CN104927740A - Environment-friendly stone seamless adhesive glue and preparing method thereof - Google Patents
Environment-friendly stone seamless adhesive glue and preparing method thereof Download PDFInfo
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- CN104927740A CN104927740A CN201510329585.6A CN201510329585A CN104927740A CN 104927740 A CN104927740 A CN 104927740A CN 201510329585 A CN201510329585 A CN 201510329585A CN 104927740 A CN104927740 A CN 104927740A
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- 239000004575 stone Substances 0.000 title claims abstract description 138
- 239000003292 glue Substances 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims abstract description 14
- 230000001070 adhesive effect Effects 0.000 title abstract description 25
- 239000000853 adhesive Substances 0.000 title abstract description 24
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 66
- 239000000203 mixture Substances 0.000 claims abstract description 40
- 239000000945 filler Substances 0.000 claims abstract description 28
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims description 117
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 78
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 claims description 58
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 46
- 239000000377 silicon dioxide Substances 0.000 claims description 39
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 38
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 38
- 239000000843 powder Substances 0.000 claims description 38
- JMWUYEFBFUCSAK-UHFFFAOYSA-L nickel(2+);octadecanoate Chemical compound [Ni+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JMWUYEFBFUCSAK-UHFFFAOYSA-L 0.000 claims description 31
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical group [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 30
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims description 26
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 claims description 26
- 235000012239 silicon dioxide Nutrition 0.000 claims description 26
- 229960001866 silicon dioxide Drugs 0.000 claims description 26
- DBOSBRHMHBENLP-UHFFFAOYSA-N 4-tert-Butylphenyl Salicylate Chemical compound C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC=CC=C1O DBOSBRHMHBENLP-UHFFFAOYSA-N 0.000 claims description 25
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 24
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 21
- 239000012745 toughening agent Substances 0.000 claims description 16
- 239000006096 absorbing agent Substances 0.000 claims description 14
- 229940063655 aluminum stearate Drugs 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 13
- 238000012986 modification Methods 0.000 claims description 13
- 238000009775 high-speed stirring Methods 0.000 claims description 11
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000004641 Diallyl-phthalate Substances 0.000 claims 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 27
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract description 14
- 239000003085 diluting agent Substances 0.000 abstract description 12
- 238000009835 boiling Methods 0.000 abstract description 7
- 238000010276 construction Methods 0.000 abstract description 5
- 238000003860 storage Methods 0.000 abstract description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 238000004062 sedimentation Methods 0.000 abstract 1
- 229940124543 ultraviolet light absorber Drugs 0.000 abstract 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 abstract 1
- ROLAGNYPWIVYTG-UHFFFAOYSA-N 1,2-bis(4-methoxyphenyl)ethanamine;hydrochloride Chemical compound Cl.C1=CC(OC)=CC=C1CC(N)C1=CC=C(OC)C=C1 ROLAGNYPWIVYTG-UHFFFAOYSA-N 0.000 description 45
- 239000000084 colloidal system Substances 0.000 description 40
- 235000019738 Limestone Nutrition 0.000 description 27
- 230000001737 promoting effect Effects 0.000 description 24
- 210000001138 tear Anatomy 0.000 description 23
- 229920002678 cellulose Polymers 0.000 description 20
- 235000010980 cellulose Nutrition 0.000 description 20
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 20
- 239000001913 cellulose Substances 0.000 description 19
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 description 18
- 238000005452 bending Methods 0.000 description 17
- 230000006835 compression Effects 0.000 description 13
- 238000007906 compression Methods 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- 238000007711 solidification Methods 0.000 description 12
- 230000008023 solidification Effects 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 230000006750 UV protection Effects 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 6
- 235000013312 flour Nutrition 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 241000208340 Araliaceae Species 0.000 description 4
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 4
- 235000003140 Panax quinquefolius Nutrition 0.000 description 4
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 235000008434 ginseng Nutrition 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000035882 stress Effects 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- -1 tertiary amine compounds Chemical class 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- CMEWLCATCRTSGF-UHFFFAOYSA-N N,N-dimethyl-4-nitrosoaniline Chemical compound CN(C)C1=CC=C(N=O)C=C1 CMEWLCATCRTSGF-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 150000002989 phenols Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses environment-friendly stone seamless adhesive glue and a preparing method thereof and relates to the technical field of stone adhesive glue. The environment-friendly stone seamless adhesive glue comprises, by weight, 100 parts of pre-promoted unsaturated polyester resin, 3-10 parts of reinforcing agents, 5-15 parts of sedimentation resistant agents, 0.5-1 part of ultraviolet light absorber, and 20-200 parts of filler, wherein the pre-promoted unsaturated polyester resin contains 25-40% of diluent by weight, and the diluent comprises divinyl benzene and phthalic acid diene propyl, or divinyl benzene and m-phthalic acid diene propyl, or divinyl benzene, phthalic acid diene propyl and m-phthalic acid diene propyl. A reactive diluent composition with a high boiling point replaces styrene, icing is avoided, and the storage and construction stability of the stone seamless adhesive glue is improved; meanwhile, the safety performance of glue is improved, and hazards to the human body and the environment are reduced; the falling-off phenomenon is eradicated, and stones can be bonded firmly in a seamless mode.
Description
Technical field
The present invention relates to stone material bonded adhesives technical field, more specifically refer to environment-friendly type stone material seamless binding glue, the invention still further relates to the preparation method of this environment-friendly type stone material seamless binding glue, it is mainly used in the seamless binding between stone material and stone material, also can be used for the seamless binding of pottery, artwork.
Background technology
In recent years, along with the development of architectural decoration, stone material is widely used in the wall ground facing of the large public buildings such as airport, subway station, shopping center, conference and exhibition center, Library, is also more and more applied to the parquets decoration etc. of star hotel and high-grade club.Seamless binding, decorative board one integrated mass develops into decoration main flow gradually.In addition, the requirement that artwork, ultra-thin type ceramic goods are seamless spliced is also more and more higher.But the not special sizing agent carrying out seamless binding for stone material on the market now, general common cloud stone glue or the jointing glue for stone of adopting replaces, but common cloud stone glue and jointing glue for stone carry out seamless binding to stone material there are some drawbacks.
With reference to patent publication No. CN1313556C " reinforced silicon dioxide transparent marble glue ", if this type of common cloud stone glue is for the seamless binding of stone material, there is following defect:
1) intensity after this type of common cloud stone glue solidification does not reach the requirement of strength of stone material seamless binding, and be lotion, it is bad that product infiltrates perviousness, bonding rear easy generation comes off, because the interface of stone material seamless binding is very little, be almost " linearly bonding ", so require very high (compression shear strength must at more than 20Mpa) for the bonding strength after colloid solidification.
2) this type of common cloud stone glue weathering resistance, ultraviolet resistance according to performance bad, solidification after color can As time goes on change, make cemented side seam and stone material produce aberration, affect attractive in appearance.
3) sophistication of this type of common cloud stone glue to colloid is less demanding, use its to stone material carry out bonding after, bonding vestige is comparatively obvious, does not reach seamless effect, can not form associative perception.
With reference to patent publication No. CN101851482B " jointing glue for stone ", patent publication No. CN101805581B " special color stone grout ",, if these jointing adhesives are used in seamless binding between stone material, also there is following defect in patent publication No. CN101851483B " a kind of jointing glue for stone ":
Jointing glue for stone is mainly used in filling up or filling of gap between stone material and stone material, therefore it requires higher for the anti-contracility after colloid solidification and surperficial air-drying property, and less demanding for the bonding strength after colloid solidification, do not reach the requirement of strength (compression shear strength must at more than 20Mpa) of seamless binding.
If insufficient strength, when using jointing glue for stone to carry out seamless binding to stone material, lessly bonding vestige can be made more shallow if applied; If but the time is longer, then easily cause colloid obscission; If coating more bonding vestige is comparatively obvious, the object of seamless binding between stone material and stone material fundamentally can not be reached.
What is more important: the reactive thinner of common cloud stone glue or jointing glue for stone unsaturated polyester resin used is vinylbenzene, vinylbenzene easily volatilizees formation " ice slush " (vinylbenzene volatilization produce self-aggregate), affects the stability in storage of colloid; And the vinylbenzene volatilized, also pollute the environment, infringement constructing operation personnel's is healthy.
Therefore, in the urgent need to researching and developing a kind of bonded adhesives for stone material seamless binding, it had both had high strength, simultaneously not easy to change can making and had formed overall aesthetic feeling between stone material, also can reduce environmental pollution simultaneously, alleviate the injury to workmen, the stability in storage of colloid is good.
Summary of the invention
The first object of the present invention is the weak point overcoming above-mentioned existing background technology, and provides a kind of environment-friendly type stone material seamless binding glue, and this bonded adhesives has increased substantially stone material bonding strength, has stopped obscission; To achieve between stone material and stone material firmly seamless binding; Ensure that the fast in colour property of colloidal condensate under ultraviolet lighting; Ensure that the stable homogeneous of colloidal state; Also can reduce environmental pollution simultaneously, alleviate the injury to workmen.
The second object of the present invention is to provide this environment-friendly type stone material seamless binding glue preparation method.
The first object of the present invention reaches by following technical solution:
Environment-friendly type stone material seamless binding glue, is made up of the filler of 20-200 part, pre-promotion unsaturated polyester resin, the toughener of 3-10 part, the UV light absorber of antisettling agent // 0.5-1 part of 5-15 part and the pigment of 0-7 weight part of 100 parts by weight; Wherein, containing weight percentage in the pre-promotion unsaturated polyester resin of described 100 parts is the thinner of 25-40%, described thinner is Vinylstyrene and Phthalic acid, diallyl ester two component, or Vinylstyrene and diallyl isophthalate two component, or Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate three components.
On the basis of technique scheme, the thinner in described pre-promotion unsaturated polyester resin by weight percentage by the Vinylstyrene of 35-75% and the Phthalic acid, diallyl ester of 25-65% or/and diallyl isophthalate forms.
On the basis of described technical scheme, the thinner in described pre-promotion unsaturated polyester resin by weight percentage by the Vinylstyrene of 40-60% and the Phthalic acid, diallyl ester of 40-60% or/and diallyl isophthalate forms.
On the basis of described technical scheme, described toughener is made up of the lignocellulose of 25-75% and the modification lignocellulose of 25-75% by weight percentage, and the consumption of described toughener is 5-9 weight part.
On the basis of described technical scheme, described modification lignocellulose is selected from Walocel MT 20.000PV, Natvosol and Vltra tears.
On the basis of described technical scheme, the order number of described toughener is 1000-1500 order, and the consumption of described toughener is 7-9 weight part.
On the basis of described technical scheme, described filler is selected from silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder and dry powder, in described filler, silicon-dioxide, water-ground limestone, aluminium hydroxide, dry powder order number are 1000-5000 order, talcum powder order number is 1000-3000 order, described filler whiteness >=90 °.
On the basis of described technical scheme, described filler counts silica 1 0%-70%, water-ground limestone 10%-70% by the weight percent of filler gross weight, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%, total amount are 100%.
On the basis of described technical scheme, described UV light absorber is selected from least two kinds in p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole and HMPA.
On the basis of described technical scheme, described antisettling agent is selected from least two kinds in aluminum stearate, barium stearate, nickel stearate and lithium stearate, and the order number of described antisettling agent is 1000-3000 order.
On the basis of described technical scheme, described environment-friendly type stone material seamless binding glue also comprises the pigment of 0-7 weight part.
The second object of the present invention is reached by following measure:
The preparation method of above-mentioned environment-friendly type stone material seamless binding glue
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring to evenly, churning time is 30-45 minute, namely obtains environment-friendly type stone material seamless binding glue.
Beneficial effect of the present invention:
1. adopt composite high boiling reactive thinner composition substituted phenylethylene, avoid finishing " ice slush " phenomenon, improve the storage of stone material seamless binding glue and the stability of construction, improve the safety performance of colloid simultaneously, decrease the harm that human body and environment are caused.
2. adopt lignocellulose and the wooden cellulosic composition of modification as toughener, and in conjunction with 0.08-0.1MPa negative pressure state and the processing condition being not less than 1500r/min rotating speed, increase substantially the bonding strength of stone material seamless binding glue, stop the generation of obscission.
3. in the filler of stone material seamless binding glue of the present invention, the whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 °, therefore the Color tunable after solidification is assigned to stone material solid colour and after adding UV light absorber, can shine by ultraviolet resistance, keep fast in colour stable, not passing in time and variable color, adds the aesthetic property of product.
4. adopt the filler of high order number, make colloid finer and smoother, stone material rear gap bonding with stone material can be made very little, close to seamless state, reach the object of seamless binding between stone material and stone material.
5. stone material seamless binding glue of the present invention is fluid or semi-fluid condition, good penetrability, can make that bonding interface is less, cemented side seam is thinner, improve the effect of seamless binding between stone material and stone material.
6. the adding of antisettling agent, make colloid not easily layering, can place for a long time, ensure that the stable homogeneous of colloidal state.
7. the present invention does not use hydrogenated castor oil, avoids the generation at oil reservoir interface, further increases bonding strength.
Accompanying drawing explanation
Accompanying drawing 1 for the present invention's pre-promotion unsaturated polyester resin used is when two component thinner (Vinylstyrene and diallyl isophthalate) total amount is 30%, the bending elastic modulus that Vinylstyrene percentage composition is wherein corresponding and impelling strength graphic representation;
Accompanying drawing 2 is the graphic representation that the compression shear strength of environment-friendly type stone material seamless binding adhesive curing thing and bending elastic modulus change with Mierocrystalline cellulose add-on;
Accompanying drawing 3 is the graphic representation that the tensile shear strength of environment-friendly type stone material seamless binding adhesive curing thing and impelling strength change with Mierocrystalline cellulose add-on;
Accompanying drawing 4 is the graphic representation that the compression shear strength of environment-friendly type stone material seamless binding adhesive curing thing changes with antisettling agent add-on.
Embodiment
Below in conjunction with drawings and Examples, the present invention is described in further detail, but they do not form limitation of the invention, only for example.Simultaneously by illustrating that advantage of the present invention will become clearly and easy understand.
A kind of environment-friendly type stone material seamless binding glue, mark meter by weight, comprise the pre-promotion unsaturated polyester resin of 100 parts, the toughener of 3-10 part, the antisettling agent of 5-15 part, the UV light absorber of 0.5-1 part, the filler of 20-200 part, containing weight percentage in the pre-promotion unsaturated polyester resin of described 100 parts is the thinner of 25-40%, described thinner is Vinylstyrene and Phthalic acid, diallyl ester two component, or Vinylstyrene and diallyl isophthalate two component, or Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate three components.Described thinner by weight percentage by the Vinylstyrene of 35-75% and the Phthalic acid, diallyl ester of 25-65% or/and diallyl isophthalate forms, more preferably by the Vinylstyrene of 40-60% and the Phthalic acid, diallyl ester of 40-60% or/and diallyl isophthalate forms.
Wherein, pre-promotion unsaturated polyester resin is also containing promotor and stopper.Unsaturated polyester resin is adjacent benzene-type unsaturated polyester resin, metaphenylene unsaturated polyester resin, terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin, dicyclopentadiene type unsaturated polyester resin, one or more in vinyl ester unsaturated polyester resin.Promotor is transition metal organic salt (manganese naphthenate, naphthenic acid vanadium, cobalt naphthenate, cobalt octoate etc.) and tertiary amine compounds (N, accelerine, N, N-Diethyl Aniline, N, N-dimethyl open-chain crown ether etc.), stopper is phenols or quinones (Resorcinol, pyrocatechol, p-ten.-butylcatechol, '-biphenyl diphenol, para benzoquinone, naphthoquinones, phenanthrenequione etc.).
Toughener is lignocellulose and modification lignocellulose composition, be made up of the lignocellulose of 25-75% and the modification lignocellulose of 25-75% by weight percentage, modification lignocellulose is selected from Walocel MT 20.000PV, Natvosol and Vltra tears.The order number of lignocellulose and modification lignocellulose composition is 1000-1500 order.
Filler counts silica 1 0%-70%, water-ground limestone 10%-70% by the mass percent of filler gross weight, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%, total amount are 100%.Silicon-dioxide, water-ground limestone, aluminium hydroxide, dry powder order number are 1000-5000 order, and talcum powder order number is 1000-3000 order.Described filler whiteness >=90 °.
UV light absorber is selected from least two kinds in p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole and HMPA.
Antisettling agent is selected from least two kinds in aluminum stearate, barium stearate, nickel stearate and lithium stearate, and the order number of described antisettling agent is 1000-3000 order.
A kind of environment-friendly type stone material seamless binding glue also comprises the pigment of 0-7 weight part.
Based on a preparation method for above-mentioned stone material seamless binding glue, comprise the following steps:
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring to evenly, churning time is 30-45 minute, namely obtains environment-friendly type stone material seamless binding glue.
Usually vinylbenzene is added as thinner in common cloud stone glue or jointing glue for stone pre-promotion unsaturated polyester resin used, vinylbenzene volatile generation self-aggregate in the process stored or transport on the one hand, formed " ice slush ", and be attached to cover place, cover is not easily opened, and impact operation uses, and after opening by force, cover is out of shape, and cannot restore; Simultaneously vinylbenzene also condensation can fall after rise and bring out top layer colloidal gel in colloid surface, shortens the colloid shelf lives.The on the other hand volatile and contaminate environment of vinylbenzene in construction process, and staff's health of construction is damaged.The present invention promotes that the thinner added in unsaturated polyester resin is selected from Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate in advance.
The boiling point of thinner selected by the present invention is all high than vinylbenzene boiling point, as shown in table 1 below.
Table 1 thinner boiling point contrast table
| Thinner kind | Vinylbenzene | Vinylstyrene | Phthalic acid, diallyl ester | Diallyl isophthalate |
| Boiling point (DEG C) | 145 | 195 | 305 | 181.5 |
With high boiling reactive thinner composition substituted phenylethylene, avoid finishing " ice slush " phenomenon, improve the storage of stone material seamless sticky gum deposit and the stability of construction, improve the safety performance of colloid simultaneously, decrease the harm that human body and environment are caused.
Find after deliberation: Vinylstyrene is owing to phenyl ring there being two vinyl substituted groups, and activity is higher, have higher cross-linking density with the unsaturated polyester resin of its solidification, its hardness and thermotolerance are all good than the resin of Styrene solidification; But its product fragility is larger.
And the activity of Phthalic acid, diallyl ester and diallyl isophthalate is lower, good stability, the electrical property of the goods obtained as the cross-linking monomer of unsaturated polyester resin with their substituted phenylethylenes and good heat resistance, but its product flexibility is larger.
Present invention employs Vinylstyrene and Phthalic acid, diallyl ester or/and diallyl isophthalate composition is as thinner, find that they make up each other, both shortcoming had each other been overcome, both advantages are had both again, make product of the present invention have good hardness, thermotolerance, rigidity and toughness, substantially increase the over-all properties of product.Add the improvement of the mechanical property of product after diluent composition of the present invention, by promoting that the impelling strength of unsaturated polyester resin cured article and bending elastic modulus characterize in advance, with reference to JC/T989-2006 method, its result is as shown in following table 2, table 3 and accompanying drawing 1 (for amount of diluent for 30%):
Table 2 adds impelling strength and the bending elastic modulus of the pre-promotion unsaturated polyester resin cured article of different single-component thinner
During table 3 the present invention pre-promotion unsaturated polyester resin thinner (Vinylstyrene and diallyl isophthalate) 30% used, the bending elastic modulus that Vinylstyrene percentage composition is wherein corresponding and impelling strength
| Vinylstyrene percentage composition (%) | Impelling strength (KJ/m 2) | Bending elastic modulus (MPa) |
| 0 | 2.05 | 1810.4 |
| 10 | 2.42 | 2846.5 |
| 20 | 2.79 | 3882.6 |
| 30 | 3.19 | 4920.2 |
| 40 | 3.58 | 5952.8 |
| 50 | 4.04 | 5840.7 |
| 60 | 4.25 | 5387.6 |
| 70 | 3.74 | 5003.5 |
| 80 | 2.98 | 4604.4 |
| 90 | 2.30 | 4186.3 |
| 100 | 1.64 | 3837.2 |
As shown in Figure 1: curve A be the present invention's pre-promotion unsaturated polyester resin used when two component thinner (Vinylstyrene and diallyl isophthalate) total amount is 30%, the bending elastic modulus that Vinylstyrene percentage composition is wherein corresponding and impelling strength figure; Straight line B be the present invention's pre-promotion unsaturated polyester resin used when thinner is vinylbenzene and content is 30%, corresponding bending elastic modulus and impelling strength figure.
Consult Fig. 1 known: be in the mixed diluent of 30% at total content, along with the continuous increase of divinyl benzene content, the bending elastic modulus of the present invention's resin used and impelling strength have lifting in various degree, after reaching maximum value, decline gradually again.And when divinyl benzene content is at 35%-41%, the bending elastic modulus containing mixed diluent resin comparatively contains the height of vinylbenzene thinner resin, but impelling strength is comparatively low containing styrene resin; When divinyl benzene content is at 41%-60%, containing the bending elastic modulus of mixed diluent resin and impelling strength all comparatively containing the height of vinylbenzene thinner resin; When divinyl benzene content is at 60%-71%, the bending elastic modulus containing mixed diluent resin comparatively contains the low of vinylbenzene thinner resin, but impelling strength is comparatively containing the height of vinylbenzene thinner resin.It can thus be appreciated that, in mixed diluent, Vinylstyrene imparts the present invention's resin rigidity used, and it is flexible that isophthalic diformazan diallyl imparts the present invention's resin used, only have when the rigidity of resin and flexibility moderate time, its bending elastic modulus and impelling strength just can reach optimum value.
When diluent composition is Vinylstyrene and Phthalic acid, diallyl ester two component, or when Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate three components, the bending elastic modulus that Vinylstyrene percentage composition is corresponding and impelling strength curve are also with above-mentioned close.
The activity of thinner draws by promoting that the gel time of unsaturated polyester resin is tested in advance, with reference to GB/T 7193-2008 " unsaturated polyester resin test method ", by gel time tester (model: GELTIME METER, producer: Cole Instrument Ltd. of BeiJing ZhongKe) to the pre-promotion unsaturated polyester resin gel time test adding different thinner, its comparing result is as following table 4:
Table 4: add the gel time of the pre-promotion unsaturated polyester resin of different thinner, set time and peak temperature
| Numbering | Gel time | Set time | Peak temperature (DEG C) |
| Ⅰ | 5′02″ | 6′10″ | 142 |
| Ⅱ | 2′45″ | 4′06″ | 154 |
| Ⅲ | 6′56″ | 8′12″ | 135 |
| Ⅳ | 6′43″ | 7′58″ | 136 |
| Ⅴ | 4′57″ | 5′56″ | 144 |
| Ⅵ | 5′03″ | 6′09″ | 142 |
| Ⅶ | 4′58″ | 6′02″ | 144 |
| Ⅷ | 5′18″ | 6′35″ | 143 |
| Ⅸ | 5′25″ | 6′44″ | 143 |
| Ⅹ | 5′21″ | 6′39″ | 143 |
| Ⅺ | 4′28″ | 5′43″ | 146 |
| Ⅻ | 3′52″ | 5′08″ | 148 |
Remarks: I-vinylbenzene
II-Vinylstyrene
III-Phthalic acid, diallyl ester
IV-diallyl isophthalate
V-Vinylstyrene and diallyl isophthalate weight ratio are 1: 1
VI-Vinylstyrene and Phthalic acid, diallyl ester weight ratio are 1: 1
VII-Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate weight ratio are 2:1:1
VIII-Vinylstyrene and diallyl isophthalate weight ratio are 2: 3
Ⅸ-Vinylstyrene and Phthalic acid, diallyl ester weight ratio are 2: 3
Ⅹ-Vinylstyrene, Phthalic acid, diallyl ester and diallyl isophthalate weight ratio are 2:2:1
Ⅺ-Vinylstyrene and diallyl isophthalate weight ratio are 3: 2
Ⅻ-Vinylstyrene and Phthalic acid, diallyl ester weight ratio are 3: 1
As shown in table 4, shorter than vinylbenzene as the pre-promotion unsaturated polyester resin gel time of thinner with Vinylstyrene, peak temperature comparatively vinylbenzene is high, and reaction is fierce; And with Phthalic acid, diallyl ester and diallyl isophthalate longer than vinylbenzene as the pre-promotion unsaturated polyester resin gel time of thinner, peak temperature comparatively vinylbenzene is low, reaction temperature and; And adopt diluent composition post Newton of the present invention and peak temperature more moderate, close with vinylbenzene.
Find after deliberation: adding cellulose substances obviously can increase gel strength, its enhanced mechanism is as follows: Mierocrystalline cellulose has very high mechanical moduli and intensity usually, when taking unsaturated polyester resin as matrix, when strengthening with Mierocrystalline cellulose, matrix can produce plasticity under stress, load is delivered on fiber, bears load by fiber.Matrix makes fibres bond fix, and protects fiber, makes it to be in steady state, material is thus formed the matrix material of a kind of high strength and high modulus.
By weight, get pre-promotion unsaturated polyester resin 100 weight part (wherein containing Vinylstyrene 15%, Phthalic acid, diallyl ester 7.5%, diallyl isophthalate 7.5%, totally 30% thinner), 3000 order silica flours 8 parts, 1250 4 parts, order aluminium hydroxides, 1000 order water-ground limestones 4 parts, 1500 order dry powders 4 parts, 2000 order aluminum stearates 2 parts, 1500 order nickel stearates 3 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, what add Different Weight part again is 1000 object tougheners, under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid.Get this colloid of 100 weight parts, the solidifying agent being blended into 3 weight parts is cured.With reference to JC/T989-2006 method, Mechanics Performance Testing is carried out to environment-friendly type stone material seamless binding adhesive curing thing, the results are shown in table 5,6,7,8, table 5, table 6, table 7, table 8 for after adding different components Mierocrystalline cellulose of the present invention respectively, the value of the compression shear strength of environment-friendly type stone material seamless binding adhesive curing thing, tensile shear strength, bending elastic modulus, impelling strength.Accompanying drawing 2 and accompanying drawing 3 be respectively table 5,6,7, the change curve of 8 correspondences, wherein:
It is lignocellulose that A representative adds Mierocrystalline cellulose.
B representative adds Natvosol and lignocellulose, and weight ratio is 1:1.
C representative adds lignocellulose, Natvosol, Vltra tears, and weight ratio is 1:1:1.
D representative adds lignocellulose, Walocel MT 20.000PV, Natvosol, Vltra tears, and weight ratio is 1:1:1:1.
Table 5 adds the compression shear strength value (MPa) after different components Mierocrystalline cellulose
Table 6 adds the tensile shear strength value (MPa) after different components Mierocrystalline cellulose
Table 7 adds the bending elastic modulus (MPa) after different components Mierocrystalline cellulose
Table 8 adds the impelling strength (KJ/m after different components Mierocrystalline cellulose
2)
Shown in accompanying drawing 2 and accompanying drawing 3, add Mierocrystalline cellulose as after toughener, compression shear strength and the tensile shear strength of environment-friendly type stone material seamless binding adhesive curing thing significantly improve, and increase along with the increase of Mierocrystalline cellulose add-on, after cellulose amount is increased to 9 weight parts, intensity level starts to decline.
Shown in accompanying drawing 2 and accompanying drawing 3, add Mierocrystalline cellulose as after toughener, the bending elastic modulus of environment-friendly type stone material seamless binding adhesive curing thing significantly improves with impact is tough, and increases along with the increase of Mierocrystalline cellulose add-on, after add-on is more than 10 weight parts, be no longer significantly increased.
In the present embodiment, by above-mentioned formula, add different types of Mierocrystalline cellulose, wherein Mierocrystalline cellulose add-on is 9 weight parts, and order number is 1000 orders, obtained environment-friendly type stone material seamless binding glue.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.The mechanical property of test environment-friendly type stone material seamless binding adhesive curing thing is as shown in table 9, wherein:
A: Walocel MT 20.000PV.
B: Natvosol.
C: Vltra tears.
D: lignocellulose.
E: Natvosol and lignocellulose weight ratio are 1:1.
F: Walocel MT 20.000PV and lignocellulose weight ratio are 1:1.
G: Vltra tears and lignocellulose weight ratio are 1:1.
H: Walocel MT 20.000PV, Natvosol and lignocellulose weight ratio are 1:1:1.
I: Walocel MT 20.000PV, Vltra tears and lignocellulose weight ratio are 1:1:1.
J: Natvosol, Vltra tears and lignocellulose weight ratio are 1:1:1.
K: Walocel MT 20.000PV, Natvosol, Vltra tears and lignocellulose weight ratio are 1:1:1:1.
Table 9 adds the colloidal condensate mechanical property after different components Mierocrystalline cellulose
Ginseng is shown in Table 9, Walocel MT 20.000PV, Natvosol, Vltra tears all has good reinforced effects, the reinforced effects of lignocellulose is relatively poor, and Walocel MT 20.000PV, Natvosol, Vltra tears are formed by lignocellulose modification, better than lignocellulose with the consistency of unsaturated polyester resin, but because the cost of lignocellulose is lower, therefore present invention employs lignocellulose and carry out interworking use with other Mierocrystalline celluloses respectively.
Find after deliberation: in environment-friendly type stone material seamless binding glue of the present invention, add UV light absorber can make colloid ultraviolet resistance photograph, color and luster keeps stable.Hydroxyl-OH and carbonyl C=O or diazo N=N is had in UV absorber molecules formula; Sauerstoffatom in carbonyl and the nitrogen-atoms in diazo all also exist lone-pair electron; it is the group that electronegativity is stronger; easily intramolecular hydrogen bond is formed with electropositive hydrogen atom aobvious in hydroxyl; form chelate ring; it is unstable after they absorb the energy of UV-light; generation molecular heat vibrates; hydrogen bond destroys; chelate ring is opened; will release energy, and change harmful UV-light into harmless heat energy, thus protect material.Therefore a small amount of UV light absorber can protect environment-friendly type stone material seamless binding adhesive curing thing color stability of the present invention enduringly.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts (wherein containing Vinylstyrene 15%, diallyl isophthalate 15%, totally 30% thinner), 1500 object lignocelluloses 2 parts, 1250 object Natvosols 2 parts, 1500 object barium stearates 5 parts, 1000 object nickel stearates 6 parts, 2500 order silica flours 20 parts, 1000 30 parts, order aluminium hydroxides, 5000 object water-ground limestones 25 parts, 1250 object talcum powder 10 parts, 3000 object dry powders 20 parts, add the UV light absorber of different ratios again, under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid, detect according to GB/T14522-2008 method, by environment-friendly type stone material seamless binding adhesive curing thing in ultraviolet light and aging proofing box (model: LRHS-UVN, producer: Shenyang ultraviolet ageing test box factory) in illumination after 70 hours under UVA340nm type fluorescent ultraviolet lamp, with color difference meter, (brand: 3nh tri-grace is speeded, model: NR110, producer: Tianyouli Standard Light-Source Co., Ltd., Shenzhen) survey its value of chromatism result as table 10, wherein:
A:2-hydroxyl-4-methoxy benzophenone.
B:2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole.
C: HMPA.
D: p-t-butylphenyl salicylate.
E:2-hydroxyl-4-methoxy benzophenone, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole weight ratio are 1:1.
F:2-hydroxyl-4-methoxy benzophenone and HMPA weight ratio are 1:2.
G: p-t-butylphenyl salicylate, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole and HMPA weight ratio are 1:2:1.
H: p-t-butylphenyl salicylate, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, ESCALOL 567 and HMPA weight ratio are 1:1:2:1.
Table 10 color difference meter institute colour examining difference
Ginseng is shown in Table 10, and makes colloid ultra-violet resistance of the present invention can have remarkable improvement after UV light absorber adds.UV light absorber of the present invention is different classes of material, find in experiment, adopt the ultra-violet resistance after two or more interworking of above-mentioned ultraviolet can significantly better than one-component ultra-violet resistance energy, value of chromatism Δ E is all less than 2.0, and therefore the present invention adopts two or more ratio interworking to use.
Find after deliberation: environment-friendly type stone material seamless binding glue of the present invention is fluid or semi-fluid condition, adds stearates as antisettling agent, colloid can be made not stratified, can place for a long time, ensure that the quality stability of colloid.Antisettling agent has very strong swelling gelatinisation ability, high polymer long chain in system can be made swelling and be mutually wound around after adding, thus changes the rheological property of system, prevents filling settlement from occurring layering.
After adding a certain amount of stearates in environment-friendly type stone material seamless binding glue of the present invention, can form oil reservoir interface when bonding stone material, affect adhesive effect, available compression shearing resistance characterizes.Count by weight, get pre-promotion unsaturated polyester resin 100 parts (wherein containing Vinylstyrene 21%, Phthalic acid, diallyl ester 14%, totally 35% thinner), 1500 object lignocelluloses 4.5 parts, 1000 object Vltra tearss 4.5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.5 part, 2000 order silica flours 15 parts, 3000 5 parts, order aluminium hydroxides, 1500 order water-ground limestones 20 parts, 3000 order dry powders 5 parts, the antisettling agent adding different amount (tests aluminum stearate and nickel stearate two component of to be weight ratio be 1:1 used, order number is 1250 orders), under 0.08Mpa negative pressure, 1500r/min high-speed stirring obtains colloid.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.Test the compression shear strength of environment-friendly type stone material seamless binding adhesive curing thing with reference to JC/T989-2006 method, its changing value lists in table 11, and accompanying drawing 4 is its corresponding change curve.
Table 11 adds compression shear strength value after aluminum stearate and nickel stearate two component
Its compression shear strength variation tendency and above-mentioned close after other stearic acid salt of the present invention adds.
Shown in accompanying drawing 4, after adding stearate in colloid, its compression shear strength can decline along with the increase of the add-on of stearate, when add-on is less than 15 weight part, compression shear strength fall is little, can obviously decline after more than 15 weight parts, therefore in environment-friendly type stone material seamless binding glue of the present invention the add-on of antisettling agent no more than 15 weight parts.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts (wherein containing Vinylstyrene 10%, Phthalic acid, diallyl ester 5%, diallyl isophthalate 10%, totally 25% thinner), 1500 object lignocelluloses 4.5 parts, 1000 object Vltra tearss 4.5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.5 part, 2000 order silica flours 15 parts, 3000 5 parts, order aluminium hydroxides, 1500 object water-ground limestones 20 parts, 3000 object dry powders 5 parts, add the antisettling agent of different components again, add-on is 6 parts.Obtained colloid is left standstill, observation colloid phase-splitting situation, record phase-splitting time.Table 8 leaves standstill the time occurring phase-splitting after adding different components stearate, adds stearate order number and all selects 1250 orders.Wherein
A: aluminum stearate.
B: barium stearate.
C: nickel stearate.
D: lithium stearate.
E: aluminum stearate and barium stearate weight ratio are 1:1.
F: aluminum stearate and nickel stearate weight ratio are 2:3.
G: aluminum stearate and lithium stearate weight ratio are 3:2.
H: barium stearate and nickel stearate weight ratio are 1:2.
I: barium stearate and lithium stearate weight ratio are 2:1.
J: nickel stearate and lithium stearate weight ratio are 1:1.
K: aluminum stearate, barium stearate and nickel stearate weight ratio are 1:1:1.
L: aluminum stearate, barium stearate and lithium stearate weight ratio are 1:2:1.
M: barium stearate, nickel stearate and lithium stearate weight ratio are 1:1:2.
N: aluminum stearate, barium stearate, nickel stearate and lithium stearate weight ratio are 1:1:1:1.
Other ratio also can produce effect same.
Table 12 adds the standing phase-splitting time after different components stearate
Note: the colloid of environment-friendly type stone material seamless binding glue of the present invention leaves standstill the phase-splitting time and must ensure more than 12 months, otherwise does not reach requirement of dispatching from the factory.
Ginseng is shown in Table 12, and makes colloid resistance to settling of the present invention have remarkable improvement after antisettling agent adds.Draw in experiment and adopt the separation time of two or more component colloid of above-mentioned antisettling agent to be obviously longer than the separation time adding single component colloid, therefore antisettling agent of the present invention have employed two or more ratio interworking use.
Filler of the present invention is 1000-5000 object silicon-dioxide, account for the 10%-70% of filler gross weight, 1000-5000 object water-ground limestone, account for the 10%-70% of filler gross weight, 1000-5000 object aluminium hydroxide, account for the 10%-70% of filler gross weight, 1000-3000 object talcum powder, account for the 0%-10% of filler gross weight, 1000-5000 object dry powder, account for the 10%-70% of filler gross weight, the filler of high order number can make colloid very fine and smooth, and above-mentioned filler all can be good at merging with stone material; And the whiteness of silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder, dry powder is all not less than 90 ° in filler of the present invention, colloid background color more shallow being conducive to can be made to mix colours.
The manufacturing condition of stone material seamless binding glue of the present invention is high-speed stirring under the negative pressure state of 0.08-0.1Mpa, and rotating speed is not less than 1500r/min.Stir under negative pressure state and can not make to produce bubble in colloid, if the bubble containing small wall thickness, colloid surface can be made coarse fineless and smooth, and after colloid solidification, inside there is cavity, produces internal stress and affects the mechanical properties.Meanwhile, adopt this technique that additive is fully homogenized, thus eliminate the interfacial stress between solid solid interface, solid-liquid interface, further increase mechanical property.
Count by weight, get pre-promotion unsaturated polyester resin 100 parts (wherein containing Vinylstyrene 14%, Phthalic acid, diallyl ester 10%, diallyl isophthalate 16%, totally 40% thinner), 5000 object silica flours 20 parts, 1000 10 parts, object aluminium hydroxides, 4000 object water-ground limestones 30 parts, 3000 object talcum powder 5 parts, 4000 object dry powders 10 parts, 1500 object aluminum stearates 5 parts, 1250 object nickel stearates 5 parts, 1250 object Natvosols 3 parts, 1250 object lignocelluloses 3 parts, under negative pressure 0.08Mpa, under 1500r/min high-speed stirring and normal pressure, 400r/min stirs obtained colloid respectively.Get this colloid of 100 weight parts, be blended into 3 weight part solidifying agent solidifications.With reference to JC/T989-2006 method, environment-friendly type stone material seamless binding adhesive curing thing mechanical property is tested.
Table 13 environment-friendly type stone material seamless binding adhesive curing thing mechanical property
Ginseng is shown in Table 13, the mechanical property that the mechanical property that high-speed stirring obtains colloid under negative pressure state obtains colloid compared with atmospheric agitation promotes to some extent, therefore processing condition of the present invention are high-speed stirring under the negative pressure state of 0.08-0.1Mpa, and rotating speed is not less than 1500r/min.
Cloud stone glue technical requirements (People's Republic of China's building material industry standard JC/T989-2006).
Below by 22 embodiments, the present invention is specifically described:
Embodiment 1 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 10.5% in advance, diallyl isophthalate 19.5%, totally 30% thinner), 1250 object lignocelluloses 1 part, 1000 object Walocel MT 20.000PVs 3 parts, 1500 object aluminum stearates 0.5 part, 1000 object barium stearates 4.5 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, 2000 object silicon-dioxide 20 parts, 4000 object water-ground limestones 10 parts, 5000 10 parts, object aluminium hydroxides, 2500 order dry powders 15 parts, 0.02 part, ultramarine, titanium dioxide 5 parts composition.
Embodiment 2 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 14% in advance, Phthalic acid, diallyl ester 6%, diallyl isophthalate 20%, totally 40% thinner), 1000 object lignocelluloses 1 part, 1500 object Natvosols 2 parts, 1000 object aluminum stearates 4 parts, 3000 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.3 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 1250 object silicon-dioxide 20 parts, 1500 object water-ground limestones 30 parts, 1000 50 parts, object aluminium hydroxides, 1250 order talcum powder 5 parts, 5000 order dry powders 80 parts, chromoxide green 1 part composition.
Embodiment 3 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 14% in advance, Phthalic acid, diallyl ester 10%, diallyl isophthalate 16%, totally 40% thinner), 1500 object lignocelluloses 4.5 parts, 1250 object Vltra tearss 1.5 parts, 1000 object aluminum stearates 4 parts, 1500 object barium stearates 2 parts, 3000 object lithium stearates 3 parts, 2000 order nickel stearates 5 parts, p-t-butylphenyl salicylate 0.3 part, ESCALOL 567 0.4 part, 3000 object silicon-dioxide 20 parts, 3500 object water-ground limestones 20 parts, 4000 140 parts, object aluminium hydroxides, 2000 order dry powder 20 parts compositions.
Embodiment 4 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 12% in advance, Phthalic acid, diallyl ester 9%, diallyl isophthalate 9%, totally 30% thinner), 1250 object lignocelluloses 4 parts, 1000 object Walocel MT 20.000PVs 3 parts, 1500 object Natvosols 2 parts, 3000 object barium stearates 5 parts, 1000 object lithium stearates 7 parts, p-t-butylphenyl salicylate 0.2 part, HMPA 0.4 part, 2500 object silica 1s 5 parts, 5000 object water-ground limestones 10 parts, 1500 10 parts, object aluminium hydroxides, 3000 order talcum powder 5 parts, 2500 order dry powders 40 parts, everbright fast red 0.01 part, medium chrome yellow medium yellow 0.5 part composition.
Embodiment 5 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 14% in advance, Phthalic acid, diallyl ester 10%, diallyl isophthalate 11%, totally 35% thinner), 1000 object lignocelluloses 1.5 parts, 1250 object Natvosols 1 part, 1500 object Vltra tearss 2.5 parts, 2000 object nickel stearates 4 parts, 3000 object lithium stearates 5 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 2500 object silicon-dioxide 80 parts, 2000 object water-ground limestones 15 parts, 3000 15 parts, object aluminium hydroxides, 2000 order talcum powder 2 parts, 1500 order dry powders 20 parts, Lithol Red 0.1 part composition.
Embodiment 6 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 13.6% in advance, Phthalic acid, diallyl ester 6.5%, diallyl isophthalate 10%, totally 30% thinner), 1500 object lignocelluloses 2 parts, 1000 order Walocel MT 20.000PVs 3 parts, 1000 object Vltra tearss 3 parts, 2000 object aluminum stearates 3 parts, 1000 object nickel stearates 2 parts, ESCALOL 567 0.45 part, HMPA 0.05 part, 3000 object silicon-dioxide 5 parts, 4500 object water-ground limestones 15 parts, 5000 10 parts, object aluminium hydroxides, 5000 order dry powders 15 parts, titanium dioxide 7 parts composition.
Embodiment 7 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 14% in advance, Phthalic acid, diallyl ester 6%, diallyl isophthalate 15%, totally 35% thinner), 1500 object lignocelluloses 4 parts, 1500 order Walocel MT 20.000PVs 1 part, 1000 order Natvosols 1 part, 1250 object Vltra tearss 3 parts, 1500 object aluminum stearates 3 parts, 3000 object barium stearates 2 parts, 1000 object nickel stearates 1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.7 part, 4000 object silicon-dioxide 20 parts, 2500 object water-ground limestones 30 parts, 3000 40 parts, object aluminium hydroxides, 1000 order talcum powder 5 parts, 2000 order dry powders 20 parts, red iron oxide 0.8 part composition.
Embodiment 8 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 18% in advance, Phthalic acid, diallyl ester 11%, diallyl isophthalate 11%, totally 40% thinner), 1000 object lignocelluloses 4 parts, 1500 object Natvosols 2 parts, 2000 object aluminum stearates 3 parts, 3000 object lithium stearates 1 part, 3000 object nickel stearates 3 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.8 part, HMPA 0.1 part, 2500 object silicon-dioxide 20 parts, 2000 object water-ground limestones 140 parts, 3000 20 parts, object aluminium hydroxides, 1500 order dry powders 20 parts, chromoxide green 2 parts composition.
Embodiment 9 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 17.5% in advance, diallyl isophthalate 17.5%, totally 35% thinner), 1000 object lignocelluloses 3 parts, 1500 order Walocel MT 20.000PVs 3 parts, 1000 order Natvosols 1 part, 1500 object aluminum stearates 4 parts, 2500 object barium stearates 3 parts, 3000 object lithium stearates 3 parts, p-t-butylphenyl salicylate 0.4 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.1 part, 5000 object silicon-dioxide 60 parts, 1500 object water-ground limestones 15 parts, 1000 20 parts, object aluminium hydroxides, 1250 order talcum powder 10 parts, 2000 order dry powders 20 parts, carbon black 1 part composition.
Embodiment 10 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 16.5% in advance, Phthalic acid, diallyl ester 13.5%, totally 30% thinner), 1500 object lignocelluloses 4 parts, 1250 object Walocel MT 20.000PVs 4 parts, 2500 object nickel stearates 5 parts, 1250 object barium stearates 4 parts, 3000 order lithium stearates 6 parts, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, HMPA 0.1 part, 1500 object silica 1s 5 parts, 1000 object water-ground limestones 15 parts, 2500 50 parts, object aluminium hydroxides, 1250 order dry powders 10 parts, iron oxide yellow 3 parts composition.
Embodiment 11 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 12.5% in advance, Phthalic acid, diallyl ester 12.5%, totally 25% thinner), 1000 object lignocelluloses 4 parts, 1500 order Walocel MT 20.000PVs 3 parts, 1000 order Vltra tearss 3 parts, 2000 object barium stearates 3 parts, 2000 object nickel stearates 4 parts, p-t-butylphenyl salicylate 0.4 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, HMPA 0.1 part, 2000 object silicon-dioxide 2 parts, 3500 object water-ground limestones 8 parts, 4000 3 parts, object aluminium hydroxides, 1250 order talcum powder 2 parts, 2000 order dry powders 5 parts, chromoxide green 0.5 part, fluorescent yellow 2.5 parts, phthalocyanine green 1 part composition.
Embodiment 12 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 22% in advance, diallyl isophthalate 18%, totally 40% thinner), 1000 object lignocelluloses 5 parts, 1250 object Walocel MT 20.000PVs 3.5 parts, 1000 object aluminum stearates 3 parts, 1500 object barium stearates 3 parts, 3000 object lithium stearates 3 parts, 2000 order nickel stearates 5 parts, p-t-butylphenyl salicylate 0.2 part, ESCALOL 567 0.3 part, 5000 object silica 1s 40 parts, 2500 object water-ground limestones 20 parts, 1500 20 parts, object aluminium hydroxides, 1500 order dry powders 20 parts, red iron oxide 1 part, everbright fast red 2 parts composition.
Embodiment 13 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 24% in advance, Phthalic acid, diallyl ester 10%, diallyl isophthalate 6%, totally 40% thinner), 1000 object lignocelluloses 2.5 parts, 1500 object Vltra tearss 4 parts, 1250 object nickel stearates 7 parts, 3000 object lithium stearates 6 parts, p-t-butylphenyl salicylate 0.25 part, ESCALOL 567 0.1 part, HMPA 0.5 part, 4000 object silicon-dioxide 20 parts, 1500 object water-ground limestones 20 parts, 3000 20 parts, object aluminium hydroxides, 4000 order dry powders 140 parts, phthalocyanine blue 0.5 part, 0.5 part, ultramarine, titanium dioxide 6 parts composition.
Embodiment 14 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 15% in advance, Phthalic acid, diallyl ester 6%, diallyl isophthalate 4%, totally 25% thinner), 1250 object lignocelluloses 2.5 parts, 1000 object Natvosols 1 part, 1500 object Vltra tearss 4 parts, 3000 object barium stearates 2 parts, 1500 object nickel stearates 5 parts, 1500 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.15 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, 5000 object silicon-dioxide 5 parts, 2500 object water-ground limestones 15 parts, 5000 5 parts, object aluminium hydroxides, 3000 order talcum powder 2 parts, 1500 order dry powder 7 parts compositions.
Embodiment 15 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 19.5% in advance, diallyl isophthalate 10.5%, totally 30% thinner), 1000 object lignocelluloses 2 parts, 1500 order Walocel MT 20.000PVs 3.5 parts, 1000 order Natvosols 2 parts, 2000 object aluminum stearates 1 part, 1500 object barium stearates 7 parts, 1000 object nickel stearates 1 part, 1500 object lithium stearates 1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.15 part, HMPA 0.2 part, 1500 object silicon-dioxide 40 parts, 4000 object water-ground limestones 8 parts, 3000 10 parts, object aluminium hydroxides, 1000 order dry powders 10 parts, iron oxide yellow 0.6 part, red iron oxide 2 parts, medium chrome yellow medium yellow 1 part composition.
Embodiment 16 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 26% in advance, Phthalic acid, diallyl ester 7%, diallyl isophthalate 7%, totally 40% thinner), 1000 object lignocelluloses 4.5 parts, 1250 object Natvosols 2.5 parts, 1500 object aluminum stearates 2 parts, 2000 object lithium stearates 2 parts, 1500 object nickel stearates 4 parts, p-t-butylphenyl salicylate 0.35 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.2 part, HMPA 0.1 part, 1500 object silicon-dioxide 20 parts, 5000 object water-ground limestones 120 parts, 5000 20 parts, object aluminium hydroxides, 3000 order talcum powder 20 parts, 1500 order dry powders 20 parts, chromoxide green 1 part, 0.1 part, ultramarine composition.
Embodiment 17 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 21% in advance, Phthalic acid, diallyl ester 10%, diallyl isophthalate 4%, totally 35% thinner), 1500 object lignocelluloses 3.5 parts, 1000 object Walocel MT 20.000PVs 1 part, 1500 object Natvosols 1 part, 1500 object aluminum stearates 3 parts, 2500 object barium stearates 4 parts, 3000 object lithium stearates 6 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.2 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.5 part, 5000 object silicon-dioxide 35 parts, 4000 object water-ground limestones 15 parts, 1250 60 parts, object aluminium hydroxides, 2000 order dry powders 40 parts, Lithol Red 0.05 part, fluorescent yellow 0.5 part composition.
Embodiment 18 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 17.5% in advance, Phthalic acid, diallyl ester 7.5%, totally 25% thinner), 1250 object lignocelluloses 5 parts, 1250 object Walocel MT 20.000PVs 4 parts, 1000 object aluminum stearates 4 parts, 2000 object nickel stearates 2.5 parts, ESCALOL 567 0.4 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.3 part, 1500 object silica 1s 4 parts, 3500 object water-ground limestones 2 parts, 5000 2 parts, object aluminium hydroxides, 2500 order dry powders 2 parts, phthalocyanine blue 1 part, fluorescent yellow 5 parts composition.
Embodiment 19 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 28% in advance, Phthalic acid, diallyl ester 4%, diallyl isophthalate 8%, totally 40% thinner), 1000 object lignocelluloses 2 parts, 1500 order Walocel MT 20.000PVs 4 parts, 1000 object Vltra tearss 2 parts, 2500 object nickel stearates 4 parts, 1500 object barium stearates 4 parts, 2500 order lithium stearates 3 parts, p-t-butylphenyl salicylate 0.2 part, HMPA 0.4 part, 2000 object silicon-dioxide 50 parts, 4000 object water-ground limestones 100 parts, 1500 20 parts, object aluminium hydroxides, 1500 order talcum powder 5 parts, 3000 order dry powder 25 parts compositions.
Embodiment 20 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 27% in advance, Phthalic acid, diallyl ester 3%, diallyl isophthalate 6%, totally 36% thinner), 1500 object lignocelluloses 2 parts, 1250 order Walocel MT 20.000PVs 1 part, 1250 order Natvosols 1 part, 1000 object Vltra tearss 1 part, 1000 object aluminum stearates 4 parts, 3000 object lithium stearates 2 parts, p-t-butylphenyl salicylate 0.4 part, ESCALOL 567 0.4 part, 2000 object silicon-dioxide 20 parts, 1000 object water-ground limestones 20 parts, 3000 15 parts, object aluminium hydroxides, 2000 order dry powders 85 parts, fluorescent yellow 0.8 part, titanium dioxide 4 parts composition.
Embodiment 21 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 27% in advance, Phthalic acid, diallyl ester 4%, diallyl isophthalate 5%, totally 36% thinner), 1500 object lignocelluloses 2 parts, 1250 order Walocel MT 20.000PVs 2 parts, 1000 order Vltra tearss 1 part, 1500 object aluminum stearates 5 parts, 3000 object barium stearates 7 parts, p-t-butylphenyl salicylate 0.1 part, ESCALOL 567 0.1 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.7 part, HMPA 0.1 part, 1000 object silica 1s 3 parts, 2500 object water-ground limestones 10 parts, 1000 60 parts, object aluminium hydroxides, 1250 order talcum powder 7 parts, 5000 order dry powders 10 parts, carbon black 0.01 part, red iron oxide 4 parts, medium chrome yellow medium yellow 1 part composition.
Embodiment 22 (counting by weight)
Stone material seamless binding glue is counted by weight, by promoting that unsaturated polyester resin 100 parts is (wherein containing Vinylstyrene 27% in advance, Phthalic acid, diallyl ester 6%, diallyl isophthalate 3%, totally 36% thinner), 1000 object lignocelluloses 5.5 parts, 1500 object Natvosols 4.5 parts, 2000 object aluminum stearates 2 parts, 2500 object nickel stearates 3 parts, p-t-butylphenyl salicylate 0.3 part, 2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole 0.4 part, HMPA 0.2 part, 4000 object silicon-dioxide 40 parts, 4000 object water-ground limestones 30 parts, 3000 40 parts, object aluminium hydroxides, 2500 order talcum powder 15 parts, 2000 order dry powders 40 parts, 0.05 part, ultramarine, iron oxide yellow 0.1 part composition.
Choose raw material by the proportioning of the stone material seamless binding glue in above-described embodiment, under the negative pressure state of 0.08-0.1MPa, to be not less than the rotating speed high-speed stirring of 1500r/min, obtain stone material seamless binding glue of the present invention.
Left standstill under 25 DEG C of conditions by gained stone material seamless binding glue in above-described embodiment, observation colloid phase-splitting situation, record leaves standstill the phase-splitting time.
Get gained stone material seamless binding glue in 100 weight part above-described embodiments, be blended into 3 weight part solidifying agent and mix and stir, according to JC/T989-2006 method, Mechanics Performance Testing is carried out to stone material seamless binding adhesive curing thing.
According to GB/T14522-2008 method, ultraviolet ageing test is carried out to above-mentioned stone material seamless binding adhesive curing thing, the results are shown in following table:
The present invention is not limited to above-mentioned embodiment, and for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications are also considered as within protection scope of the present invention.The content be not described in detail in this specification sheets belongs to the known prior art of professional and technical personnel in the field.
Claims (16)
1. environment-friendly type stone material seamless binding glue, is characterized in that: be made up of the filler of 20-200 part, pre-promotion unsaturated polyester resin, the toughener of 3-10 part, the UV light absorber of antisettling agent // 0.5-1 part of 5-15 part and the pigment of 0-7 weight part of 100 parts by weight; Wherein, be the thinner of 25-40% containing weight percentage in the pre-promotion unsaturated polyester resin of described 100 parts, described thinner is selected from: Vinylstyrene, diallyl phthalate and m-phthalic acid two propylene.
2. environment-friendly type stone material seamless binding glue according to claim 1, it is characterized in that: described thinner is Vinylstyrene and diallyl phthalate two component, or Vinylstyrene and m-phthalic acid two propylene two component, or Vinylstyrene, diallyl phthalate and m-phthalic acid two propylene three components.
3. environment-friendly type stone material seamless binding glue according to claim 1 or 2, it is characterized in that: the thinner in described pre-promotion unsaturated polyester resin is by the weight percent of thinner gross weight by the Vinylstyrene of 35-75%, and the diallyl phthalate of 25-65% is or/and m-phthalic acid two propylene composition.
4. environment-friendly type stone material seamless binding glue according to claim 3, it is characterized in that: the thinner in described pre-promotion unsaturated polyester resin is by the weight percent of thinner gross weight by the Vinylstyrene of 40-60%, and the diallyl phthalate of 40-60% is or/and m-phthalic acid two propylene composition.
5. environment-friendly type stone material seamless binding glue according to claim 1 or 2 or 4, is characterized in that: described toughener is selected from lignocellulose and modification lignocellulose.
6. environment-friendly type stone material seamless binding glue according to claim 5, it is characterized in that: described toughener is made up of the lignocellulose of 25-75% and the modification lignocellulose of 25-75% by weight percentage, and described modification lignocellulose is selected from Walocel MT 20.000PV, Natvosol and Vltra tears.
7. environment-friendly type stone material seamless binding glue according to claim 6, is characterized in that: the consumption of described toughener is 5-9 weight part.
8. environment-friendly type stone material seamless binding glue according to claim 6, it is characterized in that: the order number of described toughener is 1000-1500 order, the consumption of described toughener is 7-9 weight part.
9. the environment-friendly type stone material seamless binding glue according to claim 1 or 7 or 8, is characterized in that: described filler is selected from silicon-dioxide, water-ground limestone, aluminium hydroxide, talcum powder and dry powder.
10. environment-friendly type stone material seamless binding glue according to claim 9, it is characterized in that: in described filler, silicon-dioxide, water-ground limestone, aluminium hydroxide, dry powder order number are 1000-5000 order, talcum powder order number is 1000-3000 order, described filler whiteness >=90 °.
11. environment-friendly type stone material seamless binding glue according to claim 10, is characterized in that: described filler counts silica 1 0%-70%, water-ground limestone 10%-70% by the weight percent of filler gross weight, aluminium hydroxide 10%-70%, talcum powder 0%-10%, dry powder 10%-70%, total amount are 100%.
12. environment-friendly type stone material seamless binding glue according to claim 1 or 10, is characterized in that: described UV light absorber is selected from ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole, HMPA and p-t-butylphenyl salicylate.
13. environment-friendly type stone material seamless binding glue according to claim 12, is characterized in that: described UV light absorber is selected from least two kinds in p-t-butylphenyl salicylate, ESCALOL 567,2-(2'-hydroxyl-5'-aminomethyl phenyl) benzotriazole and HMPA.
14. environment-friendly type stone material seamless binding glue according to claim 1 or 13, is characterized in that: described antisettling agent is selected from aluminum stearate, barium stearate, nickel stearate and lithium stearate.
15. environment-friendly type stone material seamless binding glue according to claim 14, it is characterized in that: described antisettling agent is selected from least two kinds in aluminum stearate, barium stearate, nickel stearate and lithium stearate, the order number of described antisettling agent is 1000-3000 order.
16. methods preparing environment-friendly type stone material seamless binding glue described in arbitrary claim in claim 1-15, is characterized in that: comprise the following steps:
1) component is taken by above-mentioned raw materials parts by weight, for subsequent use;
2) by above-mentioned component vacuum tightness be 0.08-0.1Mpa, rotating speed be the negative pressure state being not less than 1500r/min under high-speed stirring to evenly, churning time is 30-45 minute, namely obtains environment-friendly type stone material seamless binding glue.
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| CN106281180A (en) * | 2016-08-27 | 2017-01-04 | 安徽天瞳智能科技有限公司 | A kind of resin adhesive with superior heat-stability |
| CN109825233A (en) * | 2019-01-22 | 2019-05-31 | 管小梅 | A kind of preparation method of high-adhesion high intensity cloud stone glue |
| CN113214758A (en) * | 2021-05-21 | 2021-08-06 | 武汉市科达云石护理材料有限公司 | Stone adhesive toning paste and preparation method and application thereof |
| CN113214758B (en) * | 2021-05-21 | 2022-07-08 | 武汉市科达云石护理材料有限公司 | Stone adhesive toning paste and preparation method and application thereof |
| CN116004165A (en) * | 2022-12-21 | 2023-04-25 | 武汉市科达云石护理材料有限公司 | Environment-friendly stone block coating adhesive and preparation method thereof |
| CN116332582A (en) * | 2023-05-29 | 2023-06-27 | 福建绿格新材料科技有限公司 | Method for producing biomass-containing clay and clay obtained by the method |
| CN116332582B (en) * | 2023-05-29 | 2023-08-08 | 福建绿格新材料科技有限公司 | Method for producing biomass-containing clay and clay obtained by the method |
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