CN105017708A - Flame retardant plastic for lampshade - Google Patents
Flame retardant plastic for lampshade Download PDFInfo
- Publication number
- CN105017708A CN105017708A CN201510356041.9A CN201510356041A CN105017708A CN 105017708 A CN105017708 A CN 105017708A CN 201510356041 A CN201510356041 A CN 201510356041A CN 105017708 A CN105017708 A CN 105017708A
- Authority
- CN
- China
- Prior art keywords
- lampshade
- flame retardant
- applicable
- fire retardant
- plastics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 50
- 229920003023 plastic Polymers 0.000 title claims abstract description 30
- 239000004033 plastic Substances 0.000 title claims abstract description 30
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 14
- 235000013311 vegetables Nutrition 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 241000196324 Embryophyta Species 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 8
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 8
- 239000010425 asbestos Substances 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- 229910052895 riebeckite Inorganic materials 0.000 claims description 8
- 229960001866 silicon dioxide Drugs 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000000049 pigment Substances 0.000 claims description 7
- 241000123069 Ocyurus chrysurus Species 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims description 4
- 244000157790 Buglossoides arvense Species 0.000 claims description 3
- 235000004256 Buglossoides arvense Nutrition 0.000 claims description 3
- 244000020518 Carthamus tinctorius Species 0.000 claims description 3
- 235000003255 Carthamus tinctorius Nutrition 0.000 claims description 3
- 244000163122 Curcuma domestica Species 0.000 claims description 3
- 235000003392 Curcuma domestica Nutrition 0.000 claims description 3
- 244000111489 Gardenia augusta Species 0.000 claims description 3
- 235000018958 Gardenia augusta Nutrition 0.000 claims description 3
- 235000003325 Ilex Nutrition 0.000 claims description 3
- 241000209035 Ilex Species 0.000 claims description 3
- 241001062009 Indigofera Species 0.000 claims description 3
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 3
- 235000004347 Perilla Nutrition 0.000 claims description 3
- 244000124853 Perilla frutescens Species 0.000 claims description 3
- 244000294611 Punica granatum Species 0.000 claims description 3
- 235000014360 Punica granatum Nutrition 0.000 claims description 3
- 235000003373 curcuma longa Nutrition 0.000 claims description 3
- 229940097275 indigo Drugs 0.000 claims description 3
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 3
- 235000013976 turmeric Nutrition 0.000 claims description 3
- 239000000975 dye Substances 0.000 abstract description 21
- 230000000694 effects Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 238000004040 coloring Methods 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 238000002137 ultrasound extraction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses flame retardant plastic for a lampshade. The flame retardant plastic comprises, by mass, 50-80% of ABS resin, 5-16% of a fire retardant, 8-20% of a filler, 5-15% of an assistant and a certain amount of plant dyes. The flame retardant plastic for a lampshade can effectively improve a plastic flame retardation capability, ensures good strength and wear resistance of plastic and improves safety of the lampshade in use. Through use of a plurality of the plant dyes, the flame retardant plastic for a lampshade has coloring effects and is nontoxic and environmentally friendly. The plants have a certain antibacterial property.
Description
Technical field
The present invention relates to a kind of plastics, particularly relate to a kind of flame retardant plastics being applicable to lampshade.
Background technology
At present, ABS is general thermoplastic engineering plastic, is the very outstanding plastics variety of a comprehensive mechanical property, not only there is good rigidity, hardness and processing fluidity, and there is high tenacity feature, can injection moulding, extrude or thermoforming, but at present ABS resins fire retardant performance is not good.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide one and is applicable to lampshade flame-proof ABS plastics, has good flame retardant properties.
Technical problem to be solved by this invention is achieved by the following technical solution: a kind of flame retardant plastics being applicable to lampshade, comprise: ABS resin, fire retardant, weighting agent, auxiliary agent and vegetable dye, the mass percent ratio of each component is respectively: ABS resin 50% ~ 80%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%.
Preferably, described fire retardant is phosphate type fire retardant, and described phosphate type fire retardant is the siliceous biphosphonate of polyaryl.
Preferably, also comprise vegetable dye, described vegetable dye mass percent is 3% ~ 10%, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: one or more plants in madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, purple perilla.
Preferably, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc.
Preferably, described weighting agent is one or two or more kinds in silicon-dioxide, aluminium hydroxide or asbestos.
Preferably, the mass percent of described silicon-dioxide, aluminium hydroxide and asbestos is about: 3:5:1.5.
Preferably, the mass percent ratio of each component is respectively: ABS resin 69% ~ 74%, fire retardant 8% ~ 10%, weighting agent 10% ~ 15%, vegetable dye 5% ~ 10% and auxiliary agent 6% ~ 8%.
The beneficial effect that the present invention reaches: a kind of flame retardant plastics being applicable to lampshade of the present invention can effectively promote flame retardant of plastic ability, and guarantees the intensity that plastics are good and wear resistance, adds lampshade security in use; Described a kind of flame retardant plastics being applicable to lampshade, by adding various plants source dyestuff, has painted effect, nontoxic and environmental protection, and these plants have certain germ resistance simultaneously.
Embodiment
The invention will be further described below.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
Be applicable to a flame retardant plastics for lampshade, comprise: ABS resin, fire retardant, weighting agent, auxiliary agent and vegetable dye, the mass percent ratio of each component is respectively: ABS resin 50% ~ 80%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%, described fire retardant is phosphate type fire retardant, described phosphate type fire retardant is the siliceous biphosphonate of polyaryl, also comprise vegetable dye, described vegetable dye mass percent is 3% ~ 10%, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, one or more plants in purple perilla, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc., described weighting agent is silicon-dioxide, one or two or more kinds in aluminium hydroxide or asbestos, described silicon-dioxide, the mass percent of aluminium hydroxide and asbestos is about: 3:5:1.5, and the mass percent ratio of each component is respectively: ABS resin 69% ~ 74%, fire retardant 8% ~ 10%, weighting agent 10% ~ 15%, vegetable dye 5% ~ 10%, and auxiliary agent 6% ~ 8%.
The extracting method of described vegetable dye is: plant is cleaned, dry, pulverize after, under the condition of 20-50 DEG C, by the plant of having pulverized and organic solvent by 1: 50 ~ 200 solid-liquid ratio ultrasonic extraction 0.5-5h, suction filtration, filtrate is concentrated, dry, obtain powdered dye.
A kind of preparation method being applicable to the flame retardant plastics of lampshade is: join in high-speed mixer by each component, rotating speed is controlled at 300 ~ 500 revs/min under room temperature, mix 10 ~ 30 minutes, proceed to after taking-up in screw extrusion press, extruding pelletization at 150 DEG C ~ 250 DEG C temperature, namely obtains the flame retardant plastics being applicable to lampshade.
Embodiment 1: a kind of flame retardant plastics being applicable to lampshade, the mass percent ratio of each component is respectively: ABS resin 69% ~ 74%, fire retardant 8% ~ 10%, weighting agent 10% ~ 15%, vegetable dye 5% ~ 10%, with auxiliary agent 6% ~ 8%, described fire retardant is phosphate type fire retardant, described phosphate type fire retardant is the siliceous biphosphonate of polyaryl, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc., described weighting agent is silicon-dioxide, one or two or more kinds in aluminium hydroxide or asbestos, described silicon-dioxide, the mass percent of aluminium hydroxide and asbestos is about: 3:5:1.5, described vegetable dye extracts from the plant can extracting pigment, described vegetable dye extracts from madder, madder is cleaned, dry, after pulverizing, under the condition of 30 DEG C, by the madder of having pulverized and ethanol by 1: 50 solid-liquid ratio ultrasonic extraction 1h, suction filtration, filtrate is concentrated, dry, obtain powdered dye.
A kind of preparation method being applicable to the flame retardant plastics of lampshade is: join in high-speed mixer by each component, control rotating speed under room temperature at 380 revs/min, mix 15 minutes, proceed to after taking-up in screw extrusion press, extruding pelletization at 200 DEG C of temperature, namely obtains the flame retardant plastics being applicable to lampshade.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvement and distortion, these improve and distortion also should be considered as protection scope of the present invention.
Claims (8)
1. one kind is applicable to the flame retardant plastics of lampshade, comprise: ABS resin, fire retardant, weighting agent, auxiliary agent and vegetable dye, the mass percent ratio of each component is respectively: ABS resin 50% ~ 80%, fire retardant 5% ~ 16%, weighting agent 8% ~ 20% and auxiliary agent 5% ~ 15%.
2. according to a kind of flame retardant plastics being applicable to lampshade described in claim 1, it is characterized in that, described fire retardant is phosphate type fire retardant, and described phosphate type fire retardant is the siliceous biphosphonate of polyaryl.
3. a kind of flame retardant plastics being applicable to lampshade according to claim 1, is characterized in that, also comprise vegetable dye, and described vegetable dye mass percent is 3% ~ 10%.
4. a kind of flame retardant plastics being applicable to lampshade according to claim 3, it is characterized in that, described vegetable dye extracts from the plant can extracting pigment, and the described plant containing extracting pigment comprises: one or more plants in madder, Asian puccoon, bush, indigo, safflower, pomegranate, Chinese ilex, cape jasmine, turmeric, dye yam, Turkey-galls, purple perilla.
5., according to a kind of flame retardant plastics being applicable to lampshade described in claim 1, it is characterized in that, described auxiliary agent comprises softening agent, lubricant, stablizer and oxidation inhibitor etc.
6. according to a kind of flame retardant plastics being applicable to lampshade described in claim 1, it is characterized in that, described weighting agent is one or two or more kinds in silicon-dioxide, aluminium hydroxide or asbestos.
7., according to a kind of flame retardant plastics being applicable to lampshade described in claim 6, it is characterized in that, the mass percent of described silicon-dioxide, aluminium hydroxide and asbestos is about: 3:5:1.5.
8. a kind of flame retardant plastics being applicable to lampshade according to claim 3, it is characterized in that, the mass percent ratio of each component is respectively: ABS resin 69% ~ 74%, fire retardant 8% ~ 10%, weighting agent 10% ~ 15%, vegetable dye 5% ~ 10% and auxiliary agent 6% ~ 8%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510356041.9A CN105017708A (en) | 2015-06-25 | 2015-06-25 | Flame retardant plastic for lampshade |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510356041.9A CN105017708A (en) | 2015-06-25 | 2015-06-25 | Flame retardant plastic for lampshade |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105017708A true CN105017708A (en) | 2015-11-04 |
Family
ID=54408035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510356041.9A Pending CN105017708A (en) | 2015-06-25 | 2015-06-25 | Flame retardant plastic for lampshade |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105017708A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312288A (en) * | 2017-06-26 | 2017-11-03 | 俞惠英 | A kind of low temperature resistant flame retardant material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3932321A (en) * | 1973-06-18 | 1976-01-13 | Japan Synthetic Rubber Company Limited | Flame-retardant polymer composition |
| US4022849A (en) * | 1971-01-21 | 1977-05-10 | Stauffer Chemical Company | Crosslinked vinyl halide polymers as flame retardant additives for thermoplastics |
| CN101704983A (en) * | 2009-09-30 | 2010-05-12 | 东莞市上洲塑胶科技有限公司 | High-performance flame-resistant ABS resin and preparation method thereof |
-
2015
- 2015-06-25 CN CN201510356041.9A patent/CN105017708A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4022849A (en) * | 1971-01-21 | 1977-05-10 | Stauffer Chemical Company | Crosslinked vinyl halide polymers as flame retardant additives for thermoplastics |
| US3932321A (en) * | 1973-06-18 | 1976-01-13 | Japan Synthetic Rubber Company Limited | Flame-retardant polymer composition |
| CN101704983A (en) * | 2009-09-30 | 2010-05-12 | 东莞市上洲塑胶科技有限公司 | High-performance flame-resistant ABS resin and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312288A (en) * | 2017-06-26 | 2017-11-03 | 俞惠英 | A kind of low temperature resistant flame retardant material |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151104 |