CN104983596B - A kind of mild conditioning shampoo composition of no silicone oil and preparation method thereof - Google Patents
A kind of mild conditioning shampoo composition of no silicone oil and preparation method thereof Download PDFInfo
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- CN104983596B CN104983596B CN201510439469.XA CN201510439469A CN104983596B CN 104983596 B CN104983596 B CN 104983596B CN 201510439469 A CN201510439469 A CN 201510439469A CN 104983596 B CN104983596 B CN 104983596B
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- salt
- silicone oil
- surfactant
- shampoo composition
- conditioning shampoo
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- 239000002453 shampoo Substances 0.000 title claims abstract description 66
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 40
- 230000003750 conditioning effect Effects 0.000 title claims abstract description 38
- 239000000203 mixture Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 230000008719 thickening Effects 0.000 claims abstract description 22
- 238000001179 sorption measurement Methods 0.000 claims abstract description 20
- 239000003381 stabilizer Substances 0.000 claims abstract description 20
- 150000001768 cations Chemical class 0.000 claims abstract description 17
- 239000003623 enhancer Substances 0.000 claims abstract description 17
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 230000003571 opsonizing effect Effects 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- -1 alkyl ether sulfate Chemical class 0.000 claims description 30
- 150000003839 salts Chemical class 0.000 claims description 29
- 150000001413 amino acids Chemical class 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002585 base Substances 0.000 claims description 9
- 125000003282 alkyl amino group Chemical group 0.000 claims description 7
- 208000001840 Dandruff Diseases 0.000 claims description 6
- 229920000289 Polyquaternium Polymers 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 5
- 239000004909 Moisturizer Substances 0.000 claims description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims description 5
- 150000003863 ammonium salts Chemical class 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 230000001333 moisturizer Effects 0.000 claims description 5
- 239000001103 potassium chloride Substances 0.000 claims description 5
- 235000011164 potassium chloride Nutrition 0.000 claims description 5
- 229940083466 soybean lecithin Drugs 0.000 claims description 5
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 239000003607 modifier Substances 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 239000004034 viscosity adjusting agent Substances 0.000 claims description 4
- XGIKILRODBEJIL-UHFFFAOYSA-N 1-(ethylamino)ethanol Chemical class CCNC(C)O XGIKILRODBEJIL-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical class NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims description 3
- 239000000686 essence Substances 0.000 claims description 3
- 150000002462 imidazolines Chemical class 0.000 claims description 3
- 159000000003 magnesium salts Chemical class 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- BYMMIQCVDHHYGG-UHFFFAOYSA-N Cl.OP(O)(O)=O Chemical compound Cl.OP(O)(O)=O BYMMIQCVDHHYGG-UHFFFAOYSA-N 0.000 claims description 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 150000008051 alkyl sulfates Chemical group 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 206010019049 Hair texture abnormal Diseases 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 4
- 235000002639 sodium chloride Nutrition 0.000 description 36
- 229940024606 amino acid Drugs 0.000 description 14
- 230000000694 effects Effects 0.000 description 11
- 238000006467 substitution reaction Methods 0.000 description 7
- 229920002907 Guar gum Polymers 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000665 guar gum Substances 0.000 description 6
- 235000010417 guar gum Nutrition 0.000 description 6
- 229960002154 guar gum Drugs 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000003993 interaction Effects 0.000 description 3
- 239000004973 liquid crystal related substance Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- OYINQIKIQCNQOX-UHFFFAOYSA-M 2-hydroxybutyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCC(O)C[N+](C)(C)C OYINQIKIQCNQOX-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 125000005526 alkyl sulfate group Chemical group 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 229930182478 glucoside Natural products 0.000 description 2
- 150000008131 glucosides Chemical class 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 2
- 235000010334 sodium propionate Nutrition 0.000 description 2
- 239000004324 sodium propionate Substances 0.000 description 2
- 229960003212 sodium propionate Drugs 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- OWEGWHBOCFMBLP-UHFFFAOYSA-N 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethylbutan-2-one Chemical group C1=CN=CN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 OWEGWHBOCFMBLP-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical group [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 1
- QPHPUQJVKQXISS-UHFFFAOYSA-N 4-oxo-4-sulfanylbutanoic acid Chemical compound OC(=O)CCC(S)=O QPHPUQJVKQXISS-UHFFFAOYSA-N 0.000 description 1
- ZGXJTSGNIOSYLO-UHFFFAOYSA-N 88755TAZ87 Chemical compound NCC(=O)CCC(O)=O ZGXJTSGNIOSYLO-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- FOPXWLNOVWLHMH-UHFFFAOYSA-N C(C)NC(C)O.S(=O)(=O)(O)C(C(=O)O)CC(=O)O Chemical compound C(C)NC(C)O.S(=O)(=O)(O)C(C(=O)O)CC(=O)O FOPXWLNOVWLHMH-UHFFFAOYSA-N 0.000 description 1
- SREYMYXIVZOMQY-UHFFFAOYSA-N C(C)NC(C)O.S(=O)(=O)(O)O Chemical compound C(C)NC(C)O.S(=O)(=O)(O)O SREYMYXIVZOMQY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RXMLBWIJXZNCCO-UHFFFAOYSA-N [NH4+].[NH4+].[NH4+].[NH4+].[Cl-].[O-]P([O-])([O-])=O Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[Cl-].[O-]P([O-])([O-])=O RXMLBWIJXZNCCO-UHFFFAOYSA-N 0.000 description 1
- ATWGHWZRHOJITC-UHFFFAOYSA-N [S].C1=CC=NC=C1 Chemical compound [S].C1=CC=NC=C1 ATWGHWZRHOJITC-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229960003344 climbazole Drugs 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940118199 levulan Drugs 0.000 description 1
- GVDIFMFVNGKDOP-UHFFFAOYSA-N magnesium;2-sulfobutanedioic acid Chemical compound [Mg].OC(=O)CC(C(O)=O)S(O)(=O)=O GVDIFMFVNGKDOP-UHFFFAOYSA-N 0.000 description 1
- LVWZTYCIRDMTEY-UHFFFAOYSA-N metamizole Chemical compound O=C1C(N(CS(O)(=O)=O)C)=C(C)N(C)N1C1=CC=CC=C1 LVWZTYCIRDMTEY-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229940045944 sodium lauroyl glutamate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention discloses a kind of no mild conditioning shampoo compositions of silicone oil and preparation method thereof, and the following component which calculates by weight percentage is prepared：Surfactant 10 35%, thickening stabilizing agent 0.1 10%, adsorption enhancer 1 15%, cation opsonizing agent 0.05 1%, additive 0.01 5%, deionized water surplus.The problem of present invention can be obviously improved wet hair comb rationality, hair drying comb rationality, wet hair flexibility, dry hair flexibility without the mild conditioner shampoo of silicone oil.
Description
Technical field
The present invention relates to daily chemicals field, more specifically to a kind of mild conditioning shampoo composition of no silicone oil and its system
Preparation Method.
Background technology
At present, conditioner shampoo on the market is largely containing silicone oil (silicone oil alkane product) ingredient.Silicone oil component is made
It is widely used for conditioner common in shampoo, silicone oil can so that hair hair scale piece is more smooth, can effectively reduce head
It rubs between hair so that hair is more smooth, is easy to comb.Silicone oil has water-insoluble, and permanent use can generate on hair
Degree accumulation, reduces the hair conditioning of hair and submissive sense.
Although someone cooks conditioner use in shampoo with grease, conditioning effect still can not be compared with silicone oil, and deposits
Many using limitation, such as stability problem etc..How while good cleaning efficacy (including anti-dandruff effect) is reached,
It realizes preferable conditioning effect, is to study urgent problem to be solved without silicone oil shampoo at present.
Invention content
The technical problem to be solved in the present invention is, for the drawbacks described above of the prior art, it is mild to provide a kind of no silicone oil
Conditioning shampoo composition and preparation method thereof.
The technical solution adopted by the present invention to solve the technical problems is：There is provided a kind of no silicone oil mild conditioner shampoo combination
Object, the following component calculated by weight percentage are prepared：
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the surfactant is by with parts by weight
The following component composition calculated：
0-25 parts of sulfuric acid anion surfactant
3-30 parts of amino acid surfactant
1-11 parts of zwitterionic surfactant.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the thickening stabilizing agent is by with weight percent
The following component composition that number calculates：
The weight percent summation of above-mentioned each component is 100%.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the adsorption enhancer is by with weight percent
The following component composition that number calculates：
Amino acid surfactant 5-50%
Inorganic salts 0.5-5%
Deionized water surplus.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the sulfuric acid anion surface active
Agent is selected from alkyl sulfate, alkyl ether sulfate, alkyl amino ether sulfate, the alkyl aryl ether sulphur that the total number of carbon atoms is 8-24
One or more of hydrochlorate, alkyl ether thio succinate；The salt is alkali metal salt, ammonium salt, amine salt, ethylaminoethanol
One kind in salt, magnesium salts.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the amino acid surfactant is selected from
The total number of carbon atoms is N- acylglycines salt, N- acyl glutamates, N- acylalaninies salt, the N- acyl group sarcosine of 8-18
One or more of salt, N- acyl taurine salts, N- acylaspartic acid salt, the salt for sodium salt, sylvite, ammonium salt,
One kind in triethanolamine salt.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the amphoteric surfactant is selected from beet
One or more of bases, Beta-alanine class and imidazolines.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the cation opsonizing agent is selected from guar gum
Hydroxypropyl-trimethyl ammonium chloride, polyquaternium -6, Polyquaternium-10, polyquaternium -53, myristamide propyl PG- dimethyl
One kind in ammonium chloride phosphate.
The mild conditioning shampoo composition of no silicone oil of the present invention, wherein, the additive is viscosity modifier, moisturizing
It is one or more kinds of in agent, anti-dandruff agent, acid-base modifier, preservative, essence.
The present invention also provides a kind of preparation method as described above without the mild conditioning shampoo composition of silicone oil, including walking as follows
Suddenly：
(1) appropriate amount of deionized water is added in a kettle, cation opsonizing agent is added in, is slowly stirred, is uniformly dispersed, and is heated
To 70-90 DEG C；
(2) surfactant, thickening stabilizing agent are added according to above-mentioned formula rate, makes to be completely dissolved, and after being uniformly dispersed
Cooling；
(3) temperature is down to 45 DEG C or so, and addition adsorption enhancer, additive continue to stir, and are uniformly mixed；
(4) be eventually adding deionized water complement to predetermined amount to get.
Implement the present invention without mild conditioning shampoo composition of silicone oil and preparation method thereof, have the advantages that：
(1) present invention can be obviously improved wet hair comb rationality, hair drying comb rationality, wet hair softness without the mild conditioner shampoo of silicone oil
Property, dry hair flexibility the problem of；
(2) thickening stabilizing agent in shampoo, adsorption enhancer to the stability of entire shampoo system and to moisturizer, go
The absorption stability of the bits additives such as agent plays an important role so that shampoo can reach required cleaning, conditioning, moisten and
The effect of moisturizing；
(3) thickening stabilizing agent of the invention in shampoo, can induce amino acid type surfactant solution formed it is specific
The liquid crystal of form achievees the purpose that, from thickening, therefore, the suspension stability and hair conditioning of shampoo can be significantly improved；
(4) adsorption enhancer of the invention is to utilize the phase interaction between amino acid surfactant and cation opsonizing agent
With, effectively facilitate absorption of the conditioner on hair, greatly enhance the adsorption efficiency of cation opsonizing agent, so as to improve adjust
Manage effect.
Description of the drawings
Below in conjunction with accompanying drawings and embodiments, the invention will be further described, in attached drawing：
Fig. 1 is the present invention without picture of the thickening stabilizing agent under petrographic microscope in the mild conditioning shampoo composition of silicone oil.
Specific embodiment
A kind of mild conditioning shampoo composition of no silicone oil, the following component calculated by weight percentage are prepared：
Wherein, the surfactant with the following component that parts by weight calculate by being formed：
0-25 parts of sulfuric acid anion surfactant
3-30 parts of amino acid surfactant
1-11 parts of zwitterionic surfactant.
The sulfuric acid anion surfactant is selected from alkali metal alkyl sulfates, the alkane that the total number of carbon atoms is 8-24
Base ammonium sulfate, alkylsurfuric acid amine salt, alkylsurfuric acid ethylaminoethanol salt, alkylsurfuric acid magnesium salts, alkyl ether sulfate metal salt, alkyl
Ether ammonium sulfate salt, alkyl ether sulfate amine salt, alkyl ether sulfate ethylaminoethanol salt, alkyl ether sulfate magnesium salts, alkyl amino ether sulfuric acid
Alkali metal salt, alkyl amino ether ammonium sulfate salt, alkyl amino ether sulfuric acid amine salt, alkyl amino ether sulfuric acid amino ethylate, alkyl
Amino ethers magnesium sulfate salt, alkyl aryl ether sulfuric acid metal salt, alkyl aryl ether ammonium sulfate, alkyl aryl ether sulfuric acid amine salt, alkane
Base aryl ether sulfuric acid amino ethylate, alkyl aryl ether magnesium sulfate salt, alkyl ether sulfosuccinic acid alkali metal salt, alkyl ether are thio
Succinic acid ammonium salt, alkyl ether sulfosuccinic amine acid salt, alkyl ether sulfosuccinic acid ethylaminoethanol salt, alkyl ether sulfosuccinic acid magnesium
One or more of salt；
Preferably, the alkali metal salt in sulfuric acid anion surfactant is selected from sodium salt and sylvite；Alkyl ether sulfate
Between the usual 2-50 of the number of salt ethylene oxide or propylene oxide, and advanced optimize between 2-10.
It is further preferred that sulphate anion surface active agent is selected from alkyl sulfate and alkyl ether sulfate in the present invention
Salt composite, alkyl carbon chain are C8 to C14, are further optimized for the alkyl ether sulfate of C12 to C14, wherein, sulfate fat
The quantity of ethylene oxide is 2-5 on fat chain, and the average quantity of preferred alkyl ether sulfate ethylene oxide is 3 in of the invention,
Such as poly alkyl alcohol ether sodium sulfate, poly alkyl alcohol ether ammonium sulfate.
The amino acid surfactant is selected from N- acylglycines salt, the N- acyl group paddy ammonia that the total number of carbon atoms is 8-18
Hydrochlorate, N- acylalaninies salt, N- acyl sarcosinates, N- acyl taurine salts, one kind in N- acylaspartic acid salt or
It is two or more；The salt is sodium salt, one kind in sylvite, ammonium salt, triethanolamine salt.
Amphoteric surfactant is selected from one or more of betaines, Beta-alanine class and imidazolines,
Further preferably Cocoamidopropyl betaine, cocoamido sodium propionate.
Wherein, the thickening stabilizing agent is made of the following component calculated by weight percentage：
The weight percent summation of above-mentioned each component is 100%.
Preferably, thickening stabilizing agent is made of the following component calculated by weight percentage：Amino acid surfactant 70-
85%th, soybean lecithin 5-10%, nonionic surfactant 10-30%, aliphatic acid 1-2%.Preferably, soybean lecithin is hydrogenation
Soybean lecithin, nonionic surfactant are cocoyl glucoside, and aliphatic acid is coconut oil.
The preparation method of the thickening stabilizing agent is as follows：Amino acid surfactant has been dissolved by heating in deionized water
Entirely, nonionic surfactant, soybean lecithin and aliphatic acid are sequentially added, continues to be heated to 95 DEG C or more, it is complete until dissolving,
And continue to stir 30min, cooling is cooled to room temperature.
Wherein, the adsorption enhancer is made of the following component calculated by weight percentage：
Amino acid surfactant 5-50%
Inorganic salts 0.5-5%
Deionized water surplus.
The preparation of adsorption enhancer：By amino acid surfactant in suitable deionized water, 95 DEG C or more are heated to,
Dissolving is complete, stirs evenly, adds in appropriate inorganic salts, continues to stir 30min, be cooled to room temperature.
Adsorption enhancer is using the interaction between amino acid surfactant and cation opsonizing agent, is effectively facilitated
Absorption of the conditioner on hair greatly enhances the adsorption efficiency of cation opsonizing agent, so as to improve conditioning effect.
The cation opsonizing agent be selected from guar hydroxypropyltrimonium ammonium chloride, polyquaternium -6, Polyquaternium-10,
It is one or more kinds of in polyquaternium -53, myristamide propyl pg dimonium chloride phosphate etc..Further sun from
The dosage of sub- conditioner is preferably 0.1-0.6%；Preferably, cation opsonizing agent is selected from quaternized cellulose ethers derivative,
Referred to as cationic cellulose, cationic cellulose polymer are the copolymers of hydroxyethyl cellulose and alkyl trimethyl ammonium chloride,
It is divided into according to degree ofacationic substitution difference：High-cation degree of substitution JR, middle degree ofacationic substitution LR and low degree ofacationic substitution LK
Three kinds of models, the cationic cellulose polymer of further preferred high-cation degree of substitution, i.e. Polyquaternium-10, other are suitble to
Copolymer for also having hydroxyethyl cellulose and dialkyl dimethyl ammonium chloride for cationic cellulose polymer of the invention etc.；
In addition cation opsonizing agent is preferably guar hydroxypropyltrimonium ammonium chloride in the present composition；Guar gum oxypropyl trimethyl
Ammonium chloride is cation guar gum, is the product for obtaining guar gum after quaternized, and a system can be obtained according to the difference of degree of substitution
The cationic guar product of row, preferably degree of substitution are 0.1 to 0.2, for the guar gum hydroxypropyltrimonium chloride of the present invention
Under the conditions of 25 DEG C, mass percent is that the viscosity of 1% guar gum hydroxypropyltrimonium chloride aqueous solution is 2000mPa.s-
4000mPa.s。
The additive is viscosity modifier, one kind or two in moisturizer, anti-dandruff agent, acid-base modifier, preservative, essence
Kind or more.Wherein, viscosity modifier is in sodium chloride, potassium chloride, ammonium chloride, cellulose derivative, acrylic copolymer
One kind, further preferred sodium chloride account for the 0.05-5% of shampoo composite weight percent；Moisturizer is selected from D-pantothenyl aleohol, front three
One kind in base glycine, levulan, further preferred D-pantothenyl aleohol account for the 0.05-5% of shampoo composite weight percent, into
One step is preferably 0.1%；Acid-base modifier is selected from citric acid, phosphoric acid, further preferred citric acid, it is preferable that perfume (or spice) of the invention
The pH value of wave composition is adjusted to 5-8, and it is 5.5-6.5 to advanced optimize to pH value；Anti-dandruff agent is selected from climbazole, pyridone ethyl alcohol
One kind in amine salt Octopirox, pyrithione metal salt (such as zinc pyrithione ZPT), further preferably pyridine sulphur
Ketone zinc accounts for the 0.1-3% of shampoo composite weight percent.The preservative is selected from potassium sorbate, methyl p-hydroxybenzoate
In one kind；The one kind of essence in vanillic aldehyde, peppermint, attar of rose, all components meet the regulation of hygienic standards for cosmetics,
Select the raw material of safety.
The present invention also provides a kind of preparation methods of the no mild conditioning shampoo composition of silicone oil, include the following steps：
(1) appropriate amount of deionized water is added in a kettle, cation opsonizing agent is added in, is slowly stirred, is uniformly dispersed, and is heated
To 70-90 DEG C；
(2) surfactant, thickening stabilizing agent are added according to above-mentioned formula rate, makes to be completely dissolved, and after being uniformly dispersed
Cooling；
(3) temperature is down to 45 DEG C or so, and addition adsorption enhancer, additive continue to stir, and are uniformly mixed；
(4) be eventually adding deionized water complement to predetermined amount to get.
In the following, with reference to attached drawing and specific embodiment, the present invention is described further：
Embodiment 1
Composition of the present invention without the thickening stabilizing agent in the mild conditioning shampoo composition of silicone oil：
The preparation method of thickening stabilizing agent：Sodium lauroyl sarcosine, sodium lauroyl glutamate are placed in deionized water and added
Heat of solution is complete, sequentially adds cocoyl glucoside, hydrogenated soya phosphatide and coco-nut oil fatty acid monoethanolamine, continues to be heated to
It is 95 DEG C or more, complete until dissolving, and continue to stir 30min, cooling, be cooled to room temperature to get.
The thickening stabilizing agent is layered liquid crystal (spherical shape) structure under petrographic microscope, sees Fig. 1.The thickening stabilizing agent is used for
In shampoo, the liquid crystal that amino acid type surfactant solution forms specific modality is can induce, is achieved the purpose that from thickening, therefore,
The suspension stability and hair conditioning of shampoo can be significantly improved.
Embodiment 2
Composition of the present invention without the middle adsorption enhancer in the mild conditioning shampoo composition of silicone oil：
The preparation of the adsorption enhancer：Each component is weighed according to above-mentioned formula rate, by cocoamido sodium propionate, bay
Acyl sodium glutamate, lauroyl NaAsp are heated to 95 DEG C or more in suitable deionized water, and dissolving is complete, and stirring is equal
It is even, add in sodium chloride, continue stir 30min, be cooled to room temperature to get.
Adsorption enhancer is using the interaction between amino acid surfactant and cation opsonizing agent, is effectively facilitated
Absorption of the conditioner on hair greatly enhances the adsorption efficiency of cation opsonizing agent, so as to improve conditioning effect.
Embodiment 3-12
Formula of the present invention without the mild conditioning shampoo composition of silicone oil such as following table 1-2：
1 shampoo formula (weight percent %) of table
2 shampoo formula (weight percent %) of table
In the following, the inspection of the measure and using effect of related physical and chemical index is carried out to the shampoo of embodiment 3-12：
1st, the related physical and chemical index test of the shampoo of embodiment 3-12
Wherein, the index test pH value of shampoo composite of the invention is under the conditions of temperature is 25 DEG C, containing weight percent
Than the pH value of the shampoo aqueous solution for 10%；
Foam height is measured using paddling process, i.e., adds in solution to be measured into the measuring cup of 100ml, with constant speed during experiment
Stop stirring after stirring 60s, record the foam height of generation；The foam height is used to evaluate the foamability of shampoo；
Viscosity uses NDJ-4 rotational viscometers (ten thousand CPS ranges of 0-200), and shampoo is placed in burning of the diameter not less than 70mm
In cup or straight tube container, measuring temperature is the viscosity (cps) of the shampoo at 25 DEG C, and test result is shown in Table 3.
The related physical and chemical index test result of the shampoo of 3 embodiment 3-12 of table
2nd, it is evaluated the effect of embodiment 3-12 shampoos
The evaluation of the effect of to embodiment 3-12 shampoos uses sensory evaluation method, and specific embodiment is as follows：
100 testers that are respectively issued to of the embodiment 3-12 shampoos of preparation are tested into use.Tester uses fragrant
Hair washing during wave sample in the same manner, each shampoo is continuous with two weeks respectively, and tester is according to the feeling of oneself to perfume (or spice)
Wave scores, and scoring is worst using 5 points of systems, 1 point, and 3 points moderate, and 5 points are best, and score more high effect is better, uses effect
Fruit evaluation result such as table 4.
The shampoo using effect evaluation result of 4 embodiment 3-12 of table
| Wet hair comb rationality | Hair drying comb rationality | Wet hair flexibility | Dry hair flexibility | |
| Embodiment 3 | 2.5 | 2.8 | 3.8 | 3.5 |
| Embodiment 4 | 2.8 | 2.7 | 3.9 | 3.6 |
| Embodiment 5 | 3.8 | 3.5 | 4.0 | 4.1 |
| Embodiment 6 | 4.6 | 4.5 | 4.8 | 4.5 |
| Embodiment 7 | 4.3 | 4.5 | 4.1 | 4.2 |
| Embodiment 8 | 3.0 | 2.7 | 3.7 | 3.6 |
| Embodiment 9 | 3.8 | 3.5 | 4.0 | 4.0 |
| Embodiment 10 | 4.3 | 4.8 | 4.9 | 4.6 |
| Embodiment 11 | 4.3 | 4.5 | 4.6 | 4.4 |
| Embodiment 12 | 4.6 | 4.9 | 4.5 | 4.8 |
It is shown by the test result in table, all subjects, which report, has scalp good tolerance.All subjects are
Like the feeling without the mild conditioner shampoo of silicone oil of the present invention, and 98% can continue periodically to use after the research phase of 14 days.
Scoring is higher, shows that user is more preferable to the using effect of test article, the cleaning action major embodiment of the shampoo
In the suction of thickening stabilizing agent, adsorption enhancer to the stability of entire shampoo system and to additives such as moisturizer, anti-dandruff agents
Attached stability plays an important role so that shampoo can reach the effect of required cleaning, conditioning, moist and moisturizing.By table 4
In as it can be seen that be added to the present invention thickening stabilizing agent, adsorption enhancer shampoo make user be easier receive, can be obviously improved
The problem of wet hair comb rationality, hair drying comb rationality, wet hair flexibility, dry hair flexibility.
It will be apparent to those skilled in the art that technical solution that can be as described above and design, make other various
Corresponding change and deformation, and all these changes and deformation should all belong to the protection domain of the claims in the present invention
Within.
Claims (8)
1. a kind of mild conditioning shampoo composition of no silicone oil, which is characterized in that prepared by the following component calculated by weight percentage
It forms：
Surfactant 10-35%
Thickening stabilizing agent 0.1-10%
Adsorption enhancer 1-15%
Cation opsonizing agent 0.05-1%
Additive 0.01-5%
Deionized water surplus;
The thickening stabilizing agent is made of the following component calculated by weight percentage：
Amino acid surfactant 10-85%
Soybean lecithin 5-40%
Nonionic surfactant 5-40%
Aliphatic acid 0-10%,
The weight percent summation of thickening stabilizing agent each component is 100%;
The adsorption enhancer is made of the following component calculated by weight percentage：
Amino acid surfactant 5-50%
Inorganic salts 0.5-5%
Deionized water surplus.
2. the mild conditioning shampoo composition of no silicone oil according to claim 1, which is characterized in that the surfactant by
It is formed with the following component that parts by weight calculate：
0-25 parts of sulfuric acid anion surfactant
3-30 parts of amino acid surfactant
1-11 parts of zwitterionic surfactant.
3. the mild conditioning shampoo composition of no silicone oil according to claim 2, which is characterized in that described sulfuric acid the moon from
Sub- surfactant is selected from alkyl sulfate, alkyl ether sulfate, alkyl amino ether sulfate, the alkane that the total number of carbon atoms is 8-24
One or more of base aryl ether sulfate, alkyl ether thio succinate；The salt is alkali metal salt, ammonium salt, amine
One kind in salt, ethylaminoethanol salt, magnesium salts.
4. the mild conditioning shampoo composition of no silicone oil according to claim 1 or 2, which is characterized in that the amino acids
Surfactant be selected from the total number of carbon atoms be the N- acylglycines salt of 8-18, N- acyl glutamates, N- acylalaninies salt,
One or more of N- acyl sarcosinates, N- acyl taurine salts, N- acylaspartic acid salt, the salt are sodium
One kind in salt, sylvite, ammonium salt, triethanolamine salt.
5. the mild conditioning shampoo composition of no silicone oil according to claim 2, which is characterized in that the amphoteric ion surface
Activating agent is selected from one or more of betaines, Beta-alanine class and imidazolines.
6. the mild conditioning shampoo composition of no silicone oil according to claim 1 or 2, which is characterized in that the cation is adjusted
It manages agent and is selected from guar hydroxypropyltrimonium ammonium chloride, polyquaternium -6, Polyquaternium-10, polyquaternium -53, myristoyl
One kind in amine propyl pg dimonium chloride phosphate.
7. the mild conditioning shampoo composition of no silicone oil according to claim 1 or 2, which is characterized in that the additive is
It is one or more kinds of in viscosity modifier, moisturizer, anti-dandruff agent, acid-base modifier, preservative, essence.
8. a kind of preparation method as described in claim 1 without the mild conditioning shampoo composition of silicone oil, which is characterized in that including
Following steps：
（1）Appropriate amount of deionized water is added in a kettle, is added in cation opsonizing agent, is slowly stirred, is uniformly dispersed, be heated to
70-90℃；
（2）Surfactant, thickening stabilizing agent are added according to above-mentioned formula rate, make to be completely dissolved, and after being uniformly dispersed cool down；
（3）Temperature is down to 45 DEG C or so, and addition adsorption enhancer, additive continue to stir, and are uniformly mixed；
（4）Be eventually adding deionized water complement to predetermined amount to get.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1404821A (en) * | 2001-09-20 | 2003-03-26 | 莱雅公司 | Foaming cosmetic paste |
| CN103655240A (en) * | 2013-11-28 | 2014-03-26 | 广州百孚润化工有限公司 | Liquid crystal thickener, preparation method and application thereof |
| CN104224575A (en) * | 2014-09-12 | 2014-12-24 | 广州市天吻娇颜化妆品有限公司 | Transparent silicone-oil-free hairdressing composition and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1404821A (en) * | 2001-09-20 | 2003-03-26 | 莱雅公司 | Foaming cosmetic paste |
| CN103655240A (en) * | 2013-11-28 | 2014-03-26 | 广州百孚润化工有限公司 | Liquid crystal thickener, preparation method and application thereof |
| CN104224575A (en) * | 2014-09-12 | 2014-12-24 | 广州市天吻娇颜化妆品有限公司 | Transparent silicone-oil-free hairdressing composition and preparation method thereof |
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Denomination of invention: The invention relates to a silicone oil-free mild conditioning shampoo composition and a preparation method thereof Effective date of registration: 20220113 Granted publication date: 20180612 Pledgee: Bank of China Limited by Share Ltd. Guangzhou Haizhu branch Pledgor: GUANGZHOU BAFEORII CHEMICAL CO.,LTD. Registration number: Y2021440000408 |