CN104927537A - Highly-filled zinc-enriched paint with titanate coupling agent added - Google Patents
Highly-filled zinc-enriched paint with titanate coupling agent added Download PDFInfo
- Publication number
- CN104927537A CN104927537A CN201510361348.8A CN201510361348A CN104927537A CN 104927537 A CN104927537 A CN 104927537A CN 201510361348 A CN201510361348 A CN 201510361348A CN 104927537 A CN104927537 A CN 104927537A
- Authority
- CN
- China
- Prior art keywords
- zinc
- coupling agent
- titanate coupling
- container
- rich paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 27
- 239000011701 zinc Substances 0.000 title claims abstract description 27
- 239000003973 paint Substances 0.000 title claims abstract description 23
- 239000007822 coupling agent Substances 0.000 title claims abstract description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 8
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 8
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 8
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005642 Oleic acid Substances 0.000 claims description 8
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 8
- 239000004111 Potassium silicate Substances 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000004816 latex Substances 0.000 claims description 7
- 229920000126 latex Polymers 0.000 claims description 7
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 7
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 7
- 235000019353 potassium silicate Nutrition 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 239000002184 metal Substances 0.000 abstract description 9
- 238000011049 filling Methods 0.000 abstract description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004423 acyloxy group Chemical group 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910001341 Crude steel Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052909 inorganic silicate Inorganic materials 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920006387 Vinylite Polymers 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 150000002118 epoxides Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses highly-filled zinc-enriched paint with titanate coupling agent added. Isopropyl dioleic acid acyloxy (dioctyl phosphoric acid acyloxy) coupling agent is added to enable bridged linkage to be formed between polymer and metal zinc powder, so that compatibility between the metal zinc powder and silicate is improved, thermostability of a composite material is improved, and high filling is realized.
Description
Technical field
The present invention relates to a kind of antiseptic coating ofiron and steel, particularly a kind of height adding titanate coupling agent fills zinc-rich paint, belongs to paint field.
Background technology
In life, all trades and professions all use metallic substance, and as automotive industry, production, construction industry, transportation, in metallic substance, iron and steel uses the most extensive, and within 2014, global crude steel output reaches 16.62 hundred million tons, increases by 1.2% on a year-on-year basis.Wherein Chinese crude steel output reaches 8.227 hundred million tons, and steel are mainly used in inside structured material, heavy construction and big machinery.Iron and steel easily corrodes when using, and during corrosion, the interface of metal there occurs chemistry or electrochemistry heterogeneous reaction, makes metal proceed to oxidation (ion) state.This significantly can reduce the mechanical property such as intensity, plasticity, toughness of ferrous materials, destroys the geometrical shape of hardware, shortens the work-ing life of equipment, even cause the catastrophic failure such as fire, blast.People delay the corrosion speed of iron and steel by various mode, as improved base material, selecting anticorrosive, increase metal plating, adding inhibiter etc.By add other materials to suppress in pure metal or stop the corrosion shortcoming of iron and steel to be compared with original material, its physicals often lacks to some extent, or cause cost to increase due to the cost of alloy.Therefore the most frequently used anti-corrosion mode is exactly to needing the additional top coat having a tolerance of the metal of protection.Coating is one of important channel of anticorrosion of steel structure, and zinc rich primer is one of most widely used basic silkworm race in protective system.
Zinc-rich paint is divided into organic zinc rich paint and inorganic zinc coating, and it is film forming binder that organic zinc-rich paint commonly uses epoxy resin, chlorinated rubber, Vinylite and urethane resin.But the poor electric conductivity of the organic binder of organic zinc-rich paint.Inorganic zinc coating is divided into again solvent-borne type and water-based two class.Wherein aqueous inorganic zinc-enriched coating is made up of aqueous inorganic silicate (receive, potassium, lithium) resin, zinc powder, auxiliary agent etc.In water-borne coatings, because solvent is few, wettability is low, and zinc powder adds in coating, and due to zinc powder and the more difficult fusion of inorganic silicate, zinc powder is easily assembled and sunk.
Titanate coupling agent and can form bridged bond between polymkeric substance and metal zinc, due to the polar group that induces one in coupling agent (as epoxide group), improves the compatibility of metal zinc and silicate, improves the thermostability of matrix material, realizes high filling.The present invention, by preparing in zinc-rich paint process, adds sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) coupling agent, prepares the zinc-rich paint of a kind of high filling, sticking power excellence.
Summary of the invention
The open a kind of high filling zinc-rich paint of the present invention and preparation technology thereof, contained by this coating, the mass percent of component is:
Potassium silicate 10%-20%;
Gui Suan Na 10%-20%;
Super-fine zinc dust 40%-60%;
Organosilicon crylic acid latex 15%-30%;
Sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) 3%-10%;
Dilute phosphoric acid 2-10%.
A kind of preparation method of high filling zinc-rich paint comprises the steps:
(1) get a container, potassium silicate solution and Gui Suan Na solution are poured in container, mixes and heat;
Again by a certain amount of organosilicon crylic acid latex slowly in container, and ceaselessly to stir;
(3) stop heating, then in container, add a certain amount of sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy), high-speed stirring;
(4) add zinc powder, ceaselessly stir;
(5) the dilute phosphoric acid that last interpolation is appropriate, obtains a kind of height adding titanate coupling agent and fills zinc-rich paint.
Preferentially, step (1) in, Heating temperature is 70-80 DEG C.
The present invention has following advantages and characteristic:
(1) this Paint preparation technology is simple, good operability;
(2) coating has good mobility, coating character.
Embodiment
Embodiment one:
Get a container, 50g potassium silicate solution and 100g Gui Suan Na solution are poured in container respectively, about 70 DEG C heating after mixing, slowly in container, drip 100g organosilicon crylic acid latex again, and do not stop to stir with stirrer, after dropwising, system temperature is down to room temperature, 25g sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) is added again in container, and improve stirring velocity, then add and add 200g super-fine zinc dust, finally add 25g dilute phosphoric acid, obtain a kind of height adding titanate coupling agent and fill zinc-rich paint.
Embodiment two:
Get a container, 75g potassium silicate solution and 75g Gui Suan Na solution are poured in container respectively, about 75 DEG C heating after mixing, slowly in container, drip 75g organosilicon crylic acid latex again, and do not stop to stir with stirrer, after dropwising, system temperature is down to room temperature, 15g sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) is added again in container, and improve stirring velocity, then add and add 250g super-fine zinc dust, finally add 10g dilute phosphoric acid, obtain a kind of height adding titanate coupling agent and fill zinc-rich paint.
Embodiment three:
Get a container, 100g potassium silicate solution and 100g Gui Suan Na solution are poured in container respectively, about 80 DEG C heating after mixing, slowly in container, drip 150g organosilicon crylic acid latex again, and do not stop to stir with stirrer, after dropwising, system temperature is down to room temperature, 30g sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) is added again in container, and improve stirring velocity, then add and add 600g super-fine zinc dust, finally add 20g dilute phosphoric acid, obtain a kind of height adding titanate coupling agent and fill zinc-rich paint.
Claims (3)
1. the height adding titanate coupling agent fills a zinc-rich paint, it is characterized in that the preparation method of this coating comprises the following steps:
(1) get a container, potassium silicate solution and Gui Suan Na solution are poured in container, mixes and heat;
Again by a certain amount of organosilicon crylic acid latex slowly in container, and ceaselessly to stir;
(3) stop heating, then in container, add a certain amount of sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy), high-speed stirring;
(4) add zinc powder, ceaselessly stir;
(5) the dilute phosphoric acid that last interpolation is appropriate, obtains a kind of height adding titanate coupling agent and fills zinc-rich paint.
2. a kind of height adding titanate coupling agent according to claim 1 fills zinc-rich paint, it is characterized in that, the mass percent of this zinc-rich paint component concentration is: potassium silicate 10%-20% Gui Suan Na 10%-20%, super-fine zinc dust 40%-60%, organosilicon crylic acid latex 15%-30%, sec.-propyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) 3%-10%, dilute phosphoric acid 2-10%.
3. a kind of height adding titanate coupling agent according to claim 1 fills zinc-rich paint, it is characterized in that, step (1) in, Heating temperature is 70-80 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361348.8A CN104927537A (en) | 2015-06-28 | 2015-06-28 | Highly-filled zinc-enriched paint with titanate coupling agent added |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510361348.8A CN104927537A (en) | 2015-06-28 | 2015-06-28 | Highly-filled zinc-enriched paint with titanate coupling agent added |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104927537A true CN104927537A (en) | 2015-09-23 |
Family
ID=54114973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510361348.8A Pending CN104927537A (en) | 2015-06-28 | 2015-06-28 | Highly-filled zinc-enriched paint with titanate coupling agent added |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104927537A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
-
2015
- 2015-06-28 CN CN201510361348.8A patent/CN104927537A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5413628A (en) * | 1993-09-22 | 1995-05-09 | Savin; Ronald R. | Stable inorganic zinc-powder rich coating composition |
Non-Patent Citations (2)
| Title |
|---|
| 周春婧等: ""硅丙乳液改性高模数硅酸钾水性无机富锌涂料的研究"", 《上海涂料》 * |
| 张鹏飞等: ""水性无机富锌涂料及其改性"", 《上海涂料》 * |
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Application publication date: 20150923 |