CN104911662B - Preparation method of composite ceramic coating layer - Google Patents
Preparation method of composite ceramic coating layer Download PDFInfo
- Publication number
- CN104911662B CN104911662B CN201510223610.2A CN201510223610A CN104911662B CN 104911662 B CN104911662 B CN 104911662B CN 201510223610 A CN201510223610 A CN 201510223610A CN 104911662 B CN104911662 B CN 104911662B
- Authority
- CN
- China
- Prior art keywords
- aluminum alloy
- alloy member
- coating
- preparation
- positive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 47
- 239000011247 coating layer Substances 0.000 title abstract description 5
- 238000005524 ceramic coating Methods 0.000 title abstract 4
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 127
- 239000011248 coating agent Substances 0.000 claims abstract description 64
- 238000000576 coating method Methods 0.000 claims abstract description 64
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 60
- 230000004888 barrier function Effects 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 27
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 14
- 239000010935 stainless steel Substances 0.000 claims abstract description 12
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 12
- 229910020148 K2ZrF6 Inorganic materials 0.000 claims abstract description 10
- 230000004087 circulation Effects 0.000 claims abstract description 6
- 239000000498 cooling water Substances 0.000 claims abstract description 6
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 3
- 239000000919 ceramic Substances 0.000 claims description 36
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 33
- 239000000243 solution Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 17
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000003792 electrolyte Substances 0.000 claims description 15
- JLDSOYXADOWAKB-UHFFFAOYSA-N aluminium nitrate Chemical compound [Al+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O JLDSOYXADOWAKB-UHFFFAOYSA-N 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 11
- 150000002910 rare earth metals Chemical class 0.000 claims description 11
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 229910009253 Y(NO3)3 Inorganic materials 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- BXJPTTGFESFXJU-UHFFFAOYSA-N yttrium(3+);trinitrate Chemical compound [Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O BXJPTTGFESFXJU-UHFFFAOYSA-N 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 5
- 229910020489 SiO3 Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 5
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000005011 phenolic resin Substances 0.000 claims description 5
- 229920001568 phenolic resin Polymers 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 238000002161 passivation Methods 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Inorganic materials [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 claims description 3
- LBVWQMVSUSYKGQ-UHFFFAOYSA-J zirconium(4+) tetranitrite Chemical compound [Zr+4].[O-]N=O.[O-]N=O.[O-]N=O.[O-]N=O LBVWQMVSUSYKGQ-UHFFFAOYSA-J 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000013461 design Methods 0.000 claims description 2
- 210000001367 artery Anatomy 0.000 claims 1
- 210000003462 vein Anatomy 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 31
- 238000012805 post-processing Methods 0.000 abstract description 5
- 238000009413 insulation Methods 0.000 abstract description 3
- 230000017525 heat dissipation Effects 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- 239000002345 surface coating layer Substances 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 description 12
- 229910001845 yogo sapphire Inorganic materials 0.000 description 12
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 8
- 229910001928 zirconium oxide Inorganic materials 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000007750 plasma spraying Methods 0.000 description 3
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 244000137852 Petrea volubilis Species 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910001234 light alloy Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052574 oxide ceramic Inorganic materials 0.000 description 1
- 239000011224 oxide ceramic Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- -1 yittrium oxide Chemical compound 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
A preparation method of a composite ceramic coating layer includes successively pretreating the surface of an aluminum alloy element, preparing an arc-striking barrier layer on the surface of the aluminum alloy element, preparing a thermal insulation composite ceramic coating layer on the aluminum alloy surface and post-processing; the arc-striking barrier layer on the surface of the aluminum alloy element is prepared by coating in a deionized water-electrolysis solution system composed of NaOH, Na2SiO3, (NaPO3)6 and K2ZrF6; a preparation system of the aluminum alloy element surface coating layer is composed of a stainless steel solution tank (7), a tooling (4), the aluminum alloy element (5), a stirrer (2), a thermometer (6), a cooling water circulation heat-dissipation device (1) and a power source device (8). The composite ceramic coating layer prepared by the method and the system has the advantages of high toughness, strong binding force with the surface of the aluminum alloy element, long service life, and excellent heat insulation performance.
Description
The application is Application No. 201210143986.9, the division Shen of the patent of invention on the applying date 2012 year 05 month 10
Please.
Technical field
The present invention relates to prepare a kind of composite ceramics excellent with heat-proof quality on the working face of aluminum alloy spare part
The method and its system of coating.
Background technology
Aluminium alloy as an alternative with the weight for mitigating parts industrially widely applied by the metal material such as steel
And promotion, but there is the defects such as fusing point is low, heat transfer is fast, high temperature is oxidizable in aluminium alloy.Zirconium oxide is used as excellent heat insulating coat
The attention of various countries is obtained, and has carried out substantial amounts of research, but due to the restriction of its own characteristic and preparation technology, prior art
Mainly coating preparation, plasma spraying, physical vapour deposition (PVD) are carried out by technological means such as plasma spraying, physical vapour deposition (PVD)s
All it is, in hydatogenesis to matrix surface, to be difficult to adopt because aluminum alloy materials characteristic is determined after oxidation zirconium melting etc. method
Conventional method prepares zirconia ceramics coating on its surface.
Generally speaking, the existing preparation technology of zirconia ceramics coating has that coating binding force is not enough, easy embrittlement, therefore uses
Life-span is not long, and the existing preparation technology such as technological means such as plasma spraying, electro beam physics vapour deposition is due to needing high temperature
Fusing zirconium oxide re-evaporation deposits to workpiece substrate surface, therefore can only prepare on the materials with high melting point such as steel, composite surface and apply
Layer, and crack because the difference of thermal coefficient of expansion between coating and matrix easily causes coating and is cooled in room temperature process, shadow
Coating binding force is rung, application of the zirconium oxide on the light alloy material such as aluminium alloy surface is limited.
The content of the invention
It is an object of the invention to provide a kind of system with excellent thermal insulation performance, the composite ceramic coat of long service life
Preparation Method.
The present invention seeks to be achieved through the following technical solutions：
A kind of preparation method of composite ceramic coat, it is characterised in that：It includes successively carrying out aluminum alloy member surface
Pretreatment, preparation aluminum alloy member surface starting the arc barrier layer, the heat-insulated composite ceramic coat of preparation aluminum alloy surface and post processing；Institute
The preparation for stating aluminum alloy member surface starting the arc barrier layer is with NaOH, Na2SiO3、(NaPO3)6、K2ZrF6The deionization of composition
Carry out coating in water electrolysis liquid system, the coating be with aluminum alloy member frock be sandwiched in high-voltage dc pulse power anode,
Aluminum alloy member frock is connected to the negative electrode of power supply, and coating prepares starting the arc barrier layer, wherein 3～5A/dm of current density2, frequency
800～1000Hz, the pulsewidth 30%～50% of positive pulse, 20～45min of process time；Preparing rising for aluminum alloy member surface
After arc resistance barrier, the preparation of the heat-insulated composite ceramic coat of aluminum alloy surface is carried out, specifically there is the starting the arc to stop the surface
The aluminum alloy member of layer is with NaOH, Na2SiO3、(NaPO3)6、Zr(NO3)4、Y(NO3)3、Al(NO3)3, and nanometer ZrO2With
To carry out coating in the deionized water electrolyte system of constituent, the coating is to prepare to aqueous high-temperature-resistant inorganic binder
The Al alloy parts for having starting the arc barrier layer are clamped in the negative electrode of high-voltage dc pulse power, and frock is connected to the anode of power supply, together
When add it is positive and negative to voltage, wherein 5～8A/dm of current density2, 800～1200Hz of frequency, the pulsewidth of positive pulse takes 20%～
50%, positive negative pulse stuffing compares 1:1、1:2 or 2:1,30～100min of process time.
In deionized water electrolyte system prepared by the heat-insulated composite ceramic coat of above-mentioned aluminum alloy surface, above-mentioned nanometer ZrO2
Preferably nanometer ZrO of particle diameter 20-40nm2, its addition is preferably 27-33g/L (more preferably 30g/L)；In order to enter
One step improves the resistance to elevated temperatures of final obtained coating, and above-mentioned aqueous high-temperature-resistant inorganic bond is preferably nano rare earth oxidation
Thing composite water soluble inorganic binder, the oxide nano rare earth composite water soluble inorganic binder is added in aqueous high-temperature-resistant glue
Enter lanthana, yittrium oxide that percentage by weight is 0.5%～1% or/and the obtained high temperature resistant of cerium oxide Jing bunchings reaction is combined
Aqueous inorganic binding agent is commercially available prod (as Beijing will contains the oxide nano rare earth of prestige China Tech skill Development Co., Ltd production
Aqueous high-temperature-resistant inorganic bond ZS-1071), its consumption is 31-33g/L (preferably 32g/L).
Above-mentioned each composition is commercially available prod；Obtained first by method made above is Al2O3Weight/mass percentage composition is
88%-95% is used as Al2O3Principal phase, ZrO2Weight/mass percentage composition is the aluminum alloy member surface starting the arc barrier layer of 5-12%, finally
Obtained is ZrO2Weight/mass percentage composition is 75%-85% as ZrO2Principal phase, Y2O3Weight/mass percentage composition is 5-10%, Al2O3
Weight/mass percentage composition is the heat-insulated composite ceramic coat of aluminum alloy surface of 10-20%.
In the preparation on above-mentioned aluminum alloy member surface starting the arc barrier layer, its voltage is more preferably also controlled in 0～400V；On
In stating the preparation of the heat-insulated composite ceramic coat of aluminum alloy surface, its generating positive and negative voltage ratio is more preferably also controlled for 3：1.
Specifically, a kind of preparation method of composite ceramic coat, it is characterised in that：It is included successively to aluminum alloy member
Surface carries out pre-processing oil removing dedusting, prepares aluminum alloy member surface starting the arc barrier layer, prepares the heat-insulated composite ceramic of aluminum alloy surface
Porcelain coating and post processing；
The preparation on the aluminum alloy member surface starting the arc barrier layer is with NaOH, Na2SiO3、(NaPO3)6、K2ZrF6Group
Into deionized water electrolyte system in carry out coating, wherein NaOH 8g/L, Na2SiO3 20g/L、(NaPO3)6 10g/L、
K2ZrF625g/L, the coating is anode, the aluminum alloy member work for being sandwiched in high-voltage dc pulse power with aluminum alloy member frock
Load is connected to the negative electrode of power supply and carries out coating preparation starting the arc barrier layer, wherein current density 4A/dm2, frequency 950Hz, positive pulse
Pulsewidth 40%, process time 33min, voltage is in 0～400V；
Behind the starting the arc barrier layer for preparing aluminum alloy member surface, the system of the heat-insulated composite ceramic coat of aluminum alloy surface is carried out
It is standby, specifically the surface is had into the aluminum alloy member on starting the arc barrier layer with NaOH, Na2SiO3、(NaPO3)6、Zr
(NO3)4、Y(NO3)3、Al(NO3)3, and nanometer ZrO2It is to constitute into oxide nano rare earth composite water soluble inorganic binder
Coating, wherein NaOH 6g/L, Na are carried out in the deionized water electrolyte system for dividing2SiO3 16g/L、(NaPO3)6 8g/L、Zr
(NO3)4 20g/L、Y(NO3)3 8g/L、Al(NO3)310g/L, nanometer ZrO2For nanometer ZrO of particle diameter 20-40nm2, its
Addition is 30g/L；Oxide nano rare earth composite water soluble inorganic binder is that lanthana, yittrium oxide or/and cerium oxide Jing gather
The obtained high temperature resistant composite water soluble inorganic adhesive of contracting reaction, is commercially available prod, and its consumption is 32g/L；The coating is to make
The Al alloy parts for having starting the arc barrier layer are clamped in the negative electrode of high-voltage dc pulse power, and frock is connected to the anode of power supply,
Add simultaneously positive and negative to voltage, wherein current density 6A/dm2, frequency 1000Hz, the pulsewidth of positive pulse takes 40%, positive negative pulse stuffing
Than 1:2, generating positive and negative voltage compares 3:1, process time 75min.
Most specifically say that a kind of preparation method of composite ceramic coat is carried out according to the following steps：
A. the pretreatment on aluminum alloy member surface：
Aluminum alloy member is carried out into dedusting, oil removing cleaning using ultrasonic washing instrument, then using H3PO4With Al (OH)3Instead
Should, the aqueous solution treatment fluid of biphosphate Alumina gel is obtained, aluminum alloy member is immersed into 2～3min in the solution, to remove aluminium
The oxide skin of alloy surface, deionized water cleaning after process, then aluminum alloy member immersion 10～20g/LNaOH solution is carried out
Surface alkali cleaning and Passivation Treatment at least 5 minutes；
B. the preparation on aluminum alloy member surface starting the arc barrier layer
The preparation on the aluminum alloy member surface starting the arc barrier layer is with NaOH, Na2SiO3、(NaPO3)6、K2ZrF6Group
Into deionized water electrolyte system in carry out coating, wherein NaOH 8g/L, Na2SiO3 20g/L、(NaPO3)6 10g/L、
K2ZrF625g/L, the coating is anode, the aluminum alloy member work for being sandwiched in high-voltage dc pulse power with aluminum alloy member frock
Load is connected to the negative electrode of power supply and carries out coating preparation starting the arc barrier layer, and negative voltage, wherein electric current are added without in coating preparation process
Density 4A/dm2, frequency 950Hz, the pulsewidth 40% of positive pulse, process time 33min, voltage is in 0～400V；By above-mentioned steps
Obtain Al2O3Weight/mass percentage composition is 95% Al2O3Principal phase, ZrO2Weight/mass percentage composition is that 5% aluminum alloy member surface is risen
Arc resistance barrier；
C. the preparation of the heat-insulated composite ceramic coat of aluminum alloy surface
Behind the starting the arc barrier layer for preparing aluminum alloy member surface, the system of the heat-insulated composite ceramic coat of aluminum alloy surface is carried out
It is standby, specifically the surface is had into the aluminum alloy member on starting the arc barrier layer with NaOH, Na2SiO3、(NaPO3)6、Zr
(NO3)4、Y(NO3)3、Al(NO3)3, and nanometer ZrO2It is to constitute into oxide nano rare earth composite water soluble inorganic binder
Coating, wherein NaOH 6g/L, Na are carried out in the deionized water electrolyte system for dividing2SiO3 16g/L、(NaPO3)6 8g/L、Zr
(NO3)4 20g/L、Y(NO3)3 8g/L、Al(NO3)310g/L, nanometer ZrO2For nanometer ZrO of particle diameter 20-40nm2, its
Addition is 30g/L；Oxide nano rare earth composite water soluble inorganic binder is that lanthana, yittrium oxide or/and cerium oxide Jing gather
The obtained high temperature resistant composite water soluble inorganic adhesive of contracting reaction, is commercially available prod, and its consumption is 32g/L；The coating is to make
The Al alloy parts for having starting the arc barrier layer are clamped in the negative electrode of high-voltage dc pulse power, and frock is connected to the anode of power supply,
Add simultaneously positive and negative to voltage, wherein current density 6A/dm2, frequency 1000Hz, the pulsewidth of positive pulse takes 40%, positive negative pulse stuffing
Than 1:2, generating positive and negative voltage compares 3:1, process time 75min, 0～560V of positive voltage, 0～300V of negative voltage；Obtain by above-mentioned steps
ZrO2Weight/mass percentage composition is the ZrO of 75%-85%2Principal phase, Y2O3Weight/mass percentage composition is 5-10%, Al2O3Quality percentage contains
Measure the heat-insulated composite ceramic coat of aluminum alloy surface for 10-20%；
Chemical composition in above two electrolyte system preferably adopts AR, prepares using deionized water as molten
Agent, quality of de-ionized water require 25 DEG C of preferred 10M Ω cm@and more than, the distilled water of high-purity (three distillations and more than) can
Preferably to replace deionized water as solvent, alcohol adopt purity for the analysis of 99.7% and the above it is pure；
D. post-process
The aluminum alloy member of the tool coating Jing after the process of step c is cleaned, then will have coating aluminium using hair dryer
Alloying element is dried up；
Preferably, in order to obtain further improving obtained aluminum alloy member resistance to elevated temperatures, after above-mentioned post processing
Also sealing pores are carried out to having coating aluminum alloy member, specifically using ZrO2Modified organosilicon phenolic resin (is commercially available product
Product) even application is carried out to coating aluminum alloy member.
The present invention has following beneficial effect：
Aluminum alloy member face coat obtained in preparation method of the present invention is ZrO2-Y2O3-Al2O3Heat-insulated composite ceramics is applied
Layer；Present invention utilizes there is c-ZrO in zirconium oxide2→t-ZrO2(2370 DEG C) and t-ZrO2(2370℃)→M-ZrO2(1170
DEG C) phase-change characteristic, introducing aluminum oxide, yttrium composition makes the c-ZrO of high-temperature stable2And t-ZrO2Mutually also can be in room
Temperature is stable or meta-stable is present, and toughening effect is served to zirconia coating, further to improve zirconia coating in aluminium alloy
The adhesion on surface；Meanwhile, the excellent high-temperature behavior of aluminum oxide, yittrium oxide forms reinforcement and makees to the heat-proof quality of zirconia coating
With further increasing coating heat-proof quality.The composite ceramic coat is mainly by oxides such as zirconium oxide, yittrium oxide, aluminum oxide
Ceramic phase composition, forms with zirconium oxide as principal phase, aluminum oxide, the composite coating structure of yttria toughened, the oxidation of non-master phase constituent
Aluminium, yittrium oxide have the stable effect of toughness reinforcing and phase structure to principal phase zirconium oxide, and the zirconic fusing point of principal phase is 2677 DEG C, heat conduction
Rate is 0.92wmK-1, thermal coefficient of expansion is 10 × 10-6·℃-1, with fusing point it is high, high-temperature heat-conductive rate is low, thermal coefficient of expansion
The characteristic such as close with aluminum substrate.
Obtained aluminum alloy member face coat of the invention has high tenacity and aluminum alloy member surface adhesion strong, real
Test result to show coating layer thickness adhesion is in 7.5Mpa-10Mpa in 350um or so, its long service life, heat-proof quality is excellent
It is different.Inventor by long-term theoretical research and substantial amounts of test, solve aluminum alloy member cannot low temperature preparation go out zirconium oxide
For the composite ceramic coat of principal phase, it is difficult to meet 2000 DEG C of high temperature above use requirement in short-term, improve aluminum alloy member
Heat-proof quality, realizes reliability and uses 10s-30s under obtained hot environment of the aluminum alloy member more than 2000 DEG C of the present invention；
The inventive method is applicable not only to small-sized aluminum alloy member, is also applied for large aluminum alloy parts；It is applicable not only to circle, side
The aluminum alloy member of the regular shapes such as shape, is also applied for the aluminum alloy member of the arbitrary shapes such as ellipse, flat.Aluminium of the present invention is closed
The preparation system of gold dollar part face coat is simple, workable, is easy to industrialization promotion.
Description of the drawings
Fig. 1：The ZrO obtained in embodiment 12-Y2O3-Al2O3Composite ceramic coat surface microscopic topographic figure；
Fig. 2：The ZrO obtained in embodiment 12-Y2O3-Al2O3Composite ceramic coat section microscopic appearance figure；
Fig. 3：The ZrO obtained in embodiment 12-Y2O3-Al2O3Composite ceramic coat EDAX results figure；
Fig. 4：For composite ceramic coat preparation system structural representation of the present invention；Wherein, 1- cooling water circulations heat abstractor,
2- agitators, 3- electrolyte, 4- frocks, 5- aluminum alloy members, 6- thermometers, 7- stainless steel solution tanks, 8- power-supply devices；
Fig. 5：The impulse waveform of the power supply output on aluminum alloy member surface starting the arc barrier layer, wherein T are prepared for embodiment 1:
Cycle, f:Pulsewidth；
Fig. 6：The impulse waveform of the power supply output of the heat-insulated composite ceramic coat of aluminum alloy surface is prepared for embodiment 1, wherein
T:Cycle, f:Pulsewidth；
Fig. 7：For the main circuit schematic diagram of power-supply device in composite ceramic coat preparation system of the present invention.
Specific embodiment
The present invention is specifically described below by example, it is necessary to it is pointed out here that, following instance is served only for right
The present invention is further described, it is impossible to be interpreted as limiting the scope of the invention, and the person skilled in the art in the field can
So that some nonessential modifications and adaptations are made to the present invention according to foregoing invention content.
Embodiment 1
A kind of preparation system of composite ceramic coat, as shown in figure 4, by stainless steel solution tank 7, frock 4, aluminum alloy member
5th, agitator 2, thermometer 6, cooling water circulation heat abstractor 1 and power-supply device 8 are constituted, and are wherein filled in stainless steel solution tank 7
Thermometer 6, agitator 2, frock 4 and aluminum alloy member 5 are provided with above-mentioned electrolyte 3, stainless steel solution tank 7, and are soaked
In the electrolyte 3, wherein aluminum alloy member 5 is arranged in frock 4, the positive and negative electrode and aluminum alloy member 5 of power-supply device 8,
Frock 4 connects respectively；The cooling water circulation heat abstractor 1 is arranged on the bottom of stainless steel solution tank 7 by pipeline and stainless steel
Solution tank 7 is connected；Wherein power-supply device 8 is commercially available prod, and its main circuit schematic diagram is referring to Fig. 7.
Composite ceramic coat is prepared using the system, is carried out according to the following steps：
(1) preparation of high-voltage dc pulse power and aluminum alloy member frock：Using generating positive and negative voltage it is symmetrical, generating positive and negative voltage can
Tune, positive negative pulse stuffing are than adjustable and positive negative pulse stuffing pulsewidth, the high-voltage direct-current pulse power of frequency-adjustable；Generating positive and negative voltage is all in 700V
More than, generating positive and negative voltage can smooth adjustable between 0～700V, and positive negative pulse stuffing ratio can carry out 1:2、2:1、1:1 Three models are adjustable,
Positive negative pulse stuffing width can be adjustable between 0～100%, and the frequency of positive negative pulse stuffing can be adjustable between 300Hz～3000Hz, the electricity
The supporting electrolytic bath in source has cooling capacity, it is ensured that solution temperature is maintained at less than 30 DEG C in experimentation；And for aluminium alloy
The aluminum alloy member frock that the Structural Feature Design of element goes out required for prepared by coating, the frock is simultaneously as the another of coating preparation
An outer electrode, therefore the frock needs firm clamping aluminum alloy member and with excellent electric conductivity, additionally needs and aluminium alloy
The process face of element prepares coating be in matching relationship, it is ensured that the field uniformity between frock and aluminium alloy, frock preferably with
With aluminum alloy member identical material, to ensure the symmetry between frock and aluminum alloy member；Using granularity more than 600 mesh
Sand paper frock is polished, make wear surface surface roughness in Ra more than 0.47；
(2) pretreatment on aluminum alloy member surface：
Aluminum alloy member is carried out into dedusting, oil removing cleaning using ultrasonic washing instrument, then using H3PO4With Al (OH)3Instead
Should, the aqueous solution treatment fluid of biphosphate Alumina gel is obtained, aluminum alloy member is immersed into 2～3min in the solution, to remove aluminium
The oxide skin of alloy surface, deionized water cleaning after process, then aluminum alloy member immersion 10～20g/LNaOH solution is carried out
Surface alkali cleaning and Passivation Treatment at least 5 minutes；
(3) preparation on aluminum alloy member surface starting the arc barrier layer
The preparation on the aluminum alloy member surface starting the arc barrier layer is with NaOH, Na2SiO3、(NaPO3)6、K2ZrF6Group
Into deionized water electrolyte system in carry out coating, wherein NaOH 8g/L, Na2SiO3 20g/L、(NaPO3)6 10g/L、
K2ZrF625g/L, the coating is anode, the aluminum alloy member work for being sandwiched in high-voltage dc pulse power with aluminum alloy member frock
Load is connected to the negative electrode of power supply and carries out coating preparation starting the arc barrier layer, and negative voltage, wherein electric current are added without in coating preparation process
Density 4A/dm2, frequency 950Hz, the pulsewidth 40% of positive pulse, process time 33min；The power supply output that its power-supply device is used
Impulse waveform as shown in Figure 5.Al is obtained by above-mentioned steps2O3Weight/mass percentage composition is 95% Al2O3Principal phase, ZrO2Quality hundred
Point content is 5% aluminum alloy member surface starting the arc barrier layer；
(4) preparation of the heat-insulated composite ceramic coat of aluminum alloy surface
Behind the starting the arc barrier layer for preparing aluminum alloy member surface, the system of the heat-insulated composite ceramic coat of aluminum alloy surface is carried out
It is standby, specifically the surface is had into the aluminum alloy member on starting the arc barrier layer with NaOH, Na2SiO3、(NaPO3)6、Zr
(NO3)4、Y(NO3)3、Al(NO3)3, and nanometer ZrO2It is to constitute into oxide nano rare earth composite water soluble inorganic binder
Coating, wherein NaOH 6g/L, Na are carried out in the deionized water electrolyte system for dividing2SiO3 16g/L、(NaPO3)6 8g/L、Zr
(NO3)4 20g/L、Y(NO3)3 8g/L、Al(NO3)310g/L, nanometer ZrO2For nanometer ZrO of particle diameter 20-40nm2, its
Addition is 30g/L；Oxide nano rare earth composite water soluble inorganic binder is that lanthana, yittrium oxide or/and cerium oxide Jing gather
The obtained high temperature resistant composite water soluble inorganic adhesive of contracting reaction, is commercially available prod, and its consumption is 32g/L；The coating is to make
The Al alloy parts for having starting the arc barrier layer are clamped in the negative electrode of high-voltage dc pulse power, and frock is connected to the anode of power supply,
Add simultaneously positive and negative to voltage, wherein current density 6A/dm2, frequency 1000Hz, the pulsewidth of positive pulse takes 40%, positive negative pulse stuffing
Than 1:1, generating positive and negative voltage compares 3:1, process time 75min；The impulse waveform of the power supply output that its power-supply device is used is shown in Fig. 6 institutes
Show.
Chemical composition in above two electrolyte system adopts AR, prepares using deionized water as solvent,
Quality of de-ionized water requires the distilled water of 25 DEG C of preferred 10M Ω cm@and the above or high-purity (three distillations and more than), alcohol
Adopt purity for the analysis of 99.7% and the above it is pure；
(5) post-process
The aluminum alloy member of the tool coating Jing after the process of step c is cleaned, then will have coating aluminium using hair dryer
Alloying element is dried up；Also sealing pores are carried out to having coating aluminum alloy member after above-mentioned post processing, specifically using ZrO2Change
Property organosilicon phenolic resin (be commercially available prod) even application is carried out to coating aluminum alloy member, and in 160～180 DEG C of temperature
In the range of to organosilicon phenolic resin carry out solidify 5h and more than.
Aluminum alloy member face coat obtained above has high tenacity and the strong (employing of aluminum alloy member surface adhesion
The circular specimen of band coating pulls open method test adhesion).Using GJB323A-1996《Ablator ablative test method》Test
The sample heat-proof quality of band coating：Reliability is realized under 2200-2500 DEG C of hot environment and uses 20s-24s, fully met
Aluminum alloy member use requirement in short-term at high temperature.Its obtained ZrO2-Y2O3-Al2O3Composite ceramic coat is referring to Fig. 1, figure
2nd, shown in Fig. 3.
Embodiment 2,3：Carry out by following raw material and technological parameter, remaining is with embodiment 1.
Composite ceramic coat obtained above has high tenacity and aluminum alloy member surface adhesion strong, in 2000-3000
DEG C hot environment under realize it is reliable use 15s-28s, meet its use requirement in high temperature environments.
Claims (1)
1. a kind of preparation method of composite ceramic coat, it is characterised in that carry out according to the following steps：
The preparation system that the coating is adopted, by stainless steel solution tank（7）, frock（4）, aluminum alloy member（5）, agitator（2）、
Thermometer（6）, cooling water circulation heat abstractor（1）And power-supply device（8）Composition, wherein stainless steel solution tank（7）Inside fill electricity
Solution liquid（3）, stainless steel solution tank（7）Inside it is provided with thermometer（6）, agitator（2）, frock（4）And aluminum alloy member（5）, and
And it is immersed in the electrolyte（3）In, wherein aluminum alloy member（5）It is arranged on frock（4）It is interior, power-supply device（8）Positive and negative electrode
With aluminum alloy member（5）, frock（4）Connect respectively；The cooling water circulation heat abstractor（1）It is arranged on stainless steel solution tank
（7）Bottom is by pipeline and stainless steel solution tank（7）Connection；
A. the preparation of high-voltage dc pulse power and aluminum alloy member frock：Using generating positive and negative voltage it is symmetrical, generating positive and negative voltage is adjustable,
Positive negative pulse stuffing is than adjustable and positive negative pulse stuffing pulsewidth, the high-voltage direct-current pulse power of frequency-adjustable；Generating positive and negative voltage all 700 V with
On, generating positive and negative voltage is smooth adjustable between 0 ~ 700 V, and positive negative pulse stuffing ratio carries out 1：2、2：1、1：1 Three models are adjustable, positive and negative arteries and veins
Rush that width is adjustable between 0 ~ 100%, the frequency of positive negative pulse stuffing is adjustable between 300 Hz ~ 3000 Hz, the supporting electricity of the power supply
Solution liquid bath has cooling capacity, it is ensured that solution temperature is maintained at less than 30 DEG C in experimentation；And for the structure of aluminum alloy member
The aluminum alloy member frock that characteristics design goes out required for prepared by coating, another electricity that the frock is prepared as coating simultaneously
Pole；
B. the pretreatment on aluminum alloy member surface：
Aluminum alloy member is carried out into dedusting, oil removing cleaning using ultrasonic washing instrument, then using H3PO4With Al (OH)3Reaction, obtains
To the aqueous solution treatment fluid of biphosphate Alumina gel, aluminum alloy member is immersed into 2～3 min in the solution, to remove aluminium alloy
The oxide skin on surface, deionized water cleaning after process, then the NaOH solution that aluminum alloy member immerses 10～20 g/L is carried out
Surface alkali cleaning and Passivation Treatment at least 5 minutes；
C. the preparation on aluminum alloy member surface starting the arc barrier layer
The preparation on the aluminum alloy member surface starting the arc barrier layer is with NaOH, Na2SiO3、(NaPO3)6、K2ZrF6Composition
Coating, wherein NaOH 10 g/L, Na are carried out in deionized water electrolyte system2SiO3 18 g/L、(NaPO3)6 13 g/L、
K2ZrF627g/L, the coating is anode, the aluminum alloy member work for being sandwiched in high-voltage dc pulse power with aluminum alloy member frock
Load is connected to the negative electrode of power supply and carries out coating preparation starting the arc barrier layer, and negative voltage, wherein electric current are added without in coating preparation process
Density 3A/dm2, voltage 200V, the Hz of frequency 1000, the pulsewidth 50% of positive pulse, the min of process time 25；
D. the preparation of the heat-insulated composite ceramic coat of aluminum alloy surface
Behind the starting the arc barrier layer for preparing aluminum alloy member surface, the preparation of the heat-insulated composite ceramic coat of aluminum alloy surface is carried out,
Specifically the surface had into the aluminum alloy member on starting the arc barrier layer with NaOH, Na2SiO3、(NaPO3)6、 Zr(NO3)4、Y
(NO3)3、Al(NO3)3, and nanometer ZrO2With oxide nano rare earth composite water soluble inorganic binder for constituent go from
Coating, wherein NaOH 6 g/L, Na are carried out in sub- water electrolysis liquid system2SiO3 17 g/L、(NaPO3)6 5 g/L、Zr(NO3)4
17 g/L、Y(NO3)3 9g/L、Al(NO3)39 g/L, nanometer ZrO2For nanometer ZrO of particle diameter 20-40nm2, its addition
For 27g/L；Oxide nano rare earth composite water soluble inorganic binder is the reaction of lanthana, yittrium oxide or/and cerium oxide Jing bunchings
Obtained high temperature resistant composite water soluble inorganic adhesive, its consumption is 33g/L；The coating is will to prepare the aluminium for having starting the arc barrier layer
Alloy workpiece is clamped in the negative electrode of high-voltage dc pulse power, and frock is connected to the anode of power supply, while adding positive and negative to electricity
Pressure, wherein current density 5A/dm2, positive voltage 560V, negative voltage 200V, frequency 1200Hz, the pulsewidth of positive pulse takes 50%, just
Negative pulse compares 2：1, process time 80min；
E. post-process
The aluminum alloy member of the tool coating Jing after the process of step d is cleaned, then will have coating aluminium alloy using hair dryer
Element is dried up；Also sealing pores are carried out to having coating aluminum alloy member, specifically using ZrO2Modified organosilicon phenolic resin
Even application is carried out to coating aluminum alloy member, and organosilicon phenolic resin is solidified in 160 ~ 180 DEG C of temperature ranges
5h and more than.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510223610.2A CN104911662B (en) | 2012-05-10 | 2012-05-10 | Preparation method of composite ceramic coating layer |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210143986.9A CN102634832B (en) | 2012-05-10 | 2012-05-10 | Method for preparing aluminum alloy element surface coating and system thereof |
| CN201510223610.2A CN104911662B (en) | 2012-05-10 | 2012-05-10 | Preparation method of composite ceramic coating layer |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210143986.9A Division CN102634832B (en) | 2012-05-10 | 2012-05-10 | Method for preparing aluminum alloy element surface coating and system thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104911662A CN104911662A (en) | 2015-09-16 |
| CN104911662B true CN104911662B (en) | 2017-05-10 |
Family
ID=46619405
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510223912.XA Active CN104911663B (en) | 2012-05-10 | 2012-05-10 | Durable surface coating layer preparation method and system |
| CN201510223610.2A Active CN104911662B (en) | 2012-05-10 | 2012-05-10 | Preparation method of composite ceramic coating layer |
| CN201210143986.9A Active CN102634832B (en) | 2012-05-10 | 2012-05-10 | Method for preparing aluminum alloy element surface coating and system thereof |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510223912.XA Active CN104911663B (en) | 2012-05-10 | 2012-05-10 | Durable surface coating layer preparation method and system |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210143986.9A Active CN102634832B (en) | 2012-05-10 | 2012-05-10 | Method for preparing aluminum alloy element surface coating and system thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (3) | CN104911663B (en) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104372394A (en) * | 2014-07-03 | 2015-02-25 | 西安工业大学 | Preparation method for oxide ceramic layer |
| CN104562128B (en) * | 2015-01-09 | 2017-10-03 | 西安工业大学 | A kind of method for preparing thermal protection ceramic layer on metal or metallic composite surface |
| CN105369270A (en) * | 2015-11-06 | 2016-03-02 | 和县隆盛精密机械有限公司 | Dust removing and cleaning technology for metal part |
| CN108779568B (en) * | 2016-03-11 | 2021-06-01 | 应用材料公司 | Method for electrochemically forming yttria on semiconductor processing equipment |
| CN107794558A (en) * | 2016-08-31 | 2018-03-13 | 昆山汉鼎精密金属有限公司 | Aluminum alloy surface color method and its products formed |
| CN106757265B (en) * | 2016-12-05 | 2018-12-28 | 中国科学院兰州化学物理研究所 | A kind of preparation method of the high sun light reflectivity white hot control coating of aluminum alloy surface |
| CN107723781B (en) * | 2017-08-28 | 2020-05-08 | 中国兵器工业第五九研究所 | Method for producing coating and coating apparatus |
| CN107915476A (en) * | 2017-12-06 | 2018-04-17 | 王增倍 | A kind of perforating head and preparation method |
| CN108517484B (en) * | 2018-04-16 | 2020-12-18 | 西安工业大学 | A kind of closed pore structure ceramic coating and preparation process thereof |
| CN108385156B (en) * | 2018-05-31 | 2023-12-15 | 东北大学 | Plating layer or passivation layer preparation device capable of flexibly controlling environmental parameters and application method |
| CN109267131B (en) * | 2018-09-06 | 2020-03-27 | 福铂斯（天津）科技有限公司 | Preparation method of non-combustible material |
| CN109441023A (en) * | 2018-11-06 | 2019-03-08 | 河南金拇指防水科技股份有限公司 | A kind of method that water-proof acrylic acid paint is laid with |
| CN111676499A (en) * | 2020-07-30 | 2020-09-18 | 华南理工大学 | Hydrogen-resistant coating based on cathode plasma electrolytic deposition and preparation method thereof |
| CN112760694B (en) * | 2020-12-30 | 2021-08-24 | 牡丹江师范学院 | Method for preparing high-temperature-resistant oxide film on surface of titanium alloy through double-electrode discharge |
| CN113089047A (en) * | 2021-04-12 | 2021-07-09 | 四川九洲电器集团有限责任公司 | Aluminum alloy component and preparation method and application thereof |
| CN113294261B (en) * | 2021-06-29 | 2022-08-23 | 潍柴动力股份有限公司 | Cylinder cover, coating preparation device and coating preparation method |
| CN116005223A (en) * | 2022-12-23 | 2023-04-25 | 北京星驰恒动科技发展有限公司 | Aluminum alloy surface low-absorption high-emission anti-corrosion thermal control coating and preparation method thereof |
| CN116351685B (en) * | 2023-04-10 | 2023-12-29 | 江西瑞一韵承科技有限公司 | Preparation process of aluminum alloy hub surface coating |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277606A (en) * | 2010-06-09 | 2011-12-14 | 西安康博新材料科技有限公司 | Preparation method of thermal barrier coating on surface of aluminum-magnesium alloy and composite material of alloy |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2072000C1 (en) * | 1993-08-23 | 1997-01-20 | Институт химии Дальневосточного отделения РАН | Method of multicolored dying of aluminium and aluminium-alloy objects |
| CN1138023C (en) * | 2001-05-31 | 2004-02-11 | 北京科技大学 | Cathode micro arc electrodepositing method for preparing oxide ceramic coating |
| JP2005023422A (en) * | 2003-06-09 | 2005-01-27 | Nippon Paint Co Ltd | Metal surface treatment method and surface-treated metal |
| CN1309875C (en) * | 2004-07-30 | 2007-04-11 | 哈尔滨工业大学 | Process for preparing zirconium oxide coating of titanium alloy surface |
| US20080226938A1 (en) * | 2007-03-16 | 2008-09-18 | Calvary Design Team, Inc. | Wear resistant ceramic coated aluminum alloy article and method for making same |
| EA200901050A1 (en) * | 2007-04-02 | 2009-12-30 | Владимир Никандрович Кокарев | METHOD OF FORMATION ON THE SURFACE OF METAL PRODUCTS OF PROTECTIVE CERAMIC COATINGS |
| CN102264952B (en) * | 2008-12-26 | 2014-07-23 | 日本帕卡濑精株式会社 | Method of electrolytic ceramic coating for metal, electrolysis solution for electrolytic ceramic coating for metal, and metallic material |
| CN102154644B (en) * | 2011-03-18 | 2013-03-06 | 中国兵器工业第五九研究所 | Preparation method of composite coating for light alloy component |
-
2012
- 2012-05-10 CN CN201510223912.XA patent/CN104911663B/en active Active
- 2012-05-10 CN CN201510223610.2A patent/CN104911662B/en active Active
- 2012-05-10 CN CN201210143986.9A patent/CN102634832B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102277606A (en) * | 2010-06-09 | 2011-12-14 | 西安康博新材料科技有限公司 | Preparation method of thermal barrier coating on surface of aluminum-magnesium alloy and composite material of alloy |
Non-Patent Citations (2)
| Title |
|---|
| Cathodic micro-arc electrodeposition of yttrium stabilized zirconia(YSZ)coatings;Yang Xiaozhan et al.;《Chinese Science Bulletin》;20030430;第48卷(第8期);第746-750页 * |
| 阴极气膜微弧放电沉积ZrO2-Y2O3陶瓷涂层;韩伟 等;《稀有金属》;20040831;第28卷(第4期);第622-625页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104911663B (en) | 2017-04-19 |
| CN104911663A (en) | 2015-09-16 |
| CN102634832A (en) | 2012-08-15 |
| CN104911662A (en) | 2015-09-16 |
| CN102634832B (en) | 2015-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104911662B (en) | Preparation method of composite ceramic coating layer | |
| CN102677127B (en) | Magnesium alloy microarc oxidation-electrophoresis composite coating and preparation method thereof | |
| CN103103597B (en) | A kind of titanium alloy self-lubricating composite membrane and preparation method thereof | |
| CN103551050B (en) | A kind of inorganic composite ultra-filtration membrane and preparation method thereof | |
| CN102732934B (en) | The method in aluminium alloy anode oxide film hole closed by a kind of silicon sol | |
| CN102605402A (en) | Preparation method of wear-resistant toughened composite ceramic layer on surface of aluminum alloy product | |
| CN103147109A (en) | Method for sealing aluminum alloy micro-arc oxidation film layer | |
| CN108570703A (en) | Preparation method of tungsten/copper laminated composite material based on tungsten sheet surface nanocrystallization | |
| CN103334143B (en) | A kind of Zr alloy surface prepares the differential arc oxidation method of wear-resisting zirconia and aluminum oxide mixed coating fast | |
| CN108914187A (en) | A kind of anti-oxidant complex gradient ceramic coating of titanium alloy surface high hardness wear-resisting and preparation method thereof | |
| CN107557836B (en) | TiAl alloy surface cathode micro arc plasma body electrolytic deposition prepares CeO2-Al2O3The method of composite ceramic layer | |
| Chai et al. | Effect of electrical parameters on the growth and properties of 7075 aluminum alloy film based on scanning micro-arc oxidation with mesh electrode | |
| CN106350849B (en) | The oxidation film electro-deposition preparation method of aluminium surface high-selenium corn and low transmitting solar spectrum | |
| CN107937961A (en) | The aluminium alloy surface treatment method and pulse electrodeposition hole sealing device of differential arc oxidation combination pulse electrodeposition sealing of hole | |
| CN106048730B (en) | A kind of method of titanium alloy differential arc oxidation preparing nano titanium dioxide ceramic whisker | |
| CN109440166B (en) | A kind of micro-arc oxidation composite treatment method for improving wear resistance and corrosion resistance of magnesium-lithium alloy surface | |
| CN108950651B (en) | Preparation method of magnesium alloy surface micro-arc electrophoresis HA-containing biological composite film | |
| Liu et al. | Preparation and properties of ceramic coatings by cathode plasma electrolytic deposition on titanium alloy | |
| CN112195491A (en) | SiC-Al based on micro-arc oxidation2O3Method for producing a coating | |
| CN111394771A (en) | Method for preparing coating on surface of copper and copper alloy and copper product | |
| CN101570875B (en) | Method for forming brown ceramic membrane on surface of Mg-Li alloy | |
| CN107201538A (en) | A kind of inner wall of metal tube chromium oxide alumina composite coating production | |
| CN103849917A (en) | Method of preparing geothermal water anticorrosive anti-scale titanium dioxide nanotube array and hydrophobic coating | |
| CN106283152A (en) | A kind of aluminum alloy surface has pore self-sealing characteristic black ceramic layer and preparation method thereof | |
| CN102924108A (en) | Method for preparing Y2Si2O7 whisker-toughened mullite composite coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240719 Address after: 400039 Chongqing Jiulongpo Yuzhou Road No. 33 Patentee after: Southwest Institute of technology and engineering of China Ordnance Equipment Group Country or region after: China Address before: 400039 Chongqing Jiulongpo Yuzhou Road No. 33 Patentee before: NO 59 Research Institute OF CHINA ORDNACE INDUSTRY Country or region before: China |
|
| TR01 | Transfer of patent right |