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CN105018856B - The vertically and horizontally little structural steel for bridge plate of mechanical property difference and its manufacture method - Google Patents

The vertically and horizontally little structural steel for bridge plate of mechanical property difference and its manufacture method Download PDF

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CN105018856B
CN105018856B CN201510502565.4A CN201510502565A CN105018856B CN 105018856 B CN105018856 B CN 105018856B CN 201510502565 A CN201510502565 A CN 201510502565A CN 105018856 B CN105018856 B CN 105018856B
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steel
horizontally
mechanical property
temperature
steel plate
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CN105018856A (en
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邹德辉
董汉雄
董中波
罗毅
刘敏
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Wuhan Iron and Steel Co Ltd
China State Railway Group Co Ltd
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Wuhan Iron and Steel Group Corp
China Railway Corp
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Abstract

The invention discloses a kind of little structural steel for bridge plate of vertically and horizontally mechanical property difference, its chemical component weight percentage ratio is:C:0.02~0.08%, Si:0.10~0.40%, Mn:0.90~1.50%, P≤0.020%, S≤0.010%, Cu≤0.50%, Ni:0.10~0.40%, Mo:0.30~0.50%, Cr:0.30~0.70%, Nb:0.015~0.030%, V:0.030~0.060%, Ti:0.008~0.025%, Ca≤0.0040%, remaining is Fe and inevitable impurity;Production stage include smelt, casting, heating, rolling and classification control cold.The present invention is with low cost, and process is simple is controlled, and product combination property is good, and vertically and horizontally mechanical property difference is little, can be widely applied to the structures such as LONG-SPAN RAILWAY bridge.

Description

The vertically and horizontally little structural steel for bridge plate of mechanical property difference and its manufacture method
Technical field
The present invention relates to the low-alloy structural steel making field in ferrous metallurgy materials, in particular to one kind vertically and horizontally mechanics The little structural steel for bridge plate of performance difference and its manufacture method.
Background technology
In steel structure bridge field, due to complex structure, the Impact direction of bridge rod piece is often not limited to former rolled steel A direction of plate.For the sake of security it is desirable to the vertically and horizontally mechanical property difference of steel plate is less.But, in general, The impact of collision work(of conventional steel plates will be far above laterally, and longitudinal strength especially yield strength will be far below laterally.Steel plate is thinner, This species diversity is more obvious, and that is, the mechanical property of steel plate presents obvious anisotropy, brings very to the selection of bridge steel plate Big difficulty.
Research shows, the anisotropic of mechanical property of steel plate and its chemical composition, inherent texture, fibrous tissue and banding group Knit etc. relevant.Up to the present, composition and microscopic metallographic structure form pair in yield strength 500MPa level structural steel for bridge plate There is not been reported for the vertically and horizontally diversity of mechanical property of steel plate.
Therefore, the species of appropriate design carbon and alloying element and content, develops production technology simple and easy to control, by strict Control each technological parameter, research and develop the little yield strength 500MPa level structural steel for bridge plate of vertically and horizontally mechanical property difference Have important practical significance.
Content of the invention
It is an object of the invention to overcoming above-mentioned the deficiencies in the prior art, provide a kind of low cost of manufacture, process is simple can Control, high comprehensive performance, the little structural steel for bridge plate of vertically and horizontally mechanical property difference of yield strength 500MPa level and its system Make method.
For achieving the above object, the technical solution used in the present invention is:A kind of little bridge of vertically and horizontally mechanical property difference With structural steel and iron, the chemical composition of steel plate and its percentage by weight are as follows:C:0.02~0.08%, Si:0.10~0.40%, Mn:0.90~1.50%, P≤0.020%, S≤0.010%, Cu≤0.50%, Ni:0.10~0.40%, Mo:0.30~ 0.50%, Cr:0.30~0.70%, Nb:0.015~0.030%, V:0.030~0.060%, Ti:0.008~0.025%, Ca≤0.0040%, remaining is Fe and inevitable impurity;And meet simultaneously:Carbon equivalent ce V=C+Mn/6+ (Cr+Mo+V)/5+ (Ni+Cu)/15≤0.475%, welding crack sensibility indices P cm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+ Mo/15+V/10+5B≤0.23%;Acicular ferrite content >=90% in its metallographic structure.
Further, the chemical composition of steel plate and its percentage by weight are as follows:C:0.04~0.06%, Si:0.10~ 0.40%, Mn:0.90~1.50%, P≤0.020%, S≤0.004%, Cu≤0.40%, Ni:0.15~0.20%, Mo: 0.30~0.50%, Cr:0.30~0.70%, Nb:0.015~0.030%, V:0.030~0.060%, Ti:0.008~ 0.025%, Ca≤0.0040%, remaining is Fe and inevitable impurity.
Further, the chemical composition of steel plate and its percentage by weight are as follows:C:0.04%, Si:0.25%, Mn: 1.20%, P:0.012%, S:0.002%, Cu:0.20%, Ni:0.15%, Mo:0.35%, Cr:0.45%, Nb: 0.022%, V:0.040%, Ti:0.012%, Ca:0.0025%, remaining is Fe and inevitable impurity.
In the little structural steel for bridge plate of the vertically and horizontally mechanical property difference of the present invention, each composition effect is as follows:
Carbon (C):Carbon is the effective element improving hardness of steel, and when content is more than 0.08%, after rolling, rate of cooling is larger When, easily form M/A island, and easy Assembled distribution, on segregation band, causes mechanical property of steel plate to present significantly vertically and horizontally poor Different;When its content is relatively low, such as less than 0.02%, armor plate strength can be made not enough, also can increase difficulty during smelting simultaneously.Cause This, control carbon content scope is:0.02~0.08%.
Silicon (Si):Silicon is conventional deoxidizer, has and admittedly melts invigoration effect, is conducive to improving its combination property, but Si content When higher, reduce toughness, plasticity and the ductility of steel, be easily caused cold short be unfavorable for weld.Therefore, the present invention is by the content of Si Desired value controls 0.10~0.40%.
Manganese (Mn):Manganese is important Strengthening and Toughening element, can increase the stability of austenite, expands γ phase region austenite, promotees Enter the middle temperature structural transformation of steel.Too high toughness steel billet center segregation being adversely affected, impairing steel plate of Mn content, and Easily crack during welding, Mn content is too low, middle temperature structural transformation can not be effectively facilitated, be easily reduced the intensity of steel.Therefore Control Mn content range be:0.90~1.50%.
Phosphorus (P):Phosphorus is harmful element in steel, and its content will strictly control, and high P content can increase the cold short of steel and incline To, and P is easily in the center portion segregation of steel billet, due to the high strong segregated zone of this P content more crisp so that easily producing after steel rolling Raw latent defect.The phosphorus content of the present invention is controlled to P≤0.018%.
Sulfur (S):Sulfur is harmful element in steel, and high S content not only can make steel plate, and vertically and horizontally performance produces notable difference, Also reduce its low-temperature flexibility and Z-direction performance simultaneously.Sulfur content of the present invention is S≤0.003%.
Copper (Cu):Copper can improve its quenching degree in steel, acts primarily as solid solution and precipitation enhancement, in addition with beneficial to obtaining Obtain low-temperature flexibility well, increase its fatigue crack extended capability;But when its addition is more than 0.40%, the sweating heat of steel plate Zone of influence toughness can reduce, and steel billet is also easy to produce check crack in heating process.The copper content control of the present invention be Cu≤ 0.040%.
Nickel (Ni):Nickel can improve quenching degree, has certain invigoration effect, can significantly improve its low-temperature flexibility, make base material Increase substantially with Low Temperature Impact Toughness of Heat-affected Zone, Ni can also effectively stop the hot-short check crack causing of Cu simultaneously.When itself plus Enter amount and be less than 0.10%, then Ni does not have effect, but too high levels easily cause steel-plate iron oxide scale and are difficult to come off and increase steel Cost.Ni content of the present invention is:0.10~0.40%.
Molybdenum (Mo):Molybdenum can make ferrite separate out from austenite and increase the stability of austenite, the formation to pearlite There is strong inhibition, but Mo belongs to noble element, excessive Mo will improve the cost of steel;Simultaneously too high Mo content The low-temperature flexibility that steel can be made significantly deteriorates, and forms martensite in welding, leads to welding point fragility to increase.Therefore control in steel Mo content range is:0.30~0.50%.
Chromium (Cr):Chromium can improve intensity and the hardness of steel, but its too high levels then easily increases welding difficulty, and content mistake Low, can not effectively play its effect.In the present invention, the content of Cr is controlled to 0.30~0.70%.
Vanadium (V) and niobium (Nb):In ultra-low-carbon bainite steel, only add substantial amounts of Nb, be remarkably improved intensity, due to it Substantially, it is higher to also result in yield tensile ratio, therefore, in the present invention, Nb content is limited in reduced levels, it is strong for grain refinement effect The loss of degree is then ensured by adding suitable V.In the present invention, the content of V is 0.030~0.060%.Niobium is strong carbon nitridation Compound forms element, can improve the austenite recrystallization temperature of steel, austenite can be rolled under higher rolling temperature. In addition precipitation strength effect in controlled rolling continuous cooling process for the Nb, the strain induced precipitate by the carbonitride of Nb can With pinning austenite crystal, crystal grain thinning simultaneously improves intensity and low-temperature flexibility.But when Nb content is more than 0.030%, crystal grain thinning Improve the effect of intensity clearly, but also lead to its yield tensile ratio too high;When its content is less than 0.015%, do not play controlled rolling Effect.Therefore control Nb content range be:0.015-0.030%.
Titanium (Ti):Titanium is carbide, can form trickle TiC granule, crystal grain thinning, can prevent crystalline substance Between corrosion phenomenon, improving welding property.Ti content of the present invention is:0.008~0.030%.
Calcium (Ca):Calcium can make the inclusion balling in steel, improves the toughness plasticity of steel it is often more important that improving the low temperature punching of steel Hit the anisotropic of toughness.But when Ca content is more than 0.0040%, it is also easy to produce more thick field trash, steel can be deteriorated on the contrary Performance.Therefore in the present invention, calcium content is controlled to Ca≤0.0040%.
Further, the little structural steel for bridge plate of the vertically and horizontally mechanical property difference of the present invention passes through alloying element species With the scientific design of content, strictly control each production technology it is achieved that having excellent comprehensive performance and vertically and horizontally poor mechanical property Different little structural steel for bridge plate, its yield strength ReLFor 500~630MPa, -40 DEG C of impact absorbing energy KV2>=120J, in length and breadth To yield strength difference Δ ReL< 30MPa, -40 DEG C are vertically and horizontally impacted work difference Δ KV2< 80J;And have excellent welding performance and Cold machine-shaping.
The production method of the little structural steel for bridge plate of above-mentioned vertically and horizontally mechanical property difference, comprises the steps:Smelt, Casting, heating, rolling and classification control are cold;In heating stepses, the heating-up temperature of slab is 1250~1320 DEG C;In milling step, Control broadening ratio=steel plate width/width of steel billet be 1.4~1.8, the operation of rolling controls in two stages, roughing temperature be 1000~ 1230 DEG C, total reduction >=60%, intermediate slab thickness H=finished steel plate thickness h+20~30mm, final rolling temperature be 900~ 980℃;Classification is controlled in cold step, and when 740~820 DEG C, control cooldown rate is 1~2 DEG C/s to board briquette;Board briquette exists When 480~740 DEG C, control cooldown rate is 20~40 DEG C/s;During board briquette≤480 DEG C, using the natural type of cooling cooling To room temperature.
Further, in described heating stepses, the heating-up temperature of slab is 1280~1300 DEG C.
Further, in described milling step, controlled rolling in two stages, roughing temperature is 1060~1160 DEG C, finish rolling Temperature is 930~960 DEG C.
Compared with prior art, the present invention has advantages below:The present invention is set up separately using the one-tenth of Mn microalloying in low C Meter, by heating, rolling, the control process meanses such as cold, Optimizing Process Parameters it is ensured that acicular ferrite content >=90% in steel plate, Ensure that it has excellent mechanical property, it is 500~630MPa that its performance indications meets yield strength, -40 DEG C of impact absorbing energies >=120J, vertically and horizontally less than 30MPa, -40 DEG C are vertically and horizontally impacted work difference and are less than 80J yield strength difference, have excellent weldability Can be with cold machine-shaping, can produce steel plate thickness is 10~60mm, and range of application is the welding structures such as LONG-SPAN RAILWAY bridge.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
The chemical elements in percentage by mass of the steel plate of embodiment of the present invention 1-10 as shown in table 1, balance of Fe and can not The impurity avoiding.
Various embodiments of the present invention produce according to following steps:
1) smelt and be casting continuously to form to heating strand after base, control heating-up temperature at 1250~1320 DEG C;
2) carry out hot rolling, control broadening ratio=steel plate width/width of steel billet to be 1.4~1.8, and control the roughing temperature to be 1000~1230 DEG C, total reduction >=60%, intermediate slab thickness H=finished steel plate thickness h+20~30mm, final rolling temperature is 900~980 DEG C;
3) classification control is cold:When 740~820 DEG C, control rate of cooling is 1~2 DEG C/s to temperature;Temperature is at 480~740 DEG C When, control rate of cooling is 25~40 DEG C/s;When temperature is below 480 DEG C, naturally cool to room temperature.
The main production parameter of various embodiments of the present invention is as shown in table 2.
The main technologic parameters list of table 2 various embodiments of the present invention
It should be noted that table 1 and table 2 not corresponding relation, it is only for example.
The performance parameter of various embodiments of the present invention is as shown in table 3.
From table 1, in the present invention, by limiting the interpolation of the element such as Mn, Nb in steel, reduce austenite recrystallization area Final temperature, weakens ausrolling texture;By properly increasing Mo content, it is easy to obtain acicular ferrite;By using super Low-sulfur calcification processing is so that the vertically and horizontally difference of low-temperature flexibility is less.
From table 2, in heating process, adopt higher heating-up temperature as far as possible, weaken rolling texture;Meanwhile, exist During two-stage rolling, as far as possible by reduction distribution in rough rolling step, because rough rolling step is in austenite recrystallization area, here Stage rolling, can fully weaken rolling texture.With the reduction of thickness of slab, the overall reduction of rough rolling step decreases, but one As all more than 60%.In the finish rolling stage, total drafts is 20~30mm, because the finish rolling stage is in austenite non-recrystallization Area, is so the rolling texture in order to reduce the finish rolling stage as far as possible.In the finish rolling stage, also it is in high-temperature region rolling as far as possible, So can also suitably reduce rolling texture.Between 740~480 DEG C, steel plate gives the cold by force of 25~40 DEG C/s, is so In order to fully obtain acicular ferrite structure, reduce the difference of steel plate mechanical property in length and breadth further.
From table 3, with the increase of steel plate thickness, the vertically and horizontally difference of mechanical property of steel plate is gradually lowered, and surrender is strong The vertically and horizontally poor Δ R of degreeeLLess than 30MPa, -40 DEG C are vertically and horizontally impacted work difference Δ KV2Less than 80J.
Above-described embodiment only most preferably enumerates, and is not the restriction to embodiments of the present invention.
The part that other is not described in detail is prior art.

Claims (3)

1. a kind of little structural steel for bridge plate of vertically and horizontally mechanical property difference it is characterised in that:The chemical composition of described steel plate And its percentage by weight is as follows:C:0.04~0.06%, Si:0.10~0.40%, Mn:0.90~1.50%, P≤0.020%, S≤0.004%, Cu≤0.40%, Ni:0.15~0.20%, Mo:0.30~0.50%, Cr:0.30~0.70%, Nb: 0.015~0.030%, V:0.030~0.060%, Ti:0.008~0.025%, Ca≤0.0040%, remaining is Fe and can not Avoid impurity;And meet simultaneously:Carbon equivalent ce V=C+Mn/6+ (Cr+Mo+V)/5+ (Ni+Cu)/15≤0.475%,
Welding crack sensibility index
Pcm=C+Si/30+Mn/20+Cu/20+Ni/60+Cr/20+Mo/15+V/10+5B≤0.23%;Pin in its metallographic structure Columnar ferrite content >=90%;The mechanical property of described steel plate is:Yield strength ReLFor 500~630MPa, -40 DEG C of impact absorbings Work(KV2>=120J, vertically and horizontally yield strength difference Δ ReL< 30MPa, -40 DEG C are vertically and horizontally impacted work difference Δ KV2< 80J;And have Excellent welding performance and cold machine-shaping.
2. the little structural steel for bridge plate of vertically and horizontally mechanical property difference according to claim 1 it is characterised in that:Described The chemical composition of steel plate and its percentage by weight are as follows:C:0.04%, Si:0.25%, Mn:1.20%, P:0.012%, S: 0.002%, Cu:0.20%, Ni:0.15%, Mo:0.35%, Cr:0.45%, Nb:0.022%, V:0.040%, Ti: 0.012%, Ca:0.0025%, remaining is Fe and inevitable impurity.
3. the production method of the little structural steel for bridge plate of the vertically and horizontally mechanical property difference described in a kind of claim 1, it is special Levy and be:Comprise the steps:Smelt, cast, heating, rolling and classification control is cold;In described heating stepses, the heating temperature of slab Spend for 1280~1300 DEG C;In described milling step, broadening ratio=steel plate width/width of steel billet is controlled to be 1.4~1.8, rolling Process controls in two stages, and roughing temperature is 1060~1160 DEG C, total reduction >=60%, intermediate slab thickness H=finished steel Plate thickness h+20~30mm, final rolling temperature is 930~960 DEG C;Described classification is controlled in cold step, and board briquette is at 740~820 DEG C When, control cooldown rate is 1~2 DEG C/s;When 480~740 DEG C, control cooldown rate is 20~40 DEG C/s to board briquette;Plate During base temperature≤480 DEG C, room temperature is cooled to using the natural type of cooling.
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CN107502705A (en) * 2017-07-26 2017-12-22 舞阳钢铁有限责任公司 A kind of production method for controlling ultra-thick plate performance difference in a thickness direction
CN110863139B (en) * 2019-10-31 2021-05-28 鞍钢股份有限公司 420MPa grade weathering bridge steel resistant to ultra-low temperature impact and production method
CN111926256B (en) * 2020-08-12 2021-11-23 宝武集团鄂城钢铁有限公司 Ultra-wide non-anisotropic steel plate with width larger than or equal to 3500mm and production method thereof
CN114182165A (en) * 2021-10-29 2022-03-15 南京钢铁股份有限公司 Low-yield-ratio high-toughness Q500qE bridge steel and production method thereof
CN114381663A (en) * 2021-12-16 2022-04-22 南阳汉冶特钢有限公司 100 mm-thick HPS420WZ35 weather-resistant bridge plate and production method for ensuring performance thereof

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JPH10237583A (en) * 1997-02-27 1998-09-08 Sumitomo Metal Ind Ltd High tensile steel and method for producing the same
CN101845602B (en) * 2009-03-26 2012-04-25 宝山钢铁股份有限公司 High-performance weather-proof building structural steel and manufacturing method thereof
JP5833964B2 (en) * 2012-03-29 2015-12-16 株式会社神戸製鋼所 Steel sheet excellent in bending workability, impact property and tensile property, and method for producing the same
CN103627980B (en) * 2013-11-25 2016-01-20 首钢总公司 Low temperature large wall thickness X80HD gross distortion pipe line steel and production method thereof
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