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CN104989065B - A kind of wood-plastic composite floor and preparation method thereof - Google Patents

A kind of wood-plastic composite floor and preparation method thereof Download PDF

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CN104989065B
CN104989065B CN201510403546.6A CN201510403546A CN104989065B CN 104989065 B CN104989065 B CN 104989065B CN 201510403546 A CN201510403546 A CN 201510403546A CN 104989065 B CN104989065 B CN 104989065B
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plastic composite
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composite floor
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CN104989065A (en
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刘明利
李春风
刘彦龙
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Beihua University
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Abstract

本发明是一种木塑复合地板及其制造方法,用该方法制造的木塑复合地板包括:从上至下依次由表面涂饰层、上表板层、上表板改性层、中间层、下表板改性层和下表板层复合组成。能够进一步缓解珍贵木材紧缺,以炭化表板表面改性后与中间层复合,提高了木塑复合材表面的装饰性,且经炭化处理后的单板,其尺寸稳定性好、色差小,木材利用率高。本发明18mm厚的木塑复合地板,经水煮(浸)‑冰冻‑干燥处理后抗弯载荷达到1240N,浸渍剥离率0,湿法摩擦系数为0.7;能够同时兼顾节省木材资源和具有实木地板表面效果等优点,没有有害物质释放,可广泛用于室内外。其制造方法科学合理,易于成型。

The invention relates to a wood-plastic composite floor and its manufacturing method. The wood-plastic composite floor manufactured by the method comprises: from top to bottom, a surface coating layer, an upper surface layer, an upper surface modified layer, an intermediate layer, The modified layer of the lower surface plate and the compound composition of the lower surface plate. It can further alleviate the shortage of precious wood. The surface of the carbonized surface board is modified and then compounded with the middle layer, which improves the decoration of the surface of the wood-plastic composite material. After the carbonization treatment, the veneer has good dimensional stability and small color difference. High utilization rate. The 18mm-thick wood-plastic composite floor of the present invention has a bending load of 1240N after boiling (soaking)-freezing-drying treatment, a dipping peeling rate of 0, and a wet friction coefficient of 0.7; it can simultaneously save wood resources and have solid wood flooring Surface effects and other advantages, no harmful substances released, can be widely used indoors and outdoors. Its manufacturing method is scientific and reasonable, and it is easy to shape.

Description

一种木塑复合地板及其制备方法Wood-plastic composite floor and preparation method thereof

技术领域technical field

本发明涉及一种地板,具体涉及一种木塑复合地板及其制备方法。The invention relates to a floor, in particular to a wood-plastic composite floor and a preparation method thereof.

背景技术Background technique

随着社会生活节奏的加快及人们生活水平的提高,要求更加健康的生活环境,木制品更多地被用于各种场所,尤其作为地面铺装产品-地板被广泛应用。但各种地板存在不同的优缺点。实木地板具有典雅自然、脚感舒适、保温性能好的特点,但尺寸稳定性不够好,环境过于潮湿或干燥时容易起拱、翘曲或变形等问题;实木复合地板能够较好地克服实木地板确缺点,但其在生产过程中不可避免地要用到大量的胶水,因此存在有害物质释放问题;强化复合地板与实木(复合)地板相比有更高耐磨性能,但其耐水性较差。以上三种地板作为使用量最大地板,其共同缺点是存在较差的耐老化性能及耐水性能。不能在苛刻条件下应用。木塑复合材料为木粉与塑料通过一定工艺复合而成的板材,其具有较好的耐水性能。炭化单板是在不同介质控制180~220℃条件下加工而成,其炭化后的板材具有优良的防腐和尺寸稳定性。木塑复合材料有着显著的经济、生态和社会效益,然而长期使用中在直接暴露在阳光下和由于加工方法、配方成分及环境因子等影响,木塑复合材料会发生老化,在持续应力作用下,会产生蠕变变形,甚至发生断裂影响使用寿命。实用新型专利CN202969841U一种户外地板及CN201343852Y一种木塑复合地板,以炭化单板作为地板表面的材料,通过胶黏剂将单板与木塑基材胶合在一起。并且基材为单面覆面。这两种方法由于实用胶黏剂存在有害物质释放,同时由于基材单面饰面存在应力不平衡现象,容易发生翘曲现象。With the acceleration of the pace of social life and the improvement of people's living standards, a healthier living environment is required, and wood products are more used in various places, especially as floor covering products - flooring is widely used. But each floor has different advantages and disadvantages. Solid wood flooring has the characteristics of elegance and naturalness, comfortable foot feeling, and good thermal insulation performance, but its dimensional stability is not good enough, and it is easy to arch, warp or deform when the environment is too humid or dry; solid wood composite flooring can better overcome the problems of solid wood flooring. There are indeed disadvantages, but it inevitably uses a large amount of glue in the production process, so there is a problem of releasing harmful substances; compared with solid wood (composite) flooring, laminate flooring has higher wear resistance, but its water resistance is poorer . The above three types of floors are used as the largest floor, and their common disadvantages are poor aging resistance and water resistance. Cannot be used under harsh conditions. Wood-plastic composite material is a board made of wood powder and plastic through a certain process, and it has good water resistance. The carbonized veneer is processed under the condition of controlling 180~220℃ in different media, and the carbonized board has excellent anti-corrosion and dimensional stability. Wood-plastic composite materials have significant economic, ecological and social benefits. However, in long-term use, wood-plastic composite materials will age when exposed to direct sunlight and due to processing methods, formula components and environmental factors. Under continuous stress , will produce creep deformation, and even fracture will affect the service life. The utility model patent CN202969841U is an outdoor floor and CN201343852Y is a wood-plastic composite floor. Carbonized veneer is used as the material of the floor surface, and the veneer and the wood-plastic substrate are glued together by an adhesive. And the substrate is single-sided cladding. These two methods are prone to warping due to the release of harmful substances from the practical adhesive and the unbalanced stress on one side of the substrate.

发明内容Contents of the invention

本发明目的是,克服现有实木复合地板使用大量天然珍贵木材和有害物质释放的缺陷,提供一种尺寸稳定,无有害物质释放,地板质感和质量佳,且同时兼顾节省木材资源和具有实木地板表面效果等优点,可广泛用于室内外的木塑复合地板。并提供科学合理,易于成型的木塑复合地板的制造方法。The purpose of the present invention is to overcome the defects of the existing solid wood composite floor using a large amount of natural precious wood and the release of harmful substances, to provide a floor with stable size, no release of harmful substances, good floor texture and quality, and at the same time taking into account the saving of wood resources and solid wood flooring Surface effects and other advantages, can be widely used in wood-plastic composite flooring indoors and outdoors. And provide a scientific and reasonable, easy-to-form wood-plastic composite flooring manufacturing method.

实现本发明目的采用的技术方案是,一种木塑复合地板,其特征是,它包括:从上至下依次由表面涂饰层、上表板层、上表板改性层、中间层、下表板改性层和下表板层复合组成。The technical solution adopted to realize the purpose of the present invention is a wood-plastic composite floor, which is characterized in that it includes: from top to bottom, a surface coating layer, an upper surface layer, an upper surface modified layer, an intermediate layer, a lower surface The modified surface layer and the lower surface layer are compositely composed.

一种木塑复合地板的制造方法,其特征是,它包括内容有:A method for manufacturing wood-plastic composite flooring is characterized in that it includes:

1)上表板层、下表板层结构相同,均采用刨切、旋切和锯切任意树种的单板,其厚度为2~8毫米,在温度180~220℃,湿度100%,保持时间1~4小时,进行炭化处理;1) The structure of the upper surface layer and the lower surface layer is the same, and the veneer of any tree species is planed, rotary cut and sawed. The thickness is 2~8 mm. Time 1~4 hours, carry out carbonization treatment;

2)在上表板层的下表面涂饰上表板改性层,在下表板层的上表面上涂饰下表板改性层,上表板改性层、下表板改性层结构相同,均由硅烷偶联剂40g/m2和塑料颗粒60g/m2,或亚甲基多异氰酸酯40g/m2和塑料颗粒60g/m2,通过热压机:温度180~190℃,压力0.2MPa,时间10分钟,使上表板层的下表面与上表板改性层复合、下表板层的上表面与下表板改性层复合;2) Paint the upper surface modified layer on the lower surface of the upper surface layer, and paint the lower surface modified layer on the upper surface of the lower surface layer. The upper surface modified layer and the lower surface modified layer have the same structure. Both consist of 40g/m 2 of silane coupling agent and 60g/m 2 of plastic particles, or 40g/m 2 of methylene polyisocyanate and 60g/m 2 of plastic particles, through a hot press: temperature 180~190℃, pressure 0.2MPa , the time is 10 minutes, the lower surface of the upper surface layer is compounded with the modified layer of the upper surface layer, and the upper surface of the lower surface layer is compounded with the modified layer of the lower surface layer;

3)中间层为塑料颗粒与木粉的混合物,其质量份为塑料颗粒10份、木粉3~7份,或为木塑复合材料的回收料;3) The middle layer is a mixture of plastic granules and wood powder, its mass parts are 10 parts of plastic granules, 3~7 parts of wood powder, or recycled materials of wood-plastic composite materials;

4)将上表板层复合的改性层与下表板层复合的改性层之间放置中间层,采用热压机,温度185℃,压力2.5MPa,时间25分钟,一次压合成一体;4) Place an intermediate layer between the modified layer compounded with the upper surface layer and the modified layer compounded with the lower surface layer, using a hot press at a temperature of 185°C, a pressure of 2.5MPa, and a time of 25 minutes to press into one body at a time;

5)在步骤4)的基础之上,采用榫槽设备,在中间层的一侧开出凹槽,在中间层的另一侧开出凸榫;5) On the basis of step 4), use tongue and groove equipment to make grooves on one side of the middle layer and make tenons on the other side of the middle layer;

6)在步骤5)的基础之上,在上表板层的上表面涂覆表面涂饰层, 表面涂饰层为耐温95~340℃的石蜡或地板涂饰漆,制成成品。6) On the basis of step 5), apply a surface finish layer on the upper surface of the upper surface layer. The surface finish layer is paraffin wax or floor finish paint with a temperature resistance of 95~340°C to make a finished product.

所述塑料颗粒为聚丙烯、聚乙烯、聚氯乙烯和高密度聚乙烯的至少一种。The plastic particles are at least one of polypropylene, polyethylene, polyvinyl chloride and high-density polyethylene.

所述木粉的目数为20~240目,含水率为2%~10%。The wood powder has a mesh number of 20-240 mesh and a moisture content of 2%-10%.

所述地板涂饰漆为聚氨酯漆、不饱和聚酯漆、硝基漆或、紫外光固化漆。The floor finishing paint is polyurethane paint, unsaturated polyester paint, nitro paint or UV curing paint.

本发明的木塑复合地板,以炭化表板表面改性后与中间层复合,提高了木塑复合材表面的装饰性,且经炭化处理后的单板,其尺寸稳定性好、色差小,木材利用率高。本发明18mm厚的木塑复合地板,经水煮(浸)-冰冻-干燥处理后抗弯载荷达到1240N,浸渍剥离率0,湿法摩擦系数为0.7;能够同时兼顾节省木材资源和具有实木地板表面效果等优点,没有有害物质释放,可广泛用于室内外。其制造方法科学合理,易于成型。In the wood-plastic composite flooring of the present invention, the surface of the carbonized surface board is modified and compounded with the middle layer, which improves the decorativeness of the surface of the wood-plastic composite material, and the veneer after carbonization treatment has good dimensional stability and small color difference. The wood utilization rate is high. The 18mm thick wood-plastic composite floor of the present invention has a bending load of 1240N after boiling (dipping)-freezing-drying treatment, a dipping peeling rate of 0, and a wet friction coefficient of 0.7; it can simultaneously save wood resources and have solid wood flooring Surface effects and other advantages, no harmful substances released, can be widely used indoors and outdoors. Its manufacturing method is scientific and reasonable, and it is easy to shape.

附图说明Description of drawings

图1是本发明木塑复合地板结构示意图。Fig. 1 is a schematic diagram of the structure of wood-plastic composite flooring of the present invention.

图中:1-表面涂饰层;2-上表板层;3-表板改性剂层;4-中间层;5-下表板改性剂层;6-下表板层;7-凹槽;8-凸榫。In the figure: 1-surface coating layer; 2-upper surface layer; 3-surface modifier layer; 4-intermediate layer; 5-lower surface modifier layer; 6-lower surface layer; 7-concave groove; 8-tenons.

具体实施方式detailed description

下面结合附图和实施例,对本发明作进一步说明Below in conjunction with accompanying drawing and embodiment, the present invention will be further described

参照图1,本发明的一种木塑复合地板,包括:从上至下依次由表面涂饰层1、上表板层2、上表板改性层3、中间层4、下表板改性层5和下表板层6复合组成。Referring to Fig. 1, a kind of wood-plastic composite floor of the present invention comprises: from top to bottom successively by surface coating layer 1, upper surface layer 2, upper surface modification layer 3, middle layer 4, lower surface modification The layer 5 and the lower surface layer 6 are compounded.

本发明的一种木塑复合地板的制造方法,包括内容有:A kind of manufacturing method of wood-plastic composite floor of the present invention, comprises content to have:

1)上表板层、下表板层结构相同,均采用刨切、旋切和锯切任意树种的单板,其厚度为2~8毫米,在温度180~220℃,湿度100%,保持时间1~4小时,进行炭化处理;1) The structure of the upper surface layer and the lower surface layer is the same, and the veneer of any tree species is planed, rotary cut and sawed. The thickness is 2~8 mm. Time 1~4 hours, carry out carbonization treatment;

2)在上表板层的下表面涂饰上表板改性层,在下表板层的上表面上涂饰下表板改性层,上表板改性层、下表板改性层结构相同,均由硅烷偶联剂40g/m2和塑料颗粒60g/m2,或亚甲基多异氰酸酯40g/m2和塑料颗粒60g/m2,通过热压机:温度180~190℃,压力0.2MPa,时间10分钟,使上表板层的下表面与上表板改性层复合、下表板层的上表面与下表板改性层复合;2) Paint the upper surface modified layer on the lower surface of the upper surface layer, and paint the lower surface modified layer on the upper surface of the lower surface layer. The upper surface modified layer and the lower surface modified layer have the same structure. Both consist of 40g/m 2 of silane coupling agent and 60g/m 2 of plastic particles, or 40g/m 2 of methylene polyisocyanate and 60g/m 2 of plastic particles, through a hot press: temperature 180~190℃, pressure 0.2MPa , the time is 10 minutes, the lower surface of the upper surface layer is compounded with the modified layer of the upper surface layer, and the upper surface of the lower surface layer is compounded with the modified layer of the lower surface layer;

3)中间层为塑料颗粒与木粉的混合物,其质量份为塑料颗粒10份、木粉3~7份,或为木塑复合材料的回收料;3) The middle layer is a mixture of plastic granules and wood powder, its mass parts are 10 parts of plastic granules, 3~7 parts of wood powder, or recycled materials of wood-plastic composite materials;

4)将上表板层复合的改性层与下表板层复合的改性层之间放置中间层,采用热压机,温度185℃,压力2.5MPa,时间25分钟,一次压合成一体;4) Place an intermediate layer between the modified layer compounded with the upper surface layer and the modified layer compounded with the lower surface layer, using a hot press at a temperature of 185°C, a pressure of 2.5MPa, and a time of 25 minutes to press into one body at a time;

5)在步骤4)的基础之上,采用榫槽设备,在中间层的一侧开出凹槽,在中间层的另一侧开出凸榫;5) On the basis of step 4), use tongue and groove equipment to make grooves on one side of the middle layer and make tenons on the other side of the middle layer;

6)在步骤5)的基础之上,在上表板层的上表面涂覆表面涂饰层, 表面涂饰层为耐温95~340℃的石蜡或地板涂饰漆,制成成品。6) On the basis of step 5), apply a surface finish layer on the upper surface of the upper surface layer. The surface finish layer is paraffin wax or floor finish paint with a temperature resistance of 95~340°C to make a finished product.

所述塑料颗粒为聚丙烯、聚乙烯、聚氯乙烯和高密度聚乙烯的至少一种。The plastic particles are at least one of polypropylene, polyethylene, polyvinyl chloride and high-density polyethylene.

所述木粉的目数为20~240目,含水率为2%~10%。The wood powder has a mesh number of 20-240 mesh and a moisture content of 2%-10%.

所述地板涂饰漆为聚氨酯漆、不饱和聚酯漆、硝基漆或紫外光固化漆。The floor finishing paint is polyurethane paint, unsaturated polyester paint, nitro paint or ultraviolet curing paint.

本发明所用化工原料均为市售产品。The chemical raw materials used in the present invention are all commercially available products.

以本发明18mm厚的木塑复合地板为例,经水煮(浸)-冰冻-干燥处理后抗弯载荷达到1240N,浸渍剥离率0,湿法摩擦系数为0.7;能够同时兼顾节省木材资源和具有实木地板表面效果等优点,没有有害物质释放,可广泛用于室内外。其制造方法科学合理,易于成型。Taking the 18mm thick wood-plastic composite floor of the present invention as an example, after boiling (dipping)-freezing-drying treatment, the bending load reaches 1240N, the dipping peeling rate is 0, and the wet friction coefficient is 0.7; it can simultaneously save wood resources and It has the advantages of solid wood floor surface effect, no harmful substance release, and can be widely used indoors and outdoors. Its manufacturing method is scientific and reasonable, and it is easy to shape.

本发明的实施例为有限的实例,并非穷举,不经过创造劳动的简单复制和改进,仍属于本发明权利要求所保护的范围。The embodiments of the present invention are limited examples and are not exhaustive, and they still belong to the protection scope of the claims of the present invention without simple copying and improvement through creative labor.

Claims (5)

1. a kind of manufacture method of wood-plastic composite floor, it is characterized in that, it include in have:
1)Upper table flaggy, following table layer structure are identical, and using the veneer of any seeds of slicing, rotary-cut and sawing, its thickness is 2 ~ 8 millimeters, in 180 ~ 220 DEG C of temperature, humidity 100%, carries out charing process at 1 ~ 4 hour retention time;
2)Dash board modified layer is covered with paint, lacquer, colour wash, etc. in the lower surface of upper table flaggy, dash board is modified under being covered with paint, lacquer, colour wash, etc. on the upper surface of following table flaggy Layer, upper dash board modified layer, lower dash board modified layer structure are identical, by silane coupler 40g/m2With plastic grain 60g/m2, or Methylene polyisocyanates 40g/m2With plastic grain 60g/m2, by hot press:180 ~ 190 DEG C of temperature, pressure 0.2MPa, when Between 10 minutes, make the lower surface of upper table flaggy and upper dash board modified layer be compound, the upper surface of following table flaggy and lower dash board modified layer It is compound;
3)Intermediate layer is the mixture of plastic grain and wood powder, and its mass parts is 10 parts of plastic grain, 3 ~ 7 parts of wood powder, or is wood The reclaimed materials of plastic composite materials;
4)Intermediate layer is placed between the modified layer that the modified layer and following table flaggy that upper table flaggy is combined are combined, using hot press, 185 DEG C of temperature, pressure 2.5MPa, 25 minutes time, one step press is integral;
5)In step 4)Basis on, using tongue-and-groove equipment, groove is outputed in the side in intermediate layer, in the opposite side in intermediate layer Output tenon;
6)In step 5)Basis on, in the upper surface coating surface coatings of upper table flaggy, top finishing layer is heatproof 95 Paint is covered with paint, lacquer, colour wash, etc. on ~ 340 DEG C of paraffin or floor, is made finished product.
2. the manufacture method of a kind of wood-plastic composite floor according to claim 1, it is characterized in that, the plastic grain is poly- At least one of propylene, polyethylene, polyvinyl chloride and high density polyethylene (HDPE).
3. the manufacture method of a kind of wood-plastic composite floor according to claim 1, it is characterized in that, the mesh number of the wood powder is 20 ~ 240 mesh, moisture content is 2% ~ 10%.
4. the manufacture method of a kind of wood-plastic composite floor according to claim 1, it is characterized in that, the floor is covered with paint, lacquer, colour wash, etc. paint and is Polyurethane paint, unsaturated polyester varnish, nitrate paint or ultraviolet-cured paint.
5. the manufacture method of a kind of wood-plastic composite floor according to claim 1, it is characterized in that, manufactured wood plastics composite Floor includes:From top to bottom successively by top finishing layer, upper table flaggy, upper dash board modified layer, intermediate layer, lower dash board modified layer and The compound composition of following table flaggy.
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