CN104927890B - Large-scale preparation process and device for oxidizing and infusible pitch pellets - Google Patents
Large-scale preparation process and device for oxidizing and infusible pitch pellets Download PDFInfo
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- CN104927890B CN104927890B CN201510311977.XA CN201510311977A CN104927890B CN 104927890 B CN104927890 B CN 104927890B CN 201510311977 A CN201510311977 A CN 201510311977A CN 104927890 B CN104927890 B CN 104927890B
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- 238000002360 preparation method Methods 0.000 title abstract description 6
- 230000001590 oxidative effect Effects 0.000 title abstract description 4
- 239000008188 pellet Substances 0.000 title 1
- 238000003860 storage Methods 0.000 claims abstract description 66
- 239000010426 asphalt Substances 0.000 claims abstract description 59
- 230000003647 oxidation Effects 0.000 claims abstract description 36
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 36
- 239000000284 extract Substances 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 27
- 210000000078 claw Anatomy 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000001360 synchronised effect Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims 8
- 239000004744 fabric Substances 0.000 claims 7
- 238000009835 boiling Methods 0.000 claims 4
- 238000005183 dynamical system Methods 0.000 claims 2
- 238000010257 thawing Methods 0.000 claims 2
- 238000007599 discharging Methods 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 230000008676 import Effects 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 238000002844 melting Methods 0.000 abstract description 28
- 230000008018 melting Effects 0.000 abstract description 27
- 230000008878 coupling Effects 0.000 abstract description 14
- 238000010168 coupling process Methods 0.000 abstract description 14
- 238000005859 coupling reaction Methods 0.000 abstract description 14
- 238000005485 electric heating Methods 0.000 abstract description 12
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 description 16
- 230000008569 process Effects 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000003796 beauty Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/02—Working-up pitch, asphalt, bitumen by chemical means reaction
- C10C3/04—Working-up pitch, asphalt, bitumen by chemical means reaction by blowing or oxidising, e.g. air, ozone
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Abstract
一种沥青球氧化不熔化的规模化制备工艺是将沥青球均布于环形筛框(1),将筛框组合箱(4)之间通过快速联轴器(3)组合形成小车,通过涡杆(8)转动将第一辆小车从等候位(22)进入第一存放小车舱,涡轮(7)通过筛框轴(2)带动环形筛框(1)旋转,鼓风机(P)从进气总管(21)抽取新鲜空气,使各个存放小车空间充满预热的空气,电加热板组件(11)预热到预定温度,这样沥青球的氧化不融化开始;待达到预定的氧化不融化时间后,将第二辆等候位小车推至第一存放小车舱,而第一辆小车递推到第二存放小车舱内,再重新进行沥青球的氧化不融化,以此类推。本发明具有可大规模化生产,沥青球光泽度无损伤的优点。
A large-scale preparation process for oxidizing and infusible asphalt balls is to distribute the asphalt balls evenly on the annular screen frame (1), combine the screen frame combination boxes (4) to form a trolley through a quick coupling (3), and pass the vortex The rod (8) rotates to bring the first car from the waiting position (22) into the first storage car cabin, the turbine (7) drives the ring-shaped screen frame (1) to rotate through the screen frame shaft (2), and the blower (P) from the air intake The main pipe (21) extracts fresh air, so that each space for storing trolleys is filled with preheated air, and the electric heating plate assembly (11) is preheated to a predetermined temperature, so that the oxidation and non-melting of asphalt balls begins; after reaching the predetermined oxidation and non-melting time , push the second waiting position dolly to the first storage dolly compartment, and push the first dolly to the second storage dolly compartment, and then re-oxidize the asphalt balls without melting, and so on. The invention has the advantages of large-scale production and no damage to the gloss of the asphalt ball.
Description
技术领域technical field
本发明属于一种沥青球氧化不熔化的规模化制备工艺及其装置。The invention belongs to a large-scale preparation process and a device for oxidizing and infusible asphalt spheres.
背景技术Background technique
沥青基球状活性炭由于其外观为规整的球形,高的残炭量,使得其具有较高的压碎强度和磨损强度,有望在诸多领域获得应用。但是球状活性炭的制备离不开沥青球的氧化不融化,而诸多关于沥青球的专利中谈到沥青球氧化不融化的方法较少,相应的装置就更少了。Pitch-based spherical activated carbon is expected to be applied in many fields due to its regular spherical appearance and high carbon residue, which makes it have high crushing strength and wear strength. However, the preparation of spherical activated carbon is inseparable from the oxidation and non-melting of pitch balls, and in many patents about pitch balls, there are few methods for oxidation and non-melting of pitch balls, and there are even fewer corresponding devices.
从目前已公开的专利来看,具体涉及到沥青球的氧化不融化技术和装置的专利是本发明人发明的CN201310227294.7“沥青球氧化不熔化方法”的专利。在该专利中,具有的氧化不融化方法和装置如下:在旋转炉或固定床内放入沥青球,通入空气,然后以一定升温速率从室温升温到一定温度后停留数小时;之后将该初步氧化的沥青球转入温度梯度升高的隧道窑内进行氧化,获得氧化不熔化沥青球。该专利虽然成功避免了沥青氧化过程中的着火问题,氧化不融化后的沥青球的均匀性和产能得到了一定程度的改善,但受限于所提供的方法和装置,显然均匀性和产能还有很大的提升空间。另外,由于沥青球本身强度很差,采用旋转炉将使沥青球的光泽度损伤甚至损坏。Judging from the patents that have been published so far, the patent specifically related to the oxidation and non-melting technology and device of asphalt balls is the patent of CN201310227294.7 "Method for Oxidation and Non-melting of Pitch Balls" invented by the inventor. In this patent, the oxidative non-melting method and device are as follows: put asphalt balls in a rotary furnace or a fixed bed, feed air, and then stay for several hours after heating up from room temperature to a certain temperature at a certain heating rate; The initially oxidized asphalt balls are transferred to a tunnel kiln with an elevated temperature gradient for oxidation to obtain oxidized infusible asphalt balls. Although this patent successfully avoided the ignition problem in the asphalt oxidation process, and the uniformity and production capacity of the oxidized and unmelted asphalt balls have been improved to a certain extent, but limited by the method and device provided, it is obvious that the uniformity and production capacity are not enough. There is a lot of room for improvement. In addition, due to the poor strength of the asphalt ball itself, the use of a rotary furnace will damage or even damage the gloss of the asphalt ball.
发明内容Contents of the invention
本发明的目的是提供一种可大规模化生产,沥青球光泽度无损伤的沥青球氧化不熔化的规模化制备工艺及其装置。The purpose of the present invention is to provide a large-scale production process and a device for the large-scale preparation of asphalt balls which can be produced on a large scale and have no damage to the gloss of the asphalt balls.
本发明的工艺是按如下步骤实现的:Technology of the present invention is realized as follows:
(1)、将沥青球分别均布于带轮的底层筛框组合箱内环形筛框和筛框组合箱内环形筛框中,将筛框组合箱之间,筛框组合箱与带轮的底层筛框组合箱之间通过快速联轴器组合形成小车;(1) Distribute the asphalt balls evenly in the ring screen frame in the bottom screen frame combination box with wheels and in the ring screen frame in the screen frame combination box, place between the screen frame combination boxes, the screen frame combination box and the wheeled screen frame The combination box of the bottom screen frame is combined with a quick coupling to form a trolley;
(2)、手工推动小车运行至氧化不融化装置前的等候位,开启推拉隔舱门和减速电机,进而通过减速电机所连接的涡杆推至推进档位,使卡爪与涡杆相互啮合,涡杆和涡轮处于脱离状态,将第一辆小车从等候位进入第一存放小车舱、关闭推拉隔舱门,开启鼓风机,电加热板组件,温度指示控制和阀门,将涡杆推至旋转档位,使涡杆和涡轮相互啮合,卡爪与涡杆处于脱离状态,减速电机M驱动蜗杆和涡轮旋转,涡轮通过筛框轴带动环形筛框旋转,鼓风机从进气总管抽取新鲜空气,使各个存放小车空间充满预热的空气,电加热板组件预热到预定温度,这样沥青球的氧化不融化即以开始;(2) Manually push the trolley to the waiting position in front of the oxidation and non-melting device, open the push-pull compartment door and the deceleration motor, and then push the worm rod connected to the deceleration motor to the propulsion gear, so that the claws and the worm rod mesh with each other , the worm rod and the turbine are in the disengaged state, put the first car from the waiting position into the first storage car compartment, close the push-pull compartment door, turn on the blower, the electric heating plate assembly, the temperature indication control and the valve, and push the worm rod to rotate The gear position makes the worm and turbine mesh with each other, the claw and the worm are in a disengaged state, the geared motor M drives the worm and the turbine to rotate, the turbine drives the ring-shaped screen frame to rotate through the screen frame shaft, and the blower draws fresh air from the intake manifold to make the Each storage car space is filled with preheated air, and the electric heating plate assembly is preheated to a predetermined temperature, so that the oxidation of the asphalt balls will start without melting;
(3)、待达到预定的氧化不融化时间后,关闭旋转电机,打开所有推拉隔舱门,之后电机推至推进档位并开启,将第二辆等候位小车推至第一存放小车舱,而第一辆小车递推到第二存放小车舱内,同时关闭所有推拉隔舱门,重新切换电机至旋转档位,再重新打开进气分管上的阀门,通入预定的空气量,分别进行第一存放小车舱和第二存放小车舱内沥青球的氧化不融化;(3) After the predetermined oxidation and non-melting time is reached, turn off the rotating motor, open all the push-pull compartment doors, then push the motor to the propulsion position and turn it on, push the second waiting car to the first storage car compartment, The first trolley is recursively pushed into the second storage trolley compartment, and at the same time close all the push-pull compartment doors, re-switch the motor to the rotation gear, and then reopen the valve on the air intake pipe to let in a predetermined amount of air, respectively. The oxidation of asphalt balls in the first storage compartment and the second storage compartment does not melt;
(4)、依次类推,直至小车由最后存放小车舱推出物料即为完成了氧化不融化后的沥青球产品,每次最后存放小车舱推出的小车卸料后,再装生料手工推至等候位并进入第一存放小车舱,如此连续操作至批次物料结束;(4), and so on, until the car is pushed out from the last storage car compartment, the asphalt ball product has been oxidized and not melted. position and enter the first storage car compartment, and continue to operate until the end of the batch of materials;
(5)、当批次物料投放完成后进入停车阶段,小车只出不进,该阶段开始于第一存放小车舱走空,而结束于最后存放小车舱走空,关闭全部阀门,减速电机,鼓风机,电加热板组件和温度指示控制。(5) When the batch of materials is put into the parking stage, the car can only go out but not in. This stage starts when the first storage car compartment is emptied, and ends when the last storage car compartment is emptied, all valves are closed, and the motor is reduced. Blower, electric heating plate assembly and temperature indicating controls.
如上所述的第一存放小车舱的温度为60-80℃,最后存放小车舱的温度为260-280℃;第一存放小车舱与最后存放小车舱之间的各舱温度是依次升高的,也即不同小车舱设定并运行于不同的温度。相邻的数个舱可以是相同或不同的温度。As mentioned above, the temperature of the first storage compartment is 60-80°C, and the temperature of the last storage compartment is 260-280°C; the temperature of each compartment between the first storage compartment and the last storage compartment increases sequentially , that is, different cabins are set and run at different temperatures. Adjacent compartments can be at the same or different temperatures.
如上所述的各存放小车舱的停留时间为0.5-2h;如上所述的小车经过各存放舱的停留时间均一,而小车走完各舱所需时间总和由工艺条件确定。The residence time of the above-mentioned storage cabins is 0.5-2h; the residence time of the above-mentioned trolleys passing through each storage cabin is uniform, and the sum of the time required for the trolley to complete each cabin is determined by the process conditions.
如上所述的各存放小车舱的空气量按每小时每公斤沥青球1.5-5.0m3通入,其中由前一级高温舱而来的热空气占总通入气量的1/2-2/3,剩余部分补入新鲜空气;As mentioned above, the air volume of each storage cabin is 1.5-5.0m 3 per kilogram of asphalt balls per hour, and the hot air from the previous high-temperature cabin accounts for 1/2-2/ of the total air volume. 3. Fill the rest with fresh air;
如上所述的沥青球的球径在0.1-1.2mm之间。The ball diameter of the asphalt ball as mentioned above is between 0.1-1.2 mm.
为了实现本发明目的,设计了一种氧化不熔化装置,它包括小车,动力系统,炉体,推拉隔舱门,电加热板,进出气系统,其特征在于小车包括环形筛框,筛框轴,快速联轴器,筛框组合箱,带轮的底层筛框组合箱和涡轮,筛框组合箱为不少于2个,其内有环形筛框,环形筛框与位于筛框组合箱中心的筛框轴连接,并和筛框轴一起转动,最高层筛框轴的下端固定有空心的上半联轴器,带柱芯的下半联轴器连接于下层筛框轴的上端,依次类推,位于带轮的底层筛框组合箱的筛框轴的下端有涡轮,带轮的底层筛框组合箱底部的一端有卡爪,筛框组合箱之间由筛框组合箱四周边框活动连接,带轮的底层筛框组合箱与上层筛框组合箱之间由四周边框活动连接,前后炉体有推拉隔舱门,前后炉体与推拉隔舱门之间构成存放小车舱,该存放小车舱有不少于10个,前后炉体外壁上分别连接有电加热板,前后炉体内壁分别有布风腔;动力系统包括轴承座组件,涡轮,蜗杆,卡爪,减速电机M和带轮的运动平台,轴承座组件支撑蜗杆两端,轴承座组件位于带轮的运动平台之上,带轮的运动平台位于基础之上,涡轮与蜗杆通过旋转档位连接,卡爪与蜗杆通过推进档位连接;进出气系统包括出气分管,进气分管,阀门,补气管,尾气总管,进气总管,布风腔,温度指示控制和鼓风机,在最后存放小车舱的后炉体上有进气分管连接鼓风机和阀门,鼓风机进风口与进气总管连接,鼓风机出风口经过阀门与布风腔相通,在最后存放小车舱的前炉体上有出气分管连接鼓风机和阀门,鼓风机进风口分别与二个阀门连接,一个阀门与前炉体的布风腔连接,另一个阀门补气管通过与进气总管连接,鼓风机出风口分别与尾气总管和前面存放小车舱的前炉体的布风腔连接,位于前面存放小车空间的后炉体一侧的鼓风机进气口分别通过阀门与布风腔和补气管连接,补气管与进气总管连接,位于前面存放小车舱的后炉体一侧的鼓风机出气口分别与尾气总管和前面存放小车舱的后炉体的布风腔连接,依次类推,位于第一存放小车舱的鼓风机出气口只与尾气总管连接,温度指示控制指示并控制存放小车空间的温度。In order to realize the purpose of the present invention, a kind of oxidation non-melting device has been designed, and it comprises trolley, power system, body of furnace, push-pull compartment door, electric heating plate, gas inlet and outlet system, it is characterized in that trolley comprises annular sieve frame, sieve frame shaft , quick coupling, screen frame combination box, bottom screen frame combination box with wheels and turbine, there are no less than 2 screen frame combination boxes, and there is a ring screen frame inside, and the ring screen frame is located in the center of the screen frame combination box The shaft of the screen frame is connected and rotates together with the shaft of the screen frame. The lower end of the shaft of the top screen frame is fixed with a hollow upper half coupling, and the lower half coupling with a column core is connected to the upper end of the shaft of the lower screen frame. By analogy, there is a turbine at the lower end of the screen frame shaft of the bottom screen frame combination box with wheels, and there is a claw at the bottom end of the bottom screen frame combination box with wheels, and the screen frame combination boxes are flexibly connected by the surrounding frames of the screen frame combination box , the bottom screen frame combination box with wheels and the upper screen frame combination box are flexibly connected by surrounding frames. The front and rear furnace bodies have push-pull compartment doors. There are no less than 10 cabins, electric heating plates are connected to the front and rear furnace outer walls, and air distribution chambers are respectively located on the front and rear furnace inner walls; the power system includes bearing housing components, turbines, worms, claws, gear motors M and pulleys The motion platform, the bearing housing assembly supports both ends of the worm, the bearing housing assembly is located on the motion platform with wheels, the motion platform with wheels is located on the foundation, the turbine and the worm are connected through the rotating gear, and the claws and the worm are through the advancing gear The air inlet and outlet system includes air outlet pipe, air inlet pipe, valve, air supply pipe, exhaust main pipe, air intake main pipe, air distribution chamber, temperature indication control and blower, and there is an air inlet pipe on the rear furnace body where the trolley compartment is stored at the end Connect the blower and the valve, the air inlet of the blower is connected with the air intake main pipe, the air outlet of the blower communicates with the air distribution cavity through the valve, and there is an outlet branch pipe connected to the blower and the valve on the front furnace body where the trolley cabin is finally stored, and the air inlet of the blower is respectively connected with two The valves are connected, one valve is connected with the air distribution chamber of the front furnace body, the air supply pipe of the other valve is connected with the intake main pipe, and the blower outlet is respectively connected with the tail gas main pipe and the air distribution chamber of the front furnace body where the trolley compartment is stored in front. The air inlet of the blower on the side of the rear furnace body where the trolley is stored in the front is connected to the air distribution chamber and the air supply pipe through valves, and the air supply pipe is connected to the main air intake pipe, and the air outlet of the blower is located on the side of the rear furnace body where the trolley compartment is stored in the front They are respectively connected to the exhaust gas main pipe and the air distribution chamber of the rear furnace body in the front storage car compartment, and so on. The blower outlet located in the first storage car compartment is only connected to the exhaust gas main pipe, and the temperature indication control indicates and controls the temperature of the storage car space.
如上所述的筛框组合箱为2-20个。There are 2-20 sieve frame combination boxes as mentioned above.
如上所述的存放小车舱为10-15个。There are 10-15 storage compartments as mentioned above.
如上所述的快速联轴器由空心的上半联轴器和带柱芯的下半联轴器组成,当筛框堆砌时,带柱芯的下半联轴器的柱芯起导向作用,并使得同小车中各轴同心且稳固。The above-mentioned quick coupling is composed of a hollow upper half coupling and a lower half coupling with a column core. When the screen frames are piled up, the column core of the lower half coupling with a column core acts as a guide. And make each axis in the same trolley concentric and stable.
如上所述的推拉隔舱门开启可以是电动同步的,气动同步的,或者是诸多操作人员各司其职而近乎同步推拉的。该推拉隔舱门结构同插板,一对推拉隔舱门每瓣正好阻挡半幅通道,两瓣正好对齐封闭通道。The opening of the above-mentioned push-pull compartment door can be electric synchronous, pneumatic synchronous, or many operators perform their duties and push and pull nearly synchronously. The structure of the push-pull compartment door is the same as that of the plug-in plate, and each flap of a pair of push-pull compartment doors just blocks the half-width passage, and the two petals are just aligned with the closed passage.
本发明的优点:Advantages of the present invention:
1本专利由于采用了物料的旋转,使得设备的容积可按照产能要求进行放大,再加上还可分步连续进料,故其产能得到大幅度的提升,使得沥青球的规模化氧化不融化制备成为现实;1. Due to the use of material rotation in this patent, the volume of the equipment can be enlarged according to the production capacity requirements. In addition, it can be continuously fed step by step, so its production capacity is greatly improved, so that the large-scale oxidation of asphalt balls does not melt preparation becomes a reality;
2由于采用了筛框盛放沥青球的方法,使得沥青球自身不发生任何运动,这样不再经受沥青球之间彼此的碰撞、磨损,使得氧化不融化后的沥青球的表面光泽度得以保持原料的光泽,保证了其美观漂亮;2. Due to the method of holding the asphalt balls in the sieve frame, the asphalt balls do not have any movement, so that they are no longer subject to collision and wear between the asphalt balls, so that the surface gloss of the oxidized and unmelted asphalt balls can be maintained. The luster of the raw material ensures its beauty;
3由于采用圆形筛框,这样沥青球在每层筛框中的填装厚度有限,这样可防止沥青球在氧化不融化过程中的着火,同时也利于空气与沥青球的充分接触,使沥青球实现更均匀的氧化不融化;3 Due to the use of a circular screen frame, the filling thickness of the asphalt balls in each layer of the screen frame is limited, which can prevent the asphalt balls from igniting during the oxidation and melting process, and also facilitate the full contact between the air and the asphalt balls, so that the asphalt balls Balls achieve more uniform oxidation without melting;
4本专利采用上一级高温舱的部分热空气进入下一级低温舱的方法,可大幅降低加热能耗和空气消耗;4 This patent adopts the method that part of the hot air from the upper high temperature cabin enters the lower low temperature cabin, which can greatly reduce heating energy consumption and air consumption;
5由于相邻各舱内的温度能够按工艺设定,这样沥青球在某一温度区间的停留时间能够延长,可满足沥青球氧化不融化的要求,提高其氧化不融化的均匀性。5. Since the temperature in adjacent compartments can be set according to the process, the residence time of the asphalt balls in a certain temperature range can be extended, which can meet the requirements of the asphalt balls for oxidation and non-melting, and improve the uniformity of the oxidation and non-melting of the asphalt balls.
附图说明Description of drawings
图1是本发明装置的正面结构示意图。Fig. 1 is a schematic view of the front structure of the device of the present invention.
图2是本发明装置的俯视结构示意图。Fig. 2 is a top structural schematic diagram of the device of the present invention.
图3是本发明I-I局部结构示意图。Fig. 3 is a schematic diagram of the partial structure of I-I of the present invention.
图4是本发明П-П局部结构示意图。Fig. 4 is a schematic diagram of a partial structure of П-П of the present invention.
如图所示,1是环形筛框2是筛框轴3是快速联轴器4是筛框组合箱5是推拉隔舱门6是带轮的底层筛框组合箱,7是涡轮,8是蜗杆,9是出气分管,10是进气分管,11是电加热板组件,12是阀门,13是补气管,14是布风腔,15是轴承座组件,16是带轮的运动平台,17是基础,18是卡爪,19是炉体,20是尾气总管,21是进气总管,22是等候位,M是减速电机,TIC是温度指示控制,P是鼓风机,III是旋转档位,IV是推进档位。As shown in the figure, 1 is the ring screen frame, 2 is the screen frame shaft, 3 is the quick coupling, 4 is the screen frame combination box, 5 is the push-pull compartment door, 6 is the bottom screen frame combination box with wheels, 7 is the turbine, and 8 is Worm, 9 is the air outlet pipe, 10 is the air intake pipe, 11 is the electric heating plate assembly, 12 is the valve, 13 is the air supply pipe, 14 is the air distribution chamber, 15 is the bearing seat assembly, 16 is the motion platform with wheels, 17 18 is the claw, 19 is the furnace body, 20 is the exhaust manifold, 21 is the intake manifold, 22 is the waiting position, M is the geared motor, TIC is the temperature indication control, P is the blower, III is the rotation gear, IV is the propulsion gear.
具体实施方式detailed description
实施例中沥青球氧化不熔化程度可按粘结率计算:将氧化不熔化沥青球在N2气氛中升温到800℃后停留1h,获得炭化沥青球;随机抽取30-50颗炭化后的沥青球,粘附在一起的颗粒总数占总颗粒数的百分比即为粘结率。In the examples, the degree of oxidized infusibility of asphalt balls can be calculated according to the cohesive rate: heat the oxidized infusible asphalt balls to 800°C in N2 atmosphere and stay there for 1 hour to obtain carbonized asphalt balls; randomly select 30-50 carbonized asphalt balls For balls, the percentage of the total number of particles adhering together to the total number of particles is the cohesion rate.
实施例1Example 1
一种氧化不熔化装置,它包括小车,动力系统,炉体19,推拉隔舱门5,电加热板11,进出气系统,其特征在于小车包括环形筛框1,筛框轴2,快速联轴器3,筛框组合箱4,带轮的底层筛框组合箱6和涡轮7,筛框组合箱4为4个,其内有环形筛框1,环形筛框1与位于筛框组合箱4中心的筛框轴2连接,并和筛框轴2一起转动,最高层筛框轴2的下端固定有空心的上半联轴器3b,带柱芯的下半联轴器3a连接于下层筛框轴2的上端,依次类推,位于带轮的底层筛框组合箱6的筛框轴2的下端有涡轮7,带轮的底层筛框组合箱6底部的一端有卡爪18,筛框组合箱4之间由筛框组合箱4四周边框活动连接,带轮的底层筛框组合箱6与上层筛框组合箱4之间由四周边框活动连接,前后炉体19有推拉隔舱门5,前后炉体19与推拉隔舱门5之间构成存放小车舱,该存放小车舱有10个,前后炉体19外壁上分别连接有电加热板11,前后炉体19内壁分别有布风腔14;动力系统包括轴承座组件15,涡轮7,蜗杆8,卡爪18,减速电机M和带轮的运动平台16,轴承座组件15支撑蜗杆8两端,轴承座组件15位于带轮的运动平台16之上,带轮的运动平台16位于基础17之上,涡轮7与蜗杆8通过旋转档位III连接,卡爪18与蜗杆8通过推进档位IV连接;进出气系统包括出气分管9,进气分管10,阀门12,补气管13,尾气总管20,进气总管21,布风腔14,温度指示控制TIC和鼓风机P,在最后存放小车舱的后炉体19上有进气分管10连接鼓风机P和阀门12,鼓风机P进风口与进气总管21连接,鼓风机P出风口经过阀门12与布风腔14相通,在最后存放小车舱的前炉体19上有出气分管10连接鼓风机P和阀门12,鼓风机P进风口分别与二个阀门12连接,一个阀门12与前炉体19的布风腔14连接,另一个阀门12补气管13通过与进气总管21连接,鼓风机P出风口分别与尾气总管20和前面存放小车舱的前炉体19的布风腔14连接,位于前面存放小车空间的后炉体19一侧的鼓风机P进气口分别通过阀门12与布风腔14和补气管13连接,补气管13与进气总管21,位于前面存放小车舱的后炉体19一侧的鼓风机P出气口分别与尾气总管20和前面存放小车舱的后炉体19的布风腔14连接,依次类推,位于第一存放小车舱的鼓风机P出气口只与尾气总管20连接,温度指示控制TIC指示并控制存放小车空间的温度。An oxidation non-melting device, which includes a trolley, a power system, a furnace body 19, a push-pull compartment door 5, an electric heating plate 11, an air inlet and outlet system, and is characterized in that the trolley includes an annular screen frame 1, a screen frame shaft 2, and a quick coupling Shaft device 3, screen frame combination box 4, bottom screen frame combination box 6 with wheels and turbine 7, screen frame combination box 4 is 4, there is an annular screen frame 1 inside, and the annular screen frame 1 is connected with the screen frame combination box 4. The screen frame shaft 2 in the center is connected and rotates together with the screen frame shaft 2. The lower end of the top screen frame shaft 2 is fixed with a hollow upper half coupling 3b, and the lower half coupling 3a with a column core is connected to the lower layer The upper end of the screen frame shaft 2, and so on, is located at the lower end of the screen frame shaft 2 of the bottom screen frame combination box 6 with wheels, and there is a turbine 7 at the bottom end of the bottom screen frame combination box 6 with wheels. The combination boxes 4 are connected by the surrounding frames of the screen frame combination box 4, and the bottom screen frame combination box 6 with wheels is connected with the upper screen frame combination box 4 by the surrounding frames. The front and rear furnace bodies 19 have push-pull compartment doors 5 , between the front and rear furnace body 19 and the push-pull compartment door 5, there are 10 storage car cabins, and the outer walls of the front and rear furnace bodies 19 are respectively connected with electric heating plates 11, and the inner walls of the front and rear furnace bodies 19 are respectively equipped with air distribution chambers. 14. The power system includes a bearing seat assembly 15, a turbine 7, a worm 8, a claw 18, a geared motor M and a pulley motion platform 16. The bearing seat assembly 15 supports both ends of the worm 8, and the bearing seat assembly 15 is located in the movement of the pulley. On the platform 16, the wheeled moving platform 16 is located on the foundation 17, the turbine 7 and the worm 8 are connected through the rotating gear III, the claw 18 is connected with the worm 8 through the advancing gear IV; the air inlet and outlet system includes the air outlet branch 9, Air intake branch pipe 10, valve 12, air supply pipe 13, exhaust gas main pipe 20, air intake main pipe 21, air distribution chamber 14, temperature indication control TIC and blower P, and there is an air intake branch pipe 10 on the rear furnace body 19 where the trolley cabin is finally stored Connect the blower P and the valve 12, the air inlet of the blower P is connected with the air intake main pipe 21, the air outlet of the blower P communicates with the air distribution chamber 14 through the valve 12, and there is an air outlet branch pipe 10 connected to the blower P on the front furnace body 19 where the trolley compartment is finally stored And the valve 12, the blower P air inlet is connected with two valves 12 respectively, one valve 12 is connected with the air distribution cavity 14 of the front furnace body 19, the other valve 12 is connected with the air intake main pipe 13, and the blower P air outlet They are respectively connected to the exhaust gas main pipe 20 and the air distribution cavity 14 of the front furnace body 19 storing the trolley compartment in the front, and the blower P air inlet on the side of the rear furnace body 19 where the trolley is stored in the front is respectively connected to the air distribution cavity 14 and the air distribution cavity 14 through the valve 12. The air supply pipe 13 is connected, and the air supply pipe 13 is connected with the air intake main pipe 21, and the outlet of the blower P on the side of the rear furnace body 19 where the trolley compartment is stored in the front is respectively connected with the exhaust gas main pipe 20 and the air distribution chamber of the rear furnace body 19 where the trolley compartment is stored in the front. 14 connection, and so on, the blower P outlet located in the first storage compartment is only connected to the exhaust main pipe 20, and the temperature indication control TIC indicates and controls the temperature of the storage space.
(1)、将沥青球分别均布于带轮的底层筛框组合箱6内环形筛框1和筛框组合箱4内环形筛框1中,将筛框组合箱4之间,筛框组合箱4与带轮的底层筛框组合箱6之间通过快速联轴器3组合形成小车;(1) Evenly distribute the asphalt balls in the ring-shaped screen frame 1 in the bottom screen frame combination box 6 with wheels and in the ring-shaped screen frame 1 in the screen frame combination box 4. Between the screen frame combination box 4, the screen frame combination The box 4 is combined with the bottom screen frame combination box 6 with wheels through a quick coupling 3 to form a trolley;
(2)、手工推动小车运行至氧化不融化装置前的等候位22,开启推拉隔舱门5和减速电机M,进而通过减速电机M所连接的涡杆8推至推进档位IV,使卡爪18与涡杆8相互啮合,涡杆8和涡轮7处于脱离状态,将第一辆小车从等候位进入第一存放小车舱、关闭推拉隔舱门5,开启鼓风机P,电加热板组件11,温度指示控制TIC和阀门12,将涡杆8推至旋转档位III,使涡杆8和涡轮7相互啮合,卡爪18与涡杆8处于脱离状态,减速电机M驱动蜗杆8和涡轮7旋转,涡轮7通过筛框轴带动环形筛框1旋转,鼓风机P从进气总管21抽取新鲜空气,使各个存放小车空间充满预热的空气,电加热板组件11预热到预定温度,这样沥青球的氧化不融化即以开始;(2), manually push the trolley to run to the waiting position 22 before the oxidation and non-melting device, open the push-pull compartment door 5 and the reduction motor M, and then push the worm rod 8 connected to the reduction motor M to the advancing gear position IV, so that the card The claws 18 and the worm 8 are engaged with each other, the worm 8 and the turbine 7 are in a disengaged state, the first trolley enters the first storage compartment from the waiting position, closes the push-pull compartment door 5, turns on the blower P, and the electric heating plate assembly 11 , the temperature indicator controls the TIC and the valve 12, pushes the worm 8 to the rotation gear III, makes the worm 8 and the worm 7 mesh with each other, the claw 18 and the worm 8 are in a disengaged state, and the reduction motor M drives the worm 8 and the worm 7 Rotate, the turbine 7 drives the ring-shaped screen frame 1 to rotate through the screen frame shaft, and the blower P draws fresh air from the intake manifold 21, so that each space for storing trolleys is filled with preheated air, and the electric heating plate assembly 11 is preheated to a predetermined temperature, so that the asphalt Oxidation of the ball begins without melting;
(3)、待达到预定的氧化不融化时间后,关闭旋转电机M,打开所有推拉隔舱门5,之后电机M推至推进档位IV并开启,将第二辆等候位小车推至第一存放小车舱,而第一辆小车递推到第二存放小车舱内,同时关闭所有推拉隔舱门5,重新切换电机M至旋转档位III,再重新打开进气分管10上的阀门12,通入预定的空气量,分别进行第一存放小车舱和第二存放小车舱内沥青球的氧化不融化;(3) After the predetermined oxidation and non-melting time is reached, turn off the rotating motor M, open all the push-pull compartment doors 5, then push the motor M to the propulsion position IV and turn it on, and push the second waiting car to the first Store the trolley cabin, and push the first trolley to the second storage trolley cabin, close all the push-pull compartment doors 5 at the same time, re-switch the motor M to the rotation gear position III, and then reopen the valve 12 on the intake pipe 10, Introduce a predetermined amount of air to oxidize and not melt the asphalt balls in the first storage compartment and the second storage compartment respectively;
(4)、依次类推,直至小车由最后存放小车舱推出物料即为完成了氧化不融化后的沥青球产品,每次最后存放小车舱推出的小车卸料后,再装生料手工推至等候位22并进入第一存放小车舱,如此连续操作至批次物料结束;(4), and so on, until the car is pushed out from the last storage car compartment, the asphalt ball product has been oxidized and not melted. Position 22 and enter the first storage car compartment, so continue to operate until the end of the batch of materials;
(5)、当批次物料投放完成后进入停车阶段,小车只出不进,该阶段开始于第一存放小车舱走空,而结束于最后存放小车舱走空,关闭全部阀门12,减速电机M,鼓风机P,电加热板组件11和温度指示控制TIC。(5) When the batch of materials is put into the parking stage, the car can only go out but not in. This stage starts with the emptying of the first storage compartment and ends with the emptying of the last storage compartment. Close all valves 12 and reduce the motor M, blower P, electric heating plate assembly 11 and temperature indication control TIC.
所述的存放小车舱的温度为60℃,最后存放小车舱的温度为280℃,其余各存放小车舱的温度见表1。小车经过各存放舱的停留时间见表1The temperature of the described car compartments is 60°C, and the temperature of the last car compartments is 280°C. The temperatures of the rest of the car compartments are shown in Table 1. The residence time of the trolley passing through each storage compartment is shown in Table 1
所述的各存放小车舱的空气量按表1通入,其中由前一级高温舱而来的热空气占总通入气量见表1,剩余部分补入新鲜空气;The amount of air in each of the storage compartments is introduced according to Table 1, wherein the hot air from the previous high-temperature cabin accounts for the total air intake shown in Table 1, and the remaining part is filled with fresh air;
所述的沥青球的球径在0.1mm,10kg沥青球的氧化不融化,各舱停留时间为0.5h,The diameter of the asphalt balls is 0.1mm, the oxidation of 10kg of asphalt balls does not melt, and the residence time of each cabin is 0.5h.
表1 各舱工艺参数:Table 1 Process parameters of each tank:
氧化不融化后所得产品的粘结率为0.8%。The cohesive rate of the product obtained after oxidation and non-melting was 0.8%.
实施例2Example 2
存放小车舱有13个,筛框组合箱4为10个,其余同实施例1。There are 13 trolley cabins stored, and 10 screen frame combination boxes 4, and all the other are with embodiment 1.
按照实施例的方法进行0.5mm的50kg沥青球的氧化不融化,各舱停留时间为0.5h,各舱工艺参数如表2:According to the method of the embodiment, the oxidation and non-melting of 50kg pitch balls of 0.5mm is carried out, and the residence time of each cabin is 0.5h, and the process parameters of each cabin are shown in Table 2:
氧化不融化后所得产品的粘结率为0.6%。The cohesive rate of the product obtained after oxidation and non-melting is 0.6%.
实施例3Example 3
存放小车舱有15个,筛框组合箱4为15个,其余同实施例1。There are 15 compartments for storing cars, and 15 screen frame combination boxes 4, and all the other are with embodiment 1.
按照实施例的方法进行1mm的20kg沥青球的氧化不融化,各舱停留时间为1h,各舱工艺参数如表3:According to the method of the embodiment, the oxidation and non-melting of 20kg asphalt balls of 1mm is carried out, and the residence time of each cabin is 1h, and the process parameters of each cabin are shown in Table 3:
氧化不融化后所得产品的粘结率为0.5%。The cohesive rate of the product obtained after oxidation and non-melting is 0.5%.
实施例4Example 4
存放小车舱有15个,筛框组合箱4为20个,其余同实施例1。There are 15 compartments for storing cars, and 20 sieve frame combination boxes, and all the other are with embodiment 1.
按照实施例的方法进行1.2mm的30kg沥青球的氧化不融化,各舱停留时间为1.5h,各舱工艺参数如表4:According to the method of the embodiment, the oxidation and non-melting of 30kg asphalt balls of 1.2mm is carried out, and the residence time of each cabin is 1.5h, and the process parameters of each cabin are shown in Table 4:
氧化不融化后所得产品的粘结率为0.7%。The cohesive rate of the product obtained after oxidation and non-melting is 0.7%.
实施例5Example 5
存放小车舱有11个,筛框组合箱4为10,其余同实施例1。There are 11 car compartments for storage, and 10 screen frame combination boxes 4, all the other are with embodiment 1.
按照实施例的方法进行0.8mm的100kg沥青球的氧化不融化,各舱停留时间为2h,各舱工艺参数如表5:According to the method of the embodiment, the oxidation and non-melting of 100kg asphalt balls of 0.8mm is carried out, and the residence time of each cabin is 2h, and the process parameters of each cabin are shown in Table 5:
氧化不融化后所得产品的粘结率为0.4%。The cohesive rate of the product obtained after oxidation and non-melting was 0.4%.
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