CN105018121A - Gas, tar and activated carton co-production system - Google Patents
Gas, tar and activated carton co-production system Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明属于热解气、焦油和活性炭生产技术领域,具体是涉及一种热解气、焦油和活性炭的联产系统。 The invention belongs to the technical field of pyrolysis gas, tar and activated carbon production, and in particular relates to a combined production system of pyrolysis gas, tar and activated carbon.
背景技术 Background technique
活性炭是一种疏松多孔类炭质材料,具有吸附作用,广泛应用于化工、医药、环保等行业。兰炭,即半焦,是一种采用中低温干馏工艺生产出的一种高固定碳含量的固体物质,生产半焦的同时副产焦油和焦炉煤气,半焦可广泛应用于电石、铁合金、活性炭制备和城市居民洁净用煤等生产生活领域。焦油用途极为广泛,可制取清洁燃料油,也是合成塑料、染料、纤维、橡胶、农药、医药、耐高温材料等有机化工的重要原料;焦炉煤气可用于发电、冶金、制取氢气、合成氨、甲醇、笨等化工产品以及工业煅烧用热源等。 Activated carbon is a kind of loose and porous carbonaceous material with adsorption effect, which is widely used in chemical industry, medicine, environmental protection and other industries. Semi-coke, that is, semi-coke, is a solid substance with high fixed carbon content produced by a medium-low temperature dry distillation process. During the production of semi-coke, tar and coke oven gas are by-products. Semi-coke can be widely used in calcium carbide, iron alloys , Activated carbon preparation and urban residents clean coal and other production and living fields. Tar has a wide range of uses and can be used to produce clean fuel oil. It is also an important raw material for organic chemicals such as synthetic plastics, dyes, fibers, rubber, pesticides, medicines, and high-temperature-resistant materials; coke oven gas can be used for power generation, metallurgy, hydrogen production, and ammonia synthesis. , methanol, stupid and other chemical products and heat sources for industrial calcination.
目前,国内外煤炭干馏技术包括:外热式立式炉工艺、内热式立式炉工艺、美国的Toscoal工艺、德国的LR工艺、前苏联3TX(ETCH)-175工艺、澳大利亚的流化床快速热解工艺、中国的多段回转炉工艺、中国固体热载体新法干馏、西安三瑞实业有限公司的外热式卧置回转炭化炉热解工艺等。内热式直立炭化炉热裂解制备兰炭工艺是目前运用最广泛,规模最大、最多的一种裂解原煤制备兰炭的工艺。工艺流程主要为:原料煤由炉体顶部上煤斗连续垂直加入焦炉,经预热后落入干馏段,干馏段干馏温度为600℃~700℃,干馏所用热量主要由回炉煤气与空气在火道内混合均匀后,由鼓风机经火口吹入干馏段燃烧,干馏段下部焦炭落入水封槽冷却,然后排出。荒煤气在干馏室内沿料层上升,通过煤气收集罩、上升管、桥管先后经文氏管塔、旋流板塔洗涤,煤气在风机的作用下回炉加热,剩余 部分放散。焦油进入沉淀池脱水,然后集中在焦油池进行静置恒温加热和二次脱水,脱水后的焦油即为成品油。 At present, coal carbonization technologies at home and abroad include: externally heated vertical furnace process, internally heated vertical furnace process, Toscoal process in the United States, LR process in Germany, 3TX (ETCH)-175 process in the former Soviet Union, fluidized bed rapid Pyrolysis process, China's multi-stage rotary furnace process, China's new dry distillation of solid heat carrier, Xi'an Sanrui Industrial Co., Ltd.'s external heating horizontal rotary carbonization furnace pyrolysis process, etc. The process of preparing semi-coke by thermal cracking in an internal heating vertical carbonization furnace is currently the most widely used, largest and largest process for cracking raw coal to prepare semi-coke. The process is mainly as follows: the raw coal is continuously and vertically fed into the coke oven from the coal hopper on the top of the furnace body, and then falls into the carbonization section after preheating. After mixing evenly in the fire channel, the blower blows it into the dry distillation section through the burner for combustion, and the coke in the lower part of the dry distillation section falls into the water-sealed tank to cool, and then is discharged. Raw coal gas rises along the material layer in the retort chamber, passes through the gas collection hood, rising pipe, and bridge pipe, and is washed by the Venturi tower and the swirl plate tower successively. The gas is returned to the furnace for heating under the action of the fan, and the remaining part is released. The tar enters the sedimentation tank for dehydration, and then concentrates in the tar pool for static heating and secondary dehydration. The dehydrated tar is the refined oil.
上述方法的不足之处为: The disadvantages of the above method are:
1、采用内热式干馏,炉内包含大量空气,因此生成的煤气热值较低,其中含氢气、甲烷较低,氮气含量过高,达不到化工利用的最佳条件,只能当作燃料。 1. Internal heating type dry distillation is adopted, and the furnace contains a large amount of air, so the generated gas has a low calorific value, contains low hydrogen, methane, and high nitrogen content, which cannot meet the best conditions for chemical utilization and can only be used as fuel .
2、其兰炭熄焦处理时采用湿法出焦,消耗了一部分兰炭的潜热,且产品含水量较高,影响兰炭的质量,限制兰炭的使用,增加运输成本,需要消耗额外的能量对其进行干燥;另外熄焦过程产生的废蒸汽含有大量的有毒有害物质,恶化现场操作环境,污染大气;而且熄焦产生的大量含酚废水,后处理成本昂贵。 2. The semi-coke is quenched by wet method, which consumes a part of the latent heat of semi-coke, and the product has a high water content, which affects the quality of semi-coke, limits the use of semi-coke, increases transportation costs, and consumes additional In addition, the waste steam generated during the coke quenching process contains a large amount of toxic and harmful substances, which deteriorates the on-site operating environment and pollutes the atmosphere; and the large amount of phenol-containing wastewater generated by coke quenching is expensive for post-treatment.
3、焦油回收率偏低。 3. The tar recovery rate is low.
发明内容 Contents of the invention
本发明的目的在于克服上述现有技术中的不足,提供一种煤气、焦油和活性炭的联产系统。该联产系统利用了半焦活化的伴生气体为热解供热提高了热解效率并同时减少了热解气中的含氮量;二氧化碳和水蒸气的混合气体通过冷却炉不仅能对其进行预热进而为通入活化炉作为气体活化剂使用做准备,还能够对活性炭进行有效的冷却。 The purpose of the present invention is to overcome the deficiencies in the above-mentioned prior art and provide a cogeneration system of gas, tar and activated carbon. The cogeneration system uses semi-coke activated associated gas to provide heat for pyrolysis, which improves the pyrolysis efficiency and reduces the nitrogen content in the pyrolysis gas at the same time; Preheating prepares for passing through the activation furnace as a gas activator, and can also effectively cool the activated carbon.
为实现上述目的,本发明采用的技术方案是:一种煤气、焦油和活性炭的联产系统,其特征在于:包括用于对煤进行预热和热解的热解炉、用于对热解产生的半焦进行活化的活化炉和用于对活化产生的活性炭进行冷却处理的冷却炉,所述热解炉、活化炉和冷却炉依次连通,所述热解炉、活化炉和冷却炉均为回转炉,所述热解炉包括预热炉体和与预热炉体连通的热解炉体,所述预热炉体远离热解炉体的一端设置有进煤口和热解气出口,所述活化炉的外侧设置有隔热夹套,所述活化炉与隔热夹套之间构成用于容纳活化加热气体的加热腔室,所述冷却炉远离活化炉的一端连接有 出料箱,所述出料箱上设置有活性炭出口和用于向出料箱内通入水蒸气和二氧化碳混合气体的冷却气体入口,所述冷却炉的外侧设置有冷却夹套,所述冷却炉与所述冷却夹套之间构成冷却腔室,所述冷却夹套上开设有冷却水进口和蒸汽出口,所述冷却水进口和蒸汽出口均通向所述冷却腔室,所述蒸汽出口与所述冷却气体入口相连通。 In order to achieve the above object, the technical solution adopted by the present invention is: a co-production system of gas, tar and activated carbon, characterized in that it includes a pyrolysis furnace for preheating and pyrolysis of coal, and a pyrolysis furnace for pyrolysis An activation furnace for activating the generated semi-coke and a cooling furnace for cooling the activated carbon produced by activation, the pyrolysis furnace, activation furnace and cooling furnace are connected in sequence, and the pyrolysis furnace, activation furnace and cooling furnace are all It is a rotary furnace, the pyrolysis furnace includes a preheating furnace body and a pyrolysis furnace body connected with the preheating furnace body, and the end of the preheating furnace body away from the pyrolysis furnace body is provided with a coal inlet and a pyrolysis gas outlet , the outer side of the activation furnace is provided with a heat insulation jacket, a heating chamber for accommodating the activated heating gas is formed between the activation furnace and the heat insulation jacket, and the end of the cooling furnace far away from the activation furnace is connected with a discharge box, the discharge box is provided with an activated carbon outlet and a cooling gas inlet for introducing a mixture of water vapor and carbon dioxide into the discharge box, a cooling jacket is provided on the outside of the cooling furnace, and the cooling furnace and the A cooling chamber is formed between the cooling jackets, and a cooling water inlet and a steam outlet are provided on the cooling jacket, and both the cooling water inlet and the steam outlet lead to the cooling chamber, and the steam outlet and the The cooling gas inlets are connected.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:包括用于将煤气和焦油从热解气中分离出来的分离系统,所述分离系统与所述热解气出口相连通。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that it includes a separation system for separating coal gas and tar from pyrolysis gas, and the separation system is connected to the outlet of the pyrolysis gas Pass.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:所述分离系统包括用于除去热解气中的粉尘的除尘器、用于对热解气进行冷凝处理的间接冷却器和用于对热解气冷凝后形成的油水混合物进行焦油捕集的电捕焦油器,以及采用MEA溶液对热解气中的二氧化碳进行捕集的吸收塔和解吸塔,所述热解气出口与除尘器底部相连通,所述除尘器的顶部与间接冷却器的底部相连通,所述间接冷却器的顶部与电捕焦油器的底部相连通,所述电捕焦油器的顶部与吸收塔的底部相连通,所述吸收塔的底部与所述解吸塔的顶部相连通,所述解吸塔的底部与吸收塔的顶部连通,所述吸收塔的顶部设置有煤气出口,所述解吸塔的顶部设置有二氧化碳出口,所述电捕焦油器的底部连接有焦油储槽。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that: the separation system includes a dust collector for removing dust in the pyrolysis gas, an indirect cooling system for condensing the pyrolysis gas device and an electric tar collector for trapping the oil-water mixture formed after the pyrolysis gas is condensed, and an absorption tower and a desorption tower for capturing carbon dioxide in the pyrolysis gas by using the MEA solution, the pyrolysis gas The outlet is connected to the bottom of the dust collector, the top of the dust collector is connected to the bottom of the indirect cooler, the top of the indirect cooler is connected to the bottom of the electric tar catcher, and the top of the electric tar catcher is connected to the absorption The bottom of the tower is connected, the bottom of the absorption tower is connected with the top of the desorption tower, the bottom of the desorption tower is connected with the top of the absorption tower, the top of the absorption tower is provided with a gas outlet, and the desorption tower The top of the electric tar catcher is provided with a carbon dioxide outlet, and the bottom of the electric tar catcher is connected with a tar storage tank.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:所述分离系统还包括用于收集间接冷却器中的油水混合物并分离出焦油的焦油氨水澄清池,所述焦油氨水澄清池上开设有焦油输出口、焦油渣输出口和氨水排出口。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that: the separation system also includes a tar ammonia water clarifier for collecting the oil-water mixture in the indirect cooler and separating tar, and the tar ammonia water The clarifier is provided with a tar output port, a tar residue output port and an ammonia water discharge port.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:所述焦油氨水澄清池为密封式氨水槽。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that: the tar ammonia water clarification tank is a sealed ammonia water tank.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:所述间接冷却器为列管式换热器。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that: the indirect cooler is a tube-and-tube heat exchanger.
上述的一种热解气、焦油和活性炭的联产系统,其特征在于:所述除 尘器为高温旋风除尘器。 The above-mentioned cogeneration system of pyrolysis gas, tar and activated carbon is characterized in that: the dust collector is a high-temperature cyclone dust collector.
本发明与现有技术相比具有以下优点: Compared with the prior art, the present invention has the following advantages:
1、本发明的结构简单,设计新颖合理。 1. The structure of the present invention is simple, and the design is novel and reasonable.
2、本发明通过设置加热腔室对活化炉内的半焦进行间接加热,避免采用燃烧半焦提供活化热源,从而增加了活性炭生产能力,又提高了活性炭的品质,代替现有技术中的空气燃烧室供热方式,减少了煤气中的含氮量。 2. The present invention indirectly heats the semi-coke in the activation furnace by setting a heating chamber, avoiding the use of burning semi-coke to provide an activation heat source, thereby increasing the production capacity of activated carbon, and improving the quality of activated carbon, replacing the air in the prior art The heating mode of the combustion chamber reduces the nitrogen content in the gas.
3、本发明在对活性炭冷却时,通过将间接冷却方式和直接冷却方向相结合,能够实现对活性炭充分、彻底冷却,且能够确保活性炭的含水率较低,提高了活性炭的品质。 3. When the present invention cools the activated carbon, by combining the indirect cooling method and the direct cooling direction, the activated carbon can be fully and completely cooled, and the moisture content of the activated carbon can be ensured to be low, thereby improving the quality of the activated carbon.
4、本发明通过分离系统,能够将焦油和煤气从热解气中有效的分离出来,并通过对二氧化碳的捕集能够提高煤气热值,同时又减少了二氧化碳的排放量,避免二氧化碳的存在对煤气热值产生的影响。 4. The present invention can effectively separate tar and coal gas from the pyrolysis gas through the separation system, and can increase the calorific value of the gas through the capture of carbon dioxide, and at the same time reduce the emission of carbon dioxide, avoiding the impact of the presence of carbon dioxide on The impact of gas calorific value.
5、本发明的分离系统通过设置焦油氨水澄清池,能够对热解气在间接冷却器内冷凝形成的油水混合物进行进一步的处理,从所述油水混合物中有效分离出焦油,提高了焦油的产率和回收率。 5. The separation system of the present invention can further process the oil-water mixture formed by the condensation of the pyrolysis gas in the indirect cooler by setting the tar ammonia water clarification tank, effectively separate the tar from the oil-water mixture, and improve the production of tar. rates and recovery rates.
6、本发明所述除尘器采用高温旋风除尘器。通过采用高温旋风除尘器,能够保证除尘器内的温度处于高温状态,以有效减少重油在除尘器内冷凝。 6. The dust collector of the present invention adopts a high-temperature cyclone dust collector. By adopting a high-temperature cyclone dust collector, it can ensure that the temperature inside the dust collector is at a high temperature, so as to effectively reduce the condensation of heavy oil in the dust collector.
7、本发明的原料粒径小于等于6mm的粉煤,能够充分利用小粒径煤。 7. The pulverized coal whose raw material particle size is less than or equal to 6mm in the present invention can make full use of small particle size coal.
下面通过附图和实施例,对本发明的技术方案做进一步的详细描述。 The technical solutions of the present invention will be described in further detail below with reference to the accompanying drawings and embodiments.
附图说明 Description of drawings
图1为本发明的结构示意图。 Fig. 1 is a structural schematic diagram of the present invention.
图2为图1中的A-A断面图。 Fig. 2 is a sectional view of A-A in Fig. 1 .
图3为图1中的B-B断面图。 Fig. 3 is a B-B sectional view in Fig. 1 .
附图标记说明: Explanation of reference signs:
1—热解炉; 1-1—预热炉体; 1-2—热解炉体; 1—pyrolysis furnace; 1-1—preheating furnace body; 1-2—pyrolysis furnace body;
1-3—进煤口; 1-4—热解气出口; 1-5—动力装置; 1-3—coal inlet; 1-4—pyrolysis gas outlet; 1-5—power device;
1-6—大齿轮; 1-7—第一托轮; 1-8—第一托轮座; 1-6—big gear; 1-7—the first roller; 1-8—the first roller seat;
2—活化炉; 2-1—第二托轮; 2-2—第二托轮座; 2—activation furnace; 2-1—the second supporting wheel; 2-2—the second supporting wheel seat;
2-3—第一支座; 3—隔热夹套; 3-1—活化加热气进口; 2-3—the first support; 3—heat insulation jacket; 3-1—activated heating gas inlet;
3-2—活化加热气出口; 4—加热腔室; 5—冷却夹套; 3-2—activated heating gas outlet; 4—heating chamber; 5—cooling jacket;
5-1—冷却水进口; 5-2—蒸汽出口; 6—冷却腔室; 5-1—cooling water inlet; 5-2—steam outlet; 6—cooling chamber;
7—冷却炉; 7-1—第三托轮; 7-2—第三托轮座; 7—cooling furnace; 7-1—the third supporting wheel; 7-2—the third supporting wheel seat;
7-3—第二支座; 8—出料箱; 8-1—活性炭出口; 7-3—the second support; 8—discharge box; 8-1—activated carbon outlet;
8-2—冷却气体入口; 9—除尘器; 10—间接冷却器; 8-2—cooling gas inlet; 9—dust collector; 10—indirect cooler;
11—电捕焦油器; 12—吸收塔; 12-1—煤气出口; 11—electric tar catcher; 12—absorption tower; 12-1—gas outlet;
13—解吸塔; 13-1—二氧化碳出口;14—二氧化碳储罐; 13—desorption tower; 13-1—carbon dioxide outlet; 14—carbon dioxide storage tank;
15—焦油储槽; 16—焦油中间槽; 17—焦油渣槽; 15—tar storage tank; 16—tar intermediate tank; 17—tar residue tank;
18—焦油氨水澄清池; 19—氨水回收槽。 18—tar ammonia water clarification tank; 19—ammonia water recovery tank.
具体实施方式 Detailed ways
如图1、图2和图3所示的一种煤气、焦油和活性炭的联产系统,包括用于对煤进行预热和热解的热解炉1、用于对热解产生的半焦进行活化的活化炉2和用于对活化产生的活性炭进行冷却处理的冷却炉7,所述热解炉1、活化炉2和冷却炉7依次连通,所述热解炉1、活化炉2和冷却炉7均为回转炉,所述热解炉1包括预热炉体1-1和与预热炉体1-1连通的热解炉体1-2,所述预热炉体1-1远离热解炉体1-2的一端设置有进煤口1-3和热解气出口1-4,所述活化炉2的外侧设置有隔热夹套3,所述活化炉2与隔热夹套3之间构成用于容纳活化加热气体的加热腔室4,其中,所述隔热夹套3上开设有活化加热气进口3-1和活化加热气出口3-2,所述活化加热气进口3-1和活化加热气出口3-2均通向所述加热腔室4,所述冷却炉7远离活化炉2的一端连接有出料箱8,所述出料箱8上设置有活性炭出口8-1和用于向出料箱8内通入水蒸气和二氧化碳混合气体的冷却气体入口8-2,所述冷却炉7 的外侧设置有冷却夹套5,所述冷却炉7与所述冷却夹套5之间构成冷却腔室6,所述冷却夹套5上开设有冷却水进口5-1和蒸汽出口5-2,所述冷却水进口5-1和蒸汽出口5-2均通向所述冷却腔室6,所述蒸汽出口5-2与所述冷却气体入口8-2相连通。 A cogeneration system of gas, tar and activated carbon as shown in Figure 1, Figure 2 and Figure 3, including a pyrolysis furnace 1 for preheating and pyrolyzing coal, semi-coke for pyrolysis The activation furnace 2 for activation and the cooling furnace 7 for cooling the activated carbon produced by activation, the pyrolysis furnace 1, the activation furnace 2 and the cooling furnace 7 are connected successively, and the pyrolysis furnace 1, the activation furnace 2 and the The cooling furnace 7 is a rotary furnace, and the pyrolysis furnace 1 includes a preheating furnace body 1-1 and a pyrolysis furnace body 1-2 communicated with the preheating furnace body 1-1, and the preheating furnace body 1-1 One end away from the pyrolysis furnace body 1-2 is provided with a coal inlet 1-3 and a pyrolysis gas outlet 1-4, and the outer side of the activation furnace 2 is provided with a heat insulation jacket 3, and the activation furnace 2 is insulated from the heat insulation A heating chamber 4 for accommodating activated heating gas is formed between the jackets 3, wherein an activated heating gas inlet 3-1 and an activated heating gas outlet 3-2 are opened on the heat insulating jacket 3, and the activated heating gas The gas inlet 3-1 and the activated heating gas outlet 3-2 all lead to the heating chamber 4, and the end of the cooling furnace 7 away from the activation furnace 2 is connected with a discharge box 8, and the discharge box 8 is provided with Activated carbon outlet 8-1 and the cooling gas inlet 8-2 that is used to pass into water vapor and carbon dioxide mixed gas in the discharge box 8, the outside of described cooling furnace 7 is provided with cooling jacket 5, described cooling furnace 7 and all A cooling chamber 6 is formed between the cooling jackets 5, and a cooling water inlet 5-1 and a steam outlet 5-2 are provided on the cooling jacket 5, and the cooling water inlet 5-1 and the steam outlet 5-2 are both Leading to the cooling chamber 6, the steam outlet 5-2 communicates with the cooling gas inlet 8-2.
本实施例中,该联产系统在使用时,所述热解炉1、活化炉2和冷却炉7同步回转,粉煤从进煤口1-3加入热解炉1的预热炉体1-1内,经预热后的粉煤进入热解炉1的热解炉体1-2内,在热解炉体1-2内粉煤热解生产热解气和半焦,其中热解气从所述热解气出口1-4输出以进一步分离出煤气和焦油,其中半焦进入活化炉2内活化生产活性炭,活性炭进入冷却炉7内冷却后再进入出料箱8。 In this embodiment, when the cogeneration system is in use, the pyrolysis furnace 1, the activation furnace 2 and the cooling furnace 7 rotate synchronously, and pulverized coal is fed into the preheating furnace body 1 of the pyrolysis furnace 1 from the coal inlet 1-3 In -1, the preheated pulverized coal enters the pyrolysis furnace body 1-2 of the pyrolysis furnace 1, and the pulverized coal is pyrolyzed in the pyrolysis furnace body 1-2 to produce pyrolysis gas and semi-coke, wherein the pyrolysis The gas is output from the pyrolysis gas outlet 1-4 to further separate the gas and tar, wherein the semi-coke enters the activation furnace 2 to be activated to produce activated carbon, and the activated carbon enters the cooling furnace 7 to cool and then enters the discharge box 8.
本实施例中,该联产系统通过设置加热腔室4对活化炉2内的半焦进行间接加热,避免采用燃烧半焦提供活化热源,从而增加了活性炭生产能力,又提高了活性炭的品质,代替现有技术中的空气燃烧室供热方式,减少了煤气中的含氮量。另外,通过活化炉2内产生的伴生气体进入热解炉体1-2为粉煤热解提供热量,再进入预热炉体1-1为粉煤的预热提供热量。本实施例中,由于通入活化炉2内的气体活化剂为水蒸气和二氧化碳的混合气体,在半焦活化的过程中,产生了伴生气即CO和H2的混合气体,所述伴生气中所含的H2进而实现加氢热解,大大的提高了焦油的产率和煤气的品质。所述水蒸气和二氧化碳的混合气体是通入出料箱8进而通过冷却炉7接触活性炭进行直接冷却,水蒸气和二氧化碳的混合气体在冷却活性炭的同时也被预热再进入活化炉2内作为气体活化剂使用。并且,该联产系统在对活性炭冷却时,通过将间接冷却方式和直接冷却方向相结合大大增加了对活性炭的冷却效果,其中,直接冷却方式即为上述水蒸气和二氧化碳的混合气体在冷却炉7内对活性炭的直接冷却,所述间接冷却方式为通过冷却水进口5-1向冷却腔室6内通入冷却水,冷却水以非接触的方式对冷却炉7内活性炭进行间接冷却,在冷却活性炭的同时,冷却水被加热成水蒸气形式并从蒸汽出口5-2输送至冷却气体入口8-2中以与二氧化碳混合形成用于直接冷却的冷却气 体。 In this embodiment, the cogeneration system indirectly heats the semi-coke in the activation furnace 2 by setting the heating chamber 4, avoiding the use of burning semi-coke to provide the activation heat source, thereby increasing the production capacity of activated carbon and improving the quality of activated carbon. It replaces the air combustion chamber heating mode in the prior art, and reduces the nitrogen content in the gas. In addition, the associated gas generated in the activation furnace 2 enters the pyrolysis furnace body 1-2 to provide heat for the pyrolysis of pulverized coal, and then enters the preheating furnace body 1-1 to provide heat for the preheating of pulverized coal. In this embodiment, since the gas activator passed into the activation furnace 2 is a mixed gas of water vapor and carbon dioxide, in the process of semi-coke activation, an associated gas, namely a mixed gas of CO and H 2 is produced, and the associated gas The H 2 contained in the gas can further realize hydropyrolysis, which greatly improves the yield of tar and the quality of gas. The mixed gas of water vapor and carbon dioxide is passed into the discharge box 8 and then directly cooled by contacting the activated carbon through the cooling furnace 7. The mixed gas of water vapor and carbon dioxide is also preheated while cooling the activated carbon and then enters the activation furnace 2 as a gas Activator used. Moreover, when the cogeneration system cools the activated carbon, the cooling effect on the activated carbon is greatly increased by combining the indirect cooling method and the direct cooling direction. The direct cooling of activated carbon in 7, the indirect cooling method is to pass cooling water into the cooling chamber 6 through the cooling water inlet 5-1, and the cooling water indirectly cools the activated carbon in the cooling furnace 7 in a non-contact manner. While cooling the activated carbon, the cooling water is heated into steam form and sent from the steam outlet 5-2 into the cooling gas inlet 8-2 to be mixed with carbon dioxide to form cooling gas for direct cooling.
本实施例中,所述热解炉1、活化炉2和冷却炉7依次连通,在回转时同步,于是,所述热解炉1、活化炉2和冷却炉7只需要一个动力装置1-5即可,所述动力装置1-5驱动热解炉1上的大齿轮1-6,所述大齿轮1-6带动热解炉1的预热炉体1-1和热解炉体1-2转动,所述热解炉1的两端均设置有第一托轮1-7和与所述第一托轮1-7相配合的第一托轮座1-8。所述活化炉2靠近热解炉1的部分设置有第二托轮2-1和与所述第二托轮2-1相配合的第二托轮座2-2。所述冷却炉7靠近出料箱8的部分设置有第三托轮7-1和与所述第三托轮7-1相配合的第三托轮座7-2。所述活化炉2的底部设置有第一支座2-3,所述冷却炉7的底部设置有第二支座7-3。其中,所述动力装置1-5包括电机和与电机传动连接的减速机,所述减速机的输出轴上安装有与所述大齿轮1-6相啮合的小齿轮。 In this embodiment, the pyrolysis furnace 1, the activation furnace 2 and the cooling furnace 7 are sequentially connected and synchronized during rotation, so the pyrolysis furnace 1, the activation furnace 2 and the cooling furnace 7 only need one power unit 1- 5, the power unit 1-5 drives the large gear 1-6 on the pyrolysis furnace 1, and the large gear 1-6 drives the preheating furnace body 1-1 and the pyrolysis furnace body 1 of the pyrolysis furnace 1 -2 rotation, both ends of the pyrolysis furnace 1 are provided with a first supporting wheel 1-7 and a first supporting wheel seat 1-8 matched with the first supporting wheel 1-7. The part of the activation furnace 2 close to the pyrolysis furnace 1 is provided with a second supporting wheel 2-1 and a second supporting wheel seat 2-2 matched with the second supporting wheel 2-1. The part of the cooling furnace 7 close to the discharge box 8 is provided with a third supporting roller 7-1 and a third supporting roller seat 7-2 matched with the third supporting roller 7-1. The bottom of the activation furnace 2 is provided with a first support 2-3, and the bottom of the cooling furnace 7 is provided with a second support 7-3. Wherein, the power device 1-5 includes a motor and a reducer connected to the motor, and a pinion gear meshing with the bull gear 1-6 is installed on the output shaft of the reducer.
本实施例中,该联产系统还包括用于将煤气和焦油从热解气中分离出来的分离系统,所述分离系统与所述热解气出口1-4相连通。 In this embodiment, the cogeneration system further includes a separation system for separating coal gas and tar from the pyrolysis gas, and the separation system is connected to the pyrolysis gas outlet 1-4.
如图1所示,所述分离系统包括用于除去热解气中的粉尘的除尘器9、用于对热解气进行冷凝处理的间接冷却器10和用于对热解气冷凝后形成的油水混合物进行焦油捕集的电捕焦油器11,以及采用MEA溶液对热解气中的二氧化碳进行捕集的吸收塔12和解吸塔13,所述热解气出口1-4与除尘器9底部相连通,所述除尘器9的顶部与间接冷却器10的底部相连通,所述间接冷却器10的顶部与电捕焦油器11的底部相连通,所述电捕焦油器11的顶部与吸收塔12的底部相连通,所述吸收塔12的底部与所述解吸塔13的顶部相连通,所述解吸塔13的底部与吸收塔12的顶部连通,所述吸收塔12的顶部设置有煤气出口12-1,所述解吸塔13的顶部设置有二氧化碳出口13-1,所述电捕焦油器11的底部连接有焦油储槽15。 As shown in Figure 1, the separation system includes a dust collector 9 for removing dust in the pyrolysis gas, an indirect cooler 10 for condensing the pyrolysis gas, and an indirect cooler 10 for condensing the pyrolysis gas. An electric tar catcher 11 for collecting tar from an oil-water mixture, and an absorption tower 12 and a desorption tower 13 for trapping carbon dioxide in the pyrolysis gas using MEA solution, the pyrolysis gas outlets 1-4 are connected to the bottom of the dust collector 9 The top of the dust collector 9 is connected with the bottom of the indirect cooler 10, the top of the indirect cooler 10 is connected with the bottom of the electric tar catcher 11, and the top of the electric tar catcher 11 is connected with the absorption The bottom of tower 12 is connected, and the bottom of described absorption tower 12 is connected with the top of described desorption tower 13, and the bottom of described desorption tower 13 is connected with the top of absorption tower 12, and the top of described absorption tower 12 is provided with gas Outlet 12-1, the top of the desorption tower 13 is provided with a carbon dioxide outlet 13-1, and the bottom of the electric tar collector 11 is connected with a tar storage tank 15.
本实施例中,所述分离系统在使用时,首先通过除尘器9将热解气中的粉尘有效拦截,再通过间接冷却器10对热解气进行冷凝,热解气冷凝后形成油水混合物和低温煤气,其中低温煤气进入送入电捕焦油器11进 行焦油捕集去除低温煤气中的焦油,在电捕焦油器11中捕集到的焦油输送至焦油储槽15内,剩余的煤气进入吸收塔12底部,煤气从下向上流动,贫液从吸收塔12的塔顶自上而下连续流下,与向上通入的煤气进行接触,煤气中的二氧化碳与MEA溶液发生化学反应,二氧化碳被MEA溶液吸收,净化后的煤气从吸收塔12顶部的煤气出口12-1输出,二氧化碳在吸收的同时,液体释放出反应热,富液被送入解吸塔13的塔顶,解吸塔13由再沸器提供热量,产生大量的蒸汽,蒸汽在解吸塔13内向上流动,与流下的富液接触,富液经过加热和汽提的双重作用后,二氧化碳逐渐从富液中解吸释放出来,富液成为贫液,所述贫液再从解吸塔13的底部输送至吸收塔12的顶部再次利用,解吸出的二氧化碳从解吸塔13顶部的二氧化碳出口13-1输送至二氧化碳储罐14,进而为活化炉2内半焦的活化提供活化剂。 In this embodiment, when the separation system is in use, the dust in the pyrolysis gas is first effectively intercepted by the dust collector 9, and then the pyrolysis gas is condensed by the indirect cooler 10, and the pyrolysis gas is condensed to form an oil-water mixture and Low-temperature gas, wherein the low-temperature gas enters into the electric tar catcher 11 for tar capture to remove the tar in the low-temperature gas, the tar captured in the electric tar catcher 11 is transported to the tar storage tank 15, and the remaining gas enters At the bottom of the absorption tower 12, the gas flows from bottom to top, and the lean liquid flows continuously from the top of the absorption tower 12 from top to bottom, and contacts with the gas flowing upwards. The carbon dioxide in the gas reacts with the MEA solution, and the carbon dioxide is absorbed by the MEA. Solution absorption, the purified gas is output from the gas outlet 12-1 at the top of the absorption tower 12, while the carbon dioxide is being absorbed, the liquid releases heat of reaction, and the rich liquid is sent to the top of the desorption tower 13, and the desorption tower 13 is reboiled The device provides heat to generate a large amount of steam. The steam flows upward in the desorption tower 13 and contacts the flowing rich liquid. After the rich liquid is heated and stripped, carbon dioxide is gradually desorbed and released from the rich liquid, and the rich liquid becomes The lean liquid is transported from the bottom of the desorption tower 13 to the top of the absorption tower 12 for reuse, and the desorbed carbon dioxide is transported to the carbon dioxide storage tank 14 from the carbon dioxide outlet 13-1 at the top of the desorption tower 13, and then becomes an activation furnace. Activation of the inner coke provides the activator.
本实施例中,该分离系统通过对二氧化碳的捕集能够提高煤气热值,同时又减少了二氧化碳的排放量,避免二氧化碳的存在对煤气热值产生的影响。 In this embodiment, the separation system can increase the calorific value of the gas by capturing carbon dioxide, and at the same time reduce the emission of carbon dioxide, avoiding the influence of the presence of carbon dioxide on the calorific value of the gas.
如图1所示,所述分离系统还包括用于收集间接冷却器10底部油水混合物并分离出焦油的焦油氨水澄清池18,所述焦油氨水澄清池18上开设有焦油输出口、焦油渣输出口和氨水排出口。通过设置焦油氨水澄清池18,能够对热解气在间接冷却器10内冷凝形成的油水混合物进行进一步的处理,从所述油水混合物中有效分离出焦油,提高了焦油的产率。其中,所述焦油输出口连接有焦油中间槽16,所述焦油中间槽16与焦油储槽15相连接,所述焦油渣输出口连接有焦油渣槽17,所述氨水排出口连接有氨水回收槽19。 As shown in Figure 1, the separation system also includes a tar ammonia water clarifier 18 for collecting the oil-water mixture at the bottom of the indirect cooler 10 and separating tar, and the tar ammonia water clarifier 18 is provided with a tar output port and a tar residue output. mouth and ammonia outlet. The oil-water mixture formed by the condensation of the pyrolysis gas in the indirect cooler 10 can be further processed by setting the tar ammonia water clarification tank 18, and the tar is effectively separated from the oil-water mixture, thereby increasing the yield of the tar. Wherein, the tar output port is connected with a tar intermediate tank 16, the tar intermediate tank 16 is connected with the tar storage tank 15, the tar residue output port is connected with a tar residue tank 17, and the ammonia water outlet is connected with an ammonia recovery Groove 19.
本实施例中,所述焦油氨水澄清池18为密封式氨水槽。所述间接冷却器10为列管式换热器。 In this embodiment, the tar ammonia water clarification tank 18 is a sealed ammonia water tank. The indirect cooler 10 is a shell and tube heat exchanger.
本实施例中,所述除尘器9为高温旋风除尘器。通过采用高温旋风除尘器,能够保证除尘器9内的温度处于高温状态,以有效减少重油在除尘器9内冷凝。 In this embodiment, the dust collector 9 is a high-temperature cyclone dust collector. By adopting a high-temperature cyclone dust collector, it can ensure that the temperature inside the dust collector 9 is at a high temperature, so as to effectively reduce the condensation of heavy oil in the dust collector 9 .
以上所述,仅是本发明的较佳实施例,并非对本发明作任何限制,凡 是根据本发明技术实质对以上实施例所作的任何简单修改、变更以及等效结构变换,均仍属于本发明技术方案的保护范围内。 The above are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any simple modifications, changes and equivalent structural transformations made to the above embodiments according to the technical essence of the present invention still belong to the present invention. within the protection scope of the technical solution.
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