic acid 3%, antioxidant 8%, and the balance being dextrin. Among them, the konjac polysaccharide degradation product is obtained by adding mannanase with 6% konjac polysaccharide mass to a konjac polysaccharide solution with a mass concentration of 10%, hydrolyzing it at 50°C for 12 hours, concentrating until the solid content reaches 9%, and spray drying . The viscosity of algin oligosaccharide is 75MPa·s. The antioxidant is a mixture of vitamin E, vitamin C and tea polyphenols, and the mass ratio of vitamin E, vitamin C and tea polyphenols is 1:4:7.

低聚糖保水剂的用法如下:将红虾冲洗,浸入冰水混合物中30min,取出后冲洗,去头去尾,排便,去壳后得到鲜虾仁,然后将虾仁浸泡于4-10℃的低聚糖保水剂中,料液比为1:6质量体积比,浸泡时间70min,每隔10min搅拌一次;捞出虾仁沥干,控干水分即可按照生产要求做进一步的加工。在虾仁浸泡时,使用超声波震荡,超声频率为85kHz。 The usage of oligosaccharide water-retaining agent is as follows: wash the red shrimp, immerse in the ice-water mixture for 30 minutes, take it out and rinse, remove the head and tail, defecate, get fresh shrimp after shelling, and then soak the shrimp in a low temperature of 4-10 ℃ In the polysaccharide water retaining agent, the ratio of material to liquid is 1:6 by mass to volume, the soaking time is 70 minutes, and it is stirred every 10 minutes; the shrimps are removed and drained, and the water can be controlled for further processing according to production requirements. When the shrimps are soaked, ultrasonic vibration is used, and the ultrasonic frequency is 85kHz.

在此过程中,红虾虾仁的浸泡增重率为13.6%,冻藏45天后解冻损失率为-6.5%,蒸煮损失率为10%,出品率为94%。 During this process, the soaking weight gain rate of red shrimp was 13.6%, the thawing loss rate was -6.5% after 45 days of freezing, the cooking loss rate was 10%, and the yield rate was 94%.

Claims (7)

1. the compound sugar water-loss reducer for red shrimp water conservation, it is characterized in that, be made up of the raw material of following percentage by weight: gentiobiose 3-5%, trehalose 25-30%, SKGM degradation product 3-9%, algin oligosaccharide 4.5-6.5%, lactic acid 2-3%, antioxidant 5-8%, surplus are dextrin.
2. a kind of compound sugar water-loss reducer for red shrimp water conservation according to claim 1, it is characterized in that, described konjaku polysaccharide degradation product is the enzyme adding SKGM quality 4-6% in the SKGM solution of mass concentration 6-10%, 8-12h is hydrolyzed at 45-50 DEG C, be concentrated into solid content and reach 5-9%, spraying dry obtains.
3. a kind of compound sugar water-loss reducer for red shrimp water conservation according to claim 2, it is characterized in that, described enzyme is mannase or dextranase.
4. a kind of compound sugar water-loss reducer for red shrimp water conservation according to claim 1, is characterized in that, the viscosity of algin oligosaccharide is 60-75MPas.
5. a kind of compound sugar water-loss reducer for red shrimp water conservation according to claim 1 or 2 or 4, it is characterized in that, described antioxidant is the mixture of vitamin E, vitamin C and Tea Polyphenols, and the mass ratio of vitamin E, vitamin C and Tea Polyphenols is 1:2.5-4:5-7.
6. the using method for the compound sugar water-loss reducer of red shrimp water conservation, it is characterized in that, the usage of compound sugar water-loss reducer is as follows: rinsed by red shrimp, immerses 20-30min in mixture of ice and water, take out afterflush, decaptitate and truncate, defecation, after shelling, obtain fresh shrimp, then peeled shrimp is soaked in the compound sugar water-loss reducer of 4-10 DEG C, solid-liquid ratio is 1:5-6 mass volume ratio, soak time 45-70min, stirs once every 10min; Pull peeled shrimp out to drain, control solid carbon dioxide divides and can do further processing according to production requirement.
7. the using method of a kind of compound sugar water-loss reducer for red shrimp water conservation according to claim 6, is characterized in that, when peeled shrimp soaks, use ultrasonic oscillation, supersonic frequency is 65-85kHz.
CN201510251900.8A 2015-05-18 2015-05-18 Oligosaccharide water-retaining agent used for water retention of red shrimps and use method thereof Pending CN105028603A (en)

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CN105585716A (en) * 2015-12-07 2016-05-18 南昌大学 Method for reducing viscosity of semen plantaginis polysaccharide
CN105601948A (en) * 2015-12-07 2016-05-25 南昌大学 Method for reducing viscosity of plantain seed polysaccharide by using tea polyphenol
CN106332953A (en) * 2016-08-29 2017-01-18 丁玉琴 Preparation method of meat product non-phosphorus water retaining agent
CN106912554A (en) * 2017-03-03 2017-07-04 福清朝辉水产食品有限公司 A kind of phosphate-free water-retaining agent and its application method for peeled shrimp
CN115558034A (en) * 2022-07-08 2023-01-03 山东兰华农业有限公司 Preparation method of composite trehalose powder
CN116473109A (en) * 2023-04-27 2023-07-25 海南云富渔业有限公司 Phosphorus-free water-retaining agent for frozen fish slices and preparation method and application thereof
CN116725163A (en) * 2023-06-08 2023-09-12 大连工业大学 A kind of preparation method of braised shrimp

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CN102450727A (en) * 2010-10-19 2012-05-16 天津三农金科技有限公司 Water-retaining agent for shrimps
CN104304411A (en) * 2014-10-30 2015-01-28 广东海洋大学 Freshness-keeping and water-retaining agent for prawns

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CN102450727A (en) * 2010-10-19 2012-05-16 天津三农金科技有限公司 Water-retaining agent for shrimps
CN101991178A (en) * 2010-10-28 2011-03-30 浙江工商大学 Phosphorus-free water-retaining agent for shrimp meat and use method thereof
CN104304411A (en) * 2014-10-30 2015-01-28 广东海洋大学 Freshness-keeping and water-retaining agent for prawns

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105585716A (en) * 2015-12-07 2016-05-18 南昌大学 Method for reducing viscosity of semen plantaginis polysaccharide
CN105601948A (en) * 2015-12-07 2016-05-25 南昌大学 Method for reducing viscosity of plantain seed polysaccharide by using tea polyphenol
CN105585716B (en) * 2015-12-07 2017-12-15 南昌大学 A kind of method for reducing plantago asiatica linne polyoses viscosity
CN105601948B (en) * 2015-12-07 2018-04-17 南昌大学 A kind of method that plantago asiatica linne polyoses viscosity is reduced using tea polyphenols
CN106332953A (en) * 2016-08-29 2017-01-18 丁玉琴 Preparation method of meat product non-phosphorus water retaining agent
CN106912554A (en) * 2017-03-03 2017-07-04 福清朝辉水产食品有限公司 A kind of phosphate-free water-retaining agent and its application method for peeled shrimp
CN115558034A (en) * 2022-07-08 2023-01-03 山东兰华农业有限公司 Preparation method of composite trehalose powder
CN116473109A (en) * 2023-04-27 2023-07-25 海南云富渔业有限公司 Phosphorus-free water-retaining agent for frozen fish slices and preparation method and application thereof
CN116725163A (en) * 2023-06-08 2023-09-12 大连工业大学 A kind of preparation method of braised shrimp

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