CN105017633A - Halogen-free flame retardant cable material - Google Patents
Halogen-free flame retardant cable material Download PDFInfo
- Publication number
- CN105017633A CN105017633A CN201510490085.0A CN201510490085A CN105017633A CN 105017633 A CN105017633 A CN 105017633A CN 201510490085 A CN201510490085 A CN 201510490085A CN 105017633 A CN105017633 A CN 105017633A
- Authority
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- Prior art keywords
- parts
- halogen
- retardant cable
- free flame
- cable material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 21
- 239000000463 material Substances 0.000 title claims abstract description 10
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 9
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 9
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims abstract description 8
- -1 polyethylene Polymers 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 6
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- 229920000573 polyethylene Polymers 0.000 claims abstract description 6
- 239000003822 epoxy resin Substances 0.000 claims abstract description 5
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005662 Paraffin oil Substances 0.000 claims abstract description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 229920002943 EPDM rubber Polymers 0.000 claims abstract 2
- 239000003431 cross linking reagent Substances 0.000 claims abstract 2
- 239000000806 elastomer Substances 0.000 claims abstract 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract 2
- 230000007547 defect Effects 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 description 9
- 150000002367 halogens Chemical class 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010000369 Accident Diseases 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0853—Ethene vinyl acetate copolymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
本发明公开了一种无卤阻燃电缆料，属于材料技术领域。解决了现有电缆料柔韧性和机械性能不能兼具的缺陷。其由以下重量份的原料组成：乙烯-醋酸乙烯共聚物30份，聚乙烯类弹性体20份，三元乙丙橡胶20份，环氧树脂10份，改性水滑石55份，石蜡油3份，硬脂酸锌3份，马来酸酐接枝乙烯醋酸乙烯共聚物8份，硅烷偶联剂KH550？1.7份，抗氧剂1010？1份，过氧化二异丙苯交联剂1.3份。本发明无卤阻燃电缆料适合各类电缆使用。The invention discloses a halogen-free flame-retardant cable material, which belongs to the technical field of materials. The defect that the flexibility and mechanical properties of the existing cable materials cannot be combined is solved. It consists of the following raw materials in parts by weight: 30 parts of ethylene-vinyl acetate copolymer, 20 parts of polyethylene elastomer, 20 parts of EPDM rubber, 10 parts of epoxy resin, 55 parts of modified hydrotalcite, 3 parts of paraffin oil 3 parts of zinc stearate, 8 parts of maleic anhydride grafted ethylene vinyl acetate copolymer, 1.7 parts of silane coupling agent KH550, 1 part of antioxidant 1010, 1.3 parts of dicumyl peroxide crosslinking agent . The halogen-free flame-retardant cable material of the invention is suitable for use in various cables.
Description
Technical field
The present invention relates to a kind of non-halogen flame-retardant cable, belong to field of material technology.
Background technology
Along with the frequent generation of electrical fire accident, the fire-retardant problem of electric wire causes the attention of countries in the world gradually.In order to improve the flame retardant resistance of electric wire, initial interpolation contains the fire retardant of halogen, and this type of electric wire discharges a large amount of smog and hydrogen halide in combustion, easily makes people be choked to death in fire, simultaneously comparatively large to plant and instrument corrosion, cause secondary injury.
The patent No. be 201110036169.9 patent of invention disclose a kind of Soft halogen-free flame-retardant cable material.Using aluminium hydroxide, magnesium hydroxide etc. as fire retardant, have cheap, wide material sources, nontoxic, corrosion-free, do not cause the advantages such as secondary pollution when burning.The present invention by adopt soft thermoplastic elastomer and polyolefin resin blended, its flexibility is promoted greatly.But due to dispersiveness in system of aluminium hydroxide, this based flame retardant of magnesium hydroxide and affinity poor, cause often occurring half-cooked phenomenon at high filler loading capacity, have a strong impact on the tensile strength of product, elongation and apparent mass.
Goal of the invention
The object of the present invention is to provide a kind of non-halogen flame-retardant cable, snappiness is good, and mechanical property is excellent.
Described non-halogen flame-retardant cable, be made up of the raw material of following weight part: ethylene-vinyl acetate copolymer 30 parts, 20 parts, polyethylene kind elastomerics, terpolymer EP rubber 20 parts, epoxy resin 10 parts, modified hydrotalcite 55 parts, paraffin oil 3 parts, Zinic stearas 3 parts, ethylene-vinylacetate grafting maleic anhydride copolymer 8 parts, Silane coupling agent KH550 1.7 parts, antioxidant 1010 1 part, dicumyl peroxide linking agent 1.3 parts.
Described modified hydrotalcite is sodium oleate modified hydrotalcite.
Compared with prior art the invention has the beneficial effects as follows:
Non-halogen flame-retardant cable of the present invention with ethylene-vinyl acetate copolymer and terpolymer EP rubber for major ingredient, be aided with polyethylene kind elastomerics and epoxy resin, under the flexible prerequisite of guarantee product, improve the mechanical propertys such as the shock resistance of product, tensile property, wear resisting property, tear resistance.Obviously improve through the hydrotalcite of sodium oleate modification and the dispersiveness of system and consistency, fire retardant is done with modified hydrotalcite, the tensile strength of product, elongation and apparent mass significantly improve, and its system oxygen index is apparently higher than the system doing fire retardant with aluminium hydroxide, magnesium hydroxide.Polyethylene kind elastomerics and terpolymer EP rubber add in the ratio of 1:1, and the performance of each side such as the physical and mechanical properties of products obtained therefrom and electrical insulating property, elasticity, ageing resistance, erosion resistance, wear resistance, oil-proofness is had increased significantly.Non-halogen flame-retardant cable combination of flexibility of the present invention and mechanical property, be applicable to various types of cable.
Embodiment
Below in conjunction with specific embodiment, the present invention will be further described.
Embodiment 1
Described non-halogen flame-retardant cable, be made up of the raw material of following weight part: ethylene-vinyl acetate copolymer 30 parts, 20 parts, polyethylene kind elastomerics, terpolymer EP rubber 20 parts, epoxy resin 10 parts, modified hydrotalcite 55 parts, paraffin oil 3 parts, Zinic stearas 3 parts, ethylene-vinylacetate grafting maleic anhydride copolymer 8 parts, Silane coupling agent KH550 1.7 parts, antioxidant 1010 01 parts, dicumyl peroxide linking agent 1.3 parts.
The performance test table 1 of the non-halogen flame-retardant cable described in embodiment 1:
Table 1
| Testing method | Test result | |
| Tensile strength/MPa | GB/T1040-2006 | 12.4 |
| Elongation at break/% | GB/T1040-2006 | 320 |
| Oxygen index | GB/T2408-2006 | 40 |
| Shore hardness | - | 89A |
| Insulation voltage/V | - | 6000 |
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510490085.0A CN105017633A (en) | 2015-08-11 | 2015-08-11 | Halogen-free flame retardant cable material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510490085.0A CN105017633A (en) | 2015-08-11 | 2015-08-11 | Halogen-free flame retardant cable material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105017633A true CN105017633A (en) | 2015-11-04 |
Family
ID=54407961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510490085.0A Pending CN105017633A (en) | 2015-08-11 | 2015-08-11 | Halogen-free flame retardant cable material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105017633A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949627A (en) * | 2016-05-19 | 2016-09-21 | 合肥庭索环保材料有限公司 | Cable material for weather-resistant mine cable |
| CN106279956A (en) * | 2016-08-18 | 2017-01-04 | 江苏上上电缆集团有限公司 | A kind of expansion type low-smoke halogen-free high fire-retardance oxygen barrier layer CABLE MATERIALS and preparation method thereof |
| CN106782782A (en) * | 2016-12-05 | 2017-05-31 | 国网江苏省电力公司盐城供电公司 | A kind of power cable insulation layer and its preparation technology |
| CN112662038A (en) * | 2020-12-02 | 2021-04-16 | 中广核高新核材科技（苏州）有限公司 | B1-grade flame-retardant ultralow-temperature-resistant low-smoke halogen-free polyolefin cable material |
| CN119331334A (en) * | 2024-12-20 | 2025-01-21 | 穿越电缆集团有限公司 | A high temperature resistant overhead cable |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070821A (en) * | 2010-12-14 | 2011-05-25 | 江苏德威新材料股份有限公司 | Irradiation cross-linking oil resistance type soft low smoke zero halogen flame-retardant cable material |
| CN103012941A (en) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | Non-crosslinking halogen-free flame-retardant cable insulating material or sheath material and preparation method thereof |
| CN103059404A (en) * | 2013-01-25 | 2013-04-24 | 杭州双马高分子材料科技有限公司 | Radiation cross-linking low-smoke halogen-free flame-retardant polyolefin insulating material and preparation method thereof |
| CN104530549A (en) * | 2014-12-30 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | High cold-resistance and oil-resistance low-smoke halogen-free flame retardant cable material for irradiation crosslinking rolling stock and preparation method thereof |
-
2015
- 2015-08-11 CN CN201510490085.0A patent/CN105017633A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102070821A (en) * | 2010-12-14 | 2011-05-25 | 江苏德威新材料股份有限公司 | Irradiation cross-linking oil resistance type soft low smoke zero halogen flame-retardant cable material |
| CN103012941A (en) * | 2012-09-29 | 2013-04-03 | 深圳市沃尔核材股份有限公司 | Non-crosslinking halogen-free flame-retardant cable insulating material or sheath material and preparation method thereof |
| CN103059404A (en) * | 2013-01-25 | 2013-04-24 | 杭州双马高分子材料科技有限公司 | Radiation cross-linking low-smoke halogen-free flame-retardant polyolefin insulating material and preparation method thereof |
| CN104530549A (en) * | 2014-12-30 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | High cold-resistance and oil-resistance low-smoke halogen-free flame retardant cable material for irradiation crosslinking rolling stock and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 钱康 等: "新型无机阻燃剂水滑石表面改性的研究", 《绝缘材料》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105949627A (en) * | 2016-05-19 | 2016-09-21 | 合肥庭索环保材料有限公司 | Cable material for weather-resistant mine cable |
| CN106279956A (en) * | 2016-08-18 | 2017-01-04 | 江苏上上电缆集团有限公司 | A kind of expansion type low-smoke halogen-free high fire-retardance oxygen barrier layer CABLE MATERIALS and preparation method thereof |
| CN106279956B (en) * | 2016-08-18 | 2018-10-23 | 江苏上上电缆集团有限公司 | A kind of expansion type low-smoke halogen-free high fire-retardance oxygen barrier layer CABLE MATERIALS and preparation method thereof |
| CN106782782A (en) * | 2016-12-05 | 2017-05-31 | 国网江苏省电力公司盐城供电公司 | A kind of power cable insulation layer and its preparation technology |
| CN112662038A (en) * | 2020-12-02 | 2021-04-16 | 中广核高新核材科技（苏州）有限公司 | B1-grade flame-retardant ultralow-temperature-resistant low-smoke halogen-free polyolefin cable material |
| CN119331334A (en) * | 2024-12-20 | 2025-01-21 | 穿越电缆集团有限公司 | A high temperature resistant overhead cable |
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Application publication date: 20151104 |
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